Soil samples and leaves and grains of rice ( Oryza sativa), yam ( Dioscorea esculenta), cassava ( Manihot esculenta) and guinea grass ( Panicum maximum) were systematically collected in September 1992, during the rainy season from tilled/cultivated farms in Abakaliki urban, certain rural communities, and a derelict PbZn mine in Nigeria. The samples were analysed for their concentrations of the essential trace elements copper, manganese, nickel and zinc. The investigated soils consisted mostly of loamy, clay-loamy and clayey soils with mean soil pH of 5.9, and mean organic matter content of 6.7%. The phytoavailability of the trace elements generally corresponded to their soil concentrations. The phytoavailability of the trace elements investigated depended on their speciation rather than on total soil concentrations. This was illustrated by the fact that the elemental concentrations in all the plant parts decreased in the order: Mn > Zn > Cu > Ni; whereas in the soils, the order was Mn > Zn > Ni > Cu. The best indicator plant species in the studied areas were grass (Cu), yam leaves (Cu, Ni), rice leaves (Mn), rice leaves and grains (Ni), and cassava leaves (Zn).
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