A microblock structure type of anionic flocculant for hematite wastewater treatment: template copolymerization mechanism and enhanced flocculation effect.

Abstract

In this study, a novel anionic template polymer (TPAS) with microblock structure was prepared by ultraviolet light (UV)-assisted template copolymerization (UV-TP). Acrylamide (AM) and sodium styrene sulfonate (SSS) were selected as monomers and polypropylene ammonium chloride (PAAC) was chosen as the template. Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), nuclear magnetic resonance hydrogen spectroscopy (1H NMR), and thermogravimetry/differential scanning calorimetry (TG/DSC) were used to characterize the polymer chemical structure. The results showed that the attractive anionic microblock structure was formed in TPAS. Besides, the association constant (KM) and template reaction kinetics analysis results indicated that the polymerization reaction followed I (ZIP) template copolymerization mechanism. It proved the microblock structure formation again. The anionic microblock structure in TPAM could greatly improve the ability of charge neutralization, electrical patching, and bridging. After the hematite wastewater was conditioned by TPAS with this novel anionic microblock structure, the generated hematite flocs had larger particle size and denser structure. It was favorable for the reduction of turbidity, and the turbidity removal rate could reach 97.8%. TPAS showed excellent flocculation performance for hematite wastewater and had a broad market application prospect.