Zirconium Acetylacetonate Research Articles

In Situ Growth of Suspended Zirconene Islets Inside Graphene Pores

AbstractExperiments using a transmission electron microscope decomposed zirconium acetylacetonate with an electron beam, forming zirconium nanoparticles on graphene. Continued electron irradiation transformed these nanoparticles into atomically thick zirconium islets (zirconene islets) within the graphene lattice. The electron beam caused zirconium atom dislocations and vacancies that are rapidly refilled, a process repeating until the vacancies evolved into zirconium nanoribbons before breaking. This study offers insights into the electron‐driven growth and degradation of zirconene islets, showcasing a method to fabricate freestanding zirconenes for use as atomically thin coatings in extreme environments.

Thermal Activation of Zirconium(IV) Acetylacetonate Catalysts to Enhance Polyurethane Synthesis and Reprocessing

Thermal Activation of Zirconium(IV) Acetylacetonate Catalysts to Enhance Polyurethane Synthesis and Reprocessing

Dual Passivation Strategy for Highly Stable Blue-Luminescent CsPbBr3 Nanoplatelets.

Blue-emitting colloidal CsPbX3 (X = Br, Cl, or I) perovskite nanocrystals have emerged as one of the most fascinating materials for optoelectronic applications. However, their applicability is hindered by poor stability and a low photoluminescence efficiency. Herein, highly stable CsPbBr3 nanoplatelets exhibiting intense blue luminescence are fabricated by employing a strategy in which the morphology is regulated and the surface is subjected to dual passivation through the incorporation of zirconium acetylacetonate [Zr(acac)4]. The passivated CsPbBr3 nanocrystals exhibit adjustable light emission from green to dark blue and a controllable morphology from nanocubes (NCs) to nanoplatelets (NPLs) and nanorods accomplished by varying the content of Zr(acac)4. The optimized NPLs are characterized by a bright blue emission with a central wavelength of 459 nm and a high photoluminescence quantum yield of 90%. The addition of Zr(acac)4 in the synthesis of CsPbBr3 induces oriented growth with a two-dimensional morphology. The Zr(acac)4 can repair the surface defects of the nanocrystal surface, and the surface is also capped with the Zr(OH)4 cluster layer. Therefore, the passivated blue-emitting NPLs exhibit outstanding stability compared to that of pristine NPLs during long-term storage and exposure to light. This work provides a novel strategy for fabricating highly stable PNCs with deep-blue emission and widens their potential applications in blue-emitting optoelectronic devices.

Improved resistive switching characteristics of solution processed ZrO2/SnO2 bilayer RRAM via oxygen vacancy differential

In this study, a solution-processed bilayer structure ZrO2/SnO2 resistive switching (RS) random access memory (RRAM) is presented for the first time. The precursors of SnO2 and ZrO2 are Tin(Ⅱ) acetylacetonate (Sn(AcAc)2) and zirconium acetylacetonate (Zr(C5H7O2)4), respectively. The top electrode was deposited with Ti using an E-beam evaporator, and the bottom electrode used an indium–tin–oxide glass wafer. We created three devices: SnO2 single-layer, ZrO2 single-layer, and ZrO2/SnO2 bilayer devices, to compare RS characteristics such as the I–V curve and endurance properties. The SnO2 and ZrO2 single-layer devices showed on/off ratios of approximately 2 and 51, respectively, along with endurance switching cycles exceeding 50 and 100 DC cycles. The bilayer device attained stable RS characteristics over 120 DC endurance switching cycles and increased on/off ratio ∼2.97 × 102. Additionally, the ZrO2/SnO2 bilayer bipolar switching mechanism was explained by considering the Gibbs free energy (ΔG o) difference in the ZrO2 and SnO2 layers, where the formation and rupture of conductive filaments were caused by oxygen vacancies. The disparity in the concentration of oxygen vacancies, as indicated by the Gibbs free energy difference between ZrO2 (ΔG o = −1100 kJ mol−1) and SnO2 (ΔG o = −842.91 kJ mol−1) implied that ZrO2 exhibited a higher abundance of oxygen vacancies compared to SnO2, resulting in improved endurance and on/off ratio. X-ray photoelectron spectroscopy analyzed oxygen vacancies in ZrO2 and SnO2 thin films. The resistance switching characteristics were improved due to the bilayer structure, which combines a higher oxygen vacancy concentration in one layer with a lower oxygen vacancy concentration in the switching layer. This configuration reduces the escape of oxygen vacancies to the electrode during RS.

Diffusion coefficients of zirconium (IV) acetylacetonate: Measurements and correlation in both pressurized liquid and supercritical fluid

Limited data exist on the diffusion coefficient of a solute in both pressurized and supercritical fluids, despite its crucial role as an essential transport property. In this study, we present the first-ever determined diffusion coefficients of zirconium acetylacetonate (Zr(acac)4) in two distinct fluids: pressurized ethanol and supercritical carbon dioxide. Using the Taylor dispersion method, we measured the diffusion coefficients in pressurized ethanol at temperatures between 298.15 and 333.15 K, reaching pressures up to 30.00 MPa. In supercritical carbon dioxide, we employed the chromatographic impulse response (CIR) method, conducting the experiments at temperatures from 308.15 to 343.15 K and pressures up to 35.00 MPa. Remarkably, predissolving Zr(acac)4 in supercritical carbon dioxide and injecting it into the diffusion column enabled the accurate determination of diffusion coefficients in supercritical carbon dioxide, which were approximately an order of magnitude higher than those in pressurized ethanol. Our investigation revealed diffusion activation energies, ranging from 26.7 to 10.2 kJ mol−1 at pressures between 10.00 and 30.00 MPa in supercritical carbon dioxide and from 20.4 to 19.6 kJ mol−1 at pressures between 20.00 and 30.00 MPa in pressurized ethanol. All diffusion data, in both liquid and supercritical states, can be effectively correlated using the equation Sc = ∑n=03(Cnηn) with 2 parameters and 4 adjustable coefficients. This correlation demonstrates high accuracy, with an average absolute relative deviation (AARD) of 3.7 % over a wide fluid viscosity range of 21.0 to 1305.0 μPa s. Additionally, it is observed that all diffusion data can also be well-fitted with the equation D12/T = αηβ with 2 parameters and 2 adjustable coefficients, achieving an AARD of 3.5 %.

Solution-processed zirconium acetylacetonate charge-trap layer for multi-bit nonvolatile thin-film memory transistors

ABSTRACT The charge trap property of solution-processed zirconium acetylacetonate (ZAA) for solution-processed nonvolatile charge-trap memory (CTM) transistors is demonstrated. Increasing the annealing temperature of the ZAA from room temperature (RT) to 300°C in ambient, the carbon double bonds within the ZAA decreases. The RT-dried ZAA for the p-type organic-based CTM shows the widest threshold voltage shift (∆VTH ≈ 80 V), four distinct V THs for a multi-bit memory operation and retained memory currents for 103 s with high memory on- and off-current ratio (IM,ON/IM,OFF ≈ 5Ⅹ104). The n-type oxide-based CTM (Ox-CTM) also shows a ∆V TH of 14 V and retained memory currents for 103 s with I M,ON/I M,OFF ≈ 104. The inability of the Ox-CTM to be electrically erasable is well explained with simulated electrical potential contour maps. It is deduced that, irrespective of the varied solution-processed semiconductor used, the RT-dried organic ZAA as CTL shows the best memory functionality in the fabricated CTMs. This implies that the high carbon double bonds in the low-temperature processed ZAA CTL are very useful for low-cost multi-bit CTMs in flexible electronics.

Effective interface treatment by zirconium acetylacetonate for inverted methylammonium-rich perovskite solar cells

Surface passivation of halide perovskites using suitable agents is crucial to enhance the performance of corresponding solar cells as surface defects dominate nonradiative recombination in the devices. Meantime, it is important to reduce surface recombination as well as improve the contact nature at the interface between perovskite and transport layers by introducing such an agent in devices. Many works have achieved remarkable results by designing novel interfacial modifiers, but it is still a challenge to realize excellent interface treatments by less-complicated small molecules. Here, we demonstrate that zirconium acetylacetonate (ZrAcac) provides both effective methylammonium-rich perovskites surface passivation and excellent interfacial charge transport channel between the perovskite and fullerene-based electron transport layer in inverted cell structure. We theoretically find that the deep in-gap states from the PbI and IPb anti-site defects are effectively eliminated by the strong interaction between ZrAcac and the perovskite surface, which is further confirmed by experimental Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Meantime, the suitable conduction band minimum and deep valance band maximum of the ZrAcac on perovskites surface made a better electron transporting channel and interfacial anti-transfer barrier. Consequently, the corresponding device without encapsulation shows a power conversion efficiency (PCE) of 22.1% and still retains 80% of its initial PCE after 400 h of exposure to a constant environment (∼10% RH and 30 °C). This work provides a simple and cheap alternative perovskite interface treatment for future large-scale commercialization of perovskite solar cells.

Dual-Stimuli-Sensitive Smart Hydrogels Containing Magnetic Nanoparticles as Antitumor Local Drug Delivery Systems-Synthesis and Characterization.

The aim of this study was to develop an innovative, dual-stimuli-responsive smart hydrogel local drug delivery system (LDDS), potentially useful as an injectable simultaneous chemotherapy and magnetic hyperthermia (MHT) antitumor treatment device. The hydrogels were based on a biocompatible and biodegradable poly(ε-caprolactone-co-rac-lactide)-b-poly(ethylene glycol)-b-poly(ε-caprolactone-co-rac-lactide) (PCLA-PEG-PCLA, PCLA) triblock copolymer, synthesized via ring-opening polymerization (ROP) in the presence of a zirconium(IV) acetylacetonate (Zr(acac)4) catalyst. The PCLA copolymers were successfully synthesized and characterized using NMR and GPC techniques. Furthermore, the gel-forming and rheological properties of the resulting hydrogels were thoroughly investigated, and the optimal synthesis conditions were determined. The coprecipitation method was applied to create magnetic iron oxide nanoparticles (MIONs) with a low diameter and a narrow size distribution. The magnetic properties of the MIONs were close to superparamagnetic upon TEM, DLS, and VSM analysis. The particle suspension placed in an alternating magnetic field (AMF) of the appropriate parameters showed a rapid increase in temperature to the values desired for hyperthermia. The MIONs/hydrogel matrices were evaluated for paclitaxel (PTX) release in vitro. The release was prolonged and well controlled, displaying close to zero-order kinetics; the drug release mechanism was found to be anomalous. Furthermore, it was found that the simulated hyperthermia conditions had no effect on the release kinetics. As a result, the synthesized smart hydrogels were discovered to be a promising antitumor LDDS, allowing simultaneous chemotherapy and hyperthermia treatment.

Synthesis and evaluation of water-soluble fracturing fluid thickener based on hydrophobic association

• Hydrophobically associative polymers. • Cross-linked fracturing fluid has excellent performance. • The residue content is low, and the damage to the reservoir is small. A cyclic quaternary ammonium salt type hydrophobic monomer VIM-16 was synthesized by 1-vinylimidazole and 1-bromohexadecane, and the hydrophobically associative polymer PAAV was prepared with AM and AMPS. It was cross-linked with 0.3% zirconium acetylacetonate to form a viscoelastic fracturing fluid. The rheological properties of it were found to have good thickening and shear resistance properties. Using 0.2% gel breaker, the gel was completely broken. No residue, it was a low damage fracturing fluid. Scanning electron microscopy was used to observe the microscopic morphology, and the morphology after cross-linking to form the jelly showed a uniform, regular and ordered network structure.

Suppressing interface charge recombination for efficient integrated perovskite/organic bulk-heterojunction solar cells

Integrated perovskite/bulk-heterojunction (BHJ) solar cells offer a novel way to achieve high-performance photovoltaics exceeding Shockley-Queisser limit through the utilization of complementary light absorption spectra. Despite improved photocurrent benefited from the additional near-infrared light harvesting, undesirable decrease of open-circuit voltage and fill factor are often observed due to severe charge recombination at the perovskite/BHJ interface. Herein, ultrathin bathocuproine (BCP) and zirconium acetylacetonate (ZrAcac) are inserted between perovskite and BHJ as interface modification to regulate carrier extraction and inhibit charge recombination at the interface. Fermi energy levels of perovskite shift upward after BCP and ZrAcac modification, indicating higher built-in electric field at the perovskite/BHJ interface, which is supported by the capacitance-voltage measurements. Enhanced carrier extraction and suppressed charge recombination are confirmed at the perovskite/BHJ interface according to the photoluminescence spectra and semiconductor device measurement. Consequently, large improvements of Voc and FF are obtained without sacrificing the photocurrent, resulting in a champion conversion efficiency, which is among the highest reported efficiencies of integrated perovskite/BHJ solar cells so far. Our work provides a feasible exploration from the perspective of interface modification for achieving high-efficiency integrated perovskite/BHJ photovoltaics.

Insights into the decomposition of zirconium acetylacetonate using synchrotron radiation: Routes to the formation of volatile Zr-intermediates

AbstractThe thermal decomposition of Zr(acac)4 is studied in a SiC-microreactor on the micro-second time scale. By utilizing synchrotron radiation and photoelectron photoion coincidence spectroscopy, six important zirconium intermediates, as for instance Zr(C5H7O2)2(C5H6O2), and Zr(C5H6O2)2, are identified in the gas phase for the first time. The adiabatic ionization thresholds of intermediately formed zirconium species are estimated and the main products of their thermal decomposition, acetylacetone, acetylallene and acetone are characterized unambiguously and isomer-selectively. Based on all detected intermediates, we deduce the predominant pyrolysis pathways of the precursor in the temperature range from 400 to 900 K. Our findings are complemented by numerical simulations of the flow field in the microreactor, which show that the choice of dilution gas significantly influences the temperature profile and residence times in the microreactor, such that helium provides a more uniform flow field than argon and should preferentially be used. Graphical abstract Using a soft ionization method coupled to velocity map imaging (VMI), leads to valuable insights in the thermal decomposition of Zr(C5H7O2)4, used in the synthesis of functional nanomaterials and ceramic coatings. Thanks to the use of a microreactor, important gas

Dimerization of Acetylene to Monovinylacetylene (MVA) by Bimetallic Zr/Cu Catalyst in Nieuwland Catalytic System.

Nieuwland catalyst is a key step in the dimerization of acetylene. Various zirconium metal additives incorporating Nieuwland catalysts were prepared, and their catalytic performances were assessed in acetylene dimerization. Different characterization techniques (i.e., thermogravimetric analysis, temperature-programmed reduction, X-ray diffraction, X-ray photoelectron spectroscopy, hydrogen ion concentration measurement and transmission electron microscopy) were employed in this study. The best catalytic performance was obtained over zirconium-acetylacetonate-incorporated Nieuwland catalysts, with an acetylene conversion of 53.3% and a monovinylacetylene selectivity of 87.4%. Based on these results, the zirconium acetylacetonate additive could reduce the types of transition state complexes, and it could also change the morphology of the catalyst. In addition, the additives could significantly inhibit the occurrence of trimerization products and polymers. Hence, the conversion of acetylene, monovinylacetylene selectivity, and stability of the Nieuwland catalysts were enhanced.

Transparent PC/PMMA Blends with Enhanced Mechanical Properties via Reactive Compounding of Functionalized Polymers.

Reactive compounding of terminally phenolic OH-functionalized polycarbonate (PC) with epoxy-functionalized polymethylmethacrylate (PMMA) prepared by copolymerization with glycidyl methacrylate was investigated. It was spectroscopically demonstrated that a PC/PMMA copolymer was formed during the melt reaction of the functional groups. Zirconium acetylacetonate could catalytically accelerate this reaction. Correlations of the phenomenological (optical and mechanical) properties with the molecular level and mesoscopic (morphological) structure were discussed. By the investigated reactive compounding process, transparent PC/PMMA blends with two-phase morphologies were obtained in a continuous twin-screw extruder, which, for the first time, combined the high transmission of visible light with excellent mechanical performance (e.g., synergistically improved tensile and flexural strength and high scratch resistance). The transparency strongly depended on (a) the degree of functionalization in both PC and PMMA, (b) the presence of the catalyst, and (c) the residence time of the compounding process. The in-situ-formed PC/PMMA copolymer influenced the observed macroscopic properties by (a) a decrease in the interphase tension, leading to improved and stabilized phase dispersion, (b) the formation of a continuous gradient of the polymer composition and thus of the optical refractive indices in a diffuse mesoscopic interphase layer separating the PC and PMMA phases, and (c) an increase in the phase adhesion between PC and PMMA due to mechanical polymer chain entanglement in this interphase.

Optimization of a SnO2-Based Electron Transport Layer Using Zirconium Acetylacetonate for Efficient and Stable Perovskite Solar Cells.

SnO2 is a promising material for use as an electron transfer layer (ETL) in perovskite photovoltaic devices due to its suitable energy level alignment with the perovskite, high electron mobility, excellent optical transmission, and low-temperature processability. The development of high-quality SnO2 ETLs with a large coverage and that are pinhole-free is crucial to enhancing the performance and stability of the perovskite solar cells (PSCs). In this work, zirconium acetylacetonate (ZrAcac) was introduced to form a double-layered ETL, in which an ideal cascade energy level alignment is obtained. The surface of the resulting ZrAcac/SnO2 (Zr-SnO2) layer is compact and smooth and had a high coverage of SnO2, which enhances the electron extractability, improves ion blocking, and reduces the charge accumulation at the interface. As a result, the fill factor (FF, 80.99%), power conversion efficiency (PCE, 22.44%), and stability of the Zr-SnO2 device have been significantly improved compared to PSCs with only a SnO2 ETL. In addition, the PCE of the Zr-SnO2 device is maintained at more than 80% of the initial efficiency after 500 h of continuous illumination.

Synthesis and properties of hydrophobically associating polymer fracturing fluid

The double tailed hydrophobic monomer PMB-16 was synthesized by the reaction of phenylethylamine,1-bromohexadecane and methacryloyl chloride. The ternary hydrophobic association polymer (PADM) was synthesized by free radical copolymerization of PMB-16 with acrylamide (AM) and methacryloyloxyethyl trimethylammonium chloride (DMC). The optimum synthesis conditions were as follows, the mass ratio of m (AM):m (DMC):m (PMB-16) was 80:19.6:0.4, the total monomer concentration was 35.0 wt%, the amount of initiator (V50) was 0.1 wt% of the total mass of monomer, the reaction temperature was 55 °C, the reaction time was 6.0 h, the system pH was 7, and the amount of metal ion chelating agent (EDTA-4Na) was 0.01 wt% of the total mass of monomer. The results of performance evaluation showed that PADM aqueous solution had excellent temperature and salt resistance. Using zirconium acetylacetonate as crosslinking agent, the mass crosslinking ratio of PADM solution to zirconium acetylacetonate was 100:0.9, the crosslinking temperature was 60 °C, and the pH value was 6.0. The system presented good thickening, temperature resistance, shear stability and low residue content, so it was a low damage fracturing fluid.

Synthesis and Characterization of New Biodegradable Injectable Thermosensitive Smart Hydrogels for 5-Fluorouracil Delivery.

In this paper, injectable, thermosensitive smart hydrogel local drug delivery systems (LDDSs) releasing the model antitumour drug 5-fluorouracil (5-FU) were developed. The systems were based on biodegradable triblock copolymers synthesized via ring opening polymerization (ROP) of ε-caprolactone (CL) in the presence of poly(ethylene glycol) (PEG) and zirconium(IV) acetylacetonate (Zr(acac)4), as co-initiator and catalyst, respectively. The structure, molecular weight (Mn) and molecular weight distribution (Đ) of the synthesized materials was studied in detail using nuclear magnetic resonance (NMR) and gel permeation chromatography (GPC) techniques; the optimal synthesis conditions were determined. The structure corresponded well to the theoretical assumptions. The produced hydrogels demonstrated a sharp sol–gel transition at temperature close to physiological value, forming a stable gel with good mechanical properties at 37 °C. The kinetics and mechanism of in vitro 5-FU release were characterized by zero order, first order, Higuchi and Korsmeyer–Peppas mathematical models. The obtained results indicate good release control; the kinetics were generally defined as first order according to the predominant diffusion mechanism; and the total drug release time was approximately 12 h. The copolymers were considered to be biodegradable and non-toxic; the resulting hydrogels appear to be promising as short-term LDDSs, potentially useful in antitumor therapy.

Deposition of zirconium oxide using atmospheric pressure plasma enhanced chemical vapor deposition with various precursors

• Atmospheric plasma deposition of zirconia thin films. • Liquid droplet precursor delivery for plasma deposition. • Non-thermal decomposition of nitrate salt solutions. Plasma based processes, if applied under controlled conditions, can replace harmful liquid effluents produced today in manufacturing for cleaning and surface protection of metals. In this work, an atmospheric pressure plasma process has been demonstrated to deposit zirconium oxide from three different precursors, namely zirconium tetra-tert butoxide, zirconium acetylacetonate and zirconium oxynitrate hydrate. Of these, the zirconium acetylacetonate and zirconium oxynitrate hydrate deposition processes resulted in conformal thin films. Continuous 115 nm thick zirconium oxide coatings could be deposited from zirconium acetylacetonate, although heavy carbon contamination was observed. In contrast, coatings deposited using zirconium oxynitrate hydrate as a precursor has an approximate thickness of 518 nm, a Zr:O ratio in the bulk of 1:2.2, and no nitrogen or carbon contamination. This study shows that zirconia films can be deposited using atmospheric pressure plasma and the films should be explored further as surface treatments for corrosion protection .

Effect of UV irradiation on the resistive switching characteristics of low-temperature solution-processed ZrO2 RRAM

This paper presents the fabrication of a solution-processed ZrO2 resistive random access memory (RRAM) device with low-temperature UV irradiation and the effect of UV irradiation on the resistive switching (RS) characteristics. The ZrO2 switching layer was deposited by spin-coating zirconium acetylacetonate (Zr(C5H7O2)4) precursor in an ethanol solvent; the maximum process temperature was 150 °C. The RS characteristics of the fabricated device were unstable for up to 2 h UV irradiation, but they improved after 4 h or longer UV irradiation. The 4 h and 8 h UV-irradiated devices show stable RS even after 200 dc switching cycles and long retention over 104 s. The improvement of RS characteristics caused by different UV irradiation times can be attributed to the reduction of the hydroxyl group (M–OH) and the formation of enhanced metal-oxide bonds (M–O) of the ZrO2 thin films, based on field emission scanning electron microscope and x-ray photoelectron spectroscopy analysis. This research suggests a promising approach to fabricate oxide thin films with good RS characteristics at low temperatures which has high potential to be extended to future flexible RRAM devices.

SYNTHESIS OF NANOSIZED ZIRCONIUM DIOXIDE, COBALT OXIDE AND RELATED PHASES IN SUPERCRITICAL CO2 FLUID

This study is devoted to obtaining nanoscale zirconium dioxide, cobalt oxide and related phases by SAS method in supercritical carbon dioxide. The synthesized compounds were characterized by a complex of physico-chemical analytical methods: infrared spectroscopy, differential scanning calorimetry, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy. The experimental parameters for obtaining the nanoparticles were: pressure 10 MPa, temperature 40 °C, carbon dioxide supply rate 35 g/min, the initial solution supply rate 0.5 ml/min. Individual phases containing zirconium and cobalt, and also samples with zirconium to cobalt molar ratios 3:1, 2:1, 1:1, 2:1 and 1:3 were obtained. The use of zirconium and cobalt acetylacetonates as initial components leads to formation of stable products – nanoparticles of acetates of the corresponding metals in the X-ray amorphous state. When heated to 340-350 °C, the destruction of organometallic complexes to oxides occurs with formation of a continuous series of X-ray amorphous solid solutions in the ZrO2-CoO system. At temperatures above 600 °C, the phases crystallize with the decomposition of solid solutions into ZrO2 and Co3O4. When temperature is above 900 °C, further oxidation of cobalt occurs. Thus, cobalt oxide oxidation into Co3O4 proceeds in two steps, at 600 and 900 °C. For samples of zirconium dioxide with cobalt oxide admixture at a temperature of 700 °C stabilization of the cubic modification is observed which is probably due to the entry of cobalt into the cubic structure of zirconium oxide, which prevents transition to tetragonal and monoclinic modifications.

Polychelates Based on Magnesium, Aluminum, Iron, Zirconium, and Vanadyl Acetylacetonates - Synthesis, Structure and Properties

The formation of polymeric acetylacetonates of magnesium, aluminum, iron, zirconium, and vanadyl under conditions of mechanochemical activation with subsequent condensation in boiling toluene has been investigated. The obtained compounds have been studied by the methods of gel chromatography, X-ray diffractometry, and positron annihilation and IR spectroscopy. Aluminum chelates have been studied by means of NMR spectroscopy. It has been demonstrated that the mechanochemical activation with subsequent boiling in toluene results in the formation of polymeric chelates, mostly those of iron, zirconium and, to a smaller degree, chelates of aluminum, magnesium, and vanadyl. The molecular weight of soluble high-molecular fractions is in the range 3000–5000 Da. The layered polymer structure has been revealed. Cross-section areas of polymer chains and volumes of coherent scattering regions have been calculated from the diffractometry data. The morphology of polymers consisting of spherical particles of sizes in the range 100–700 nm has been investigated. Based on the data of positron annihilation spectroscopy (PAS), density, and nitrogen low-temperature adsorption, the dependence of the chelate stability on the specific polarizing potential has been determined. A fractal structure of solid-state polychelates has been revealed.