Abstract
Methods for preparation of poly(alkylene H-phosphonate)s and characteristic reactions of its P–H group are described. Oxidation (Atherton–Todd reaction), nonoxidative chlorination, reduction (silylation), and polymer analogous reactions—addition to carbon–carbon double bond, carbonyl compounds, Schiff bases—of P–H group of poly(alkylene H-phosphonate)s are included. Fundamental results obtained for the reactivity of P–H group of low molecular compounds, especially cross and dehydrogenative coupling, open attractive perspectives in the field of polymer modification of poly[(alkylene, or arylene) H-phosphonate]s. These polymer analogues reactions have big potential for preparation of novel poly[aryl (alkylene, or arylene) phosphonate]s, poly(alkylene aminophosphonate)s.
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