Abstract
A microporous metal–organic framework [InL][(CH3)2NH2]·(H4L=9-(3,5-dicarboxyphenyl)carbazole-3,6-dicarboxylic acid) (1) was hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction and powder X-ray diffraction. The adsorption behavior of 1 has been investigated with respect to CO2, CH4 and N2, and the separation efficiency has been calculated by the Henry’s law analysis of isotherm data. The results indicated that the anionic framework with the inside protonated dimethylamine could enhance its selective adsorption performance for CO2 through strong adsorbent–adsorbate interaction aroused by a strong electrostatic field and pore size effect.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
