For the input of the correct intensity-data-collection parameters – the scan width and the number of steps – the expected full widths at half-maximum of the Bragg intensity profiles (FWHM) for the whole θ range under consideration must be known. These FWHMs depend on the divergence of the incident synchrotron beam, on the monochromator and on the mosaic structure of the sample used. They are also affected by absorption and extinction. A simple but very effective resolution function for a triple-crystal diffractometer, applicable also to single- and double-crystal diffractometers, is given, taking all the dependences mentioned above into account. The calculated FWHMs are compared with the measured ones of three different single-crystal samples, namely the FWHMs of a YIG sphere and an Si sphere, obtained at various wavelengths in the range 0.3 to 2.2 A with the new Huber four-circle diffractometer set up at HASYLAB and the FWHMs of a CaF2 sphere, given in the literature and measured with the old five-circle Stoe diffractometer at HASYLAB (DESY, Hamburg, Germany). It is shown that, with use of the proposed resolution function, the beam characteristics – divergence and wavelength spread – as well as the characteristics of the samples – mosaic spread and mosaic block size – can be determined from comparison with experimental FWHMs, measured at different wavelengths.
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