Zhejiang Fujian Research Articles

Sediment resuspension and transport in the offshore subaqueous Yangtze Delta during winter storms

Storm-induced episodic sediment redistribution in coastal systems can reshape geomorphic bodies, disrupt ecosystems, and cause economic damage. However, cold-wave-storm-induced hydrodynamic changes and residual sediment transport in large, exposed subaqueous deltas, such as the Yangtze Delta, are poorly understood because it is typically expensive and difficult to obtain systematic field data in open coast settings during storm events. We conducted a successful field survey of waves, currents, changes in water depth, and turbidity at a station (time-averaged water depth of 20 m) in the offshore subaqueous Yangtze Delta over 10 days during winter, covering two storms and two fair-weather periods. During the storm events, strong northerly winds drove southward longshore currents (~0.2 m/s) and resulted in increased wave height and sediment resuspension, thereby leading to massive southward sediment transport. In contrast, both southward and northward transports were limited during the fair-weather periods. A better understanding of the storm-induced sediment transport can be obtained by using an approximately half-day lag in sediment transport behind wind force, given the time needed to form waves and longshore drift, the inertia of water motion, and the slow settling velocity of fine-grained sediment. Our results directly support previous findings of southward sediment transport from the Yangtze Delta during winter, which is deposited in the Zhejiang–Fujian mud belt in the inner shelf of the East China Sea. In addition, the southward sediment transport from the Yangtze Delta occurs mainly during episodic storm events, rather than during the winter monsoon, and winter storms dominate over typhoons in driving southward sediment transport from the delta. This study highlights the importance of storms, especially during winter storms, in coastal sediment redistribution, which is of particular significance when considering the projected increase in storm intensity with global warming.

Mechanism and genesis of Sanmen Bay as a sink of Holocene Yangtze River sediment, Zhejiang Province, China

Introduction: The Holocene mud deposits that extend from the Yangtze River mouth to the Taiwan Strait along the Zhejiang–Fujian coast, East China Sea (ECS), have attracted considerable research attention. However, there is a lack of consensus regarding the redistribution flux of Yangtze River sediment after it enters the sea. There are many bays along the Zhejiang and Fujian coasts, but their role in the source–sink process of Yangtze River sediment is not well-documented owing to limited data.Methods: In this study, data from shallow seismic profiles, core samples, and surface sediment samples were analysed to assess the role of Sanmen Bay, the second largest bay in Zhejiang Province, in the source–sink process of Yangtze River sediments.Results: The results showed that Sanmen Bay is an important sink for Yangtze River sediments. The characteristics of the clay minerals indicate that the fine-grained sediments in Sanmen Bay are mainly derived from Yangtze River sediments. The thickness of Holocene deposits in Sanmen Bay ranges from 8.2 to 32.0 m, with an average of 23.4 m and a total sediment volume of 5.06 × 104 Mt, accounting for 1% of Yangtze River sediment in this time period. The Bayesian age-depth model based on borehole accelerator mass spectrometry (AMS) 14C dating shows that a high sedimentation rate occurred in the early and late Holocene but decreased significantly in the mid-Holocene, which is similar to that of the inner shelf of the East China Sea (ECS).Conclusion: The variation in the Holocene sedimentation rate in Sanmen Bay is related to the southward transport process and mechanism of Yangtze River sediments. The results of this study provide a basis for understanding the source–sink process of sediment in large rivers.

Late Pleistocene to Holocene facies architecture and sedimentary evolution of the Zhejiang coast, East China Sea

The Holocene mud wedge that extends from the Yangtze River mouth to the Taiwan Strait along the Zhejiang–Fujian coast, East China Sea, has attracted considerable research attention; however, the pre-Holocene sedimentary evolution of the same area has been less well documented owing to limited data. We conducted an integrated analysis of 7000 km of high-resolution shallow seismic profiles and two ∼60–80-m-long borehole cores from the Zhejiang coast of eastern China to improve our understanding of the formation of the mud wedge in the context of the post-Late Pleistocene sedimentary evolution of the coastal area. Five major seismic units (numbered SU 1 to SU 5 in descending order) and various subunits that have formed since Marine Oxygen Isotope Stage (MIS) 5 were identified in the study area. SU 5 is recognizable only in the southeastern part of the study area and is interpreted to comprise subtidal to inner-shelf deposits (SU 5b) that were formed during MIS 5 and littoral to tidal-flat deposits (SU 5a) that were formed during the overall sea-level fall of MIS 4 and early MIS 3 (∼60–40 ka). These two subunits are divided by an intervening erosional surface that was likely generated by subaerial exposure of the study area during the sea-level lowstand of MIS 4. During the period from late MIS 3 to MIS 2, the study area was gradually exposed subaerially owing to further sea-level fall, with numerous small rivers incising the underlying strata to form a subaerial unconformity surface (T4). During the early postglacial transgression between ∼15.0 and ∼ 14.0 ka, the study area was progressively flooded, and the river channels were transformed into small estuaries (tidal rivers) that then coalesced into a large-scale, wave-dominated estuary during sea-level rise from ∼14.0 to ∼10.0 ka. The sandy fluvial and/or tidal-river deposits above T4 constitute SU 4. The wave-dominated estuary included a central estuarine bay on the landward side and an estuary-mouth complex on the seaward side, corresponding to fine-grained (muddy) deposits (SU 3a) and coarse-grained (sandy) deposits (SU 3b), respectively. The estuarine deposition concluded with the formation of a transgressive ravinement surface by erosional shoreface retreat during the rising sea level in the early MIS 1 from ∼13.5 ka in the southeasternmost part of the study area to ∼10.0 ka in the area closer to the shore. During the following transgressive phase, the study area was under coastal to shelf sedimentary environments during deposition of SU 2a. Tidal sand ridges (SU 2b) in the eastern part of the study area were formed at ∼11.5 ka and have been active since then. The maximum flooding surface was formed at ∼7.6 ka, and a mud wedge (SU 1) in the study area (except in the eastern part) has been developing since that time and is interpreted to have resulted from the deposition of sediments derived predominantly from the Yangtze River under the modern current system established since the maximum flooding in the Middle Holocene. The study provides new insights into the paleoenvironmental and paleogeographic evolution and facies architecture of the Zhejiang coast since MIS 5, which were controlled by preexisting geomorphological conditions and changes in sea level, hydrodynamics, and sediment supply.

Evolutions of upwelling and terrestrial organic matter input in the inner shelf of the East China Sea in the last millennium revealed by long-chain alkyl diols proxies

Long-chain alkyl diols (LCDs) can be used as organic geochemical proxies for paleoceanographic change, especially in marginal sea areas where large volumes of sediments are deposited rapidly and continuously. However, little is known about the applicability and response on a millennium scale in relation with existing records in those sediments. We reconstruct changes in upwelling and terrestrial organic matter (OM) input in core sediments from the Zhejiang Fujian coastal station (T08) and Yangtze River Estuary station (T06) in the inner shelf of the East China Sea (ECS) over the last millennium, using the LCD based proxies: diol index 2 (DI-2), and FC321,15-diol. Our results show that DI-2 values ([(C28+C30)1,14-diols]/([(C28+C30)1,13-diols]+[(C28+C30)1,14-diols])) at T08 decrease significantly during 600–400 yr BP but increase gradually after 400 yr BP. The FC321,15-diol proxy ([C321,15-diol]×100/([(C28+C30)1,13-diols]+[(C30+C32)1,15-diols])) at T06 shows marked fluctuations during 1000–800 yr BP, followed by a significant decline during 800–500 yr BP but a subsequent increase from 500 to 300 yr BP. We find that variations in DI-2 values are broadly consistent with changes in the strength of the East Asian Summer Monsoon (EASM) and the Kuroshio Current and are likely linked to changes in the frequency and intensity of the El Niño-Southern Oscillation (ENSO). The increased strength of the EASM causes greater offshore movement of the upper layer of seawater, which in turn triggers upwelling of bottom waters formed by Kuroshio subsurface waters. We find that variations in FC321,15-diol proxy are controlled mainly by the East Asian Winter Monsoon (EAWM) and the Yangtze River discharge. By increasing the strength of the EAWM, southward transportation of material deposited in the estuary of the Yangtze River by the ECS coastal currents is promoted. In addition, we synthesize records of other organic geochemical indicators nearby core sediments in the ECS; these records emphasize the importance of reconstructing the evolutionary history of upwelling and subdividing the relative inputs of terrestrial OM. Our study provides a new means for reconstructing the evolution of upwelling and terrestrial OM input in the inner shelf of the ECS over the last millennium.

Provenance Shift during the Plio-Pleistocene in the Vertex of Yangtze Delta and Its Geomorphological Implications

One of the key issues of the Source-to-Sink process is revealing the geomorphological evolutions of large rivers from the perspective of river sink areas. This study aims to reveal the provenance change near the vertex of the Yangtze delta during the late Cenozoic and provide insight into the Yangtze channelization into the sea due to regional tectonic subsidence. Heavy minerals and zircon geochronology in the Plio-Pleistocene sediments of the vertex of the modern Yangtze delta (core RGK15) reveal that a significant provenance shift occurred at ~2.6 Ma (the beginning of the Pleistocene). During the Pliocene, ultra-stable heavy minerals and pre-Mesozoic zircon grains predominated in the sediments, probably derived from contemporary outcrops of sedimentary rock that were widely distributed in the delta and its surrounding area. They are completely different from those in the Pliocene sediments of the south delta, indicating that decentralized, local, small watersheds dominated the Yangtze delta during the Pliocene. This resulted from the relatively elevated terrain of this region due to the adjacent ancient Zhejiang–Fujian Uplift (ZFU) at that time. However, diversified heavy minerals and zircon geochronology similar to those of the modern upper Yangtze fingerprints occur in the Pleistocene sediments of core RGK15, implying that a significant provenance shift to the Yangtze River occurred here at ~2.6 Ma. The provenance shift recorded by the cores in the south delta mainly occurred at ~1.2 Ma, indicating that the Yangtze River channel was dragged southward with the further subsidence of the ancient Zhejiang–Fujian Uplift. This study reveals the southward migration process of the Yangtze River channel with the regional tectonic subsidence from the perspective of provenance evolution, which contributes to an understanding of when the Yangtze River channelized into the sea.

Multiple lipid biomarkers record organic matter sources and paleoenvironmental changes in the East China Sea coast over the past 160 years

The use of lipid biomarkers as paleoenvironmental proxies relies on an accurate assessment of their organic matter (OM) sources. In this study, we analyzed multiple lipids in core sediments recovered from the Zhejiang–Fujian coastal mud area to provide a 160-year record of OM input to the East China Sea (ECS) coastal sediments and to reconstruct paleoenvironmental conditions over this interval. The molecular composition of the samples was characterized by a mixture of natural lipids, particularly those derived from terrestrial vascular plants, marine/riverine plankton and macrophytes, and bacteria. The sources of some lipid components were ambiguous/mixed as they were potentially derived from multiple precursor organisms and because of limitations associated with modern survey techniques. There is evidence that early diagenesis caused the preferential degradation of labile aquatic lipids and that the degradation of terrestrial lipids was more severe when subjected to complex horizontal–vertical transportation processes associated with deposition, resuspension, and redeposition. These processes may have led to an enhanced terrestrial OM signal in the normal ( n)-alkane and n-alkanol records, which is at odds with, for example, those of the n-fatty acids, hopanoids, steranes, and sterols, which suggest a dominant marine OM source. Furthermore, we conclude that the occurrence of multiple sources, selective diagenesis, and test error has led to the distortion of redox and maturity indicators based on evidence from pristane-to-phytane (Pr/Ph) ratios and sterane/hopane indices in century scale. Overall, the phytol record suggests an increase in productivity after the early 20th century. Correspondingly, the diatom lipid biomarker records (based on C25 highly branched isoprenoid alkenes and C18:1ω9 fatty acids) reveal a fluctuating but overall increasing diatom productivity after the early 20th century, which coincides with a decreased proportion of the contribution from diatoms relative to that of total phytoplankton. This is believed to correspond to natural environmental changes, as well as anthropogenic impact.

The M2 Cotidal Chart in the Bohai, Yellow, and East China Seas from Dynamically Constrained Interpolation

AbstractThe harmonic constants extracted from tidal gauge stations and satellite altimeter observations are usually sparsely distributed in the continental marginal seas, but they are precious data for addressing the main characteristics of different constituents. In this paper, a dynamically constrained interpolation methodology (DCIM) is developed and applied to interpolate the observed harmonic constants of the M2 constituent from satellite altimeter observations in the Bohai, Yellow, and East China Seas (BYECS) with those from tidal gauge stations for validation. In the DCIM, the tide model provides dynamical constraints to interpolate the observations, and the adjoint assimilation method provides iterative optimization for the interpolated results by adjusting key model parameters. In particular, a substantial quantity of enhanced “observations” generated from the interpolated results of the domain are further interpolated with the sparse observations in the subdomain. The final interpolated results for each subdomain, naturally blending the dynamical constraints from the dynamical model with statistical information from observations, can describe the main characteristics of the M2 constituent in the BYECS, the continental shelf sea of the East China Sea, and the Zhejiang–Fujian coastal area, respectively. The results indicate that the DCIM is feasible and effective to utilize the observations to obtain high-accuracy cotidal charts for regional ocean.

Distribution, sources and burial flux of sedimentary organic matter in the East China Sea

Distribution of total organic carbon (TOC), total nitrogen (TN), stable isotope ratio of organic carbon and nitrogen (δ13C and δ15N) in 31 surface sediments were examined to quantitatively discriminate the source and burial of sedimentary organic matter (SOM) in the East China Sea (ECS). Results show that high content of TOC and TN occurred in the southern inner shelf and the northeast area due to the transport of organic matter (OM) from the Changjiang (Yangtze) River southwards by the Zhejiang Fujian Coastal Current (ZFCC) and the delivery from the old Huanghe (Yellow) River estuary by the Subei Coastal Current (SbCC), respectively. The significant relationship of TOC to clay provided evidence that the fine-grained sediment was the primary carrier for SOM from the inner shelf to open sea. The TN varied proportionally to the TOC with the neglected intercept, suggesting that most of nitrogen measured was related to the SOM and the influence of the sorption of inorganic nitrogen was insignificant. The seaward enrichment of δ13C and seaward depletion of C/N and δ15N illustrated the decrease of terrestrial OM (TOM) and the increase of marine OM (MOM). The close of average C/N ratio to the Redfield ratio indicated the minor role of terrestrial plant debris in the SOM. Distribution of bulk OM properties was ascribed to the terrestrial and marine input by the shelf circulation and phytoplankton with the contributions of 76.1% MOM and 23.9% TOM to SOM, respectively. The burial flux of OC ranged within 0.34-7.56 mg/(cm2·a) (averaged 2.80 mg/(cm2·a)) and enriched along the shore and in the fine-grained area, manifesting the significant input of the land-based sources and the effect of shelf mud depositional process on the fate of SOM. The sharp seaward decrease of burial fluxes of terrestrial and marine OC gave evidences that the majority of organic carbon were settled in the inner shelf with the small fraction of them further transported eastwards.

Grain-size characteristics and net transport patterns of surficial sediments in the Zhejiang nearshore area, East China Sea

Summary Spatial variations in grain-size parameters can reflect sediment transport patterns and depositional dynamic environments. Therefore, 616 surficial sediment samples taken from the Zhejiang nearshore area in the East China Sea were analyzed to better understand the net sediment transport pattern in this region. The study area is generally dominated by clayey silt and has relatively coarse mud sediment in the southeast. The sorting coefficient of surface sediment is higher than 1.4, and sediment is poorly sorted throughout the study area. The skewness has a strong correlation with the mean grain-size diameter. The net sediment transport pathways obtained by the grain-size trend analysis indicate several distinct characteristics of the surficial sediment transport. The sediment is transported southward under the action of the stronger southward Zhejiang–Fujian Coastal Current (ZMCC) in winter in the upper part of the nearshore area. Influenced by the obstruction of the Taiwan Warm Current (TWC) and the tidal current, surficial sediment transport vectors display two areas of grain-size trend convergence and indicate the net deposition environment has a high sedimentation rate. However, the transport is mainly toward the north under the control of the prevailing northward ZMCC and the strong TWC in the summer. The sedimentary rate is closely related to the processes of the sediment transport. On the one hand, sediment transportation affects the depositional rate in a different environment. On the other hand, the modern sedimentary rate can reflect indirectly the sediment source and sediment transportation.

Sources and distribution of tetraether lipids in sediments from the Zhejiang–Fujian coastal mud area, China, over the past 160 years: Implications for paleoclimate change

Proxies based on glycerol dialkyl glycerol tetraether (GDGT) lipids in surface sediments have been successfully used to reconstruct sea surface temperature (SST), mean annual air temperature (MAAT), and soil pH in the East China Sea and its adjacent ocean margins. In this study, two cores from the Zhejiang–Fujian coastal mud area (ZFCMA) were studied in detail to investigate temporal changes in the source and distribution of tetraether lipids in the area, and the implications of such data for paleoclimate change. The results indicate that isoprenoid GDGTs (isoGDGTs) in the ZFCMA were derived mainly from Thaumarchaeota, with a minor contribution from in situ and allochthonous methanogenic archaea in upwelling areas, whereas branched GDGTs (brGDGTs) originated mainly from terrigenous bacteria and in situ organisms. However, the minor methanogen-derived and allochthonous isoGDGTs were considered to have had no effect on inferred SSTs in this study. The presence of brGDGTs produced in situ might corrupt the relationship between the methylation index of branched tetraethers or the cyclization index of branched tetraethers (MBT/CBT) and MAAT or pH, particularly in hypoxic areas. However, #ringtetra data, used here as an index to evaluate the sources of the brGDGTs, indicated that the brGDGTs buried in the sediments are predominantly derived from soil erosion. Furthermore, temporal changes in the GDGT-based proxy records indicate that climate changes and events (e.g., relating to the East Asian Monsoon, Pacific Decadal Oscillation (PDO)/Kuroshio Current (KC) intensity, and flood events), as well as anthropogenic influences (e.g., dam construction, soil conservation, fertilizer usage, and discharge of industrial waste water and domestic sewage) affect the signal in the core sediments. SSTs fluctuated over the past 160 years in the ZFCMA, with higher values in the 20th century than in the 19th century. In addition, the humidity, as inferred from the relationship between precipitation/soil water content and pH, and continental temperature in the mid–lower Yangtze River basin switched between dry–hot/dry–cool and wet–hot/wet–cool over the last 160 years. The results also indicate that PDO/KC intensity plays a key role in temperature changes and has a larger impact on terrestrial ecosystems than on ocean ecosystems in the ZFCMA and the adjacent continent.

Geochronology, geochemistry, and petrogenesis of the late Mesozoic Luoyang volcanics: Implications for the geodynamic evolution of the Zhejiang–Fujian region, SE China

The Zhejiang–Fujian region, situated along the southeastern coast of China and in the eastern part of the Cathaysia Block, is characterized by large volumes of late Mesozoic granitoid volcanics. We present new zircon U–Pb ages, whole‐rock geochemistry, and Sr─Nd─Hf‐isotope data for 3 rhyolite porphyries from the Luoyang region (LY‐1, LY‐2, and LY‐3). We identify 2 magmatic events. In Stage 1 (146 Ma), rhyolite porphyry LY‐1 was produced by the partial melting of Proterozoic Mayuan Group amphibolites and metasediments. In Stage 2 (130–126 Ma), rhyolite porphyries LY‐2 and LY‐3 were generated by the continued melting of amphibolites but with only a minor contribution from metasedimentary rocks. The fractionation of plagioclase, biotite, titanite, and allanite (degree of fractionation 0.7–0.5) from an LY‐2 parent magma produced LY‐3. Our new data, together with other published data, indicate that minor volcanism, related to the initial northwestward subduction of the Paleo‐Pacific Plate beneath SE China, occurred in a continental arc setting in the Zhejiang–Fujian coastal region from 160 to 140 Ma but that the major period of volcanism took place from 140 to 120 Ma in a back‐arc setting and occurred because of rollback of the subducting slab.

Early Jurassic granitoids from deep drill holes in the East China Sea Basin: implications for the initiation of Palaeo-Pacific tectono-magmatic cycle

ABSTRACTThe timing of the Palaeo-Pacific Plate (PPP) subduction in East Asia, following the amalgamation of the North and South China Blocks (NCB and SCB), remains equivocal despite several investigations on the widespread subduction-related Mesozoic magmatism in this region. Here we report newly discovered granodiorites in the East China Sea Basin (ECSB) from deep boreholes (2945–2983 m), which yield SHRIMP zircon U–Pb age of 174 ± 1.1 Ma. The rock shows relatively high Sr/Y and La/Yb ratios, low contents of Ni, Cr, and MgO, and markedly negative values of εHf(t) (21.0 to −27.0). These geochemical and isotopic features are similar to those of the tonalite-trondhjemite-granodiorite (TTG) suites produced by the partial melting of the thickened lower continental crust. Our data, together with the ca. 190–180 Ma I-type granites reported from the eastern Zhejiang–Fujian and Taiwan areas, lead us to conclude that the continental crust in the coastal areas of South China underwent some degree of thickening during the Early Jurassic. A comparison with the coeval magmatic rocks in South Korea and Japan suggests that a large NE-trending continental arc (ca. 190–170 Ma) might have been constructed along the eastern margin of Asia at this time. Our study provides insights into the initiation of the Palaeo-Pacific tectono-magmatic cycle immediately following the consolidation of the SCB and NCB.

Modern muddy deposit along the Zhejiang coast in the East China Sea: Response to large-scale human projects

Grain size and clay minerals in the surface sediment off Zhejiang Province, China, of the East China Sea were analyzed to study changes in grain size, muddy deposit boundary, and major riverine and other derived matters transport paths in the Zhejiang coastal muddy deposit since the impoundment of the Three Gorges Dam and after other large-scale human projects. The results show that the sediment types are mainly silt and mud in the muddy deposit, divided based on the 10% isoline of the sand-sized component. The sources of sediment in the muddy deposit are mainly the Yangtze River and simultaneously supplies from the Qiantang Jiang, Ou Jiang, relict fine-grain matter, and hydrolyzed volcanic rocks around the Zhoushan Islands. The transport and dispersal of sediments in the study area are largely controlled by the Zhejiang–Fujian coastal current and the Taiwan Warm Current and appear seasonally. The contributions from the Ou Jiang, relict matter, local hydrolyzed matter, and the Qiantang Jiang are enlarged owing to the decline of Yangtze suspended matter and the constructions of major human projects in the Hangzhou Bay, respectively. In addition, the sediment grain size exhibits a fining trend because of the influence of the Three Gorges Dam. The boundary of the muddy deposit is relatively stable after the Three Gorges Dam impoundment north of the city of Zhoushan. In contrast, south of the city of Zhoushan the boundary of the muddy deposit lies toward the east because the sediment supply from the relict fine-grained matters resuspended by the Taiwan Warm Current east of the study area. The changes in the grain size and contributions from smaller rivers and other derived matter as well as the boundary of the muddy deposit there will probably become more pronounced in the future.

Holocene sedimentary systems on a broad continental shelf with abundant river input: process–product relationships

Abstract The region consisting of the Bohai, Yellow and East China seas represents a typical wide continental shelf environment with abundant terrestrial sediment supply. Here, a variety of sedimentary systems have been formed during the Holocene period. These systems have unique characteristics in terms of spatial distribution, material composition, deposition rate, and the timing and duration for their formation, which are related to active sediment-transport processes induced by tides and waves, shelf circulations, and sediment gravity flows. The sedimentary records contained within the deposits have a high temporal resolution, but each with a limited temporal coverage. However, if these records are connected, then they may form a complete archive for environmental change studies. In the field of process–product relationship studies, the mid-Holocene coastal deposits on the Jiangsu coast, the early–middle Holocene sequences of the Hangzhou Bay, the Holocene mud deposits off the Zhejiang–Fujian coasts and the other mud areas over the region are of importance. These systems may be understood by identifying the material supply (from both seabed reworking during the sea-level rise events and river discharges), transport-accumulation processes, the formation of sediment sequences and the future evolution of the sediment systems, for which numerical modelling becomes increasingly important.

Using multi-radiotracer techniques to better understand sedimentary dynamics of reworked muds in the Changjiang River estuary and inner shelf of East China Sea

Reworked muds, including mobile muds, resuspended sediments, and bio-mixed muds are ephemeral layers in the benthic boundary of large-river delta-front estuaries (LDEs). In this study, multiple radiotracers (210Pb, 137Cs, 234Th, 7Be, 235U, 228Th, 228Ra, 226Ra and 40K) were combined to evaluate the sedimentary dynamics of the mud belt on the inner shelf of the East China Sea (ECS) adjacent to the Changjiang River Estuary. We first categorized eight types of typical 210Pb profiles in marine sediments, and specified which ones could be used as possible evidence of reworked muds. The types of 210Pb profiles observed in previous studies and this study were then used to examine the depth distribution of reworked mud layers of the benthic boundary of ECS. We found that reworked mud depth in the along-shore mud belt of the inner shelf of ECS was deeper than those in the outer shelf and slope area, reaching up to 150cm deep in the Changjiang River LDE, and up to 50cm deep in the Zhejiang–Fujian coast mud area. Sediment core tracer profiles also showed that the reworked mud layer could be further divided into several sub-layers with distinct redox conditions and microbe (sulfate-reducing bacterial) abundance. SRB abundance intensively fluctuated with changing redox environment, and larger abundance values were usually observed in anoxic conditions. Based on 7Be and 234Th, the top layer (ca. 2–4cm thick) was the most modern and active zone, showing evidence of reworking on seasonal timescales. The deeper sections of the reworked mud layer were generally modified over longer timescale (years) which were examined using the more long-lived tracers, e.g., 137Cs, 228Thex, and 228Ra/226Ra ratio. We found for the first time in this region that age of the reworked layers was usually much younger than underlying accumulating (burial) layers. We posit that this multi-radionuclide approach is critical for evaluating the complex biogeochemical sediment record on delta-front estuaries of large rivers subject to changing climate conditions and human impacts over the last several centuries.

Air–sea CO<sub>2</sub> fluxes in the East China Sea based on multiple-year underway observations

Abstract. This study reports the most comprehensive data set thus far of surface seawater pCO2 (partial pressure of CO2) and the associated air–sea CO2 fluxes in a major ocean margin, the East China Sea (ECS), based on 24 surveys conducted in 2006 to 2011. We showed highly dynamic spatial variability in sea surface pCO2 in the ECS except in winter, when it ranged across a narrow band of 330 to 360 μatm. We categorized the ECS into five different domains featuring with different physics and biogeochemistry to better characterize the seasonality of the pCO2 dynamics and to better constrain the CO2 flux. The five domains are (I) the outer Changjiang estuary and Changjiang plume, (II) the Zhejiang–Fujian coast, (III) the northern ECS shelf, (IV) the middle ECS shelf, and (V) the southern ECS shelf. In spring and summer, pCO2 off the Changjiang estuary was as low as < 100 μatm, while it was up to > 400 μatm in autumn. pCO2 along the Zhejiang–Fujian coast was low in spring, summer and winter (300 to 350 μatm) but was relatively high in autumn (> 350 μatm). On the northern ECS shelf, pCO2 in summer and autumn was > 340 μatm in most areas, higher than in winter and spring. On the middle and southern ECS shelf, pCO2 in summer ranged from 380 to 400 μatm, which was higher than in other seasons (< 350 μatm). The area-weighted CO2 flux on the entire ECS shelf was −10.0 ± 2.0 in winter, −11.7 ± 3.6 in spring, −3.5 ± 4.6 in summer and −2.3 ± 3.1 mmol m−2 d−1 in autumn. It is important to note that the standard deviations in these flux ranges mostly reflect the spatial variation in pCO2 rather than the bulk uncertainty. Nevertheless, on an annual basis, the average CO2 influx into the entire ECS shelf was 6.9 ± 4.0 mmol m−2 d−1, about twice the global average in ocean margins.

Distribution and cross-front transport of suspended particulate matter over the inner shelf of the East China Sea

An obvious shear front between the Taiwan Warm Current and the Zhe–Min (Zhejiang–Fujian) Coastal Current exists over the inner shelf of the East China Sea (ECS) in winter. Although the cross-front spread of surface water in the ECS has been reported based on satellite images, the cross-front transport of suspended particulate matter (SPM) has not been well studied. To reveal the detailed characteristics of SPM in vertical direction, in terms of different fractions, and to study its cross-front transport and mechanism, high-vertical resolution profiles of SPM concentrations observed by Laser In-Situ Scattering and Transmissometry (LISST) and derived from water samples at various levels, together with salinity and temperature, were measured in February 2007, from 34 stations in the ECS. Results showed that volume concentration (VC) of SPM finer than 280.07µm has a good correlation with mass concentration (MC), because coarser factions were thought to be biological components. The VC was then converted to the MC of different fractions at high resolution, by reducing the influence of biological sources. Both temperature and salinity data showed an obvious front along 50m-isobath in the bottom layer, tilting seaward toward the surface layer. Within 50m-isobath, the MC was higher than 2mg/L in the surface layer and 10mg/L in the bottom layer. The SPM could be transported across the front to the sea in the bottom layer, even to the east of 100m-isobath, where the MC of SPM was less than 1mg/L in the surface layer and 2mg/L in the bottom layer. The SPM across the front was mainly silt fraction with some fraction of clay. An idealized numerical model was established. Numerical experiment results showed that bottom Ekman transport produced by the northerly wind in winter is the key factor controlling cross-front transport, and strong northerly wind is responsible for its expansion. This study helps our understanding of material exchange in the coastal and shelf seas.

Double SST fronts observed from MODIS data in the East China Sea off the Zhejiang–Fujian coast, China

We report a double coastal front system off the Zhejiang (Zhe) and Fujian (Min) Provinces in the East China Sea in winter. In addition to the well-known Zhe–Min offshore coastal front along 50m isobath, a secondary near-shore coastal thermal front along 20m isobath is also apparent in December and January. The fronts were observed by Moderate Resolution Imaging Spectroradiometer (MODIS) at monthly mean nighttime sea surface temperature (SST) during 2000–2013 in terms of SST gradients. Our results showed temporal and spatial variations of the two fronts as follows: (1) both offshore front and near-shore front often co-exist between 26.5°N and 29.5°N in December and between 28.0°N and 29.5°N in January. However, only the offshore front is apparent in November and February. (2) The near-shore front is narrow (4–16km), while the offshore front is three to four times wider (16–48km). (3) In contrast to the well-known offshore front which exists throughout the winter with a strong intensity, the near-shore front has a shorter lifetime with a weak intensity, and has been overlooked by previous studies. Finally, we proposed that the bottom bathymetric gradients may play an important role in the frontogenesis of the double fronts.

Magnetostratigraphy and luminescence dating on a sedimentary sequence from northern East China Sea: Constraints on evolutionary history of eastern marginal seas of China since the Early Pleistocene

Owing to the large and increasing population density in low-lying coastal regions, even small changes in sea level can have substantial societal and economic impacts. Alternations of terrestrial and marine sediments deposited in coastal areas or continental shelves are important and effective indicators of sea-level changes, and thus, have been widely studied in the marginal seas of China over the past 30 years. However, sea-level change results from not only eustatic factors but also tectonic activity. The Zhe-Min (or Zhejiang–Fujian) Uplift (ZMU) was such an important factor in geomorphology, and formed a barrier preventing entry of sea water into the northern marginal seas of China, but its Quaternary history is poorly known.In this study, a new borehole (ECS-DZ1) was drilled in the Zhoushan Islands, northern East China Sea to obtain information on the evolution of the ZMU during the Quaternary. Information from paleomagnetic and luminescence dating was combined with data on sedimentary changes. The main results are: (1) constrained by luminescence ages, the upper sedimentary units were extrapolated to have been deposited since ∼0.2 Ma; (2) paleomagnetic results suggest that the ECS-DZ1 borehole sequence spans from the pre-Olduvai Matuyama reverse chron to the Brunhes normal chron, approximately constraining the age of the basal sedimentary unit to ∼2.0 Ma; (3) a significant hiatus or erosion between two major sedimentary units possibly occurred between the late Early Pleistocene and Middle Pleistocene.As the Zhoushan Islands are within the ZMU and considering previous transgression studies around this region, it is inferred that the ZMU subsided at ∼2.0 Ma, allowing sea water to invade northward in the Yellow Sea basin. The ZMU might have been uplifted again no later than 1.0 Ma, causing a sedimentary hiatus or lacustrine development. After ∼0.2 Ma, the ZMU subsided completely, allowing large transgressions to develop across the northern marginal seas of China in the context of global sea-level changes.

Source and Migration of Short-Chain Chlorinated Paraffins in the Coastal East China Sea Using Multiproxies of Marine Organic Geochemistry

Multiple proxies of terrestrial organic matters (TOM) were introduced to study the migration behaviors of short-chain chlorinated paraffins (SCCPs) in the coastal East China Sea (ECS). The contents of SCCPs in the surface sediment collected from Changjiang (Yangtze) River Delta (CRD) and along the Zhejiang-Fujian coastline ranged from 9.0 to 37.2 ng/g (dry weight, d.w.), displaying a "band-style" distribution trend. Spatial distribution patterns of SCCP congeners presented an increasing trend seaward and southward along the coastline for shorter carbon length (C₁₀ + C₁₁) and lower chlorinated (Cl₅ + Cl₆ + Cl₇) congeners, suggesting a spreading tendency seaward and southward from the CRD and the north of the inner shelf. The significant relationship between ΣSCCPs and total organic carbons (TOC) (r(2) = 0.402, p < 0.05) indicated that the migration of SCCPs in sediments was markedly affected by TOC. The spatial patterns of the TOM proxies of TOC δ(13)C, the contents of ΣC₂₇ + C₂₉ + C₃₁ n-alkanes, terrestrial marine biomarker ratio (TMBR), and terrestrial TOC (T-TOC) were all similar to that of ΣSCCPs. Linear relationships between SCCP contents and both the contents of ΣC₂₇ + C₂₉ + C₃₁ n-alkanes (r(2) = 0.537, p < 0.05) and T-TOC (r(2) = 0.495, p < 0.05) were also observed. The consistence demonstrated that a major portion of sedimentary SCCPs in the coastal ECS should be from the river input of Changjiang River and deposited in the CRD and along the inner shelf of the ECS, but only a minor fraction was transported to the offshore areas.