A Drop-in High-Temperature Pb-Free Solder Paste that Outperforms High-Pb Pastes in Power Discrete Applications

Abstract

Sn-based high-temperature lead-free (HTLF) solder pastes have been developed as a drop-in solution to replace the high-Pb solder pastes in power discrete applications. The pastes were designed to combine the merits of two constituent powders. A SnSb-based Ag/Cu-containing high temperature powder, with the melting temperature above 320° C, was designed to maintain a high-temperature performance. A Sn-rich SnAgCu-Sb powder, with a melting temperature around 228° C, was added to the paste to enhance wetting and improve joint ductility. In the design, the final joint will have the low-melting phase (the melting temperature >228o C) in a controllable quantity embedded into the high-melting SnSb matrix. HTLF-1, one of the designs, maintained the bond shear strength up to 15MPa, even around 290° C. Another design, HTLF-2, has a similar bond shear strength as Pb92.5/Sn5/Ag2.5 around 290° C, but exceeds substantially below 250° C. The power discrete components had been built with both HTLF solder pastes for both die-attach and clip-bond through the traditional high-Pb process, which demonstrated the drop-in processing compatibility. The components survived three additional SMT reflows (peak temperature of 260° C) and passed moisture sensitivity level 1. This confirmed that the maintained joint strength (comparable to or stronger than high-lead), helped to keep the joint integrity within the encapsulated components in the following SMT process, even with the controlled quantity of the melting phases above 228° C. Both HTLF solder pastes outperformed Pb92.5/Sn5/Ag2.5 in the resistance from drain to source when power is on (RDS(on)), even after 1000cycles of TCT (-55/175o C), which is attributed to the intrinsic lower electrical resistivity of Sn of both HTLF pastes. Microstructural observation had shown no corner cracks for both die-attach and clip-bond joints after TCT.