Pb-Zn Mineralization Research Articles

Drivers and mechanisms of spontaneous plant community succession in abandoned Pb[sbnd]Zn mining areas in Yunnan, China

The drivers and mechanisms underlying succession and the spontaneous formation of plant communities in mining wasteland remain largely unknown. This study investigated the use of nature-based restoration to facilitate the recovery of viable plant communities in mining wasteland. It was found that scientific analyses of spontaneously formed plant communities in abandoned mining areas can provide insights for nature-based restoration. A chronosequence (“space for time”) approach was used to establish sites representing three successional periods with six successional stages, and 90 quadrats were constructed to investigate changes in plant species and functional diversity during succession in abandoned PbZn mining areas. A total of 140 soil samples were collected to identify changes in soil properties, including plant nutrient and heavy metal concentrations. Then, this paper used structural equation models to analyze the mechanisms that drive succession. It was found that the functional diversity of plant communities fluctuated substantially during succession. Species had similar functional traits in early and mid-succession, but traits tended to diverge during late succession. Soil bulk density and soil organic matter gradually increased during succession. Total nitrogen (N), pH, and soil Zn concentrations first increased and then decreased during succession. Concentrations of Mn and Cd gradually decreased during succession. During early succession, soil organic matter was the key factor driving plant colonization and succession. During mid-succession, soil Zn functioned as an environmental filter factor limiting the rates of succession in mining wasteland communities. During late succession, soil bulk density and competition for nutrient resources contributed to more balanced differentiation among plant species. This thesis proposed that a nature-based strategy for the stabilization of abandoned mining lands could facilitate effective plant community restoration that promotes ecosystem services and functioning.

Geology, fluid inclusions, and isotope signatures reveal hydrothermal evolution and genesis of the Aqishan Pb-Zn deposit in Eastern Tianshan and implications for exploration of skarn mineralization

The Aqishan deposit (1.97 Mt at 1.05 % Pb + Zn) is located in the Aqishan-Yamansu arc, on the southwest section of the Eastern Tianshan, Northwest China. Pb-Zn mineralization is mainly hosted by garnet skarn and the volcaniclastic rocks of the Yamansu Formation. To decipher the evolution of ore fluids and source(s) of ore-forming components, and constrain the ore genesis, a combination of geological work, fluid inclusions, and C-O-S-Pb isotope systematics is presented. Detailed field and microscopic observations reveal that the skarn alteration and ore formation at Aqishan could be divided into four hydrothermal stages, consisting of prograde skarn (I), retrograde skarn (II), quartz–sulfides (III), and carbonate stage (IV). Sphalerite and galena are the dominant ore minerals generally occurring as disseminations and veins with locally laminated ores in stage III. Fluid inclusion data show that the fluids responsible for prograde skarn are high-temperature (342–518 °C) and high-salinity (7.3–44.2 wt% NaCl equiv.), and recorded fluid phase separation from an intermediate-salinity supercritical fluid, which was exsolved from crystallizing granitic magma. Microthermobarometry results limit the retrograde alteration within the temperature range of 313 to 388 °C and trapping pressures of 98 to 241 bars (1.0–2.5 km), with pressure dropping from lithostatic to hydrostatic regimes associated with a phase separation event. The boiling fluid inclusions in ore stage quartz show that the Pb-Zn mineralization formed at 205–357 °C, with a decrease in temperature facilitating the precipitation of ore-forming metals from hydrothermal system. Carbon and oxygen isotope compositions of calcite indicate a predominantly magmatic source for ore fluids at Aqishan with later meteoric water involved. Bulk and in situ sulfur values of sulfides range from −6.4 to −0.7 ‰, consistent with a dominantly magmatic origin. Sulfides together with the granite porphyry and tuff, show relatively homogeneous Pb isotope compositions, indicating that abundant ore-forming metals were sourced from a magmatic reservoir with contribution from country rocks. Fluid inclusion study and available calcite C-O isotopes suggest that significant decrease in temperature and fluid-rock interactions remarkably contributed to the metal deposition at Aqishan. The skarn alteration with typical alteration assemblages of garnet–diopside is proposed as an effective mineral exploration target of skarn(–like) ores in Eastern Tianshan.

A Spatial Data-Driven Approach for Mineral Prospectivity Mapping

Mineral prospectivity mapping is a crucial technique for discovering new economic mineral deposits. However, detailed knowledge-based geological exploration and interpretations generally involve significant costs, time, and human resources. In this study, an ensemble machine learning approach was tested using geoscience datasets to map Cu-Au and Pb-Zn mineral prospectivity in the Cobar Basin, NSW, Australia. The input datasets (magnetic, gravity, faults, electromagnetic, and magnetotelluric data layers) were chosen by considering their association with Cu-Au and Pb-Zn mineralization patterns. Three machine learning algorithms, namely random forest (RF), support vector machine (SVM), and maximum-likelihood (MaxL) classification, were applied to the input data. The results of the three algorithms were ensembled to produce Cu-Au and Pb-Zn prospectivity maps over the Cobar Basin with improved classification accuracy. The findings demonstrate good agreement with known mineral occurrence points and existing mineral prospectivity maps developed using the weights-of-evidence (WofE) method. The ability to capture training points accurately and the simplicity of the proposed approach make it advantageous over complex mineral prospectivity mapping methods, to serve as a preliminary evaluation technique. The methodology can be modified with different datasets and algorithms, facilitating the investigations of mineral prospectivity in other regions and providing guidance for more detailed, high-resolution geological investigations.

Vanished evaporites, halokinetic structure, and Zn-Pb mineralization in the world-class Angouran deposit, northwestern Iran

The Angouran deposit (19.3 Mt at 23.4% Zn and 4% Pb) is the second-largest Zn-Pb deposit in Iran. The deposit is hosted in a Neoproterozoic−Cambrian marble-schist sequence within a breccia pipe in a domal structure, with sulfide mineralization under low-temperature hydrothermal conditions (<200 ºC). The features of the ore-hosting breccias are similar to known halokinetic diapir breccias in the world but evaporite minerals are subtle. The common types of breccia clasts in the Angouran breccia pipe include a matrix-supported angular clast (float breccia) with highly variable sizes and orientations and exotic volcanic clasts. The volcanic clasts were derived from the underlying Miocene volcanic rocks, evidenced by the consistent petrography and zircon U-Pb ages dated at 20−19 Ma. Abundant smithsonite pseudomorphs after anhydrite and anhydrite inclusions within sphalerite and pre-ore marcasite in the breccia matrix indicate that the breccia pipe contains abundant anhydrite prior to the Zn-Pb mineralization. The enrichment of evaporite is also supported by the occurrence of considerable double-terminated quartz crystals that contain spherical and tabular carbonate inclusions and anomalously high Li, Na, and K concentrations, relatively high B concentration, and high δ18O values (up to 28.3‰). These observations suggest the Angouran deposit formed in a former halokinetic diapir breccia pipe. The halokinetic diapirism was possibly triggered by thrust loading of the marble-schist sequence over the Miocene evaporite beds during the Arabia-Eurasia continental collision. Halokinetic structures elsewhere in the Angouran region warrant this consideration. Most of the evaporite minerals in the breccia pipe were dissolved and replaced before and/or during subsequent Zn-Pb sulfide and smithsonite mineralization events. This study provides a good example for the identification of vanished evaporites, halokinetic structure, and associated Mississippi Valley-type mineralization.

A circular economy approach to drinking water treatment residue management in a catchment impacted by historic metal mines

Drinking water treatment residues (DWTR) from mining areas which remove and contain potentially toxic elements (PTE) could still potentially be used as a soil amendment to restore contaminated sites in the same catchment, thus eliminating waste and reducing the chemical and physical mobility of the pollutants. To assess this restorative and regenerative approach to DWTR management, field and pot trials were established with soils from a historic Pb–Zn mine site in the North East of England, amended with either local DWTR or the nearest available municipal green waste compost (GWC). Soils from the mine site were found to have very low levels of nutrients and very high levels of PTE (Pb and Zn > 13, 000 mg/kg). The perennial grass species Phalaris arundinacea, known for many ecosystem service benefits including soil stabilization, was used throughout this study. The application of the BCR sequential extraction to soils amended with the DWTR in the pot trials found a significant decrease in the bioavailability of Pb and Cu (p < 0.05) after plant growth when compared with an unamended control. The field trial involved 648 pre-grown grass plants planted-out into mine soils amended with either DWTR, GWC or a mixture (MIX) of the two, all at rates of 25–30% w/w. Both amendments and the MIX had significant positive effects on biomass production compared to the unamended control in the following order GWC > MIX > DWTR (p < 0.05). Results of the elemental analysis of biomass from the field trial were generally ambiguous and did not reflect the decreased bioavailability noted in the pot trials using the BCR procedure. Pot trials, however, showed increases in plant growth and decreases in concentrations of Cr, Cu, Pb and Zn in above ground biomass following the application of both amendments. Further work should involve the testing of a mixture of DWTR and other soil amendments to enhance plant growth. The success of these trials should provide confidence for those working in drinking water treatment and catchment management to reuse the waste residues in a circular economy and a sustainable way that could improve water quality over time.

Spatiotemporal records of major historical events and human activities in river sediments: A coupled study of heavy metals distribution and lead isotopic dating

Thirty sediment samples (11 on the surface and 19 from a 55 cm core) collected in the Dadu River, upstream of the Yangtze River, China, were analyzed by ICP-MS and Laser diffraction particle size techniques to determine heavy metal spatial-temporal distribution and particle size characteristics, respectively. The intent was to clarify the impact of human activities such as Pb-Zn mining and exploration on the distribution of potentially toxic elements (As, Cd, Cr, Cu, Pb and Zn) in adjacent fluvial deposits. Moreover, 210Pb isotope dating was applied to study the historical variation and distribution of heavy metal pollution in a sedimentary profile in the middle section of the Dadu River. Results suggest that Cd concentration is notably high, exceeding by 16.3 times the soil background value in Sichuan Province, China, which can be intensified by Pb-Zn ore smelting. Surface sediments are mainly composed of silt, accounting for 79% on average, and relatively minor amounts of clay and sand. The fraction of clay in the downstream segments of the Dadu River is significantly higher than that upstream, indicating that the hydrodynamic force in the downstream region is relatively low compared with the upstream flow. Samples in the sedimentary profile, collected at 3 cm intervals, are mainly composed of silty sand, accounting for 75.6%, which comprehensively reflects the strong hydrodynamic force in this area. The results of 210Pb dating of these samples indicate three intervals of historical fluctuation in heavy metal concentrations: 1950–1966, 1988–1991 and 1996–2006, respectively, which coincide to significant historical events (the Cultural Revolution, the construction of Pubugou reservoir and local smelting activities, and the implementation of environmental protection policies). Enrichment factor (EF) values of all heavy metals in the profile began to increase after 1994, and relatively high EF values of Cr and Cd indicated a significant enrichment due to increasing anthropogenic activities during this period. Our study demonstrates that anthropogenic activities can be well recorded in sedimentary profiles and provide new insights to retrieving the history of human developments.

Genesis of the Meng’entaolegai Ag–Pb–Zn polymetallic deposit, inner Mongolia, Northeastern China

The large-scale Meng’entaolegai Ag–Pb–Zn polymetallic deposit is located in the Great Hinggan Range metallogenic belt, northeastern China. To better understand the formation of the Meng’entaolegai deposit, we present in situ S isotope data, zircon U–Pb isotope data, sulfide Rb–Sr data, and molybdenite Re–Os data for the units associated with the deposit and surrounding regions. In situ analyses show that the δ34S values of the sulfides (galena, sphalerite, and pyrite) vary from + 2.4‰ to + 6.6‰ (mean = +4.7‰, n = 60). The data herein confirm that the sulfur was mainly derived from a magmatic source. Zircon U–Pb dating of the medium- to coarse-grained monzogranite, plagiogranite, and fine-grained monzogranite from the Duerji batholiths and granodiorite and monzogranite from the Meng’entaolegai deposit yield weighted mean ages of 244.3 ± 1.7, 243.0 ± 2.1, 151.8 ± 1.5, 232.6 ± 2.2, and 223.1 ± 2.3 Ma, respectively. The Meng’entaolegai deposit yields a molybdenite Re–Os age of 229.5 ± 1.5 Ma, but sulfide Rb–Sr dating yields an isochron age of 147.2 ± 2.3 Ma. These new age data have revealed that the Meng’entaolegai polymetallic deposit formed during two mineralization episodes: an early episode at 230 Ma and a second episode at 147 Ma. The Late Triassic hydrothermal activity and weakly Mo mineralization formed in an extensional setting after the final closure of the Palaeo-Asian Ocean. The Late Jurassic hydrothermal activity and Ag–Pb–Zn mineralization formed in an extensional environment related to the Mongol–Okhotsk Ocean, but these exposed granitic rocks are unlikely to be related to the Ag–Pb–Zn mineralization, suggesting that more research is needed on the magmatic hydrothermal activity within the study area.

The role of mantle melting in granite-associated hydrothermal systems: He–Ar isotopes in fluids responsible for Sn–Ag–Pb–Zn mineralization in northeast China

The role of mantle melting in granite-associated hydrothermal systems: He–Ar isotopes in fluids responsible for Sn–Ag–Pb–Zn mineralization in northeast China

Robust dating of Pb–Zn skarn systems by LA–ICP–MS garnet U–Pb geochronology

Lawu and Yaguila are two Pb–Zn skarn deposits in the eastern Nyainqêntanglha metallogenic belt, central Lhasa subterrane, Tibet. The genesis of Pb–Zn deposits in this belt and the crustal processes leading to their formation remain ill-constrained, mostly because of the lack of precise mineralization ages. We integrate textural information, geochemistry, and in-situ garnet U–Pb geochronology to constrain the timing and genesis of Pb–Zn mineralization. Garnets from the two deposits display oscillatory compositional zoning (And14Gr86 to And100) and contain variable U contents (0.07–5.3 ppm). Aluminum-rich garnet displays a chondrite-normalized rare earth element (REE) fractionation pattern in which LREEs are depleted relative to flattish HREE segments. In contrast, Fe-rich garnet shows LREE-enriched, relatively HREE-poor patterns with positive Eu-anomalies. Uranium concentration is correlated with total REE and Fe components in garnets, implying that U incorporation is largely controlled by coupled substitution mechanisms. The same garnets also contain measurable contents of other metals (up to hundreds of ppm), such as Sn, W, and In. The distribution and fractionation of major and trace elements in zoned garnets record periodic fluid pluses with different compositions during hydraulic fracturing. The new garnet U–Pb data show that the Yaguila deposit formed between 68.5 ± 3.4 and 65.0 ± 4.7 Ma, and the Lawu deposit formed at 54.6 ± 2.9 Ma. Within the geochronological framework of igneous rocks and Pb–Zn mineralization in the Nyainqêntanglha metallogenic belt, the new garnet ages suggest a magmatic-hydrothermal origin for related mineralization, with the causative magma likely derived from partial melting of ancient continental material due to rollback and subsequent breakoff of the Neo-Tethys oceanic slab during India–Asia continental collision. This study highlights the opportunities offered by garnet U–Pb dating for elucidating the formation age and ore genesis of base metal skarn systems.

Geochemical distributions of natural radionuclides in surface soils and sediments impacted by lead-zinc mining activity

This study investigated the distribution features of uranium-238 (238U), radium-226 (226Ra), thorium-232 (232Th), and potassium-40 (40K) and evaluated the associated environmental radiological hazards of the topsoil and river sediments in the Jinding lead-zinc (Pb-Zn) mine catchment from Southwest China. The activity concentrations of 238U, 226Ra, 232Th, and 40K ranged from 24.0 ± 2.29–60.3 ± 5.26 Bq.kg-1, from 32.5 ± 3.95–69.8 ± 3.39 Bq.kg-1, from 15.3 ± 2.24–58.3 ± 4.92 Bq.kg-1, and from 203 ± 10.2–1140 ± 27.4 Bq.kg-1, respectively. The highest activity concentrations for all these radionuclides were primarily found in the mining areas and decreased with increasing distance from the mining sites. The radiological hazard indices, including radium equivalent activity, absorbed gamma dose rate in the air, outdoor annual effective dose equivalent, annual gonadal dose equivalent, and excess lifetime cancer, revealed that the highest values were observed in the mining area and downstream, specifically in the vicinity of the ore body. These elevated values exceeded the global mean value but remained below the threshold value, suggesting that routine protection measures for Pb-Zn miners during production activities are sufficient. The correlation analysis and cluster analysis revealed strong associations between radionuclides such as 238U, 226Ra, and 232Th, indicating a common source of these radionuclides. The activity ratios of 226Ra/238U, 226Ra/232Th, and 238U/40K varied with distance, suggesting the influence of geological processes and lithological composition on their transport and accumulation. In the mining catchment areas, the variations in these activity ratios increased indicated the impact of limestone material dilution on the levels of 232Th, 40K, and 238U in the upstream region. Moreover, the presence of sulfide minerals in the mining soils contributed to the enrichment of 226Ra and the removal of 238U caused those activity ratios decreased in the mining areas. Therefore, in the Jinding PbZn deposit, the patterns of mining activities and surface runoff processes in the catchment area favored the accumulation of 232Th and 226Ra over 40K and 238U. This study provides the first case study on the geochemical distributions of natural radionuclides in a typical Mississippi Valley-type PbZn mining area and offers fundamental information on radionuclide migration and baseline radiometric data for PbZn deposits worldwide.

Multi-layer metallogeny of the maoping carbonate-hosted Pb–Zn deposit, SW China: Constraints from C–O–S–Pb isotopes

The Maoping carbonate-hosted Pb–Zn deposit, located in the Sichuan-Yunnan-Guizhou metallogenic belt (SYGMB), comprises numerous ore bodies hosted in Devonian and Carboniferous Systems. Multi-layer Pb–Zn mineralization (two or more systems) at deposit scale is still rare in the SYGMB and poorly understood. Although δ18O values (+9.4 to +12.3‰) of calcite in Devonian System is similar to those (+9.2 to +12.0‰) of calcite in Carboniferous System, δ13C values (−1.7 to −0.2‰) of calcite in Devonian System is significantly higher than those (−5.4 to −2.7‰) of calcite in Carboniferous System. Such C–O isotopic characteristics suggest that the source of C was ore-hosting carbonate rocks, whereas the source of O was basement metamorphic rocks. The simulation of C–O isotopes shows that water-rock interaction was the main mechanism for calcite precipitation. The δ34S values (+18.3 to +22.7‰) of sulfides in Devonian System are higher than those (+7.1 to +17.5‰) of sulfides in Devonian System. This implies that reduced sulfur in Devonian System originated from Devonian marine sulfate, while those in Carboniferous System originated from Carboniferous marine sulfate. Such S isotopic compositions also show that thermochemical sulfate reduction (TSR) was the dominant mechanism for the reduction of marine sulfate. The isotopic ratios (206Pb/204Pb = 18.680–18.744, 207Pb/204Pb = 15.753–15.764, 208Pb/204Pb = 39.282–39.399) of galena in Devonian System and those (206Pb/204Pb = 18.554–18.581, 207Pb/204Pb = 15.722–15.752, 208Pb/204Pb = 39.018–39.109) of galena in Carboniferous System are similar to those of basement metamorphic rocks and cover carbonate rocks. This indicates that ore-forming metals had mixed sources. Considering the above results, the multi-layer metallogeny is the mixing of metal and sulfate-bearing fluids with metal-rich but reduced sulfur-poor fluids at the depositional site where methane or other organic matter reduces sulfate and precipitates sulfides. In the future, A multi-layer exploration strategy for Pb–Zn deposits in the SYGMB should be emphasized.

Effects of multi-heavy metal composite pollution on microorganisms around a lead-zinc mine in typical karst areas, southwest China

Heavy metal pollution poses a serious hazard to the soil bacterial community. The purpose of this study is to understand the characteristics of soil heavy metal pollution in lead-zinc mines in karst areas and the response of Pb, Zn, Cd, and As-induced composite pollution to soil microorganisms. This paper selected soil samples from the lead-zinc mining area of Xiangrong Mining Co., Ltd., Puding County, Guizhou Province, China. The soil in the mining area is contaminated by multiple heavy metals such as Pb, Zn, Cd and As. The average levels of Pb, Zn, Cd and As in the Pb-Zn mining soil were 14.5, 7.8, 5.5 and 4.4 times higher than the soil background in this area, respectively. Bacterial community structures and functions were analyzed using 16 S rRNA high-throughput sequencing technology and the PICRUSt method. A total of 19 bacterial phyla, 34 classes and 76 orders were detected in the tested soil. At the phylum level, the Proteobacteria are the dominant flora of the soil in the tailings reservoir area of the lead-zinc mine, respectively GWK1 (49.64%), GWK2 (81.89%), GWK3 (95.16%); and for the surrounding farmland soil, the Proteobacteria, Actinobacteriota, Acidobacteriota, Chloroflexi and Firmicutes are the most abundant in five bacterial groups. RDA analyses revealed that the heavy metal pollution of the lead-zinc mining area has a significant impact on the diversity of soil microorganisms. As the distance from the mining area increased, the heavy metal comprehensive pollution and potential risk value decreased, and the bacterial diversity increased. Additionally, various types of heavy metals have different effects on bacterial communities, and soil heavy metal content will also change the bacterial community structure. Proteobacteria positively related to Pb, Cd, and Zn, therefore, Proteobacteria were highly resistant to heavy metals. PICRUSt analysis suggested that heavy metals significantly affect the metabolic function of microorganisms. Microorganisms might generate resistance and enable themselves to survive by increasing the transport of metal ions and excreting metal ions. These results can be used as a basis for the microbial remediation of heavy metal-contaminated farmland in mining areas.

Identification of possible sources for potentially toxic elements and polycyclic aromatic hydrocarbons and their spatially varying relationships in urban soils of Dublin, Ireland

Potentially toxic elements (PTEs) and polycyclic aromatic hydrocarbons (PAHs) harm the ecosystem and human health, especially in urban areas. Identifying and understanding their potential sources and underlying interactions in urban soils are critical for informed management and risk assessment. This study investigated the potential sources and the spatially varying relationships between 9 PTEs and PAHs in the topsoil of Dublin by combining positive matrix factorisation (PMF) and geographically weighted regression (GWR). The PMF model allocated four possible sources based on species concentrations and uncertainties. The factor profiles indicated the associations with high-temperature combustion (PAHs), natural lithologic factors (As, Cd, Co, Cr, Ni), mineralisation and mining (Zn), as well as anthropogenic inputs (Cu, Hg, Pb), respectively. In addition, selected representative elements Cr, Zn, and Pb showed distinct spatial interactions with PAHs in the GWR model. Negative relationships between PAHs and Cr were observed in all samples, suggesting the control of Cr concentrations by natural factors. Negative relationships between PAHs and Zn in the eastern and north-eastern regions were related to mineralisation and anthropogenic Zn–Pb mining. In contrast, the surrounding regions exhibited a natural relationship between these two variables with positive coefficients. Increasing positive coefficients from west to east were observed between PAHs and Pb in the study area. This special pattern was consistent with prevailing south-westerly wind direction in Dublin, highlighting the predominant influences on PAHs and Pb concentrations from vehicle and coal combustion through atmospheric deposition. Our results provided a better understanding of geochemical features for PTEs and PAHs in the topsoil of Dublin, demonstrating the efficiency of combined approaches of receptor models and spatial analysis in environmental studies.

Origin of the Yinshan Pb-Zn-Ag Deposit in the Edong District Section of the Middle–Lower Yangtze River Metallogenic Belt: Insights from In-Situ Sulfur Isotopes

The investigation into the enigmatic origin of Pb-Zn mineralization within the Middle-Lower Yangtze River Metallogenic Belt has long been marred by a paucity of prior studies. Seeking to alleviate this dearth of knowledge, our study meticulously scrutinizes the Yinshan Pb-Zn-Ag deposit nestled within the Edong district of the belt, endeavoring to cast an illuminating spotlight upon its enigmatic genesis. We identify two distinct epochs: (1) the pre-mineralization pyrite epoch (Epoch I) mainly characterized by colloform and massive pyrite, and (2) the hydrothermal mineralization epoch (Epoch II) which can be further divided into three stages: pyrite-arsenopyrite (stage 1), galena-sphalerite (stage 2), and vein pyrite (stage 3). We conduct in-situ sulfur isotope analyses on sulfide minerals from both epochs, revealing δ34S values ranging from −0.5 to 4.8‰ for Epoch I and varying from 2.2–4.9‰ (stage 1), 1.1–3.0‰, 4.2–7.1‰ (stage 2), and 2.1–3.8‰ (stage 3) for Epoch II. Integrating our sulfur isotope data with the geological characteristics of the deposit, we infer that Pb-Zn mineralization was related to a granite of ~130 Ma age. Additionally, our study suggests the possibility of coexisting Mo mineralization beneath the Pb-Zn mineralization. Our findings contribute to a better understanding of the origin of Pb-Zn mineralization in the Middle-Lower Yangtze River Metallogenic Belt.

Lithogenic and anthropogenic distribution of chemical elements in soils from Pb-Zn mining area. Case study: Kriva River basin, North Macedonia

ABSTRACT Previous studies have shown that certain areas in the territory of the Republic of Macedonia are affected by anthropogenic input of large amounts of various chemical elements into the soil. The area in the vicinity of the Toranica lead and zinc mine near the town of Kriva Palanka, North Macedonia, was studied for the lithogenic and anthropogenic distribution of seventeen elements (Al, As, Ba, Ca, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, Pb, Sr, V and Zn). Automorphic soil samples (topsoil and subsoil) as well as alluvial sediments and fluvisol samples were collected from the Kriva River basin. Elemental contents were determined by inductively coupled plasma – atomic emission spectrometry (ICP-AES). Data processing was performed using combinations of multivariate statistical methods (factor analysis and cluster analysis). The summarised data for topsoil and subsoil samples show strong correlations between the element distributions in topsoil samples and subsoil samples along the Kriva River basin. Anthropogenic influences were observed in Zone 1 (the area affected by hydrothermal Pb-Zn exploitation). The topsoil layer was affected by enrichment with As, Mn, Pb, and Zn up to 220, 3400, 1700 and 1100 mg/kg, respectively.

Genesis of the Mengxing Pb-Zn deposit in Baoshan block, SW China: Constraints from geology, fluid inclusion and isotopes

The Mengxing Pb-Zn deposit is located in the central-southern Baoshan block, SW China, which contains over 1.02 Mt metals with the average Pb + Zn grade of 12.12 %. In this deposit, the orebodies are mainly stratabound and developed in the Silurian limestone of the Shangrenheqiao Formation. The mineral assemblage is mainly consisted of sulfides, quartz, calcite and barite. Based on petrographic observation, three mineralization stages have been recognized, including the pre-ore, syn-ore (including stage I and II) and post-ore stages. Fluid inclusion study shows that the ore-forming fluid in Mengxing deposit belongs to a NaCl-H2O-(CO2) system with medium–high temperature (187.3–320.1 °C) and medium–low salinity (2.1–17.9 wt% NaCl equiv.). H-O-S-Pb isotopic studies reveal that the ore-forming fluid dominantly originated from magmatic water, and reacted with organic matter preserved in sedimentary strata at stage I and mixed with metamorphic/meteoric water at stage II. The sulfur for mineralization was mainly contributed by magmatic sulfur. Marine sulfates preserved in Silurian sedimentary strata also contributed some ore-forming sulfur in stage II. The ore-forming metals in Mengxing deposit were jointly contributed by sedimentary strata and deeply concealed granitic magmatism. Based on these geological and geochemical characteristics, we suggest that the Mengxing Pb-Zn mineralization is Epithermal type and formed in multiple stages.

A Permian intermediate-sulfidation epithermal Pb–Zn–Ag deposit in the northern margin of North China Craton

Recent Pb–Zn–Ag exploration in the northern margin of North China Craton has made significant new discoveries. Here we report one Pb–Zn–Ag deposit in the Shaolanghe orefield with typical signatures of intermediate-sulfidation epithermal deposits. Zhangjiagou Pb–Zn–Ag mineralization occurs within the Early Permian quartz diorite and Late Permian andesite. Three mineralization stages were identified: white quartz–rhodochrosite–sulfide Pb–Zn–mineralization stage (I), smoky quartz–sulfide Pb–Zn–Ag–mineralization stage (II), and calcite–quartz non–mineralization stage (III). Four sphalerite samples yield the Rb–Sr age of 265.3 Ma, indicating that Pb–Zn–Ag mineralization was associated with the Late Permian andesite. The liquid-rich fluid inclusions of Stage I show low–medium temperatures of 190–270 °C and low salinities (1–3 wt%), and those of Stage III are slightly lower (190–250 °C, 0.5–2 wt%), suggesting a low-salinity, low-temperature H2O–NaCl fluid system for the Zhangjiagou deposit. The H–O–C isotopic signatures indicate a mixed fluid of magmatic water with meteoric water. S and Pb isotopes suggest magmatic source for Zhangjiagou Pb–Zn–Ag mineralization, most likely shallow hydrous intermediate magma. Collectively, these geological, geochronological, and geochemical features indicate that Zhangjiagou is an intermediate-sulfidation epithermal Pb–Zn–Ag deposit.

The world-class carbonate-hosted Fankou Zn-Pb deposit in China. Part I. Structural analysis: Evolutionary three-order thrusting structures control on the localization of Zn-Pb orebodies

The Fankou giant deposit (with exceeding 10 Mt Zn + Pb metals, grading at 15 wt%) is a carbonate-hosted, stratabound Zn-Pb deposit in the northern Quren Basin, South China. Lenticular, stratiform and wedge-shaped orebodies are strictly hosted in specific layers of Upper Devonian to Lower Carboniferous carbonate sequences along a series of NE and NNE trending faults. Previous ore geological and geochemical studies proposed that the Fankou can be analogous to a Mississippi Valley-type (MVT) deposit, but how the evolution of complex fault system controls ore-forming fluids migration, metals accumulation and orebodies localization remains unclear. To address this question, we conducted a deposit-scale structural analysis based on the geological mapping, underground works, and diamond drills logging. We identified three-order structures gradually growing in the Fankou deposit, including: 1) The first-order fault represented by F203 is a NW-striking thrust fault penetrating basement and acts as a major conduit for ultimate hydrothermal fluids migrations from depth; 2) The second-order faults include a spectrum of NNW-striking faults F2, F3, F4, F4, F5, F6, F7, F8 and F9. They are intersected with F203 in depth, and soon before and synchronous activities with Zn-Pb mineralization; 3) The third-order faults contain a series of NNE-striking F100, F101 and F102 with limited scale, which is subordinate to second-order faults and control the terminal localization of Zn-Pb orebodies. Collectively, we conclude that the evolutionary three groups of deposit-scale faults, derived from the regional NE-striking Wuchuan-Sihui Fault, jointly control the ore-forming fluids migrations from deep to shallow and from SE to NW in space. It is noteworthy that the second- to third-order faults act as the direct metal precipitation space when the upwards metalliferous fluids replaced with the favorable lithological layers. Therefore, we highlight that the southeast part of the mining area, where the metalliferous fluids came from, is a promising exploration target area in future.

The Characteristics and Origin of Barite in the Giant Mehdiabad Zn-Pb-Ba Deposit, Iran

Abstract Mehdiabad is the world’s largest Mississippi Valley-type (MVT) Zn-Pb deposit (394 million tonnes [Mt] of metal ore at 4.2% Zn, 1.6% Pb) and contains significant barite resources (&amp;gt;40 Mt). Such large accumulations of barite are not common in carbonate-hosted Zn-Pb deposits. Therefore, the origin of the barite and its association with the Zn-Pb mineralization is of significant interest for further investigation. Field work and petrographic studies indicate that the Zn-Pb-Ba orebodies in the Mehdiabad deposit are hosted by Lower Cretaceous carbonate units of the Taft and Abkuh Formations. Fine- to coarse-grained barite with lesser siderite formed in three stages (S1, S2, and S4), along with a quartz-sulfide stage (S3) with minor quartz, sphalerite, galena, chalcopyrite, and pyrite, and the main Zn-Pb sulfide stage (S5) with massive sphalerite and galena. The barites have δ34S values from 17.7 to 20.6‰, δ18O values from 13.2 to 16.8‰, Δ33SV-CDT values from –0.001 to 0.036‰, and initial 87Sr/86Sr ratios from 0.707327 ± 0.000008 to 0.708593 ± 0.000008 (V-CDT = Vienna-Canyon Diablo Troilite). The siderites have δ13CV-PDB values from –3.8 to –2.7‰, and δ18OV-SMOW values from 18.2 to 20.9‰ (V-PDB = Vienna-Pee Dee Belemnite, V-SMOW = Vienna-standard mean ocean water). These geochemical data, and the barite morphology, point to a diagenetic origin for all stages of barite. We suggest that S1 and S2 barite precipitated from pore fluids at the sulfate-methane transition zone in a methane-diffusion-limited environment with increasing methane content. S4 barite precipitated when the methane- and barium-bearing cold-seep fluid migrated to the shallow carbonate sediments and formed a methane-in-excess setting. For the three stages, the SO42- in barite came from the residual SO42- in pore fluids undergoing sulfate-driven anaerobic oxidation of methane, and the Ba2+ came from dissolved biogenic barite and terrigenous materials in the Taft and Sangestan Formations. Primary fluid inclusions trapped in S3 quartz have salinities of 5.6 to 8.1 wt % NaCl equiv and homogenization temperatures of 143.8° to 166.1°C. The quartz has δ18OV-SMOW values ranging from 9.8 to 22.5‰ and δ30Si values from –1.3 to –0.9‰. These data indicate hydrothermal fluid flow occurred between the diagenetic S2 and S4 events. Secondary fluid inclusions with salinities of 17.70 to 19.13 wt % NaCl equiv and homogenization temperatures of 123.0° to 134.0°C are found in the S3 quartz, too. They might represent the hydrothermal event formed by basinal brines in S5. According to the ore textures and the comparison of the sulfur isotopes between S5 Zn-Pb sulfides and the digenetic barites, the barite provided a host and a sulfur source for the later Zn-Pb mineralization. The relationship between barite and the Zn-Pb mineralization indicates that significant accumulations of sulfates may be a critical exploration target for this kind of giant deposit.

Concentrations and biomagnification of multiple metals/metalloids are higher in rice than in sugarcane agroecosystems of southern China

Agricultural lands have been increasingly reported to be contaminated by metals and metalloids, leading to exposure to these toxins for humans and wildlife. Previous studies on metal/metalloid contamination have reported biomagnification of total elemental Hg (THg) and, less consistently, of Cd, in both aquatic and terrestrial ecosystems. Whether other metals or metalloids can biomagnify in food webs, especially those that produce food for humans, is uncertain. We aimed to compare metal/metalloid contamination and their biomagnification patterns between rice paddy and sugarcane agroecosystems. We collected samples at an inactive Pb-Zn mine site, and two reference sites in southwestern Guangxi, southern China. Samples were widely distributed across the food web, including soil, rice grain and leaves, sugarcane leaves, crickets, grasshoppers, spiders, and frogs. We found that Cr, Cd, Pb, THg, and Zn were the metals associated with mining activities, while As and Cu were higher at the reference sites. In soil, and in the majority of species for which there were significant differences between agroecosystems, concentrations of Cd, Cr, Cu, Pb, THg, and Zn were higher in rice, suggesting that the rice paddy ecosystem is particularly sensitive to metal contamination. When quantitatively rating the patterns of biomagnification using post-hoc multiple comparisons among species’ bioaccumulation factors (BAFs), rice paddies had stronger patterns of biomagnification (3 strong relationships [e.g., all insectivores had higher or as high BAFs compared to all other species], 7 medium relationships [e.g., one of the insectivores had the highest BAFs, but another had an intermediary value, similar to an herbivore], 6 weak [e.g., one insectivore had the highest BAFs, but the other was as low as a primary producer], and 3 no relationships [e.g., no significant differences among species in BAFs]) than sugarcane ecosystems (1 strong, 2 medium, 8 weak, and 9 no relationships; Repeated measures t-test, P-value = 0.0023) across 6 metals (Cr, Cd, Cu, Hg, Pb, Zn). The strongest biomagnification was evident for THg and Zn, whereas an intermediary level of biomagnification was found for Cd, Cr, Cu, and Pb; biodilution was observed for As and Mn. Therefore, focusing on metal/metalloid apportionment to better understand the sources of the metals at our study sites would be of utility to lower the exposure of wildlife and people. Most importantly, the local authorities should check metal concentrations in any farming product from the mining area and even the close reference site to safeguard human health.