Abstract
Poly[alkylene(arylene) phosphite]s and poly[alkylene(arylene) phosphonite]s , the representatives of the trivalent phosphorus acids, are of scientific interest due to their high reactivity—oxidation, addition of sulfur, participation in Arbuzov alkylation. This chapter includes methods for preparation of poly[alkylene(arylene) phosphite]s and poly[alkylene(arylene) phosphonite]s . They undergo a number of chemical transformation resulted in the formation of the corresponding linear and cross-linked polyphosphates, polythiophosphates, poly(alkylphosphonate)s. The polyphosphites and polyphosphonites are viscous liquids or glass-like substances possessing adhesion to glass, metal, and wood.
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