Abstract

A flow injection method for automating the DPD reaction with free Cl in water samples has been described. The carrier stream consists of a 1∶1 (v/v) mixture of N,N-diethyl-p-phenylene diamine (DPD) indicator and phosphate buffer. A sampling rate of 252 per hour has been obtained and the detection limit is 0.3 ppm. Substitution of DPD with N,N-p-dimethylaniline sulphate also appears to be satisfactory for Cl analysis. The effects of reagent concentrations, flow parameters and additions of anions, cations and organic haloamines on the peak height have been investigated. The ammonium-Cl reaction has been studied and potentialities of the flow technique for the analyses of chloramines have been explored.

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