Abstract

A rapid spectrophotometric method for the determination of SO 4 2− in surface water is reported. It is based on the reaction of CPA III-Ba2+ complex with SO 4 2− in acidic medium in the presence of ethanol. Beer's law is obeyed up to 120 Μg of SO 4 2− in 25 ml solution. The molar absorptivity is 6.3×103 l · mol−1 · cm−1 at 500 nm, and the coefficient of variation varies from 1.85% to 3.10%. The absorbance remains stable for at least 24 h and interfering ions are separated by strongly acidic cation-exchange resin.

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