Exploring the concealed subsurface structures and materials beneath the lunar surface can reveal significant insights into geological history. This study offers a comprehensive analysis of the stratigraphic interpretation and subsurface material composition at the Chang'E-4 landing site, integrating both in-situ and orbital radar with multispectral datasets. We report the identification of a subsurface structure, which resembles a buried impact crater (∼420 m in diameter) under the Yutu-2 rover's path. This crater could degrade over a period of 0.42 to 0.53 Ga, with an initial diameter of 293 to 323 m and an initial depth of 45.9 to 51.4 m. Surface material above the buried crater, evaluated by the in-situ visible and near-infrared imaging spectrometer (VNIS) detector, shows a higher abundance of clinopyroxene compared to surrounding areas, where a near-equal mix of clinopyroxene and orthopyroxene is observed. Assessment of crater diameters in proximity to the Chang'E-4 landing site, along with the mineral compositions at their epicenters, reveals a decrease in the abundance of clinopyroxene and plagioclase with depth. Conversely, the quantities of orthopyroxene and olivine increase, implying that orthopyroxene-rich Finsen ejecta significantly influenced the Chang'E-4 landing site's geological composition. Two potential stratigraphic boundary depths are identified at 13.5 and 22 m, based on pronounced variations in mineral abundance, offering fresh insights into subsurface delineation beyond radar data. Considering the VNIS and vertical mineral composition, we propose the buried crater's formation resulted from Finsen crater's ejecta. Also, we identify eight potential historical impacts by comparing subsurface relief variations with mineral composition ratios between clinopyroxene and orthopyroxene. The integration of subsurface structure, along with surface and subsurface mineral composition, enables a more robust stratigraphic interpretation, facilitates shallow material source analysis, and allows for historical impact tracing.