Zircon Hf Isotopic Compositions Research Articles

Zircons underestimate mantle depletion of early Earth

The mechanism and timing of crustal growth and differentiation on early Earth are debated. Evidence of crustal differentiation is detectable as deviations from Earth’s assumed chondritic uniform reservoir (CHUR) as crust is extracted from the mantle leading to a melt-depleted reservoir. For the long-lived zircon Lu-Hf system, no incontrovertible evidence of significant mantle depletion >3.8 Ga exists. We conduct combined U-Pb and Lu-Hf isotopic analyses for the detrital zircon from the Caozhuang supracrustal sequence in North China. The zircon Hf isotopic compositions are broadly scattered along the CHUR evolution line. However, given the possibility of potential systematic biases in zircon petrogenesis and the unique tectonic setting of early Earth, we posit that magmatism controlled by the nascent forms of plate tectonics during the Eoarchean could have likely hidden the degree of ancient crust-mantle differentiation. The non-depleted zircon Hf isotopes observed in North China and globally during early Earth may in verity imply the existence of ubiquitous depleted mantle domains at that time.

Zircon Hf–isotopic mapping of Middle–Lower Yangtze River Valley Metallogenic Belt, China: Constraints on crustal properties and ore cluster formation

The formation of endogenic mineral deposits is commonly thought to be closely related to the initiation and evolution of magmatic systems, which are controlled by deep structure and dynamic processes. The Middle–Lower Yangtze River Valley Metallogenic Belt (MLYB), a paramount metallogenic belt in eastern China, lies between the Dabie and Jiangnan orogens. Although large-scale mineralization occurred in MLYB during the Mesozoic, it is unclear why numerous metals were enriched in such a narrow region. We integrated geological, geochemical, and geochronological data (specifically zircon UPb dating and LuHf isotope data) for the Mesozoic magmatic rocks in MLYB and adjacent parts of the Dabie and Jiangnan orogens. Then, we first drew regional zircon Hf–isotope compositions and model-age maps from 259 weighted-average data values (64 new and 195 prior published) and marked 98 major deposits of MLYB on the contour maps according to their latitude and longitude.The results showed a wide range of zircon crustal Hf–isotopic model ages (TDMC) of MLYB, indicating that its basement is more likely generated by the mixing of the Jiangnan and Dongling basements. Almost all large deposits in the metallogenic belt were concentrated on these basement interfaces, indicating that the junction zone of two basements is favorable for mineralization.Almost all large Cu–Au–Mo polymetallic deposits of MLYB formed during the compression–extension transition stage from 151 to 138 Ma, and zircon Hf–isotope compositions of related high-K Calc–alkali intrusions evolved from high to low. During 137–126 Ma, numerous magnetite deposits formed, and the amount of Cu–Au–Mo polymetallic deposits rapidly decreased. The zircon Hf–isotope compositions of magmatic rocks in this stage evolved from low to high. The concentration of S and Cu–(Au) in the mother magma might be diluted by a large amount of crustal materials, and the Cu content in the magma was significantly reduced by magnetite formation.There was a wide range of Hf–isotope compositions in Mesozoic high-K calc–alkaline series and shoshonite series magmatic rocks, which are closely related to MLYB mineralization, and almost all Cu–Au–Mo deposits and magnetite–apatite deposits were developed in the εHf(t) isotopic boundary. Therefore, magma mixing played a key role in the formation of deposits in MLYB.The Mesozoic magmatism and mineralization of MLYB migrated from Edongnan to Jiurui ore clusters northeastern with time (151–105 Ma). This phenomenon was related to the rollback of the subducting Paleo–Pacific slab in the Late Jurassic and Early Cretaceous, which led to the earlier heating of the lithospheric mantle base in the southwest than in the northeast when the metasomatic mantle source partially melted.Hf–isotope mapping showed spatiotemporal relationships among crustal structure, crust–mantle interaction, and ore cluster formation process, thereby demonstrating that the structure, nature, and composition of the crust control the location of ore deposits and the migration of ore-forming metals within the terrane.

Geochronology and geochemistry of Middle Permian tuff in Chaohu region, China: Implications for their origin and geological significance

Tuff of Middle Permian as a record of volcanic activity are widely distributed in the northern hemisphere, such as South China, but origin of the tuff bed remains unclear. Stratigraphy, geochronology, geochemistry, and zircon Hf isotopic composition of the tuff layers from Gufeng Formation in Chaohu region, South China, are systemically investigated to reveal the origin of the tuff. The stratigraphical investigation and geochronological dating reveal that zircon U–Pb age of 271.6 ± 3.1 Ma for lower tuff layer is identical to the formation age (272 Ma) of the bottom boundary in the Gufeng Formation, while the zircon U–Pb age of 263.6 ± 3.8 Ma for upper tuff layer represents the boundary age between the lower and upper Gufeng Formation. The tuff with a lot of clastic materials has high Th/Ce (0.18–0.84) and Th/La (0.29–1.23) ratios, enrichment in LREE, Th, U and Hf, and depletion in Ba, Nb and Sr, with obviously negative Eu anomalies (δEu = 0.41–0.58). Compared with the lower tuff layer, the upper tuff layer has higher zircon εHf (t) values (−5.65 to 10.2) and lg fO2 values (−14.6 to −7.42). The distinctly chemical and isotopic results indicate that the intermediate-felsic tuff in the Chaohu region were originated from more crustal materials in early stage of the Gufeng Formation and increased juvenile crustal materials and higher oxygen fugacity in late stage of the Gufeng Formation.

Origin of K-bentonites in the Doushantuo cap dolostones from South China and its potential link with the sedimentary model of the Marinoan cap dolostones

A study of the K-bentonites in the Doushantuo cap dolostones on the Yangtze Platform in South China would facilitate understanding the origin of the Marinoan cap dolostones and testing the snowball Earth hypothesis. To date, sporadic work has been conducted on the whole-rock geochemistry of the K-bentonites from the platform and slope of the Yangtze Platform, to preliminarily understand the genesis of the K-bentonites. However, a study of the whole-rock geochemistry of the K-bentonites from the basin and on zircon geochemistry of the K-bentonites from the entire Yangtze Platform has not been carried out. Therefore, the nature of the primary magmas, source and tectonic setting of the source volcanoes, and the episodes of source volcanic eruptions of the K-bentonites are unknown, which hinders unraveling the possible link between the sedimentary model of the Marinoan cap dolostone and the K-bentonites. Here, we perform a systematic study of the whole-rock and zircon geochemistry of the K-bentonites. The major and trace element concentrations of the K-bentonites and trace element contents in their volcanic zircons suggest that the primary magmas of the K-bentonites from the Jiuqunao and Heyu sections are different in nature. The same geochemical results indicate that the source volcanoes of all the K-bentonites may occur in the extensional setting on the northern margin of the Yangtze Block. Hf isotopic compositions of the volcanic zircons in the K-bentonites imply that the source magmas of the K-bentonites are mainly mantle-derived, and may have mixed with the crustal materials from the northern margin of the Yangtze Block. Based on the difference in whole-rock and zircon geochemistry of the K-bentonites from Heyu and Jiuqunao, two episodes of the source volcanic eruptions of the K-bentonites could be identified. The K-bentonite at Heyu most probably represents the record of the old episode, while that at Jiuqunao represents the record of the young one. The here proposed dual episodic deposition of K-bentonites within the Doushantuo cap carbonates holds potential significance to constrain 1) the duration of the cap carbonate deposition and 2) their genesis in potential slushball or snowball Earth environments.

Controls on the formation of porphyry Mo deposits: Insights from porphyry (-skarn) Mo deposits in northeastern China

AbstractPorphyry Mo deposits have traditionally been classified into two major classes, arc-related and Climax-type, based on the tectonic setting and chemistry of associated intrusions. Although there is a consensus that porphyry Mo systems were formed by the optimal coincidence of geological processes operating at different scales, it is unclear what key parameter(s) render systems productive and whether the two classes of porphyry Mo deposits are unique in their mode of formation, or if they share fundamentally similar geological processes. These questions are important as a clearer understanding of the optimum conditions for the formation of porphyry Mo deposits is a prerequisite for more efficient exploration.This contribution presents a detailed assessment of the factors affecting the formation of porphyry Mo deposits through the investigation of barren and mineralized intrusions from the arc-related Songbei-Yangjiazhangzi-Lanjiagou (SYL) ore zone and the Climax-type Hashitu deposit of northeastern China. Our results show that the syn-mineralization intrusions from the SYL ore zone are quite evolved (SiO2 ~ 75 wt%; Na2O+K2O ~ 8.7 wt%) and are characterized by apparent light rare earth element (LREE) enrichments (LaN/YbN = 2.7–33.1) and moderate negative Eu anomalies (Eu/Eu* = 0.4–0.7). They show enriched zircon Hf isotopic compositions [εHf(t) = –11.9 to –4.8], indicating their parental magmas were likely derived from an ancient crustal source. Melt inclusions from the SYL syn-mineralization intrusions contain negligible F and Cl. In contrast, Hashitu syn-mineralization intrusions are characterized by weak LREE enrichments (LaN/YbN = 2.2–6.9) and strong negative Eu anomalies (Eu/Eu* = 0.02–0.10), with SiO2 and Na2O+K2O contents similar to the SYL syn-mineralization intrusions. They show depleted zircon Hf isotopic compositions [εHf(t) = 3.1–5.0], indicating their parental magmas were likely derived from a juvenile crustal source. Melt inclusions from the Hashitu syn-mineralization intrusions contain up to 0.4 wt% F and 0.03 to 0.09 wt% Cl. However, in both cases, the syn-mineralization intrusions are Mo-poor (1–7 ppm Mo), oxidized (above the quartz-fayalite-magnetite buffer), water-saturated (4.4–7.8 wt% H2O), and were emplaced at palaeodepths of 3.3 to 8.3 km. These data imply that magma source composition is not a key factor in the formation of porphyry Mo deposits. In contrast, magma oxygen fugacity, water content, and emplacement depth appear to play fundamental roles in the formation of porphyry Mo deposits of both arc-related and Climax-type.Within individual deposits, no systematic differences between pre- and syn-mineralization intrusions are observed in terms of magma source, fractionation degree, oxygen fugacity, emplacement depth, and volatile and Mo contents. Instead, a crucial apparent difference lies in the geometry of the intrusions, i.e., pre-mineralization intrusions generally occur as flat, ponded bodies, whereas syn-mineralization intrusions commonly develop as small stocks or dikes. Our results, in combination with an examination of other porphyry Mo systems, suggest that the sudden depressurization of magma chambers and subsequent venting of voluminous fluids along focusing structures (such as small stocks or dikes) most likely plays a critical role in the formation of porphyry Mo deposits of both arc-related and Climax-type. The findings of this study indicate that fluid processes in the shallow crust are pivotal for the formation of porphyry Mo deposits and that settings with ideal magmatic-hydrothermal architectures are most likely to develop into productive porphyry Mo systems.

Late Eocene Two-Pyroxene Trachydacites from the Southern Qiangtang Terrane, Central Tibetan Plateau: High-Temperature Melting of Overthickened and Dehydrated Lower Crust

AbstractOrthopyroxene-bearing granitic rock (e.g. charnockite) is relatively rare but provides an excellent opportunity to probe the thermal and tectonic evolution of deep orogenic crust because of its distinct mineral assemblage. Here we present petrological, mineralogical, elemental, and Sr–Nd–Hf–O isotopic data for late Eocene (ca. 36 Ma; zircon U–Pb ages) volcanic rocks exposed in the Ejiu region in the southern Qiangtang Terrane to investigate how the central Tibetan crust evolved to its modern thickness and thermal state. The Ejiu volcanic rocks (EVRs) are trachydacites with anhydrous mineral assemblages (i.e. two pyroxenes, sanidine, plagioclase, and ilmenite, without amphibole and biotite) and geochemical characteristics (e.g. high P2O5 and TiO2) that resemble those of charnockite-type magmatic rocks. Mineral and whole-rock thermometry and hygrometry suggests that the parent magma crystallized under hot (~1000°C) and dry (H2O < 2 wt.%) condition. Besides, the EVRs display adakitic affinities according to their high SiO2 and Al2O3 contents, high Sr/Y, La/Yb, and Gd/Yb ratios, and low Y and Yb contents, without marked negative Eu anomalies. The calculated melts in equilibrium with pyroxenes also display adakitic compositions (e.g. high Sr/Y and La/Yb ratios), indicating that the adakitic compositions of the EVRs did not result from late-stage magmatic evolution. In addition, the melts of the EVRs were saturated in TiO2, as inferred from the high TiO2 contents of these rocks and the presence of ilmenite. An integrated analysis of the geochemical, petrological, and mineralogical data suggests that the EVRs were neither evolutional products nor partial melts of hydrous mafic materials at normal crustal pressures, but were formed by fusion of an eclogitized mafic protolith with residue containing garnet and rutile but lacking amphibole and plagioclase. The whole-rock Sr–Nd and zircon Hf isotope compositions of the EVRs [(87Sr/86Sr)i = 0.7053 to 0.7066; εNd(t) = −1.40 to −0.99; zircon εHf(t) = +1.08 to +5.31] indicate that the parental protolith was relatively juvenile in nature, but also contained some supracrustal materials given the high zircon δ18O values [zircon δ18O = +8.21‰ to +11.00‰]. The above arguments lead us to propose that of partial melting of a previously dehydrated—but chemically undepleted—mafic lower continental crust at high pressure (>1.5 GPa) and high temperature (>1000°C) generated the EVRs. Based on a synthesis of independent geological and geophysical data, we further suggest that the southern Qiangtang Terrane crust of the central Tibetan Plateau was thick, dry, and elevated during the Late Cretaceous to early Eocene time, and that it became abnormally hot owing to the ascending asthenosphere after lithospheric foundering during the middle Eocene.

Exploring volcanic-intrusive connections and chemical differentiation of high silica magmas in the Early Cretaceous Yanbei caldera complex hosting a giant tin deposit, Southeast China

Study of the origin and chemical differentiation of silicic magmas can provide important insights into crustal evolution and rare metal metallogeny. Tin mineralization always tends to form in relatively reduced, highly fractionated granite systems. Recognition of distinctions between fertile and barren magmas is of enormous benefit to mineral exploration. The Yanbei caldera complex (YCC), is a typical inland volcanic-intrusive complex that also hosts a giant porphyry-type tin ore deposit in Southeast China. To study the origin and chemical differentiation of the YCC and constrain its relationship with tin mineralization, a comprehensive petrological, whole-rock major and trace element geochemical data, along with zircon UPb ages, trace element and Hf isotopic data of the Yanbei caldera complex (YCC) and the Xiaoji granite (XG) near the YCC are carried out. LA-ICP-MS zircon UPb dating indicates that the generation and evolution of the YCC and the XG took place in a short time (4 M.y.) of between 142.4 and 138.4 Ma. Distinct zircon Hf isotopic compositions of the volcanic and intrusive units from the YCC suggest that they were derived from different magma sources. The volcanic rocks and the XG have consistent and low zircon Hf isotopic compositions (εHf(t) = −14.9 ~ −9.0), implying that they were almost exclusively derived from melting of Paleoproterozoic crustal rocks. But the magma source of the intrusive units (the granite porphyry, GP and the biotite granite, BG) (εHf(t) = −6.0 ~ −0.8) contains a significant mantle-derived component input. The whole-rock and zircon compositions suggest that the compositionally zoned volcano of the YCC can be interpreted in terms of the “crystal mush model”. The rhyolite has the geochemical characteristics of highly evolved magmas which undergo crystal fractionation, while the dacite displays a complementary geochemical signature implying that it represents the residual crystal mush after extraction of the rhyolitic melts. The XG displays similar chronological, compositional, and isotopic features to the rhyolite, suggesting that it is the intrusive equivalent of the rhyolite. The intrusive units (GP and BG) of the YCC are highly-evolved granites with elevated tin contents, responsible for tin mineralization. By comparison of fertile and barren systems in the YCC, we suggest that simple crystal fractionation for the high-evolved/extracted granitic melt does not necessarily lead to tin mineralization. A tin-bearing and volatile-rich melt originated under high-temperature partial melting of crustal source induced by underplating/input of a hot mantle magma is an essential precondition for some magmatic-hydrothermal tin mineralization systems.

Evidence for continental rifting from two episodes of mid-Neoproterozoic silicic magmatism in the northeastern Yangtze Block, China

Mid-Neoproterozoic (850–720 Ma) magmatism around the periphery of the Yangtze Block records an intense extensional event related to the breakup of Rodinia. However, the detailed geodynamic mechanisms of this extensional tectonism are still poorly constrained. To address this issue, we undertook a whole-rock geochemical and Sr–Nd isotopic, and zircon U–Pb–Hf–O isotopic study of mid-Neoproterozoic silicic meta-igneous rocks from the Feidong Complex and Zhangbaling Group in the northeastern Yangtze Block. These rocks can be classified into two groups: Group A (granitoids) and Group B (volcanic rocks). Zircon U–Pb dating revealed that Group A (808–786 Ma) pre-dates Group B (762–750 Ma). All these rocks are characterized by A-type granite features, with high heavy REE, Zr, and Hf contents, (K2O + Na2O)/CaO ratios, Fe index values, and zircon saturation temperatures, and formed during a mid-Neoproterozoic extensional event. However, the extremely enriched whole-rock Sr–Nd and zircon Hf isotopic compositions (ISr = 0.7024–0.7068, εNd(t) = −19.3 to −14.1, and εHf(t) = −25.7 to −11.8) of Group A suggest derivation by reworking of ancient crustal basement. Group B is characterized by relatively depleted Sr–Nd–Hf isotopic compositions (ISr = 0.7015–0.7063, εNd(t) = −1.6 to +3.6, and εHf(t) = −4.8 to +4.1), indicating a significant contribution from juvenile-crust-derived material. Group A contains zircons with δ18O = 4.1‰–7.1‰, whereas Group B contains zircons with δ18O = 1.6‰–3.1‰. These chemical and isotopic data, along with the gradual change in residual mineralogy from garnet to plagioclase (Group A to B), indicate that magmatism transitioned from an ancient lower crustal source to a juvenile middle–upper crustal source that had experienced intense high-temperature meteoric water–rock interactions. Our results provide new insights into the tectonic evolution from early extension to peak rifting driven by upwelling asthenosphere, due to rifting of the Yangtze Block from Rodinia during the mid-Neoproterozoic.

The coupled Hf-Nd isotope record of the early Earth in the Pilbara Craton

Initial Hf and Nd isotope compositions of Earth's oldest rocks provide essential information on the differentiation of the Earth into enriched crustal and depleted mantle reservoirs in its early history. The majority of Eo-Paleoarchean rocks worldwide, however, have isotope compositions that appear to be decoupled: initial Hf isotope compositions, determined on zircon, are broadly chondritic with little variation; initial Nd isotopes on bulk rocks, in contrast are highly variable with both supra- and sub-chondritic compositions. Most of these studies are from polymetamorphic terranes where the potential for disturbance of the isotope system is high. This is particularly true for the Sm-Nd system where more easily altered REE-rich accessory phases are the major repositories for these elements.In order to better understand crust-mantle evolution during the Archean—and to address the issue of Hf and Nd isotope decoupling—we examine a suite of well-preserved Paleoarchean granites from the Pilbara Craton. Our approach integrates the initial Hf isotope composition and U-Pb ages of zircon, the initial Nd isotope compositions of titanite and apatite, and U-Pb ages of titanite by laser ablation split stream (LASS) analysis. The zircon and titanite U-Pb data yield crystallization ages of 3.47 to 3.28 Ga, in good agreement with the combined apatite-titanite-WR Sm-Nd isochron ages of each sample, demonstrating that both the U-Pb and Sm-Nd systems have not been modified since igneous crystallization. The initial Hf isotope compositions of zircon from all samples are broadly chondritic with εHf(i) values of −0.3 to +0.8, in agreement with the bulk-rock Hf. The initial Nd isotope compositions of the titanite and apatite are also broadly chondritic (εNd(i) titanite, −1.0 – +2.0; apatite, −0.6 – +0.9) and agree with the Nd isotope composition of the bulk-rock (εNd(i) = +0.2 to +1.2) and the initial 143Nd/144Nd ratios determined from the titanite-apatite-WR isochrons (εNd(i) −0.9 to +1.3).From these data, we make two fundamental observations. First, the granites in this study were derived from a source that was chondritic with respect to both Hf and Nd isotopes from 3.47 to 3.28 Ga; neither system supports the presence of either a strongly depleted mantle or enriched crustal source. Second, the Lu-Hf and Sm-Nd isotope systems in the Pilbara samples are in full agreement. This stands in stark contrast to the record of rocks from Eo-Paleoarchean terranes of higher metamorphic grade, where the Hf and Nd isotope compositions have been “decoupled”. This further underscores the importance of recognizing potential effects of high-grade metamorphism on the Sm-Nd bulk-rock record. The integrated age-isotope approach taken here illustrates a way to assess the integrity of bulk-rock Nd isotope data through examination of the Sm-Nd isotope systematics of the LREE-rich accessory minerals in rocks.

Late Carboniferous – Early Permian mafic dikes and granitoids in the heart of the Western Tianshan Orogen, NW China: Implications for a tectonic transition from a syn- to post-collisional setting

Syn- to post-collisional magmatism in the Chinese western Tianshan Orogen is recorded in the Late Carboniferous to Early Permian magmatic rocks of the Awulale Mountains. However, the orogen's tectono-magmatic evolution remains controversial. In particular, two contrasting genetic models have been proposed, i.e., post-collisional extension vs. mantle plume. Here, we report zircon U-Pb ages, whole-rock geochemical data and Nd-Hf isotopic data from the mafic dikes and granitoids of the western Awulale Mountains. These data better constrain the rock's petrogenesis and geodynamic processes following the amalgamation of the Tianshan Orogen. In combination with previous data, we have identified two magmatic episodes in the Awulale Mountains. The Late Carboniferous (ca. 319–307 Ma) episode emplaced the mafic gabbro dikes and intermediate-acidic granitoids with I-type and adakitic affinity. The latest Carboniferous-Permian (ca. 302–286 Ma) episode emplaced bimodal intrusions containing mafic diabase dikes, acidic adakite and I- and A-type granites. Mafic dikes and granitoids of both episodes show depleted whole-rock Nd and zircon Hf isotopic compositions (εNd(t): +2.21 ~ +7.54, εHf(t): +6.48 ~ +15.97), indicating a juvenile magmatic source. However, the mafic dikes have variable geochemical features that clearly suggest their derivation from two distinct mantle sources during the two magmatic episodes. The earlier gabbro dikes have lower Th/Yb (0.08–0.12) and Zr/Yb ratios (15.32–25.45) that resemble a normal mid-ocean ridge basalt (N-MORB) from a depleted mantle source. In contrast, the later diabase dikes show enrichment in the light rare earth elements (LREE) with relatively higher Th/Yb (0.22–0.86) and Zr/Yb ratios (38.05–68.97) that are similar to an enriched mid-ocean ridge basalt (E-MORB) mantle source. Also, the Nb/Ta ratios from the earlier adakitic granitoids (21.26–23.28) differ markedly from the later acidic adakites (0.41–19.50), which implies the transition from a thicker to a thinner crust. Integrating our results with the previous geological records, leads us to propose a two-stage tectonic model for the Chinese western Tianshan Orogen's transition from syn- to post-collision. The Late Carboniferous stage of magmatism was triggered by the break-off of the North Tianshan Oceanic slab as the Yili Block and Junggar Terrane collided. The subsequent latest Carboniferous-Permian stage followed the switch to a post-collisional setting with delamination of the thickened lower crust and the intrusion of voluminous lithospheric mantle-induced bimodal magmatism.

Provenance of the Middle Jurassic-Cretaceous sedimentary rocks of the Arequipa Basin (South Peru) and implications for the geodynamic evolution of the Central Andes

The provenance of Middle Jurassic-Cretaceous sedimentary rocks deposited in the southern Peruvian Arequipa Basin has been investigated based on the measurement of 41 Sr-Sm-Nd isotopic compositions of sedimentary rocks, 993 U-Pb zircons ages, and 202 Lu-Hf zircon isotope data. The Middle Jurassic units are dominated by Brazilian/Pampean and Grenville/Sunsas and have juvenile to evolved Hf isotopic compositions of Permian zircons. These are consistent with an Eastern Cordillera (EC) provenance. In contrast, the Late Jurassic Labra Formation presents the first appearance of Triassic-Jurassic zircons and an increase in Famatinian zircons thus suggesting a mixed provenance from the EC and/or Altiplano and the Coastal Cordillera (CC). The Gramadal Formation shows older U-Pb zircon ages, which reflect a major contribution from Precambrian sources either from the Amazon craton or the EC thus implying a change in provenance. Another change in provenance is documented for the Hualhuani Formation with sources located both in the CC and EC. Finally, the Santonian Chilcane Formation is characterized by a large contribution of Cretaceous to Famatinian zircons indicating that it was mainly sourced from the CC. Our provenance dataset associated with the depositional setting of the Middle Jurassic to Early Cretaceous formations and the cumulative curves of zircon age distribution, indicate that the Arequipa Basin was not a back-arc setting but rather a rift-like setting. Contrary to the older formations, the Chilcane Formation is dominated by contributions from the CC in a retroarc foreland basin setting. This statement further implies that the Andean basin located eastward of the volcanic arc had evolved directly from a rift to a retroarc foreland basin and implies that the control of Andean subduction on these basins might be much younger than previously thought.

Petrogenesis of the Early Paleozoic S-type granites in southern Alxa, Northwest China and its implications on fluid flourishing in the middle and lower crust

Fluids play a key role in the partial melting of crustal materials which leads to the formation of the andesitic continental crust. However, the origin of the aqueous fluid in the lower and middle crust remains unclear. Here, we present three early Paleozoic S-type granites of the Yabulai Mountain in southern Alxa in an attempt to clarify the origin of the fluid and its implications for the geodynamic processes of the Late Silurian to Early Devonian. The coarse-grained two-mica granite and fine-grained two-mica granite formed during 423–417 Ma, whereas the muscovite granite was relatively younger (408 Ma). The fine-grained two-mica granites contain high SiO2 (72.56–75.77 wt%) and are metaluminous to weakly peraluminous (A/CNK = 0.97–1.07), while the coarse-grained two-mica granites contain comparable SiO2 (72.18–74.56 wt%) and are strongly peraluminous (A/CNK = 1.10–1.16). The muscovite granites (SiO2 = 72.50–76.04 wt%) are different from the two-mica granites in having higher Na2O (3.38–4.58 wt%) and lower K2O (3.70–4.90 wt%) with higher Na2O/K2O ratios (0.71–1.24). In addition, they have higher Ba (1071–2152 ppm) and Sr (640–801 ppm) contents and lower Rb (66.7–107 ppm) and U (0.23–0.74 ppm) contents and lower Rb/Sr (0.09–0.17) ratios and higher Eu/Eu* (0.95–3.92) ratios than those of the two-mica granites. These geochemical features imply that the two-mica granites were derived from fluid-absent partial melting and the muscovite granites were formed by fluid-present partial melting and their magma sources were plagioclase-rich metapsammite. The whole-rock Sr–Nd and zircon Hf isotopic compositions suggest that the metapsammite sources originated from parts of the Mesoproterozoic basement in the Alxa block. It is proposed that a tectonic shift from southward advancing to northward retreating of the Paleo-Asian slab subduction took place during 423 to 397 Ma and this caused a progressive back-arc extension in southern Alxa. Such a tectonic transformation may promote fluids release from the mantle wedge and upward infiltration through the crustal fractures resulting in intense fluid-present melting in the back-arc setting.

Petrogenesis of the Pandao granites in the Wutai Mountains area in the North China Craton: Constraints from geochemistry, zircon U–Pb geochronology, and Hf isotopes

The Trans‐North China Orogen (TNCO) is a part of the North China Craton (NCC) and together provides a classic example of lithospheric destruction. The Pandao granites outcropping in the Wutai Mountains area provide a window to investigate the Mesozoic magmatism in the TNCO. Here, this paper presents the new zircon geochronology, whole‐rock geochemistry, and zircon Hf isotope data for the Pandao granites to discuss their petrogenesis and tectonic implications. The Pandao granites are mainly composed of light‐red medium‐ to coarse‐grained biotite granite and light‐grey fine‐ to medium‐grained biotite granite. Zircon U–Pb ages of 110.05 ± 0.67 Ma and 108.35 ± 0.81 Ma suggest that the Pandao granites were crystallized in the Early Cretaceous. The Pandao granites are classified as high‐K calc‐alkaline and weak peraluminous series. The rocks display abundance in large‐ion lithophile elements (LILE) and light rare‐earth elements (LREE) but show depletion in high‐field‐strength elements (HFSE) and heavy rare‐earth elements (HREE), with strong negative Eu anomalies. The classification diagrams indicate that the Pandao granites are A‐type granites and thus belong to the A1 subtype, formed in an intraplate extensional environment. The Pandao granites have homogeneous zircon Hf isotopic compositions. Their zircons have negative εHf(t) values (−19.1 to −17.1) and old Hf isotope crustal model ages (2,250–2,375 Ma), suggesting that the Pandao granites were formed by partial melting of the Paleoproterozoic lower crustal material. Therefore, it is suggested that the Pandao granites were formed under an intraplate extensional tectonic environment of remote effect due to the ancient Pacific Plate subduction and retreat beneath the Eurasian continent. The TNCO was influenced by the subduction and retreat of the ancient Pacific Plate in the late Early Cretaceous.

U-Pb ages and Hf isotopic compositions of detrital zircons from the Seochangni Formation of the northeastern Okcheon Metamorphic Belt: Implications to the crustal evolution of the Sino-Korean craton since Paleoproterozoic

The age-unknown Seochangni Formation is distributed in the northeastern part of the Okcheon Metamorphic Belt in central South Korea. It unconformably overlies the Paleoproterozoic Busan gneiss complex exposed as a small dome and is in contact with the Cambrian-Ordovician Joseon Supergroup of the Taebaeksan Basin to the east. We separated detrital zircons from the quartzite units of the Seochangni Formation and used SHRIMP and LA-MC-ICPMS to determine their UPb ages and Hf isotopic compositions. The UPb age distribution of the detrital zircons is divided into two types. In the main type, the ages of Late Paleoproterozoic to Mesoproterozoic are dominant, whereas they have little or no older age components of about 1.87Ga and 2.5Ga, which are characteristic of the Korean peninsula basement rocks. However, the minor type has age components of 0.75 Ga and 1.87 Ga. Age patterns similar to the former type have recently been reported in the western region of the Gyeonggi Massif on the Korean peninsula, as well as in the Sangwon System in North Korea and the southern margin of North China Craton. It suggests a correlation between them and a common crustal evolution within a single craton linked since the Paleoproterozoic. The high positive εHf(t) values of detrital zircons in the Late Paleoproterozoic to Mesoproterozoic period indicate an enhanced input of juvenile materials from the depleted mantle, reflecting the igneous activity associated with the breakup of the supercontinent Columbia.

Multistage Fractional Crystallization in the Continental Arc Magmatic System: Constraints from the Appinites in Tengchong Block, Southeastern Extension of Tibet

Abstract The petrogenesis and evolution process of continental arc magmatism provide insight into discovering the formation and differentiation of continental crust. Therefore, the geochemical, isotopic, and mineralogical analyses were conducted for coeval continental arc igneous rocks in the Tengchong Block to clarify their evolution process in the continental arc magmatic systems. The Middle Triassic appinites in the Tengchong Block, southeastern extension of Tibet, were generated at the subduction setting with zircon U-Pb age of ca. 243 Ma. The Nb/Yb, Zr/Yb, and Ta/Yb ratios along with depleted zircon Hf isotopic compositions indicate a source with an N-MORB affinity for the appinites. However, relatively enriched whole-rock Sr-Nd isotopic compositions with the characteristic of high Sr/Nd, Ba/Th, Th/La, and Th/Nd ratios suggest the source was metasomatized by ~2% subducted sediment-derived fluid. According to the REE ratios modeling, the primary magma of Nabang appinites was due to 5-10% partial melting of such metasomatized mantle source. The appinites are characterized by variable compositions, such as SiO2 contents of 47.82-61.74 wt.% and MgO of 10.61-2.61 wt.%, which resulted from the polybaric and multistage fractional crystallization of a slightly hydrous primary magma in a thick crust. At lower crustal pressures, clinopyroxene was the main fractionating phase, and at middle crustal pressures, amphibole+magnetite were the dominant fractionating phases; predominant plagioclase fractionation occurred at the magma emplacement level. This process could be an effective mechanism to induce the differentiation of continental crust. The fractionation of clinopyroxene and amphibole, accompanied by suppressing plagioclase at lower-middle crustal pressures, induces the high alumina in the evolved melt and forms high-alumina basaltic to andesitic magma.

Crustal architecture studies in the Iranian Cadomian arc: Insights into source, timing and metallogeny

The Jalal Abad magmatic rocks, situated at the southern edge of the Saghand-Bafgh-Zarand district, include a thick pile of Cadomian extrusive and pyroclastic units intruded by younger granitoid stocks. New zircon U–Pb ages show eruptions at ∼552 Ma, followed by emplacement of granodiorite at ∼537 Ma. The Jalal Abad magmatic rocks have typical high-K and shoshonitic signatures, and are characterized by enrichment in large-ion lithophile elements (LILEs) and depletion in high-field-strength elements (HFSE). Zircon ɛHf(t) from the Jalal Abad magmatic rocks ranges from +3.9 to −3.9 for volcanic rocks and −1.2 to +8.1 for granodiorite. Zircon δ18O values for the Jalal Abad are variable from +5.1 to +8.8‰, progressively higher than those of mantle-derived melts. The whole-rock ɛNd(t) values range between −7.7 to −7.4 for granodiorite, −4.6 to −3 for volcanic rocks and −6.2 to −8.2 for ignimbrites/tuff. The whole-rock Nd and zircon Hf crustal model ages (TDMC) for the Jalal Abad magmatic rocks range between 0.8 and 2.3 Ga. All of the Jalal Abad magmatic rocks have quite similar trace element patterns, and slightly different whole-rock Nd and zircon Hf isotopic composition, indicating the involvement of the thick continental crust during the formation of these rocks. Modeling of zircon Hf–O data, bulk-rock trace elements, and Sr–Nd isotopes suggest the magmas were generated by interaction of mantle–derived melts with thick continental crust through assimilation/fractional crystallization (AFC) processes. However, crustal architecture studies in the Iranian Cadomian arcs show that AFC processes were more important during the Mesoarchean–Early Neoproterozoic (3000–1000 Ma), whereas juvenile magmas became increasingly important to the Cadomian (600–500 Ma) magmatism. Early Cambrian intrusive magmas seemingly intruded sedimentary sequences in the study region and provided magmatic constituents and a heat source for hydrothermal processes and mineralization.

Geochronology and petrogenesis of Eocene gabbros and granitic rocks of the eastern Gangdese belt, southern Tibet: Implications for the timing of India-Asia collision

The Palaeocene-Eocene (66–41 Ma) hosts the most intense stage of extensive magmatism in the Gangdese belt of southern Tibet. However, the magma sources and tectonic setting of this magmatic belt have been a matter of discussion for decades. In this study, we conducted zircon geochronological and geochemical studies on Eocene gabbroic rocks and granitic rocks from the Jiacha area in the eastern Gangdese belt. Laser ablation-ICP-MS zircon U–Pb dating suggests almost synchronous crystallization ages of 50–47 Ma for both rock types. Geochemically, the gabbroic rocks have low total rare earth elements and high positive zircon εHf(t) values (from +8.4 to +15.0), indicating that the parental magma was derived from an isotopically depleted mantle. The granitic rocks are magnesian calc-alkalic to calcic granites that are characterized by variable zircon εHf(t) values (from +3.0 to +10.8), indicating that the magmas were generated by differentiation of a mantle-derived magma with variable contributions from ancient crustal materials. Furthermore, an enlarged database of 66–41 Ma plutonic rocks and coexisting Linzizong volcanic rocks reveals an evolutionary trend from mafic to silicic rocks. The zircon Hf and Nd isotopic compositions become more evolved with increasing whole-rock SiO2. The whole-rock and isotope geochemistry of the 66–41 Ma plutonic rocks and the Linzizong volcanic rocks indicate an origin and evolution of these rocks in an active continental margin setting. Therefore, we argue that the Gangdese belt was associated with the subduction of the Neo-Tethyan Oceanic plate throughout the Early Eocene, thereby implying that the initial India-Asia collision occurred after ~ 41 Ma.

Diversity of granitic rocks constrained by disequilibrium melting and subsequent incremental emplacement and differentiation

Compositional diversity is a fundamental feature of Earth's granitoids and it has been prevailing on Earth since the early Archean. Although the exotic mechanisms, like magma mixing, crustal assimilation and contamination, could place constraints on the diversity, the compositional diversity of common huge batholiths in the field require intrinsic mechanisms running in the magma itself. This paper highlights the detailed processes from melting of a given source to subsequent incremental emplacement and differentiation control the diversity of granitic rocks as we observed on the Earth's surface. The diversity is firstly introduced from the significant heterogeneity of crustal rocks (in minerals and geochemistry) and the melting behaviors (congruent or incongruent melting), by which disequilibrium melting of crustal rocks could generate heterogeneous radiogenic isotopes. At the second stage, such heterogeneity inherited from source and melting behaviors in different melt batches can be reconciled to some extents during the incremental emplacement of melt batches, self-mixing and differentiation in magma chambers, which represent a homogenization process in magma system. The homogenization extent depends on temperature, residence time and other parameters of granitic melts. A large amount of published Hf isotopic data in zircon from granitic rocks provide us a way to assess the roles of disequilibrium melting and homogenization process. On the basis of the difference in zircon Hf isotope compositions and the diffusivity of Hf in granitic melts, we propose a new thermometry for granitic magmatism. Given a certain melt residence time, the compiled global Hf isotopic ratios in zircon from granitic rocks indicate that the magma temperatures of intermediate–felsic rocks decreased steadily throughout Earth's history, corresponding to the secular cooling of Earth's mantle.

Linking ocean subduction with early Paleozoic intracontinental orogeny in South China: Insights from the Xiaying complex in eastern Guangxi Province

The tectonic setting of the early Paleozoic orogeny in the South China Block (SCB) has been hotly controversial. Although most studies have ascribed it to an intracontinental orogeny, there are various views on the geodynamic drivers of the intracontinental orogeny. This study reports on the Ordovician Xiaying igneous complex in the eastern part of Guangxi province, southern South China. This complex is composed of granodiorite, monzogranite and micro-granular diorite enclosed by granodiorite. The zircon U–Pb dating suggests that these three types of rocks emplaced synchronously at around 464–442 Ma, significantly older than those S- and I-type granites (450–400 Ma) distributed in the interior of the SCB. One monzogranite collected in the border of the complex has an older age (480 Ma). The Xiaying hornblende–bearing granodiorites have low SiO2 (61.8–68.7 wt%), P2O5 (0.07–0.10 wt%), Rb/Sr (0.52–1.30) and Rb/Ba (0.13–0.34) and high Fe2O3t (3.84–5.57 wt%), MgO (1.48–2.35 wt%), CaO (2.28–4.54 wt%) and Na2O/K2O (0.90–1.91), with metaluminous to weakly peraluminous features (most A/CNK = 0.87–1.07), showing typical I-type granitoid characteristics. The Nd–Hf isotopic model ages (ca 1.6–1.8 Ga) indicate that the Xiaying granodiorites were probably formed by partial melting of a late Paleoproterozoic basement in the deep crust. The micro–granular dioritic enclaves (MMEs) have similar formation ages and Nd–Hf isotopic compositions to the host granodiorites, and show geochemical evolution relation with granodiorites, suggesting that they resulted from the mixing of mafic and granodioritic magmas, which derived from a depleted mantle and a Paleoproterozoic crust, respectively. Based on their similar formation ages and zircon Hf-isotope compositions and the assimilation and fractional crystallization (AFC) modelling, it is suggested that major monzogranites were generated from the granodioritic magma through the AFC process. The rock associations and arc-related geochemical characteristics of the granodiorites and dioritic MMEs suggest that they probably formed in a subduction-related tectonic setting. Combined with the spatial distribution of the rock types and formation ages of these early Ordovician to early Devonian magmatic rocks in the SCB from southeast to northwest, it is inferred that there was an Ordovician northwestward subduction of the proto–South China Ocean occurring to the south of the SCB, which may connect with the Tam Ky–Phuoc Son Suture Zone in the eastern Indochina Block. It was the subduction of the proto–South China Ocean and subsequent collision between the southern SCB and an unknown continent that triggered early Ordovician to early Devonian intracontinental orogeny in the interior of the SCB.

On the petrogenesis of Paleoarchean continental crust: U-Pb-Hf isotope and major-trace element constraints from the Bastar Craton, India

Combined geochronological and (isotope) geochemical investigations of tonalite-trondhjemite-granodiorite (TTG) suites, which dominate Archean cratons, provide constraints on the sources and petrogenetic processes that gave rise to the Earth's early continental crust. In situ U-Pb and bulk Lu-Hf analyses of single zircon grains from TTGs of the Paleoarchean Bastar Craton in central India date the emplacement of the igneous rock suite and trace the chemical evolution of its source rocks. Complementary whole rock Lu-Hf and major and trace element data constrain the petrogenesis of the TTGs. The rocks are variably enriched in fluid mobile elements, particularly K and Pb, and are characteristically depleted in heavy rare earth elements. Calculated initial Hf isotopic compositions of zircon and whole rocks cluster around the chondritic value at ca. 3.55 to 3.45 Ga. The high precision Hf-isotope data reveal a trend of increasing radiogenic 176Hf/177Hf with age, the slope of which implies a 176Lu/177Hf = 0.02, and thus derivation from a mafic protolith. Geochemical modeling indicates that the granitoids can be directly produced by melting of a hydrous basalt in the garnet stability field, followed by minor fractional crystallization. Variations in the modal abundance of garnet suggest the source rocks melted at different depths. Rocks with moderately to strongly depleted HREE patterns require >10% garnet in the residue, consistent with derivation from a garnet-amphibolite or garnet-pyroxenite source. Modeling of the Lu-Hf systematics further highlights the important role of melting as opposed to fractional crystallization for reproducing the primary chemical characteristics of TTGs.The global Hf-isotope record of Archean mantle-derived rocks is considerably more radiogenic than that of the bulk silicate Earth, providing unambiguous evidence that parts of the mantle were significantly depleted in incompatible elements since at least the early Archean. The differences between Hf isotopic compositions of the mafic (greenstone belts) and felsic (gneissic terranes) rocks can be accounted for by crustal residence times of several 100 million years for the protoliths of the felsic magmatic suites. Consequently, TTGs integrate the geologic history of their precursor(s), complicating their isotopic record. Therefore, the near-chondritic Hf isotopic composition of TTGs is not direct evidence for their derivation from a primitive mantle, but rather a consequence of their specific petrogenesis involving an aged, mafic precursor. This relationship introduces uncertainties into models of crustal growth and geodynamics that are based on the felsic record, especially where the whole rock context is absent. In contrast, high-precision Hf-isotope analyses of single zircon grains, combined with whole rock isotope and elemental constraints, can be used to reliably identify the sources and processes involved in the generation of Earth's oldest continental crust.