Abstract

This chapter covers processes that do not naturally slot into the previous sections. This material largely follows themes of kinetic resolution and transition metal controlled processes. The former includes crystallization-induced and dynamic kinetic resolution/deracemization, and the desymmetrization of meso compounds, and involves some applications of auxiliaries as process reagents. The latter deals with carbene reactions and a range of coupling and cyclizations processes. The collection is completed with a small number of miscellaneous cyclizations, eliminations, and bio-transformations.

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