Zn Foil Research Articles

Dual-Induced Directed Deposition Mechanism Based on Anionic Surfactants Enables Long Cycle Aqueous Zinc Ion Batteries.

Aqueous zinc-ion battery has low cost, and environmental friendliness, emerging as a promising candidate for next-generation battery systems. However, it still suffers from a limited cycling life, caused by dendritic Zn growth and severe side reactions. Recent research highlights that the Zn (002) crystal plane exhibits superior anti-corrosive properties and a horizontal growth pattern. However, achieving uniform deposition on the Zn (002) plane remains a formidable challenge. Here, preferential rapid growth of the Zn (002) plane is manipulated via the dual-induced deposition effect of anionic surfactant (2-acrylamido-2-methylpropanesulfonic acid, AMPS), achieving Zn metal anode with ultralong cycle life. AMPS can preferentially adsorb on the Zn (100) and Zn (101) crystal planes, exposing the Zn (002) plane as a nucleation site for Zn2+ ions, while the abundant presence of amide groups in AMPS can form fast ion channels, inducing rapid and uniform Zn deposition. Thus, even using 30 µm Zn foils, the symmetric cells can maintain a stable plating-stripping process over 5000 h, and Zn.

Can NiFe-Layered-Double-Hydroxide Catalysts Suppress Carbon Corrosion in Electrochemical Oxygen Evolution?

Sustainable energy societies demand rechargeable batteries using ubiquitous-material electrodes of geopolitical-risk-free elements. We aim to develop low-overpotential oxygen-evolution-reaction (OER) catalysts that suppress carbon corrosion of gas-diffusion electrodes (GDEs) to realize two-electrode rechargeable Zn-air batteries (r-ZABs). Herein, single-walled-carbon-nanotube (SWNT) thin films are used as a scaffold for a benchmark OER catalyst, doping-free NiFe-layered double hydroxide (NiFeLDHs), operating in r-ZABs using alkali aqueous electrolytes. Metal compositions of NiFeLDHs are controlled with an atomic-level quality using Prussian-blue-analog nanoparticles of NixFe1-x[Fe(CN)6]0.67 (x = 0-1). The nanoparticles with dimensions of ∼8 nm adhere to SWNTs on carbon paper as a GDE model by a drop-casting method using their aqueous dispersion solutions. Ni0.6Fe0.4[Fe(CN)6]0.67 shows OER activity by hydrolysis for generating NiFeLDH nanodots of metal compositions between Ni0.5Fe0.5 and Ni0.6Fe0.4 with a size distribution of 1.75 ± 0.26 nm and exposing OER-active (018) and (015) planes on SWNTs. The activity is investigated by regulating the loading amounts of the NPs to avoid aggregating the nanodots. An optimal low-loading amount of 270 nmol cm-2 minimizes iR-corrected overpotential to 156 mV at 10 mA cm-2. The iR-uncorrected overpotential is 260 mV and suppresses carbon corrosion of SWNTs and carbon black. Using an r-ZAB half-cell with a Zn foil, OER-driven charging stably proceeds at 10 mA cm-2 over 3 h with an average voltage of 1.99 V vs Zn/Zn2+. Limited metal electrodes have further improved OER overpotentials by third-element doping, while carbon electrodes still offer room for discovering intrinsically high OER activities of NiFeLDHs without doping.

Self-Powered Hydrogen Production via Laser-Coordinated NiCoPt Alloy Catalysts in an Integrated Zn-Hydrazine Battery with Hydrazine Splitting.

This study proposes a novel approach for the rapid transformation of bimetallic NiCo-oxides into trimetallic NiCoPt alloys using a pulsed laser technique in an ethanol medium in the presence of Pt salts. The electrochemical results demonstrate the exceptional dual-functional activity of the optimized NiCoPt-10 alloy, effectively catalyzing both hydrogen evolution reaction (HER) and hydrazine oxidation reaction (HzOR). Specifically, the NiCoPt-10 alloy presents a low overpotential of 90 mV at 10 mA·cm-2 for HER and a small working potential of 0.068 V versus the reversible hydrogen electrode (RHE) at 10 mA·cm-2 for HzOR. In situ Raman spectroscopy and theoretical calculations delivered insights into the dual-functional activity of the NiCoPt alloy. Consequently, the overall hydrazine splitting (OHzS) electrolyzer, employing a NiCoPt-10||NiCoPt-10 configuration, required only 0.295 V to deliver 10 mA·cm-2. Notably, using this dual-functional NiCoPt-10 catalyst as the cathode combined with Zn foil as the anode in a Zn-hydrazine (Zn-Hz) battery, achieved efficient hydrogen (H2) production with an energy efficiency of 97%. Furthermore, self-powered H2 production is realized by integrating the Zn-Hz battery with the OHzS electrolyzer, demonstrating its excellent potential for practical applications. Thus, this rapid synthetic strategy can aid in designing effective electrocatalysts for addressing challenges in H2 energy production.

Comprehensive review for zinc powder anodes: Significance, optimizing design, and industrial feasibility in zinc-ion batteries

Rechargeable aqueous zinc-ion batteries (AZIBs) have emerged as promising candidates for sustainable energy storage systems, due to their low cost, enhanced safety, and high-power density. Nevertheless, practical applications are still hampered by inherent challenges related to the zinc (Zn) foil anode, including dendrite formation and interfacial parasitic reactions. As an alternative, Zn powder (Zn-p) presents significant potential, owing to its cost-efficiency, large-scale processability, versatility, and industrial applicability. Notably, the amount of Zn-p can be accurately regulated, enhancing Zn anodes utilization efficiency and facilitating industrial applications. Nevertheless, the unique spherical microstructure of Zn-p introduces specific challenges, such as complex ion pathways, uneven Zn deposition, and a complicated electrode manufacturing process, which directly impact the battery performance, safety, and lifespan. In pursuit of a deeply comprehensive relationship between electrode structure and electrochemical performance for Zn-p-based anodes, this review provides a detailed examination of the working mechanisms of Zn-p-based anodes, while also identifying both the opportunities they present and the unique challenges they face. Moreover, the latest research progress is summarized, with a focus on innovative design strategies for optimizing Zn-p-based anodes. The relationship between these structural aspects and the resulting electrochemical performance, including safety, cycle life, and capacity, is thoroughly examined to provide a deeper understanding of how to achieve optimal battery system design and performance. Meanwhile, the fabrication processes and potential for practical flexible applications of Zn-p-based batteries were detailed. Finally, prospects for achieving high performance and practical utilization of Zn-p-based anodes are offered, providing scientific guidance for their practical application.

Zn-Sn Alloy Seed Layer-Coated Cu Current Collector for Anode-Free Aqueous Zn Ion Batteries

Zn ion batteries (ZIB) stand at the forefront of alternative advanced energy storage technologies due to the intrinsic properties of Zn, including its low reduction potential (-0.76 V vs. SHE), and high theoretical specific capacity (820 mAh g-1) acquired by its multi-electron redox processes. Nonetheless, the utilization of current thick Zn foil anode remains a big challenge to commercialization, caused by the dendrite growth, severe surface side reaction, and high N/P ratio, which leads to the limitation of cell energy density. Herein, we report anode-free technology based on ultra-thin Zn-Sn alloy seed layer-coated Cu foil (ASL@Cu), to break through the limit of cell energy density. Incorporating Sn and carbon in the seed layer results in a strong affinity towards Zn, inhibiting the irreversible surface reactions, and eventually offering efficient electron transport routes. The resulting ASL showed rapid kinetics for Zn2+ deposition (lower nucleation overpotential) and exhibited an extended cycle life at a current density of 4 mA cm-2. This work sheds light on the strategic design of anode-free to achieve outstanding performance with a constrained amount of Zn on the Cu current collector.

Constructing 3D Crosslinked Macromolecular Networks as a Highly Efficient Interface Layer for Ultra-Stable Zn Metal Anodes.

Aqueous zinc ion batteries (AZIBs) are experiencing rapid development due to their high theoretical capacity, abundant zinc resources, and intrinsic safety. However, the progress of AZIBs is hindered by uncontrollable parasitic reactions and excessive dendrite growth, which compromise the durability and effective utilization of zinc metal anodes. To address these challenges, the study has constructed a 3D crosslinked macromolecular network composed of zinc ion-bonded potato starch (StZ) as an interface layer on Zn foil (StZ-Zn) to inhibit hydrogen evolution, regulate Zn2+ flux, and ensure uniform Zn deposition. Density functional theory calculations, molecular dynamics simulations, COMSOL Multiphysics simulations, and in situ Raman spectra demonstrate that the 3D StZ interface layer facilitates Zn2+ desolvation by restructuring the solvation shells. This process reduces the concentration of H2O at the anode, thereby inhibiting the hydrogen evolution reaction. Consequently, Zn2+ transport is more efficient, promoting a homogeneous Zn2+ flux and enabling dendrite-free Zn deposition. As a result, StZ-Zn||StZ-Zn symmetric cell delivers a superb lifespan of 4800 h at the current density of 5 mA cm-2, and the corresponding cumulative capacity is as high as 12000 mAh cm-2. Notably, StZ-Zn||NaV3O8·1.5H2O full cell can stably operate for 2500 cycles at 5 A g-1 with an outstanding capacity retention of 92%.

Synthesis of pure ZnO and carbon nanoparticle/ZnO nanostructures for highly efficient glucose sensors

ABSTRACT This work presents a promising method to prepare pure zinc oxide (ZnO) films and carbon nanoparticles (CNPs) decorated ZnO (CNP/ZnO) nanostructured films as glucose sensors. ZnO nanostructure film was grown on Zn foil via the anodisation method, whereas the carbon nanoparticles were synthesised by the hydrothermal method, the decoration process of carbon nanoparticles on ZnO film nanocomposites was conducted using the ultrasonication method. Numerous experiments were conducted, such as microstructure observation, crystallinity analysis, and electrochemical property research. The nanostructures were ascertained by energy-dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FE-SEM), transmission electron microscope (TEM), UV-vis spectroscopy, photoluminescence (PL) measurements, and X-ray diffraction (XRD). ZnO NPs displayed a structure with an average crystallite size of 5.12–13.47 nm, and the PL emission spectra were found to be in the 387 nm range, ZnO films were created by annealing ZnO samples at 200°C for 2 h, and FE-SEM presented nanoparticle-like shapes with a particle size range of (20–50 nm) for voltage anodisation (6 v). This led to an elevation of the energy gap to 3.20 eV. The electrochemical characterisation of the CNPs/ZnO nanostructures refines remarkably the sensitivity to glucose via pure zinc oxide nanostructures. The CNP/ZnO nanostructures demonstrated improved glucose-sensing ability with a sensitivity value of 2827 µA. m M − 1 . The low detection limit is 0.8 mm with a linear range from (0.3 mm to 1 mm). The sensitivity and repeatability of the biosensors were assessed by measuring and analysing their I–V characteristics at different glucose concentrations. Based on a straightforward, affordable, and innovative sensor design, this result validates the sensor’s significant potential as a high-performance nonenzymatic glucose sensor. It was observed that when zinc oxide films were decorated with carbon nanoparticles, there was an increase in the sensitivity of glucose detection. This is due to an increase in charge transfer and conductivity, as well as an increase in the oxidation and reduction process.

Hybrid Particle Size Template Method for Controllable Synthesis of Nitrogen-Doped Multilevel Porous Carbon as High-Rate Zn-Ion Hybrid Supercapacitor Cathode Materials.

Achieving high rate performance without compromising energy density has always been a critical objective for zinc-ion hybrid supercapacitors (ZHSCs). The pore structure and surface properties of carbon cathode materials play a crucial role. We propose utilizing a hybrid particle size (20 and 40 nm) magnesium oxide templates to regulate the pore structure of nitrogen-doped porous carbon derived from the soybean isolate. The multilevel pore structure enhanced ion transport efficiency while also improving the utilization of micropores. Nitrogen doping and oxygen-containing functional groups enhanced the wettability of carbon materials with aqueous electrolytes and facilitated the chemisorption of Zn2+ on the carbon material surface. The nitrogen-doped multilevel porous carbon material (HT-NMPC-1/1) prepared with a 1 : 1 mass ratio of the two templates exhibited a specific capacity of 146.65 mAh g-1 at 0.2 A g-1. Moreover, the Swagelok cells assembled with HT-NMPC-1/1 and Zn foil achieved a high energy density of 121.5 W h kg-1, high power output of 166 W kg-1, and 93.09 % capacity retention after 8000 cycles at 2 A g-1. Therefore, HT-NMPC-1/1 is a highly promising candidate for ZHSCs cathode materials. Furthermore, the novel pore regulation strategy and straightforward preparation method offer valuable reference points for other porous carbon-based functional materials.

Polyethylene Glycol-Protected Zinc Microwall Arrays for Stable Zinc Anodes.

Aqueous zinc-ion batteries promise good commercial application prospects due to their environmental benignity and easy assembly under atmospheric conditions, positioning them as a viable alternative to lithium-ion batteries. However, some inherent issues, such as chaotic zinc dendrite growth and inevitable side reactions, challenge the commercialization progress. In this work, we imprint highly ordered zinc microwall arrays to regulate the electric field toward uniform Zn deposition. Afterward, coating a polyethylene glycol protection layer on the zinc microwalls aims to passivate the surface defects that rise unintentionally by mechanical imprinting. Polyethylene glycol can also boost oriented Zn deposition along the (002) plane and inhibit hydrogen gas production, further enhancing the stability of such three-dimensional (3D) hybrid anodes. Compared to the messy electric field near the polyethylene glycol-protected Zn foil, the uniform electric field provided by these 3D hybrid anodes can regulate the Zn deposition behaviors, enabling a longer lifespan and thus certifying the necessity of adding 3D microstructures. Additionally, 3D microstructures can offer a larger surface area than that of the planar Zn foil, providing more reaction sites and higher specific capacity. In this case, the 3D hybrid electrode exhibits a good initial capacity of approximately 120 mA h/g at a current density of 5 A/g and a nice retention of more than 80% after 800 cycles. The proposed scheme paves the way for a long-term stable 3D zinc anode solution with promising application prospects.

3D Leaf-Like Copper-Zinc Alloy Enables Dendrite-Free Zinc Anode for Ultra-Long Life Aqueous Zinc Batteries.

Metallic zinc exhibits immense potential as an anode material for aqueous rechargeable zinc batteries due to its high theoretical capacity, low redox potential, and inherent safety. However, practical applications are hindered by dendrite formation and poor cycling stability. Herein, a facile substitution reaction method is presented to fabricate a 3D leaf-like Cu@Zn composite anode. This unique architecture, featuring a 3D network of leaf-like Cu on a Zn foil surface, significantly reduces nucleation overpotential and facilitates uniform Zn plating/stripping, effectively suppressing dendrite growth. Notably, an alloy layer of CuZn5 forms in situ on the 3D Cu layer during cycling. DFT calculations reveal that this CuZn5 alloy possesses a lower Zn binding energy compared to both Cu and Zn metal, further promoting Zn plating/stripping and enhancing electrochemical kinetics. Consequently, the symmetric Cu@Zn electrode exhibits remarkable cycling stability, surpassing 1300 h at 0.5mA cm-2 with negligible dendrite formation. Furthermore, full cells comprising Cu@Zn||VO2 exhibit superior capacity and rate performance compared to bare Zn anodes. This work provides a promising strategy for constructing highly stable and efficient Zn anodes for next-generation aqueous zinc batteries.

Nonflammable Fluorinated Electrolyte Realizing High Voltage Anode-Free Zn Dual-Ion Batteries.

Due to the low decomposition potential of H2O and its corrosive effect to Zn foil, the Zn metal battery with aqueous electrolytes operates within a narrow electrochemical window and exhibits low anode utilization ratio. Fluorinated carbonate ester, exhibiting low highest occupied molecular orbital (HOMO) energy level, is suitable for constructing high-voltage batteries, yet its application in Zn metal battery has been scarcely explored. Herein, we propose an electrolyte based on fluorinated solvents and ethoxy (pentafluoro) cyclotriphosphazene (PFPN) additive, which exhibits a high decomposition voltage of 2.75 V in Zn batteries. The fluorinated carbonate esters possess non-flammability and exhibit reduced solvation capacity which in turn promotes the incorporation of anions into Zn2+ solvation shell. Consequently, an anion-derived interface layer is formed on Zn anode, aiding the compact and planar growth of deposited Zn. Therefore, the Zn//Zn cell exhibits an impressive Zn utilization of 91 % for 140 h, a level seldom reported previously. Benefitting from the oxidation resistant solvents and cathode-electrolyte interface layer formed by PFPN additive, the Zn//graphite dual-ions battery shows an extended cycling life of 1000 cycles. Furthermore, an anode-free cell was constructed and stably operated for 100 cycles, with a notably high average discharge midpoint voltage of 1.84 V.

Comprehensive Understanding of Steric‐Hindrance Effect on the Trade‐Off Between Zinc Ions Transfer and Reduction Kinetics to Enable Highly Reversible and Stable Zn Anodes

AbstractThe electrode interface concentration polarization attributed to the contradiction between sluggish mass transfer process and rapid electrochemical reduction kinetics significantly restricts the practical application of Zn anode. Creating a moderate Zn ions transfer and reduction chemistry is essential for durable zinc‐ion batteries. In this work, this trade‐off effect is realized by selecting large‐size 4‐Aminomethyl cyclohexanecarboxylic acid (AMCA) molecule as the electrolyte additive. Intriguingly, AMCA molecules reorganize the Zn2+ solvation structure via the robust coordination with Zn2+ and reconstruct H‐bond networks, giving a pulled desolvation process. Meanwhile, AMCA enlarges the Zn2+ solvation size with a push force, confining the rapid electrochemical reduction kinetics. The balanced chemical environment is maintained via the moderate pull‐push interplay. Besides, AMCA can anchor on zinc surface to create a water‐poor microenvironment, fostering homogeneous Zn (002) deposition and effectively restricting water‐induced side‐reactions. Notably, the Zn||Zn symmetric cell with AMCA operates stably over 167 days at 20 mA cm−2. Moreover, the Zn||VOX full cell employed AMCA ensures outstanding capacity retention of 99.15% after 590 cycles at 2 A g−1, even with low N/P (4.3), lean electrolyte (50 µL mAh−1) and ultrathin Zn foil of 10 µm. This work reveals unique insights into the balanced interfacial chemistry design toward high‐performance zinc batteries.

Zinc-tin binary alloy interphase for zinc metal batteries

Aqueous zinc ion batteries are rapidly developing as the most propitious energy storage system due to their high security, high specific capacity and low cost, etc. However, zinc anodes suffered from dendrite growth and hydrogen evolution reactions during cycling, so it is of utmost importance to upgrade zinc anode properties. In this study, the homogeneous layer of ZnSn alloy interphase was formed by introducing metallic tin to the anode surface using an ion sputtering technique. ZnSn alloy can reduce the hydrogen evolution over-potential of anode and the corrosion current, inhibiting the occurrence of hydrogen evolution and corrosion reaction. Moreover, the ZnSn alloy anode can provide uniform nucleation sites and uniformize the electric field on the anode surface, promote the uniform deposition of Zn2+, thus inhibiting the formation of zinc dendrites. Notably, compared to the Zn foil//Zn foil cell (400 h), the ZnSn alloy symmetric cell showed excellent cycling performance by cycling for 1000 h at 0.5 mA cm−2. Furthermore, even at current density of 1 A/g, the capacity retention of the ZnSn alloy//MnO2 full cell was up to 89.5 % compared to only 32.3 % for Zn foil//MnO2 cell. The preparation of this ZnSn alloy anode may provide new ideas for future alloying strategies.

Synthesis of Amorphous Nickel-Cobalt Hydroxides for Ni-Zn Batteries.

In this work we developed a hydrothermal method for synthesizing amorphous Ni-Co hydroxide (NC(OH)) and in the subsequent step crystalline NiCo2O4 (NCO) has been produced using water as the solvent. For nickel-zinc batteries, NC(OH) was found to have superior performance to its NCO prepared by two-step process. The thermal stability analysis exhibited the optimum temperature to obtain the NC(OH), and NCO electrode materials. The XRD pattern showed mixed phases containing both Ni and Co hydroxides (during the initial step) and in the subsequent step (calcined) the formation of cubic spinel structure was noticed. For NC(OH), aggregated particles with irregular morphology were observed while clustered nanorod-like shapes were noticed for NCO samples. To be noted, that the nanorod morphology was obtained through a facile approach without employing any structure-directing agent. Both NC(OH) and NCO were employed as cathodes for Ni-Zn battery studies against Zn foil anode with a polyamide-based separator soaked in 6 M KOH saturated with ZnO additive was used as electrolyte. The Ni-Zn cell was fabricated in CR2032 coin cell configuration. The electrochemical studies such as cyclic voltammetry (CV) showed the characteristic redox peaks for NC(OH) sample exhibiting high peak current compared to its NCO counterpart. The NC(OH) had a capacity of 268 mAh g-1 against 120 mAh g-1 for NCO at a current density of 1 Ag-1. The cell was able to retain 85 % of the capacity at the end of 500 cycles and showed remarkable rate capability. The Ni-Zn battery presents energy and power densities of 428.8 Wh Kg-1 and 2.68 kW Kg-1, respectively surpassing the normal values reported for aqueous rechargeable batteries. Owing to the presence of Ni and Co in hydroxide form (reduced crystallinity) the NC(OH) sample showed improved electrochemical activity. This work provides a facile approach and effective strategy for developing bimetallic hydroxides for optimal energy storage performance.

An interfacial dual-regulation strategy for ultra-stable 3D Zn metal anodes

The development of Zn metal-batteries, which are viewed as one of the most potential alternatives to lithium ion batteries, is severely hindered by sluggish ion diffusion kinetics and uncontrollable dendritic growth for anodes. Herein, we propose an interfacial dual-regulation strategy for the fabrication of 3D Zn anode through the direct in-situ treatment of benchmark Zn foil. Both rapid ion migration dynamics and homogeneous bottom-up Zn2+ deposition are achieved due to the unique open nanoarray structure with superhydrophilic and zincophilic interface to the electrolyte. Theoretical calculations and finite element simulations reveal this design can effectively redistribute Zn2+ and increase ion flux with a long-lasting 3D diffusion mode, enabling exceptional reversibility during Zn plating/stripping. The as-prepared anode therefore achieves an ultralong lifespan over 3000 h along with high rate capability even at 40 mA cm−2 (depth of discharge ≈ 68.4%). Furthermore, its practical feasibility is validated by a superior capacity retention of 92.5% after 1000 cycles for full cell and high capacity of 112.2 mAh g−1 for pouch cell. This study opens up new opportunities for the development of dendrite-free anodes for aqueous metal batteries.

Grain Boundary Filling Empowers (002)-Textured Zn Metal Anodes with Superior Stability.

Aqueous Zn battery is promising for grid-level energy storage due to its high safety and low cost, but dendrite growth and side reactions at the Zn metal anode hinder its development. Designing Zn with (002) orientation improves the stability of the Zn anode, yet grain boundaries remain susceptible to corrosion and dendrite growth. Addressing these intergranular issues is crucial for enhancing the electrochemical performance of (002)-textured Zn. Here, a strategy based on grain boundary wetting to fill intergranular regions and mitigate these issues is reported. By systematically investigating boundary fillers and filling conditions, In metal is chosen as the filler, and one-step annealing is used to synergistically convert commercial Zn foils into single (002)-textured Zn while filling In into the boundaries. The inter-crystalline-modified (002)-textured Zn (IM(002) Zn) effectively inhibits corrosion and dendrite growth, resulting in excellent stability in batteries. This work offers new insights into Zn anode protection and the development of high-energy Zn batteries.

Electrodeposited Zn-Mn on three-dimensional electrodes as anodes in liquid and quasi-solid-state zinc-air batteries

Zinc-air batteries (ZABs) are eco-friendly and sustainable energy storage devices. There are different challenges to overcome in ZABs, where anodic issues such as shape changes, passivation, self-corrosion, and dendrite formation require urgent solutions. In this work, Zn and Zn-Mn alloys were electrodeposited on three-dimensional porous carbon electrodes varying the Mn composition (2, 20 and 40 g L−1) and studying its effect during the operation of a 6 M KOH liquid ZAB and a quasi-solid-state ZAB based on poly(vinyl alcohol)/poly(acrylic acid) PVA/PAA gel polymer electrolyte (GPE). Scanning electron microscopy (SEM) images indicated that Zn and Zn-Mn were deposited as platelet-like bi-dimensional structures. Additionally, the use of 20 and 40 g L−1 of the Mn precursor resulted in larger Zn deposition covering the 3D structure of the carbon paper. Elemental analysis indicated that the Mn content in Zn-Mn was 1.3, 2.4 and 6 %. In the aqueous ZAB, the Zn-Mn with 2.4 % Mn enabled to increase the maximum current density achieving the highest power density of 45 mW cm⁻2. In QSS-ZAB, Zn-Mn at 1.3 and 2.4. % Mn displayed higher stability to recovery after demanding different current densities, while the first anode displayed higher cyclability, presenting a similar round trip after 240 charge/discharge cycles This ZAB was maintained functional during 290 cycles vs. 120 cycles for Zn foil. The rechargeability was improved because of the decrease in Zn dendritic growth and passivation.

Hydrophilic and Insulative Interface Strategy Against Side Reactions for Dendrite‐Free Zinc Metal Anodes

AbstractThe zinc dendrite growth and the parasitic hydrogen evolution reactions (HER) hinder the commercialization of zinc batteries. To address this, a hydroxyl‐rich Boehmite coating (HR‐BC) strategy is developed that combines excellent electrical insulation and high zinc ion conductivity. The hydrophilic hydroxyl groups facilitate hydrogen bond formation with the hydrated zinc ions, accelerating the de‐solvation process and suppressing the HER. Additionally, the electrically insulative nature of Boehmite prevents the reduction of zinc ions within HR‐BC and results in preferential Zn deposition underneath it, leading to a dendrite‐free “sandwich structure” of HR‐BC//Zn deposition//Zn foil. Symmetric cells using HR‐BC‐Zn electrodes obtain an ultralong and stable cycling lifetime of 1700 h at 5 mA cm−2, along with a high cumulative plating capacity of 4250 mAh cm−2. When paired with a V2O5 cathode, the HR‐BC‐Zn anode demonstrates a high capacitance retention of 90% and an average Coulombic efficiency (CE) of 99.8% after 4000 cycles. Furthermore, when combined with a heteroatoms‐doped carbon (HDC) cathode, the HR–BC–Zn//HDC pouch‐type cell exhibits superior lifetime performance with nearly 100% average CE after 15000 cycles at 3.0 A g−1. This work highlights the effectiveness of hydrophilic and insulative coating strategies in fostering the progression of long‐lasting zinc‐based energy storage systems.

Enhanced Nonenzymatic Glucose Biosensor of ZnO Nanostructure via Nonthermal Plasma

The sensitive nonenzymatic sensing of glucose has been made feasible for the first time using a nonthermal plasma (NTP)-synthesized ZnO nanostructure. This work presents an interesting and novel method for surface modification. The effects of flow gas of Argon/Oxygen (20, 30 and 40 l/min) on the Zn foil surface and various properties were investigated. Optical emission spectroscopy OES has been used to characterize transmissions for positive and negative systems of Ar/O plasma. X-ray diffraction showed close adjacent tops and the strongest peak at Zn (101). EDX displays the constants (Ok_[Formula: see text], (Znk_[Formula: see text] and (Znk_[Formula: see text] and change in (ZnL_[Formula: see text]. Photoluminescence (PL) Analysis shows a shift at the vertex toward the left and then toward the right confirming the reaction of all PL spectra within a strong UV emission peak. Raman spectroscopy analysis demonstrates two clear peaks gradually shifting to the right with an increase in the percentage of gas flowing compared to the blank metal, and scanning electron microscopy (FE-SEM) images show changes in the shape of nanoparticles due to increasing gas flow, the surface of zinc metal is affected by cold plasma and forms particles with very small diameters ranging from 10.8[Formula: see text]nm to 123[Formula: see text]nm. Also altered the surface morphology where the nano shape changed from flower-like particles to sheets with diameters ranging 282.7–643.5[Formula: see text]nm and the sheets grew with the increase of gas flow to diameters ranging 132–710[Formula: see text]nm. ZnO nanostructures are employed as biosensor electrodes (nonenzymatic) glucose as the increase in current is proportional to the flowing gas (2.06E-03[Formula: see text]mA, 2.09E-03[Formula: see text]mA and 4.34E-03[Formula: see text]mA).

Adaptive No‐Tip Distribution of Rich Charge‐Density‐Clusters Guiding Confinement Deposition with Repair Function toward Highly Reversible Zinc Anode

AbstractThe plating/stripping behavior of Zn ions on the Zn anode, driven by an electric field, is a key process in determining the performance of aqueous zinc ion batteries (AZIBs). Process‐induced unevenness of commercial Zn foils results in poor reversibility of Zn anodes. Herein, a self‐healing dynamic anode/electrolyte interface is constructed by incorporating hydroxyl‐rich alcohols with high charge density and zincophilicity into the original electrolyte. These alcohols selectively anchor on electron‐poor sites in the charging state, inducing domain‐limited deposition of Zn2+ to achieve a dense, uniform, and flat deposition state. As a result, a durable Zn anode with excellent electrochemical reversibility can be realized in practical cycling (average Coulombic efficiency of 99.5%). Even under deep plating/stripping conditions (5 mA cm−2 and 5mAh cm−2), the modified electrolyte exhibits a remarkable repair effect on corroded Zn anodes that have been cycled in base electrolyte, extending the lifespan to over 1,020 h. This represents a 15.6‐fold enhancement in lifespan compared to recycling in the base electrolyte. This strategy for electrolyte additive directly influences the design of ultra‐long‐life AZIBs and provides concrete concepts for the recovery of zinc anodes.