Ytterbium Oxide Research Articles

A novel short-wavelength near-infrared certified reference material from dysprosium and ytterbium oxides

A novel short-wavelength near-infrared certified reference material from dysprosium and ytterbium oxides

Temperature Dependent Growth of Ytterbium Oxide as Gate Dielectric on Silicon Substrate Via Combination of Nitrogen and Oxygen Ambient

The ongoing trend towards downsizing silicon (Si)-based metal-oxide semiconductor (MOS) devices has led to constraints on the silicon dioxide (SiO2) gate dielectric due to increased leakage current through the thin SiO2. In this study, ytterbium oxide (Yb2O3) as a high dielectric constant (k) gate oxide material was deposited on a Si substrate and subjected to annealing at different temperatures ranging from 400 to 1000oC in a nitrogen-oxygen-nitrogen ambient atmosphere. The successful formation of Yb2O3 was verified using X-ray diffraction (XRD), Fourier transform infrared (FTIR), and ultraviolet-visible (UV-VIS) spectroscopy. The FTIR analysis indicated that Yb2O3 gate dielectrics post-annealing exhibited Yb-O bonding due to oxygen diffusion, as well as N-O bonding and NO3-bonding, demonstrating the formation of a nitrogen barrier at the interface to hinder oxygen diffusion. The optical band gap values of Yb2O3 gate dielectrics post-annealing ranged from 3.092 eV to 3.267 eV. Notably, the Yb2O3 gate dielectric annealed at 800 °C showed no breakdown within the 0–3 V range across all samples. The acquisition of a high k value of 19.40 and a low effective oxide charge (Qeff) of 5.32 x 1011 cm-2, along with the superior I-V characteristics, suggest that the Yb2O3 gate dielectric annealed at 800oC has the potential to be employed for next generation MOS applications.

Development and performance evaluation of medical radiation-reducing creams using eco-friendly radiation-shielding composites

To ensure the safety of medical personnel in healthcare organizations, radiation-shielding materials like protective clothing are used to protect against low-dose radiation, such as scattered rays. The extremities, particularly the hands, are the most exposed to radiation. New materials that can be directly coated onto the skin would be more cost-effective, efficient, and convenient than gloves. We developed protective creams using eco-friendly shielding materials, including barium sulfate, bismuth oxide, and ytterbium oxide, to avoid harmful effects of heavy metals like lead, and tested their skin-protective effects. Particularly, the radiation-shielding effect of ytterbium oxide was compared with that of the other materials. As shielding material dispersion and layer thickness greatly affect the efficacy of radiation-shielding creams, we assessed dispersion in terms of the weight percentage (wt%). The effective radiation energy was reduced by 20% with a 1.0-mm increase in cream thickness. Ytterbium oxide had a higher radiation-shielding rate than the other two materials. A 28% difference in protective effect was observed with varying wt%, and the 45 wt% cream at 63.4 keV radiation achieved a 61.3% reduction rate. Higher content led to a more stable incident energy-reducing effect. In conclusion, ytterbium oxide shows potential as a radiation-shielding material for creams.

Anti-biofouling evaluation of vacuum-assisted hydrophobic ytterbium oxide (Yb2O3) coating on stainless steel by facile spray combustion

Anti-biofouling evaluation of vacuum-assisted hydrophobic ytterbium oxide (Yb2O3) coating on stainless steel by facile spray combustion

Ligature synthesis by aluminothermic reduction of ytterbium oxide with the formation of nanoscale intermetallides

Ligature synthesis by aluminothermic reduction of ytterbium oxide with the formation of nanoscale intermetallides

Efficient selective leaching of ytterbium and lutetium oxides by new hydrophobic deep eutectic solvents

This research reports the first study of selective leaching of ytterbium-lutetium oxides mixture with hydrophobic deep eutectic solvents (DESs), and high-efficiency and simple-prepared were used to separate and beneficiate lutetium. With hydrophobic DESs, which were formed with hydrophobic salicylic acid (SA) or 3,5-dinitrosalicylic acid (DNS) as the hydrogen bond donor (HBD) and hydrophobic tri-n-octyl phosphine oxide (TOPO) as the hydrogen bond acceptor (HBA), powdered eutectic mixtures of ytterbium-lutetium oxides were leached. The separation factor of ytterbium-lutetium was concluded to reached 2.11 with a solid-liquid (S/L) ratio of 1/50 g/ml, a temperature of 90 °C and a 4 h leaching time, and the experimental conditions, such as the S/L ratio, temperature and reaction time, were explored. The formation of intermolecular hydrogen bonds between the HBD and HBA was revealed through multiple methods, such as IR (disappearance of OH characteristic peaks), 1H NMR (formation of sharp peaks not present for intramolecular hydrogen bonds) and 31P NMR (shift of P = O peaks to higher fields). The lattice energies of the intermolecular hydrogen bonds and the solid oxide lattice energies, which were calculated with Gaussian 16 software (0.87 eV for SA/TOPO = 1:1 and 0.94 eV for DNA/TOPO = 1:1) and the Born–Haber cycle (12957.56 kJ/Mol for Yb2O3 and 12993.59 kJ/Mol for Lu2O3), provided a theoretical illustration of preferential Yb/Lu dissolution leading to separation. The stripping, regeneration and recycling capabilities of the DESs were investigated with stripping and recirculation experiments. Based on these results, the new DES as the leaching agent to separation of ytterbium lutetium oxide is identified as a new efficient mothed with industrialization potential.

Biotemplated silicon carbide-loaded ytterbium oxide: Effective catalyst for photocatalytic hydrogen evolution reactions

SiC-doped Yb2O3 structure (Yb2O3/SiC) was prepared to enhance the photocatalytic hydrogen evolution performance of Yb2O3 nanofiber, which have been performed by using catalyst in the presence of eosin-Y dye and triethanolamine, called photosensitizer and electron donor, respectively under solar light with/out cellulose and chitosan. In this study, cellulose and chitosan were used as biotemplates to increase the hydrogen production of Yb2O3/SiC nanofibrous catalyst in the photocatalytic hydrogen evolution reaction. Bioorganic-inorganic structures, cellulose-Yb2O3/SiC and chitosan-Yb2O3/SiC, were obtained by simply adding cellulose and chitosan to the reaction cell without any additional treatment. Cellulose and chitosan also used as a mediator for dispersion, hydrophilicity, morphological transformation and adhesion to semiconductor with the help of functional groups. The hydrogen production rate of bare SiC, bare Yb2O3, Yb2O3/SiC composite have been measured as 391 μmol g−1, 818 μmol g−1 and 1685 μmol g−1, respectively. Moreover, the hydrogen production rate of cellulose-Yb2O3/SiC and chitosan-Yb2O3/SiC composites were came up to 3346 μmol g−1, 4084 μmol g−1, respectively. These results have been showed that the Yb2O3/SiC nanofibrous catalyst showed higher activity in the presence of cellulose and chitosan. The existence of biopolymers will create a new field in photocatalytic hydrogen production studies with the advantages mentioned above, thanks to the functional groups.

Multifunctional ytterbium oxide buffer for perovskite solar cells.

Perovskite solar cells (PSCs) comprise a solid perovskite absorber sandwiched between several layers of different charge-selective materials, ensuring unidirectional current flow and high voltage output of the devices1,2. A 'buffer material' between the electron-selective layer and the metal electrode in p-type/intrinsic/n-type (p-i-n) PSCs (also known as inverted PSCs) enables electrons to flow from the electron-selective layer to the electrode3-5. Furthermore, it acts as a barrier inhibiting the inter-diffusion of harmful species into or degradation products out of the perovskite absorber6-8. Thus far, evaporable organic molecules9,10 and atomic-layer-deposited metal oxides11,12 have been successful, but each has specific imperfections. Here we report a chemically stable and multifunctional buffer material, ytterbium oxide (YbOx), for p-i-n PSCs by scalable thermal evaporation deposition. We used this YbOx buffer in the p-i-n PSCs with a narrow-bandgap perovskite absorber, yielding a certified power conversion efficiency of more than 25%. We also demonstrate the broad applicability of YbOx in enabling highly efficient PSCs from various types of perovskite absorber layer, delivering state-of-the-art efficiencies of 20.1% for the wide-bandgap perovskite absorber and 22.1% for the mid-bandgap perovskite absorber, respectively. Moreover, when subjected to ISOS-L-3 accelerated ageing, encapsulated devices with YbOx exhibit markedly enhanced device stability.

A wafer scale thin film of ultra-small Sc2O3 nanocrystals on a 2D COF with high rigidity.

Scandium oxide (Sc2O3) has a wide range of applications in metallurgy, chemical industry, electronics and many other high-tech fields. However, most Sc2O3 materials exist in the powder or bulk form, while nanostructured Sc2O3 has rarely been reported as there is a lack of a common method to control its dimensionality, hindering the understanding of new properties and potential applications of nano-Sc2O3 materials. In this paper, we establish a procedure to synthesize a two-dimensional (2D) Sc2O3-covalent organic framework (COF) composite film where the crystal size of Sc2O3 domains is as small as ∼3 nm. The composite film is prepared by a Schiff base condensation reaction at the sharp n-pentane/water interface using a combination of surfactant-monolayer-assisted interfacial synthesis and laminar assembly polymerization methods. Then the conditions of nucleation and uniform film formation of the 2D Sc2O3/COF are explored further. Meanwhile, an atomic force microscopy indentation test shows that the material has a high Young's modulus of 89.1 ± 3.8 GPa, which is much higher than those of the majority of reported 2D polymer materials. We further extended this synthesis method to the preparation of Yb2O3 (ytterbium oxide) and/or Er2O3 (erbium oxide)-incorporated 2D COF composite films, verifying the universality of this strategy. This work provides an opportunity to vary the dimensionality of many kinds of metal oxides and explore the potential applications of low-dimensional Sc2O3 materials.

Highly efficient enzyme less glucose sensor based on cross-linked nitrogen-doped graphene aerogel incorporated with ytterbium oxide and decorated with nickel nitride nanoparticles

Highly efficient enzyme less glucose sensor based on cross-linked nitrogen-doped graphene aerogel incorporated with ytterbium oxide and decorated with nickel nitride nanoparticles

Hydrothermally fabricated Yb2O3 catalyst for vapor-phase dehydration of 3-methyl-1,3-butanediol to isoprene

Several rare-earth oxides, prepared through a hydrothermal process, were employed as catalysts for vapor-phase dehydration of 3-methyl-1,3-butanediol (3MBDO) to isoprene. Ytterbium oxide (Yb2O3) emerged as the most efficient catalyst for the dehydration of 3MBDO to isoprene. The hydrothermal time and calcination temperature influenced the performance of Yb2O3. The reaction temperature and contact time strongly affect the dehydration of 3MBDO and unsaturated alcohols, while the major side reaction of isobutene formation via decomposition of 3-methyl-3-butene-1-ol was mainly influenced by the reaction temperature. The highest isoprene yield of 92% was achieved at 450 °C and a long contact time of 3.75 h. The poisoning experiment using CO2, 2,6-, and 3,5-dimethylpyridine revealed the importance of base and acid sites of Yb2O3 in the dehydration of 3MBDO, indicating the dehydration of 3MBDO to isoprene proceeded via an acid-base concerted mechanism.

Ytterbium (III) Fluoride in Dental Materials

(1) Background: The compound ytterbium trifluoride is used as a component of several dental materials, and this is reviewed in the current article. (2) Methods: Published articles on this substance were identified initially from PubMed, and then from Science Direct and Google Scholar. The publications identified in this way showed that ytterbium trifluoride has been included in a variety of dental restorative materials, including composite resins, glass polyalkenoate cements, and calcium trisilicate cements. (3) Results: Ytterbium trifluoride is reported to be insoluble in water. Despite this, its presence is associated with fluoride release from dental materials. There is evidence that it reacts with the components of calcium trisilicate cements to form small amounts of a variety of compounds, including ytterbium oxide, Yb2O3, and calcium–ytterbium fluoride, CaYbF5. In nanoparticulate form, it has been shown to reinforce glass polyalkenoates and it also provides high contrast in X-ray images. (4) Conclusions: Ytterbium trifluoride is a useful component of dental materials, though some of the published findings suggest that there are aspects of its chemistry which are poorly understood.

Multimode Ytterbium–Aluminosilicate Core Optical Fibre for Amplification and Laser Applications

Rare-earth-doped optical fibres are widely used in lasers and amplifiers. The incorporation of ytterbium and aluminium oxide in a high doping concentration has led to the fabrication of a multi-mode (MM) optical fibre. Within this research, the design, preparation and calculation for the production of a fibre with a targeted 45 μm core diameter are explored. By Energy Dispersive X-ray (EDX) analysis, the doping concentrations of the elements in the core have been measured as 60.4 at.% Al and 1 at.% Yb. Supporting micrographs are used for confirming the core/cladding ratio. Based on the atomic percentage concentration, the calculated refractive index of the multi-element core has an n = 1.61 and an NA = 0.678. Characterisation of the fibre, including absorption and emission cross-section analysis, was performed in order to prove the ability of the fibre to be used for amplification as well as lasing applications.

Damage Grading Evaluation of Thermal Barrier Coatings under CMAS Corrosion

Thermal barrier coatings (TBCs) material has excellent high-temperature resistance and heat insulation performance, which plays a vital role in improving the working efficiency and running life of the engine. During the flight, the engine will inhale dust particles in the air. These particles are mostly from siliceous debris, which are usually called calcium magnesium aluminum silicate (CMAS). At present, CMAS corrosion has become one of the important problems affecting the service life of thermal barrier coatings. In this study, conventional yttrium oxide stabilized zirconia (YSZ) coatings and ytterbium oxide and yttrium oxide co-stabilized zirconia (YbYSZ) coatings were prepared by atmospheric plasma spraying. The two coatings were examined under thermal cycling-CMAS coupling conditions and divided into six life stages. The failure modes, CMAS permeation behavior, crack characteristics and mechanical properties of the two coatings at different life stages were evaluated systematically. The experimental results show that the YbYSZ coating has a longer life than YSZ coating under the thermal cycling and CMAS coupling condition, which increases by about 83% compared with the conventional YSZ coating. In the whole life stage, the porosity of YbYSZ coating is always higher than that of YSZ coating. The phase transition is not the reason for the failure and spalling of the coatings. The crack length of the two coatings showed an increasing trend, but the crack length of the YSZ coating was higher than that of the YbYSZ coating, and the crack density of the two coatings showed a “saddle shape”, which was more obvious for the YSZ coating. The YbYSZ coating shows better mechanical properties under the thermal cycling-CMAS coupling condition with the evolution of life.

Ultrapure single-band red upconversion luminescence in Er3+ doped sensitizer-rich ytterbium oxide transparent ceramics for solid-state lighting and temperature sensing.

Achieving single-band upconversion (UC) is a challenging but rewarding approach to attain optimal performance in diverse applications. In this paper, we successfully achieved single-band red UC luminescence in Yb2O3: Er transparent ceramics (TCs) through the utilization of a sensitizer-rich design. The Yb2O3 host, which has a maximum host lattice occupancy by Yb3+ sensitizers, facilitates the utilization of excitation light and enhances energy transfer to activators, resulting in improved UC luminescence. Specifically, by shortening the ionic spacing between sensitizer and activator, the energy back transfer and the cross-relaxation process are promoted, resulting in weakening of green energy level 4S3/2 and 2H11/2 emission and enhancement of red energy level 4F9/2 emission. The prepared Yb2O3: Er TCs exhibited superior optical properties with in-line transmittance over 80% at 600 nm. Notably, in the 980nm-excited UC spectrum, green emission does not appear, thus Yb2O3: Er TCs exhibit ultra-pure single band red emission, with CIE coordinates of (0.72, 0.28) and color purity exceeding 99.9%. To the best of our knowledge, this is the first demonstration of pure red UC luminescence in TCs. Furthermore, the luminescent intensity ratio (LIR) technique was utilized to apply this pure red-emitting TCs for temperature sensing. The absolute sensitivity of Yb2O3: Er TCs was calculated to be 0.319% K-1 at 304 K, which is the highest level of optical thermometry based on 4F9/2 levels splitting of Er3+ known so far. The integration between pure red UC luminescence and temperature sensing performance opens up new possibilities for the development of multi-functional smart windows.

Thermal diffusivity measurement of undoped Yb2O3 oxide by self-made photoacoustic cell

Photoacoustic spectroscopy is an essential technique for material characterization by measuring acoustic noise inside a cell. In this work, we have fabricated a photoacoustic cell and a pre-amplifier circuit and optimized both for maximum sensitivity. The cavity volume is measured ∼4.90 × 10−6 m3 at optimum condition. After that, the thermal diffusivity of undoped ytterbium oxide is measured by recording photoacoustic voltages. It is found 42.22–44.90 mm2/s for the excitation pump power 150–300 mW range by 980 nm diode laser source.

Radiopacity and physical properties evaluation of infiltrants with Barium and Ytterbium addition.

Radiopaque properties in the infiltrant should be interesting for clinicians to feel more confident to indicate this treatment. Thus, the aim of this study was to evaluate the effect of the incorporation of barium and ytterbium particles on the physical properties of resin infiltrants. Groups were divided according to the addition of ytterbium oxide (Y) alone (30 or 40%) or Y with barium (YB) (15/15% or 20/20% respectively) in the Icon commercial infiltrant and in the experimental infiltrant base. Digital radiography (n=5), Microradiography (n=5), Microtomography (n=3), degree of conversion (n=5), water sorption (n=16), solubility (n=16), contact angle (n=16), flexural strength (n=16), elastic modulus (n=16) and Energy dispersive X-ray Spectroscopy (n=10) were performed. Analyses were performed using the R program, with a significance level of 5%, and microradiography and Microtomography analyses were evaluated qualitatively. In groups with 30 or 40% of ytterbium, radiopacity was higher or equal to enamel. Microradiography and Microtomography appear to have more radiopacity in groups with 40% (Y). Among the groups with no particle addition, those of the experimental infiltrant presented a higher degree of conversion than those of Icon®. In most groups, there was solubility below the ISO-recommended levels. The addition of particles resulted in higher viscosity. Groups with Icon had higher flexural strength and elastic modulus than groups with experimental infiltrant. The addition of 40% (Y) improved polymerization, had low solubility, and had greater radiopacity than enamel, however negatively affected the viscosity increasing then. Experimental groups with the base showed a higher water sorption than Icon groups.

Exploring the KERMA, mass stopping power and projected range values against heavy-charged particles: A focusing study on Sm, Yb, and Nd reinforced tellurite glass shields

In present study, the behavior of ytterbium (III) oxide, samarium (III) oxide and neodymium (III) oxide reinforced novel TeO2–B2O3–V2O5 (TBV groups, tellurite-vanadium–boro) glasses groups are investigated against heavy charged particles, on mass stopping power, projected range and KERMA parameters. SRIM and PAGEX codes are used for determination of the mass stopping power, projected range and KERMA parameters in a kinetic energy range of 0–10 MeV. The highest KERMA values of TBV(X) glasses were achieved at 0.6 MeV. Among TBV(X) glasses, the TBVY1.5 sample with the highest material density (i.e. 5.01038 g/cm3) had the highest KERMA value. The TBVY1.5 sample has the lowest projected range values for alpha and protons with the same kinetic energy. The lowest values of mass stopping power were reported for the TBVY and TBVS groups, which had the highest density values among the analyzed glass samples. The TBVY1.5 sample provides the greatest stopping and slowing characteristics for alpha and proton kinetic energies ranging from 0 to 10 MeV. In this case, it can be said that these two glass groups may slow down alpha particles with a certain kinetic energy the most effectively. It can be concluded that TBV(Y) and TBV(S) glass groups might be useful for stopping the alpha, proton and electron particles.

Effect of ytterbium oxide on the structure and corrosion resistance of micro-arc oxide coatings of Mg-Nd binary alloys in the natural seawater

MAO coatings were prepared on Mg-0.5Nd by adding four different concentrations of Yb2O3 in the electrolyte. The thickness, microstructure and chemical composition of the MAO coating were characterized. The results revealed that the thickness of MAO coating after adding Yb2O3 reduced 1/2 to the original. But the compactness of MAO coating was improved after adding Yb2O3. The compactness and corrosion resistance of MAO coating were positively correlated with Yb2O3 concentration.

Substrate heat-assisted spray pyrolysis of crack-free ytterbium sesquioxide-Si heterojunction diodes for photo-sensing applications

A simple spray pyrolysis is used to develop ytterbium sesquioxide (Yb2O3) on aluminoborosilicate glass substrates at variable substrate temperatures. A cubic crystal system grows along the (222) plane as substrate temperature changes from 600 to 700 °C. Dispersed grains become cluster-like particles in film structures as the temperature rises. The Yb2O3 composition purity.is further ensured by energy dispersive x-ray analyses. Structure improves with optical spectrum transparency. The altered crystallite and grain size shifted the bandgap energy to higher wavelengths. Regarding Ag/n-Yb2O3/p-Si/Ag heterojunction diode performance, the barrier height increases from 0.67 to 0.70 as the substrate temperature rises. The film structure at 700 °C exhibited the best results, including an electrical conductivity of 2.503×10–15 S/cm and an activation energy of 0.129 kJ/mol. In addition, the estimated ideality factors (n) are 4.5 and 2.9 under dark and light conditions, respectively.