Abstract
The title compound, (2,6-diisopropylphenylimido)[hydrotris(1-pyrazolyl-N 3 )borato](2-methyl-2-phenylpropylidene) (trifluoromethanesulfonato) molybdenum(VI), [MO(CF 3 O 3 S)(C 10 H 12 )(C 12 H 17 N)(C 9 H 10 BN 6 )], has been synthesized and its crystal structure determined. The geometry around the Mo atom, imposed by the tridentate tris(pyrazolyl)borate ligand, is that of a distorted octahedron. There appears to be significant interaction between the ligands and the transition metal center. Principal distances include Mo-N(imido) 1.753(8), Mo-C(propylidene) 1.949(10), Mo-O(trifluoromethanesulfonate) 2.121(7) and Mo-N(pyrazolyl) 2.167 (8)2.311(9) A.
Published Version
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