Zero-valent Iron Particles Research Articles

Incorporation of nanoscale zero-valent iron particles in monodisperse mesoporous silica nanospheres: Characterization, reactivity, transport in porous media

In this study, nanoscale zerovalent iron (nZVI) was incorporated inside the channels of monodisperse mesoporous silica nanospheres (MSN). The techniques of TEM, XRD, FTIR, N2 adsorption-desorption and XPS were conducted to characterize the composition and structure of the composite materials. Results revealed that nZVI was well dispersed in the channels of MSN, and the synthesized Fe/Si composite materials (nZVI@MSN) remained monodisperse nanospheres with the size of 100 nm which was in the optimal size range for transport through porous media. The loading of Fe (wt %) in nZVI@MSN was 4.3% and the BET surface area of nZVI@MSN was 743.49 m2/g. Batch experiment results revealed that the removal efficiency of nitrobenzene (NB) by nZVI@MSN was 42.9% higher than that of bare nZVI. Lower initial solution pH could favour the removal of NB. Most of the common ions including Na+, K+, Cl−, NO3− and SO42- presented no obvious effect on NB removal. While, Ca2+, Mg2+ and HCO3− showed promoted inhibitory effect on NB degradation with the increased of ion concentration. After seven cycles of reduction, the removal efficiency of NB by nZVI@MSN was higher than 86%, indicating its high stability and durability. Transport experiments showed that nZVI@MSN performed better mobility in porous aquifer media than bare nZVI.

Sorption of Perfluoroalkyl Acids to Fresh and Aged Nanoscale Zerovalent Iron Particles

The sorption of perfluoroalkyl acids (PFAAs), particularly perfluorooctanesulfonic acid (PFOS), to freshly synthesized nanoscale zerovalent iron (nZVI) and aged (oxidized) and sulfidated nZVI, was investigated under anaerobic conditions. The sorption of PFAAs to nZVI was 2-4 orders of magnitude higher than what has been reported for sediments, soils, and iron oxides. The hydrophobicity of the perfluorocarbon chain dominated the sorption, although FTIR spectra indicated specific interactions between sulfonate and carboxylate head groups and nZVI. The contributions from electrostatic interactions depended on the surface charge and pH. Humic acids influenced sorption only at concentrations above 50 mg/L. nZVI aged in deoxygenated water up to 95 days showed similar sorption isotherms for PFOS to fresh nZVI, because Fe(OH)2 was the predominant phase on the nZVI surface independent of aging time. Sulfidation of nZVI reduced sorption of PFOS by 1 log unit owing to the FeS deposited, but the sorption affinity was restored after aging because of formation of Fe(OH)2. Oxidation of nZVI by water and dissolved oxygen also resulted in similar sorption of PFOS as fresh nZVI at environmentally relevant concentrations. The results suggest that injection of nZVI could reduce PFAA concentrations in groundwater despite changes to its surface chemistry with aging.

Preparation of wheat straw-supported Nanoscale Zero-Valent Iron and its removal performance on ciprofloxacin

Wheat straw-supported Nanoscale Zero-Valent Iron particles (WS-NZVI) were successfully synthesized, which were used for Ciprofloxacin hydrochloride (CIP) removal in simulation wastewater. The structure, chemical composition and micro-morphology of WS-NZVI and Nanoscale Zero-Valent Iron (NZVI) were characterized by scanning electron microscopy analysis (SEM), X-ray diffraction (XRD), as well as the Fourier Transformed IR spectra (FT-IR). XRD results proved the existence of Fe°, and SEM images indicated that the agglomeration of NZVI was effectively inhibited when loaded on wheat straw. Besides, the effects of initial solution pH, CIP concentration, adsorbents dosage and contacting time on the removal efficiency of CIP by WS-NZVI and NZVI were investigated. The experimental results showed that, compared with NZVI and wheat straw, WS-NZVI possessed higher removal efficiency for CIP, and the maximum removal capacity of CIP by WS-NZVI was 363.63 mg g−1 (25 °C). Furthermore, WS-NZVI was suitable for wider pH range (pH = 4–10) in comparison with NZVI. For the WS-NZVI, the kinetic was better fitted with pseudo-second-order equation, rather than pseudo-first-order equation. The Mass spectrometry (MS) analysis deduced that the degradation reaction mainly occurred on quinolone groups piperazinyl ring. Therefore, it is feasible that using wheat straw as a support material to enhance the performance of NZVI, and the synthesized WS-NZVI has a potential in the organic compounds elimination because of its redox reaction activity.

Using Silica Coated Nanoscale Zerovalent Particles for the Reduction of Chlorinated Ethylenes

The impact of a silica coating on the degradation potential of nanoscale zerovalent iron (nZVI) particles toward a mixture of chlorinated ethylenes is presented. The newly employed stabilization method for nZVI, based on silica deposition from saturated sodium silicate water glass, produces nZVI particles with a similar reactivity as non-stabilized particles. Moreover the removal rate constant kM of trichloroethylene (0.1740 L g−1 d−1 Fe0) and cis-dichloroethylene (0.1045 L g−1 d−1Fe0) was significantly improved (almost by a factor of 2) for stabilized nZVI. X-ray photoelectron spectroscopy (XPS) and Wavelength Dispersive X-ray Fluorescence (WDXRF) analyzes revealed a high durability of silica coating and the coating left at least half of nZVI surface silica free for reaction for more than 5 weeks. The silica coating did not affect the surface composition of silica coated nZVI which was confirmed by the very similar distribution of degradation products and corrosion products (Fe3O4, FeOOH) as was found for non-coated nanoparticles. An enhanced reactivity supplemented with a stable corrosion properties indicates that silica coated nZVI has potential as an efficient remediation agent toward chlorinated ethylenes.

Leaf-extract mediated zero-valent iron for oxidation of Arsenic (III): Preparation, characterization and kinetics

In recent years, leaf-extract mediated green synthesis of zero-valent iron nanoparticles is gaining much popularity as it is cost effective and an eco-friendly alternative to chemically synthesized zero-valent iron. The present study reports the synthesis and characterization of nanoscale zero-valent iron particles obtained from various leaf extracts viz. eucalyptus (Eucalyptus globulus), mango (Mangifera indica), jamun (Syzygium cumini) and guava (Psidium guajava). The synthesized nanoparticles were characterized on the basis of size distribution, UV–Vis absorption spectroscopy, Fourier transform infrared spectroscopy, Field emission scanning electron microscopy and powder X-ray diffractometer. This study further investigates the potential of these nanoparticles for oxidation of arsenite (1000 µg/L) at various pH (3, 7 and 9). Results indicate that green nanoparticles synthesized from guava leaves were capable of oxidising As(III) to As(V) at all investigated pH values, the kinetics of which varied depending on the pH. As(III) oxidation kinetic model fitted well to first order with Kobs values of 0.3444 s−1, 0.0482 s−1 and 0.0155 s−1 for pH 3, 7 and 9 respectively. This study provides a novel mechanism for oxidation of arsenite to arsenate, thus providing an effective and sustainable solution for remediation of toxic trivalent arsenic.

Immobilization of nanoscale zero-valent iron particles (nZVI) with synthesized activated carbon for the adsorption and degradation of Chloramphenicol (CAP)

Nanoscale zero-valent iron particles (nZVI) immobilized by Enteromorpha prolifera based-activated carbons were applied for Chloramphenicol (CAP) treatment. The porous structure, morphology and chemical composition of as-synthesized adsorbents were detected by scanning electron microscope (SEM), transmission electron microscope (TEM), N2 adsorption–desorption isotherms, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The kinetics models (pseudo-first-order and pseudo-second-order model) and isotherms models (Langmuir, Freundlich and Temkin model) were introduced to investigate the CAP removal mechanisms, and the degradation products were analyzed using 3D-EEM fluorescence, Ultraviolet-visible spectroscopy (UV–VIS) and mass spectrograph. The modified nZVI exhibited excellent removal capacity for CAP (545.25 mg/g) because of the cooperative effects of adsorption and degradation of nZVI/AC system. Thermodynamic parameters revealed an endothermic, spontaneous and feasible process for nZVI/AC with a tendency of out-of-order. Besides, 3D-EEM fluorescence and UV–VIS analysis implied that could be thoroughly decomposed by nZVI/AC but decomposition of CAP was less efficient by the nZVI. According to the degradation products of CAP analyzed utilizing mass spectrometry, dechlorination by radicals was inferred to be the potential degradation routine of CAP by nZVI/AC.

Preparation of Pyramids Structured Silicon as a Support for Nano Sized Zero Valent Iron Particles for Nitrate Removal from Water

In this study, pyramids structured silicon (PSi) has been made from metallurgical grade silicon powder with wet alkaline etching and then chemically activated with nano zero valent iron (NZVI) to eliminate nitrate. The NZVI/PSi composite was characterized by scanning electronic microscopy (SEM), X-ray diffraction(XRD), X-ray fluorescence spectrometer (XRF), energy dispersive X-ray spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), and UV–Vis spectrophotometry. The size of NZVI particles was between 30–100 nm coated on PSi without clustering of the NZVI particles due to the electromagnetic attraction forces. The synergistic effect of NZVI/PSi composites obviously increased remarkably nitrate removal efficiency than NZVI alone. Chemical reduction of nitrate by zerovalent iron in water requires acidic pH conditions but NZVI/PSi composite can reduce nitrate in water in the pH range of 2–7. Also, removal of nitrate complete in 20 min by NZVI/PSi composite that was shorter than NZVI in 120 min. Above all, this composite completely was separated from solution with external magnetic field.

Nanoscopic Zero-Valent Iron Supported on MgO for Lead Removal from Waters

Lead is one of the most toxic heavy metals that can create a severe risk to water ecosystem health. Zero-valent iron is an effective material for Pb2+ removal treatments. In particular, nanoscopic zero-valent iron (nZVI) particles are characterized by high reaction rates; nevertheless, their utilization in water and groundwater remediation techniques requires further investigations. Indeed, it is necessary to define effective methods able to avoid the drawbacks due to the aggregation tendency of nanoparticles and their potential uncontrolled transport in groundwater. In this work, nZVI was supported on magnesium oxide grains (MgO_nZVI) to synthesize an alternative material for lead removal from aqueous solutions. Many experiments were conducted under several operating conditions in order to analyze the effectiveness of the produced material in Pb2+ abatement. The performance of MgO_nZVI was also compared with those detected using commercial microscopic Fe0 (mZVI) as a reactive material. The experimental findings showed a much greater reactivity of the supported nanoscopic iron particles. By means of a kinetic analysis of batch tests results, it was verified that, both for MgO_nZVI and mZVI, the lead abatement follows a pseudo-second-order kinetic law. The reaction rates were affected by the initial pH of the treatment solution and by the ratio between the Fe0 amount and initial lead concentration. The efficiency of MgO_nZVI in a continuous test was steadily around 97.5% for about 1000 exchanged pore volumes (PV) of reactive material, while by using mZVI, the lead removal was approximately 88% for about 600 PV. X-ray diffraction (XRD) and energy-dispersive spectroscopy EDS analyses suggested the formation of typical iron corrosion products and the presence of metallic lead Pb0 and Pb2+ compounds on exhausted materials.

Sorption and fractionation of rare earth element ions onto nanoscale zerovalent iron particles

The removal behaviour of rare earth element (REE), (Sc, Y, La-Lu), ions onto nanoscale zerovalent iron (nZVI) particles has been investigated. Batch sorption isotherms were conducted using REE-bearing acid mine drainage (AMD) and a range of different synthetic REE solutions, which were exposed to nZVI at 0.1–4.0 g/L. Maximum adsorption capacity of Yb and La was 410 and 61 mg/g respectively (1000 mg/L LaCl3 and YbCl3 starting concentration, initial pH = 4.5, T = 294 K), the highest currently reported in the literature. Aqueous REE removal to ultratrace concentrations (<1 µg/L, >99.9% removal) was also recorded after 30 min (the first sampling interval) exposure of ≥0.5 g/L nZVI to 10 mg/L aqueous REE solutions (nitrate counterion). Similar rapidity and near-total removal ability was recorded for the exposure of nZVI to the AMD, however, a greater nZVI concentration was required, with the removal of all REEs (with the exception of La, Ce, Nd and Gd) to <1 µg/L when exposed to nZVI at 4.0 g/L for 30 min. In all systems nZVI was selective for the removal of HREE ions in preference to LREE ions, with the mechanism determined using HRTEM-EDS and XPS analysis as via surface mediated precipitation. Overall the results demonstrate nZVI as exhibiting great promise as an effective and versatile agent for simultaneous REE ion recovery and fractionation.

Towards “Precision Mining” of wastewater: Selective recovery of Cu from acid mine drainage onto diatomite supported nanoscale zerovalent iron particles

This paper introduces the concept of ‘Precision Mining’ of metals which can be defined as a process for the selective in situ uptake of a metal from a material or media, with subsequent retrieval and recovery of the target metal. In order to demonstrate this concept nanoscale zerovalent iron (nZVI) was loaded onto diatomaceous earth (DE) and tested for the selective uptake of Cu from acid mine drainage (AMD) and subsequent release. Batch experiments were conducted using the AMD and nZVI-DE at 4.0–16.0 g/L. Results demonstrate nZVI-DE as highly selective for Cu removal with >99% uptake recorded after 0.25 h when using nZVI-DE concentrations ≥12.0 g/L, despite appreciable concentrations of numerous other metals in the AMD, namely: Co, Ni, Mn and Zn. Cu uptake was maintained in excess of 4 and 24 h when using nZVI-DE concentrations of 12.0 and 16.0 g/L respectively. Near-total Cu release from the nZVI-DE was then recorded and attributed to the depletion of the nZVI component and the subsequent Eh, DO and pH recovery. This novel Cu uptake and release mechanism, once appropriately engineered, holds great promise as a novel ‘Precision Mining’ process for the rapid and selective Cu recovery from acidic wastewater, process effluents and leach liquors.

Nanomaterials application for heavy metals recovery from polluted water: The combination of nano zero-valent iron and carbon nanotubes. Competitive adsorption non-linear modeling

Carbon Nanotubes (CNTs) and nano Zero-Valent Iron (nZVI) particles, as well as two nanocomposites based on these novel nanomaterials, were employed as nano-adsorbents for the removal of hexavalent chromium, selenium and cobalt, from aqueous solutions. Nanomaterials characterization included the determination of their point of zero charge and particle size distribution. CNTs were further analyzed using scanning electron microscopy, thermogravimetric analysis and Raman spectroscopy to determine their morphology and structural properties. Batch experiments were carried out to investigate the removal efficiency and the possible competitive interactions among metal ions. Adsorption was found to be the main removal mechanism, except for Cr(VI) treatment by nZVI, where reduction was the predominant mechanism. The removal efficiency was estimated in decreasing order as CNTs-nZVI > nZVI > CNTs > CNTs-nZVI* independently upon the tested heavy metal. In the case of competitive adsorption, Cr(VI) exhibited the highest affinity for every adsorbent. The preferable Cr(VI) removal was also observed using binary systems of the tested metals by means of the CNTs-nZVI nanocomposite. Single species adsorption was better described by the non-linear Sips model, whilst competitive adsorption followed the modified Langmuir model. The CNTs-nZVI nanocomposite was tested for its reusability, and showed high adsorption efficiency (the qmax values decreased less than 50% with respect to the first use) even after three cycles of use.

Response surface methodology as a tool for modeling and optimization of Bacillus subtilis spores inactivation by UV/ nano-Fe0 process for safe water production

One of the most important aspects of environmental issues is the demand for clean and safe water. Meanwhile, disinfection process is one of the most important steps in safe water production. The present study aims at estimating the performance of UV, nano Zero-Valent Iron particles (nZVI, nano-Fe0), and UV treatment with the addition of nZVI (combined process) for Bacillus subtilis spores inactivation. Effects of different factors on inactivation including contact time, initial nZVI concentration, UV irradiance and various aerations conditions were investigated. Response surface methodology, based on a five-level, two variable central composite design, was used to optimize target microorganism reduction and the experimental parameters. The results indicated that the disinfection time had the greatest positive impact on disinfection ability among the different selected independent variables. According to the results, it can be concluded that microbial reduction by UV alone was more effective than nZVI while the combined UV/nZVI process demonstrated the maximum log reduction. The optimum reduction of about 4 logs was observed at 491 mg/L of nZVI and 60 min of contact time when spores were exposed to UV radiation under deaerated condition. Therefore, UV/nZVI process can be suggested as a reliable method for Bacillus subtilis spores inactivation.

Synergistic reduction of copper (II) and oxidation of norfloxacin over a novel sewage sludge-derived char-based catalyst: Performance, fate and mechanism

Abstract Nowadays, clean-up of waters with coexisting heavy metal ions and organic pollutants is of great environmental importance. In this study, a novel sewage sludge-derived char-based catalyst was firstly synthesized, and coupled with hydrogen peroxide for the simultaneous removal of copper (II) and norfloxacin in aqueous solutions. The most relevant findings revealed that zero-valent iron and zero-valent aluminum particles were successfully formed on the catalyst surface when the leaching of the sludge-derived char was reduced by the green tea extract. Nearly 100% of both copper (II) and norfloxacin were simultaneously removed due to a synergistic effect between the reduction of copper (II) and the oxidation of norfloxacin over the catalyst. The gradual addition mode of hydrogen peroxide exhibited a better performance on the simultaneous removal of copper (II) and norfloxacin. The coexisting anions like nitrate and phosphate had significant negative effects on the copper (II) removal, whereas carbonate, fluoride and phosphate had significant negative effects on the norfloxacin removal. Different copper species like zero-valent copper, copper oxide and copper hydroxide were identified in copper (II) reduction process, whereas a total of eight oxidative products were identified in norfloxacin oxidation process. A possible reaction mechanism for the simultaneous removal of copper (II) and norfloxacin by the sewage sludge-derived char-based catalyst/hydrogen peroxide system was proposed. The adsorption of both copper (II) and norfloxacin over the catalyst were firstly occurred, and then the reduction of copper (II) over both zero-valent iron and zero-valent aluminum particles on the catalyst surface as well as the Fenton oxidation of norfloxacin were followed.

Enhanced reactivity of nZVI embedded into supermacroporous cryogels for highly efficient Cr(VI) and total Cr removal from aqueous solution

Novel supermacroporous PSA-nZVI composites with nanoscale zero-valent iron particles (nZVI) embedded into poly (sodium acrylate) (PSA) cryogels were synthesized through ion exchange followed by in-situ reduction. The magnetic composites were evaluated for material characterizations and their efficiency for Cr(VI) and total Cr removal from aqueous medium in batch experiments. PSA-nZVI composites with high nZVI loading capacity up to 128.70 mg Fe/g PSA were obtained, and the interconnected macroporous structure of PSA cryogel remained unaltered with nZVI uniformly distributed on PSA cryogel as determined by TGA, SEM, TEM, XRD and XPS analyses. PSA-nZVI composites showed faster reaction rate than free nZVI both for Cr(VI) and total Cr removal, suggesting no mass transfer resistance and the enhanced reactivity of nZVI in PSA carrier. PSA-nZVI composites exhibited much more remarkable performance for Cr(VI) and total Cr removal than free nZVI particles in high removal capacity and broad pH application range (pH 4–10). The reaction mechanisms were also elucidated with XPS analyses before and after Cr(VI) reduction reactions. These results demonstrate that PSA cryogel acts as an excellent carrier and shows multiple functions in nZVI particle dispersion, pH buffering and oxidation resistance in addition to immobilizing nZVI particles from release.

Influences of benzene or toluene on dechlorination of perchloroethene and trichloroethene in a simulated zero-valent iron permeable reactive barrier

Abstract Column studies were conducted to investigate the influence of benzene or toluene on the dechlorination of perchloroethene (PCE) and trichloroethene (TCE) in columns packed with zero-valent iron (ZVI) in order to simulate a permeable reactive barrier (PRB). Enhancive and inhibitive influences of benzene and toluene, respectively, on PCE and TCE reduction were observed within 10–80 pore volumes (PV) that flowed through the columns. However, such influences dissipated when the flow-through volume increased above 80 PV. The presence of benzene increased the mean dechlorination kobs of PCE and TCE by 7% and 6%, respectively; in contrast, the presence of toluene decreased the mean dechlorination kobs of PCE and TCE by 21% and 10%, respectively. We presumed that the more competitive adsorption between benzene and toluene in comparison to PCE and TCE on the ZVI particle surface might have caused the disparate influences. With a lower affinity for ZVI, benzene has no substantial influence on PCE and TCE adsorption on the ZVI particle surface. However, toluene has a higher affinity for ZVI and could compete with PCE and TCE by contacting the ZVI particle surface. Moreover, given benzene's higher polarity, it could also benefit electron transfer from ZVI to PCE and TCE.

Removal of Pb(ii) and Cr(vi) from aqueous solutions using the prepared porous adsorbent-supported Fe/Ni nanoparticles.

In this study, Fe/Ni nanoparticles supported by a novel fly ash-based porous adsorbent (FBA-Fe/Ni) for Cr(vi) and Pb(ii) removal were investigated. In order to enhance the reactivity of zero-valent iron (ZVI), ZVI particles were deposited on the surface or in the inner pores of FBA as a support material and Ni nanoparticles were introduced. FBA was prepared with the solid waste such as Enteromorpha prolifera, bentonite and fly ash. FBA-Fe/Ni was characterized via Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction and the Brunauer–Emmett–Teller model and energy-dispersive spectrometry. The effects of various parameters on Cr(vi) and Pb(ii) removal by FBA-Fe/Ni, such as FBA-Fe/Ni dosage, pH of the solution, reaction temperature, Cr(vi) and Pb(ii) concentrations, co-existing ions and ionic strength were discussed. The possible removal mechanisms were proposed and the results indicated that there was a three-step reaction including the adsorption of Cr(vi) and Pb(ii) on the surface of FBA-Fe/Ni, the subsequent reduction and precipitation. The removal capacity of Cr(vi) and Pb(ii) by FBA-Fe/Ni was 25.07 mg g−1 and 164.19 mg g−1 at 303 K with an initial concentration of 1000 mg L−1 and FBA-Fe/Ni dosage of 0.20 g. In conclusion, this work demonstrated that FBA-Fe/Ni was a promising alternative material for Cr(vi) and Pb(ii) removal.

Degradation of the antibiotic ornidazole in aqueous solution by using nanoscale zero-valent iron particles: kinetics, mechanism, and degradation pathway.

Degradation of ornidazole (ONZ) by nanoscale zero-valent iron (nZVI) particles was investigated for the first time in this work. The results showed that ONZ was almost completely degraded within 30 min by 0.1 g L−1 nZVI at pH 5.8 and 25 °C. The effects of the nZVI dose, initial ONZ concentration, pH, and temperature on ONZ removal were systematically investigated, and removal of ONZ was followed by a pseudo-first-order kinetics model. Experimental results demonstrated that higher nZVI doses, lower initial ONZ concentrations, and lower pH levels could increase the pseudo-first-order rate constant (kobs) of ONZ removal. While higher temperatures favored removal, the activation energy results suggested that mass transfer was the limiting step during the removal process. The possible effect of oxygen was ruled out by introducing hydroxyl radical scavengers into the experiment. The variation of ONZ concentrations and total organic carbon (TOC) contents in the solution indicated that adsorption was not the main mechanism. The possibility that precipitation was the main mechanism was also excluded by the results for the change in pH and effect of pH. The characterization of nZVI before and after the reaction indicated that ONZ was reduced on the surface of nZVI, which was the main mechanism. Three intermediates and two final products were detected based on the results of UV-vis and high performance liquid chromatography/mass spectrometry (HPLC-MS) analyses. Dechlorination, nitro reduction, N-denitration, and cleavage were all involved in the entire reaction process, and therefore a complicated potential degradation pathway was proposed.

Reductive degradation of high concentration nitrobenzene using nanoscale zero-valent iron particles immobilized on Polyaniline

Reductive degradation of high concentration nitrobenzene using nanoscale zero-valent iron particles immobilized on Polyaniline

Different effects of nano-scale and micro-scale zero-valent iron particles on planktonic microorganisms from natural reservoir water

This study compares the effect of nanoscale and microscale zerovalent iron on natural freshwater microplankton over 21 days.

Selective formation of copper nanoparticles from acid mine drainage using nanoscale zerovalent iron particles

Nanoscale zerovalent iron (nZVI) has been investigated for the selective formation of Cu nanoparticles from acid mine drainage (AMD) taken from a legacy mine site in the UK. Batch experiments were conducted containing unbuffered (pH 2.67 at t = 0) and pH buffered (pH < 3.1) AMD which were exposed to nZVI at 0.1–2.0 g/L. Results demonstrate that nZVI is selective for Cu, Cd and Al removal (>99.9% removal of all metals within 1 h when nZVI ≥ 1.0 g/L) from unbuffered AMD despite the coexistent of numerous other metals in the AMD, namely: Na, Ca, Mg, K, Mn and Zn. An acidic pH buffer enabled similarly high Cu removal but maximum removal of only <1.5% and <0.5% Cd and Al respectively. HRTEM-EDS confirmed the formation of discrete spherical nanoparticles comprised of up to 68% wt. Cu, with a relatively narrow size distribution (typically 20–100 nm diameter). XPS confirmed such nanoparticles as containing Cu°, with the Cu removal mechanism therefore likely via cementation with Fe°. Overall the results demonstrate nZVI as effective for the one-pot and selective formation of Cu°-bearing nanoparticles from acidic wastewater, with the technique therefore potentially highly useful for the selective upcycling of dissolved Cu in wastewater into high value nanomaterials.