Abstract
The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O—H⋯O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.
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