ZnCl2 Research Articles

Precipitation of non-therapeutic monoclonal antibodies with polyethylene glycol and zinc chloride: challenges and remarks from precipitation to resolubilization step

Monoclonal antibodies (mAbs) have become fundamental across various sectors, with growing demands in both therapeutic and non-therapeutic applications. For the antibodies capture step, precipitation stands out as an alternative or precursor method to chromatographic techniques. However, research on unconventional precipitants, such as polyethylene glycol (PEG) and ZnCl2, for diluted non-therapeutic mAbs is still scarce. This study evaluates the potential and challenges of combining PEG 6000 kDA and ZnCl2 as precipitants to capture anti-human IgG1 mAbs from highly diluted cell culture supernatants. We established mAbs solubility curves, identified optimal conditions for batch precipitation, fine-tuned the resolubilization step and conducted a viscosity analysis for the precipitates. We achieved 100% yield and 59% purity for the redissolution step, after using a 12% PEG 6000/3 mmol L−1 ZnCl2 precipitation condition with a 1:1 dilution ratio at pH 6.0 for resolubilization. Nevertheless, results also indicate that the resolubilization step potentially leads to mAb fragmentation and that protein aggregates might impact mAb viscosity and flow behavior. In conclusion, the combination of these agents is promising for mAbs capture, however, pre-concentration techniques are advised for severely diluted systems and caution toward ZnCl2 is recommended, especially concerning the pH of the system and ZnCl2 concentration.

Immobilization of collagenase in inorganic hybrid nanoflowers with enhanced stability, proteolytic activity, and their anti-amyloid potential

Organic-inorganic hybrid nanomaterials are considered as promising immobilization matrix for enzymes owing to their markedly enhanced stability and reusability. Herein, collagenase was chosen as a model enzyme to synthesize collagenase hybrid nanoflowers (Col-hNFs). Maximum collagenase activity (155.58 μmol min−1 L−1) and encapsulation yield (90 %) were observed in presence of Zn(II) ions at 0.05 mg/mL collagenase, 120 mM zinc chloride and PBS (pH 7.5). Synthesized Col-Zn-hNFs were extensively characterized by scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD), Fourier transform infrared (FTIR), circular dichroism (CD), fluorescence spectroscopy, dynamic light scattering (DLS) and zeta potential measurements. SEM images showed flower-like morphology with average size of 5.1 μm and zeta potential of −14.3 mV. Col-Zn-hNFs demonstrated superior relative activity across wide pH and temperature ranges, presence of organic solvents and surfactants as compared to its free form. Moreover, Col-Zn-hNFs exhibited excellent shelf life stability and favorable reusability. Col-Zn-hNFs showed the ability to suppress and eradicate fully developed insulin fibrils in vitro (IC50 = 2.8 and 6.2 μg/mL, respectively). This indicates a promising inhibitory potential of Col-Zn-hNFs against insulin amyloid fibrillation. The findings suggest that the utilization of Col-Zn-hNFs as a carrier matrix holds immense potential for immobilizing collagenase with improved catalytic properties and biomedical applications.

Copper-doped zinc tartrate (Cu-ZnT) nanocrystals: Exploring their physical and antimicrobial properties

This study investigates the growth and properties of pure zinc tartrate (ZnT) and copper-doped zinc tartrate (Cu-ZnT) nanocrystals synthesized via a sol-gel technique using double-distilled water, sodium metasilicate, and tartaric acid. Controlled pH gels were prepared with the subsequent addition of zinc chloride and copper chloride solutions to facilitate nanocrystal formation. The synthesized nanocrystals were characterized using various techniques, including Energy-Dispersive X-ray analysis, Fourier Transform Infrared Spectroscopy, Thermogravimetric analysis, UV–visible-near infrared spectral analysis, X-ray diffraction (XRD), and Field Emission Scanning Electron Microscopy. EDAX confirmed the elemental composition of Zn, Cu, C, and O in the crystals. FTIR spectra revealed the presence of functional groups corresponding to water of crystallization, tartaric acid moieties, and potentially other compounds. TGA analysis indicated a two-stage decomposition process for ZnT and the formation of zinc copper oxide in Cu-ZnT. UV–vis-NIR analysis yielded a low cut-off wavelength of 285 nm for both crystals, suggesting electronic transitions below 350 nm. Both ZnT and Cu-ZnT nanocrystals are transparent in visible and near-infrared light, absorbing strongly in the ultraviolet. Copper doping enhances Cu-ZnT light absorption. While both act as insulators, Cu-ZnT exhibits significantly higher conductivity due to copper doping. XRD analysis estimated an average crystalline size of 42 nm, while FE-SEM images revealed a quasi-spherical morphology. Refractive index, extinction coefficient, and optical bandgap were further determined, highlighting the potential suitability of these nanocrystals for optoelectronic applications. Antibacterial and antifungal assays demonstrated moderate effectiveness against tested microorganisms compared to standard drugs.

Enhancing methylene blue removal: Synthesis, characterization, and performance evaluation of chemically activated carbon adsorbents

In response to the pressing environmental issue of efficiently removing methylene blue (MB) from aqueous solutions, this study introduces a novel approach utilizing activated carbon (AC) synthesized via a two-stage activation process involving zinc chloride (ZnCl2) and ammonium sulfate ((NH4)2SO4). SEM analysis confirms the development of a porous structure at distinct activation temperatures (700 °C and 260 °C), while comprehensive characterizations, including FTIR, BET, TGA, CHNOS, and XRD, provide valuable insights into the structural and chemical properties of the synthesized AC. Optimization of the activation process at the second stage using (NH4)2SO4 yields a remarkable surface area of 939.63 m2/g, crucially enhancing functional groups such as Hydroxyl (O-H) and Carbonyl (CO). The experimental design involved optimizing various parameters, including contact time (0–180 mins), initial concentration (200–500 ppm), temperature (25–55 °C), pH (4−10), and adsorbent dosage (0.4–0.65 g). Batch adsorption optimization experiments demonstrate exceptional efficiency, achieving 99.91 % MB removal and a 90.827 mg/g capacity. Furthermore, Langmuir and second-order kinetic model fitting indicate favorable adsorption behavior, supported by thermodynamic analysis revealing an endothermic process. Notably, AC exhibits excellent regenerative potential over four cycles, emerging as a promising candidate for advancing water purification practices; the modified AC achieves WHO standards for MB removal in drinking water.

Sustainable conversion of polyethylene plastic bottles into terephthalic acid, synthesis of coated MIL-101 metal–organic framework and catalytic degradation of pollutant dyes

Persistent environmental colored compounds, resistant to biodegradation, accumulate and harm eco-systems. Developing effective methods to break down these pollutants is crucial. This study introduces Ag-MIL-101 (Ag-MIL-101) as a composite and reusable catalyst that efficiently degrades specific colored organic pollutants (COPs) like Methylene blue (MB), 4-Nitrophenol (4-NP), and 4-Nitroaniline (4-NA) using sodium borohydride at room temperature. The MIL-101 was synthesized using Terephthalic acid (TPA) derived from the degradation of Polyethylene Terephthalate (PET) plastic waste, with the assistance of zinc chloride. To further investigation, the kinetics of degradation reaction was studied under optimized conditions in the presence of Ag-MIL-101 as catalyst. Our results demonstrated the remarkable efficiency of the degradation process, with over 93% degradation achieved within just 8 min. The catalyst was characterized using FTIR, XRD, FESEM, and TEM. In this study, the average particle size of Ag-MIL-101 was determined using SEM and XRD analysis. These methods allow us to accurately and precisely determine the particle size. We determined the reaction rate constants for the degradation of each COP using a pseudo first-order kinetic equation, with values of 0.585, 0.597 and 0.302 min−1 for MB, 4-NP, and 4-NA, respectively. We also evaluated the recyclability of the catalyst and found that it could be reused for up to three cycles with only a slight decrease in efficiency (10–15%). Overall, our findings highlight the promising application of Ag-MIL-101 as an effective catalyst for the degradation of COPs, emphasizing the importance of optimizing reaction conditions to achieve enhanced efficiency.

Reducing Free Fatty Acids in Crude Palm Oil Using Diethylene Glycol and Zinc(II) Chloride Based Deep Eutectic Solvent

Deep eutectic solvents (DES) were prepared by precise combinations of mol fractions of chemical compounds, resulting in a lowered melting point due to hydrogen bonding. This research aimed to elucidate the physicochemical attributes of DES and its effectiveness in mitigating free fatty acid (FFA) levels in crude palm oil (CPO). Zinc(II) chloride (ZnCl2) served as the hydrogen bond acceptor (HBA) while diethylene glycol (DEG) as the hydrogen bond donor (HBD). Characterization included freezing point, density, viscosity, conductivity, and pH determination. At a ZnCl2 mol fraction of 0.30, the resulting DES exhibited homogeneity with transparent liquid properties, featuring a freezing point below −10 °C, density of 1.42 g/mL, viscosity of 1933.40 cP, conductivity of 66.13 µS/cm, and pH 3.42. FTIR spectra confirmed hydrogen bond interactions between HBA and HBD. Applied to CPO at a 1:1 volumetric ratio (DES:CPO), with 2 h of stirring time at 50 °C, FFA content decreased from 4.11 to 0.86%. This research highlights DES as an environmentally sustainable purification agent, significantly reducing FFA levels in unrefined palm oil.

Treatment of Bamboo for Sustainable Construction Practise: A Comprehensive Review

Abstract Bamboo is a versatile and sustainable natural resource that has been used for centuries by numerous cultures. Untreated bamboo, on the other hand, has limitations in terms of durability, strength, and decay resistance, which limit its usage in specific conditions. To overcome these restrictions and realise its full potential, researchers have investigated various bamboo treatment methods. This research presents an overview of bamboo treatment methods, effects on their performance, and emphasises possible uses in a variety of construction practises. The study looks into the usage of synthetic resin and synthetic rubber as bamboo protective coatings. These coatings improve durability, water repellence, dimensional stability, mechanical strength, and fungal growth resistance. They are also simple to use and contribute to environmentally friendly practises. To protect bamboo from fungal deterioration and insect infestation, chemical substances such as boron-based additions, zinc chloride, sodium pentachloro-phenate, and copper-chrome-arsenic (CCA) are employed as preservatives. These chemicals increase the longevity of bamboo while also ensuring its structural integrity. The use of epoxy resins to improve the tensile strength of bamboo composites is also being observed. It increases flexural and compressive strength by improving adhesion between bamboo fibres and the matrix. The use of epoxy glue also retains the natural strength and durability of bamboo. Heat treatment of bamboo entails treating it to high temperatures in order to enhance its qualities such as dimensional stability, hardness, and resistance to decay and insect assault. Heat-treated bamboo is used in building, furniture, flooring, and composite materials. Understanding and implementing these treatment procedures can help to encourage the wider use of bamboo as a sustainable and environmentally friendly construction material. The findings of this study have the potential to drive decision-making, encourage innovation, and have a positive impact on the environment, society, and economy. Bamboo may be used as a viable alternative to traditional materials in a variety of sectors by exploiting its unique qualities and improving its durability and strength.

A comparative study of brine solutions as completion fluids for oil and gas fields

Completion fluids play a vital role in well-related processes within the oil extraction industry. This article presents a comprehensive study of the properties and performance of various brine solutions as completion fluids for different well and reservoir conditions. Attributes examined include density, corrosion resistance, temperature stability, compatibility with formation fluids, clay swelling potential and influence on wettability. The research highlights the significance of selecting appropriate completion fluids to optimize well and reservoir operations. Zinc chloride emerges as an excellent option for high density applications, while sodium chloride and potassium formate solutions are ideal for extreme cold conditions. Potassium acetate outperforms calcium chloride and potassium chloride and has excellent pH stability. The compatibility of completion fluids with formation water has been observed to be excellent, with no sedimentation or emulsion formation. Potassium acetate also experiences minimal clay swelling, making it suitable for clay-rich formations. On the other hand, calcium chloride has a higher clay swelling than most of the brines tested, making it less suitable for sandstone formations with a higher clay content than these brines. The research evaluates the water-wetting abilities of completion fluids in carbonate and sandstone formations. Potassium chloride and zinc chloride have the most significant impact in carbonate formations, while potassium acetate and potassium formate excel in sandstone formations. This study provides a comprehensive understanding of completion fluids, facilitating informed decisions that maximize operational efficiency, protect reservoir integrity, and enhance hydrocarbon recovery. The appropriate selection of completion fluids should align with specific well and reservoir conditions, considering the priorities of the application.

Synthesis, structural investigations, in vitro cytotoxicity, apoptotic activity, cell cycle analysis, and molecular modeling studies of nano‐sized Zn(II) Schiff base complex

A new novel tetradentate ligand, [(1E,1′E)‐N,N′‐(1,2‐phenylene)bis(1‐(5‐(2‐fluorophenyl)furan‐2‐yl)methanimine) (PFPFMI), and its nano‐sized [Zn(PFPFMI)Cl2].3H2O complex were synthesized. The geometry of PFPFMI and its Zn(II) complex was described through CHN analyses, Fourier‐transform infrared spectroscopy (FTIR), UV–visible, X‐ray diffraction (XRD), thermal gravimetric analysis (TGA), and mass spectral data tests. The spectral data of the nano‐sized [Zn(PFPFMI)Cl2].3H2O complex indicates that the PFPFMI ligand functions as a tetradentate (N2O2) coordination through two azomethine nitrogen groups (N) and two furan ring oxygen (O) atoms. Density functional theory (DFT) calculations were performed using the molecular studio software to investigate the optimal geometry of PFPFMI and its [Zn(PFPFMI)Cl2].3H2O complex. The SEM, TEM, XRD, AFM, and energy dispersive X‐ray analysis (EDX) analyses of the studied complex unveil distinct and strong diffraction peaks, indicating its crystalline nature and providing evidence of its nano‐sized particle sizes. Additionally, the inhibition zone diameter was used to assess the in vitro antimicrobial action of PFPFMI and the particular complex against Gram‐positive bacteria Streptococcus pneumonia and Bacillus subtilis, Gram‐negative bacteria Pseudomonas aeruginosa, Salmonella typhi, and Escherichia coli, as well as fungi Aspergillus fumigatus, Geotricum candidum, Syncephalastrum racemosum, and Candida tropicalis. The [Zn(PFPFMI)Cl2].3H2O complex exhibits higher activity than the ligand PFPFMI. In vitro cytotoxicity of the synthesized [Zn(PFPFMI)Cl2].3H2O complex was explored using MCF7 (breast cancer), HCT116 (colon cancer), A549 (lung cancer), HePG‐2 (liver cancer), A375 (melanoma cancer), and normal lung fibroblast (WI38) cell lines. Based on IC50 and selective index (SI) values, it was shown that the complex exhibited higher potency against MCF7 cell lines. Moreover, the Zn(II) complex exhibited the ability to induce DNA damage in MCF7 cells, resulting in dose‐dependent cell apoptosis. Subsequent investigations revealed that complex 2 also induced cell cycle arrest in the G2 and S phases.

Electrochemical Polishing Method for Titanium Alloys with a Microgroove Structure

TI–6AL–4V alloys are widely used in various fields owing to their excellent corrosion resistance, high-temperature resistance, and low-temperature toughness. Herein, a microgroove fixture was used to simulate the microgrooves in a titanium alloy with different aspect ratios to study the influence of the electrolyte flow rate on the polishing effect. The optimization of the electrochemical polishing parameters was conducted using experiments and simulations. The effects of process parameters, such as the concentration of sodium chloride (NaCl) and zinc chloride (ZnCl2), polishing time, and processing voltage, on the quality of the post-polished surface were studied. Experiments were conducted on microgrooves with different aspect ratios under the optimized polishing process parameters. Changes in the surface elements of the microgrooves after polishing were detected. The experimental results indicated that the optimal electrochemical polishing solution flow rate, NaCl concentration, ZnCl2 concentration, polishing time, and processing voltage were 0.2 m/s, 4.0 wt.%, 0.4 wt.%, 8 min, and 90 V, respectively. After 8 min of electrochemical polishing, a TiO2 passivation film was formed on the surface of the microgroove. The surface roughness of the notch and bottom of the microgroove decreased from 250 nm to below 40 nm, with a minimum of 24.5 nm.

Effect of milling atmosphere on stability and surface properties of ZnO/vermiculite hybrid nanocomposite powders

The zinc acetate dihydrate and anhydrous zinc chloride were used as precursors for the sonochemical preparation of the zinc oxide/vermiculite and organically modified zinc oxide/vermiculite_chlorhexidine nanocomposite materials. The nanocomposites were mechanically processed via a high-energy ball milling for 30 min at 300 rpm using two types of atmospheres an air or a nitrogen. Changes in temperature and pressure inside the grinding vessels were measured during mechanical processing in an air atmosphere. The ZnO(Cl)/V_30/300 sample reached the highest pressure (1161 mbar) and temperature (30.3 °C) in the milling vessels and for the ZnO(ac)/V_CH_30/300 sample the highest temperature difference was measured at the beginning and at the end of the milling (7 °C). The phase transformation, chemical composition and particle size of the hybrid nanocomposite materials were investigated using X-ray diffraction method, Fourier-transform infrared spectroscopy, X-ray fluorescence spectroscopy, carbon phase analysis and particle size distribution analysis. Changes in morphology and particle arrangement were characterised using scanning electron microscopy. The effect of mechanical processing in a protective atmosphere on surface properties such as specific surface area, surface conductivity and ζ-potential were demonstrated in relation to the type of precursor used for the preparation of ZnO nanoparticles in the structure of hybrid nanocomposite materials.

Structural, optical and morphological characterization of Zinc Selenide Nanoparticles synthesized by Solvothermal method

Zinc Selenide nanoparticles were synthesized via solvothermal method using zinc chloride and selenium powder. X-ray diffraction (XRD), Scanning Electron Microscope (SEM), Ultraviolet – Visible spectroscopy and Photoluminescence Spectroscopy were used to analyze the sample. XRD confirmed the cubic zinc blende phase and the mean size of the particle was determined using Scherrer formula was 65nm. SEM image revealed the spherical shape of the particles. Photoluminescence spectra with excitation wavelength (325nm) show a weak emission peak at 555nm. Key Words: ZnSe ,SEM, UV – Vis, XRD

Study of the process of obtaining zinc chloride from zinc-containing concentrate

The article presents data on the production of zinc chloride by autoclave leaching of zinc from zinc concentrate with hydrochloric acid. The influence of the Zn : HCl ratio on the chemical composition of the liquid and solid phases, and the degree of zinc extraction by 28 % hydrochloric acid at a process duration of 10 hours was studied. The liquid phase contains mainly zinc chloride, concentrate impurities, of which calcium, iron, copper, cadmium, and lead predominate, with the their contents of 0.181–0.314 % for calcium and 0.951–1.654 % for lead. The temperature of the leaching process in this case is 65-75°C, the pressure is 1.72 MPa. The recovery rate at these parameters is 71.22–90.10 % depending on the Zn:HCI ratio. The optimal ratio is 1 : 1.1. It has been established that the interaction of zinc concentrate occurs in the kinetic region and continues in the diffusion region, where the duration of the process has a significant effect. The reaction rate constant versus temperature obeys the Arrhenius equation and the average activation energy is 4.05 kJ/mol.

Catalytic strategies for uniform monolayer MoSe2 growth in CVD processes

To facilitate the widespread utilization of devices based on two-dimensional transition metal dichalcogenide (TMDC) materials, addressing the challenge of producing large-area and uniform monolayers is crucial. In this study, we investigated the efficacy of various catalysts in promoting the growth of monolayer MoSe2 through chemical vapor deposition (CVD) as a potential solution to improve surface coverage and uniformity while maintaining the monolayer structure. Five distinct water-soluble catalysts (sodium chloride (NaCl), zinc chloride (ZnCl2), potassium hydroxide (KOH), potassium chloride (KCl), potassium oxalate (K2C2O4)) were employed in conjunction with a glass substrate for the CVD-based growth of monolayer MoSe2. We applied these catalyst solutions as thin layers onto SiO2/Si substrates to observe their specific catalytic effects on monolayer MoSe2 formation. MoSe2 was selected as the target material due to its promising characteristics within the TMDC family, particularly its high mobility. Our findings revealed that NaCl, ZnCl2, KCl, and K2C2O4 catalysts enhanced monolayer growth in the 2H phase on SiO2/Si substrates, while the glass substrate resulted in a hybrid 1T/2H MoSe2 structure, albeit with the highest surface coverage. Furthermore, the use of a catalyst allowed us to bypass the laborious transfer step by enabling direct growth of the MoSe2 flakes on the Si/SiO2 substrate, eliminating the risk of flake damage arising from the transfer process. Among the catalyst solutions, NaCl yielded the most homogeneous MoSe2 monolayer growth with relatively high coverage.

Zinc chloride-assisted activation of açaí biomass for herbicide removal: Insights from adsorption and molecular modeling

In addressing the environmental impact of açaí pulp production waste, this study explores the sustainable transformation of Euterpe oleracea fruit pits into activated carbon using a zinc chloride (ZnCl2) activation process. The primary aim is to repurpose this agricultural by-product for the efficient removal of atrazine (ATZ) and 2,4-dichlorophenoxyacetic acid (2,4-D) herbicides from contaminated water. The produced activated carbon demonstrated superior adsorptive properties, with a specific surface area (SBET) of 920.5 m2 g-1, substantial pore volume (Vp) of 0.467 cm3 g-1, and an average pore diameter (Dp) of 1.126 nm, showcasing its potential as an effective adsorbent. Experimental adsorption tests revealed that this carbonized material could remove up to 95% of ATZ and 89% of 2,4-D under optimized conditions. Advanced techniques, including Density Functional Theory (DFT) simulations and COSMO-RS analysis, provided profound insights into the adsorption mechanisms, particularly emphasizing the crucial role of hydrogen bonding interactions. Identified as key mediators, hydrogen bonding-induced contact energy facilitated herbicide adsorption, corroborated by Electron Localization Function (ELF) analysis. These findings not only suggest a viable method for mitigating the environmental issue posed by açaí pulp waste but also contribute to the development of eco-friendly adsorbents for water purification. The research underscores the potential of using biomass waste for environmental remediation, aligning with global sustainability objectives.

Phytic acid extracted cellulose nanocrystals for designing self-healing and anti-freezing hydrogels’ flexible sensor

Phytic acid (PA), a naturally occurring organic acid, has been extensively researched in various fields such as flame retardants, electroactive materials, metal coatings and flexible sensors. This study proposes a method for extracting cellulose nanocrystals (CNCs) utilizing PA and ingeniously applies them to hydrogels, endowing the hydrogels with exceptional mechanical properties, anti-freezing capabilities and high electrical conductivity. First of all, the CNCs@PA and PA were integrated into a multi-component network consisting of hyperbranched polyethyleneimine (HPEI), polyvinyl alcohol (PVA), and zinc chloride (ZnCl2), and their complex interactions resulted in the formation of a robust three-dimensional structure. Consequently, the hydrogels formed after just a single freeze–thaw cycle exhibited exceptional mechanical properties (2.6 MPa) and a significant self-healing ability (92.3 %). Moreover, the strategic addition of PA to the hydrogels effectively immobilizes H2O, providing anti-freeze properties and enabling the hydrogels to maintain their structure and performance even at −20.0 °C. Notably, following hydrolysis, PA generates a substantial number of hydrogen ions, markedly enhancing the conductivity (2.3 S/m) and a sensitivity gauge factor (GF = 2.5) of the hydrogels. This work offers a cost-effective, eco-friendly, and scalable method for the manufacturing of nanomaterials, and opens new avenues for creating anti-freeze wearable flexible sensors.

Effect of Modified Carbon Felt Anodes on the Performance of Microbial Fuel Cell

In this paper, phosphoric acid, nitric acid, zinc chloride, ammonia and melamine are used as cheaper activators to modify the carbon felt material, exploring the changes of various activation materials on the power production performance and degradation performance of the device after MFC carbon felt anode treatment, and finding that phosphoric acid-activated carbon felt has the highest output voltage and the best degradation effect on the ship's oily wastewater as a MFC anode device.

Model-based electrolyte design for near-neutral aqueous zinc batteries with manganese-oxide cathodes

Most modern zinc-ion batteries (ZIBs) with MnO2 cathodes utilize near-neutral aqueous electrolytes based on a zinc sulfate (ZnSO4) salt. They achieve good cycling stabilities with high intrinsic safety, employ environmentally friendly materials, and deliver competitive volumetric energy densities. However, the limited solubility of zinc-sulfate species influences the performance and cycling mechanism of these cells. We examine the speciation and solubility limits of ZnSO4, zinc chloride (ZnCl2), and zinc triflate (Zn(CF3SO3)2) in aqueous solutions and simulate their intrinsic transport properties. We use our earlier developed and validated full-cell model to investigate the effects of several electrolytes on the two-phase cycling behavior. Previously, we reported that the origin of the second phase is based on an interaction mechanism between cathodic dissolution and a precipitation reaction at the cathode. We investigate this interplay between electrolyte stability and cathodic dissolution based on electrolyte choice. Our theory-based approach allows us to identify performance indicators of aqueous electrolytes and draws a consistent pathway to optimize electrolyte design for manganese-based ZIBs.

Management of toxic waste released by incorrectly discarded batteries in Brazil

Abstract The main difference between a dry cell battery and an alkaline one is the composition of the electrolyte. In zinc–carbon batteries, dry cell, the electrolyte is a paste formed by mixing ammonium chloride and zinc chloride, whereas in alkaline batteries, the electrolyte is a concentrated aqueous solution of potassium hydroxide containing a certain amount of zinc oxide, hence the name alkaline for this battery. Therefore, the improper disposal of these materials has numerous consequences for the environment, since the potentially toxic metals present in them can be leached, infiltrating, and contaminating the soil layers, the groundwater, as well as the fauna and flora of the regions nearby. Thus, the objective is to perform studies that aim to simulate and analyze the release of potentially toxic metals present in batteries found in normal environmental conditions, through leaching tests from regular batteries (Zn–C) on fertilized soil, simulating a landfill, in addition to tests on sandy soil in order to aid the identification of possible waste release.

Bleomycin‐dependent DNA damage, erythrocyte hemolysis, antitumor MTT assay, and antimicrobial activity studies for Cd (II), Mn (II), Zn (II), Cr (III), and Fe (III) complexes of a multidentate carbohydrazone ligand

Cd (II), Mn (II), Zn (II), Cr (III), and Fe (III) complexes of a carbohydrazone ligand H4EBC, prepared by the reaction of ethyl acetate and carbohydrazide, have been prepared and fully characterized. The ligand H4EBC acted as a bidentate carbohydrazone with Cd (II) and coordinated through the nitrogen of both (‐NH) and (C=N)azomethine groups, while with Mn (II) and Zn (II), it acted as a neutral NN bidentate ligand. In complexes with Fe (III) and Cr (III), H4EBC acts a bi‐negative tetra‐dentate, coordinating through the oxygen atoms of both enolized (C=O)ester groups and the nitrogen of both (C=N)azomethine groups. To illustrate the proposed geometries and chemical reactivity of the compounds, we employed DFT calculations. Additionally, thermal studies provided insights into the stability of the isolated compounds. Interestingly, the prepared complexes demonstrated emission broad bands at various wavelengths, indicating ligand to metal charge transfer. Based on the inhibition of DNA destruction, the complexes can be ranked in the following order: [Cd(H4EBC)Cl2].2H2O] (1) > H4EBC > [Mn(H4EBC)Cl2)].(H2O)2] (2) > [Zn(H4EBC)Cl2].2H2O] (3) > [Fe(H2EBC)Cl(H2O)].H2O (5) > [Cr(H2EBC)Cl (H2O)].H2O (4). Regarding erythrocyte hemolysis, the order of effectiveness can be arranged as follows: (2) > (1) > H4EBC > (5) > (3) > (4). We further investigated the compounds for their potential in antitumor activity against two cell lines and antimicrobial behavior.