Yield Limit Research Articles

Boosting light olefin production from pyrolysis of low-density polyethylene: A two-stage catalytic process

The increasing production of waste plastics poses significant environmental and health risks. Low-density polyethylene (LDPE), a major component of plastic waste, is a high-quality feedstock for pyrolysis due to its high carbon and hydrogen content. Traditional pyrolysis methods, such as thermal cracking and one-step catalytic pyrolysis, have limitations in yield and selectivity of valuable products like light olefins. This study introduces a two-stage catalytic pyrolysis (TSCP) process aimed at enhancing the production of light olefins from LDPE. In the first stage, LDPE undergoes pyrolysis with MCM-41 catalyst, yielding a substantial number of liquid products and a minor portion of light olefins. The second stage utilizes Mg-ZSM-5 catalyst to further crack the high-temperature volatile matter into light olefins. The optimal conditions identified were 450 °C in the first stage and 500 °C in the second stage, achieving a maximum light olefin yield of 45.80 wt% and a low reaction temperature, decreasing the energy consumption. Additionally, the MCM-41 catalyst demonstrates excellent regeneration performance, with only a slight decrease in liquid yield after nine cycles. The Mg-ZSM-5 catalyst maintains high stability, with light olefin yield remaining at 83.60 % of the initial yield after 48 h of operation.

Mechanical behaviour of low-, medium- and high-entropy Ti-Hf-Zr-Ni-Cu-Co shape memory alloys

The mechanical behaviour was studied in twelve senary Ti-HfXZrX-Ni-CuXCoX alloys with various configuration entropies, which were regulated by the X value - concentration of doping elements (Hf, Zr, Cu, and Co) that varied from 1 at% to 17 at% and the concentration of the Ni group (Ni+Cu+Co) that varied from 49 to 51 at%. The stress vs strain curves were obtained at three temperatures (-100oC, 22oC and 100oC) at which the alloys were in different states (martensite, austenite, or a mixture of both). It was found that the senary Ti-Hf-Zr-Ni-Cu-Co alloys could undergo deformation via martensite reorientation, stress-induced martensitic transformation, and dislocation slip. The activation of the mechanisms depends on the deformation temperature compared to the temperatures of the martensitic transformations, as in the binary NiTi alloys. An increase in the X value from 1 to 10 at% increased the yield limit for dislocation slip in the austenite phase, while a further rise in the X value by 17 at% decreased this limit. An increase in the X value decreased the strain up to failure. The larger the [Ni] concentration or deformation temperature, the more pronounced the reduction in strain up to failure. An increase in X value from 1 to 5 at% significantly changed the fracture mechanisms from ductile to brittle due to the suppression of the dislocation movement.

Investigation of the large-diameter monopiles response under flow-controlled loading

The mechanical behavior of monopile support systems for offshore wind turbines under current-induced loads was investigated through numerical simulations. Using the Large Eddy turbulence model, the fluid-structure coupling was analyzed in both unidirectional and bidirectional directions. In the unidirectional coupling, the pressure and velocity profiles of the fluid around the pile were determined. While in the bidirectional coupling, the force distribution, pile displacement, and moment distribution were obtained, along with the current-induced load transmitted from the pile to the soil. The coupling analysis revealed that the fluid flow around the pile exhibited cyclic loading behavior due to the interaction between the fluid and the pile, effectively resulting in an oscillating pile within a steady flow. Additionally, the pile’s stress distribution remained within the tensile yield limit of the steel, indicating a stable state in the fluid-pile model within the given flow conditions. Furthermore, the soil reaction forces obtained from the fluid-pile-soil coupling model validated the accuracy of the current-induced load calculations. This study introduces a novel approach that considers the fluid-pile-soil coupling, offering valuable insights for pile foundation design. The findings of this research have significant engineering implications and practical value, providing a robust foundation for future offshore wind turbine installations.

Unveiling Metabolic Engineering Strategies by Quantitative Heterologous Pathway Design.

Constructing efficient cell factories requires the rational design of metabolic pathways, yet quantitatively predicting the potential pathway for breaking stoichiometric yield limit in hosts remains challenging. This leaves it uncertain whether the pathway yield of various products can be enhanced to surpass the stoichiometric yield limit and whether common strategies exist. Here, a high-quality cross-species metabolic network model (CSMN) and a quantitative heterologous pathway design algorithm (QHEPath) are developed to address this challenge. Through systematic calculations using CSMN and QHEPath, 12,000 biosynthetic scenarios are evaluated across 300 products and 4 substrates in 5 industrial organisms, revealing that over 70% of product pathway yields can be improved by introducing appropriate heterologous reactions. Thirteen engineering strategies, categorized as carbon-conserving and energy-conserving, are identified, with 5 strategies effective for over 100 products. A user-friendly web server is developed to quantitatively calculate and visualize the product yields and pathways, which successfully predicts biologically plausible strategies validated in literature for multiple products.

Seismically induced torsional amplification in limited ductile buildings

This article deals with the seismic demand on limited ductile buildings featuring plan asymmetry. When the yielding occurs in a structural wall positioned at the edge of the building remote from the centre of resistance (CR), the position of the CR would shift even further away from the wall, causing an additional, and momentarily, increase in torsion. The undesirable shift in the position of the CR is usually shortlived and would reverse as other walls in the building also surpass the yield limit. However, the limited ductile construction (typical of low to moderate seismicity regions) can be vulnerable. This additional amplification in torsion can only be captured by Incremental Dynamic Analyses (IDA), but not by elastic analyses nor by nonlinear analyses of high ductility demand. Thus, the phenomenon as described is not widely known in spite of torsion being a well researched topic. In this study, parametric studies employing IDA of limited ductile buildings of different structural configurations were undertaken to capture the trends and develop recommendations for guiding structural design.

Computational Insight into Transition Metal Atoms Anchored on B2C3P as Single‐Atom Electrocatalysts for Nitrogen Reduction Reaction

AbstractNH3 is not only an important chemical raw material but also a high‐energy storage chemical with zero carbon. Electrocatalytic nitrogen reduction reaction (NRR), which can be driven by clean electric energy under ambient conditions, has become a promising technology for NH3 synthesis due to its environmentally friendly properties. Because of the limitations of low yield and high overpotential, efficient catalysts are urgently needed to solve this problem. In this study, based on density functional theory method and high throughput screening strategy, the NRR was investigated on transition metal single atom anchored to 2D B2C3P surface (TM@B2C3P) as single‐atom catalysts (SACs). The results showed that V@B2C3P and Ti@B2C3P have good catalytic properties, and the limiting potentials were −0.10 and −0.24 V, respectively. Furthermore, the charge density difference and crystal orbital Hamilton population calculations demonstrated that the high catalytic activity can be attributed to the obvious charge transfer between TM@B2C3P and the adsorption intermediates. It is hoped that this work can play a certain role in exploring the application of SACs in NRR.

МЕХАНІЗМИ ПЛАСТИЧНОГО РУЙНУВАННЯ АРОК

The method of determining the limit load for double-hinged and hingeless arches of fixed and variable rigidity is considered. The calculation is performed using the limit equilibrium method. Arches under the influence of a vertical uniformly distributed load are considered. The cross section is taken in the form of a non-reinforced rectangle. The stress-strain state of an elastic-plastic material is described by the Prandtl diagram. The peculiarities of material deformation are that the yield limits in tension and compression are different. The determination of the limit load is based on taking into account only one factor - the bending moment. When a limiting moment occurs in the arch section, a plastic hinge is formed, which allows unlimited angular deformation without increasing the bending moment. When several plastic hinges are formed, the design diagram of the arch turns into a mechanism. Of course, this approach leads to inaccuracies in determining the limit load. However, at the first stage of the study, the task was to study in detail the features of the plastic mechanism of arch destruction. To study the limiting state of the arches, two methods were used - analytical calculation and numerical calculation using the finite element method. The use of two calculation methods allows you to control the results and increase their reliability. Using analytics, formulas were obtained to determine the limit load and coordinates of the sections where plastic hinges are formed. For arches of constant stiffness, formulas are written to determine the limit load, and for arches of variable stiffness, nonlinear equations are written, the solution of which allows us to find the limit load. For the numerical calculation, a simple method was used, when at each stage of the calculation the coordinate of the formation of the plastic hinge and the corresponding load were determined. The calculation program is written in APDL. As a result of the study, it was revealed that a hingeless arch, depending on the ratio of the lifting boom to the span, has three forms of plastic destruction, while a double-hinged arch has only one form of plastic destruction.

Sealing Characteristics Analysis of New Subsea Wellhead Sealing Device

Subsea wellhead systems are the crucial equipment for the development of oil and gas resources offshore, while the sealing device plays a vital role as the main component of the wellhead system. Once the seal fails, it is necessary to retrieve the original wellhead system and either repair the sealing device or reinstall a new one. This will result in a delay in normal production and an increase in development costs. Therefore, a novel subsea wellhead sealing device is designed. A finite element analysis model is developed to study the underwater wellhead sealing mechanism regarding the equivalent stress and contact stress. The research results show that as the driving block gradually increases from 4 mm to 12 mm, the stress of the 12 convex parts on the sealing body also increases. The maximum equivalent stress reaches 3.5 times the yield limit, indicating that it has entered the yield stage and can achieve a more effective seal. The analysis of the contact stress of the sealing body reveals that the contact stress of the driving block increases, leading to plastic deformation of the sealing body while driving it to achieve a complete seal. In general, the finite element simulation results are consistent with the engineering practice. By analyzing the sealing characteristics, it can serve as the foundation for designing and providing theoretical support for the optimization of the metal-sealing structure.

Comparative evaluation of pediatric endodontic rotary file systems to bending and torsion tests: A finite element analysis

Background and objectiveThe introduction of Paediatric NiTi instruments has transformed the field of paediatric endodontics. However, no studies are available on the mechanical behaviour of these files, wherein Finite Element Analysis (FEA) was found to play a major role. The objective of this study is to evaluate the mechanical behavior of three commercially available pediatric endodontic rotary file systems to bending and torsion stress analysis test through Finite Element Analysis (FEA). MethodsA Finite Element Analysis study was performed on three commercially available pediatric endodontic rotary files (Pro AF baby, Kedo SG and Neoendo pedoflex) available for cleaning and shaping the narrow root canals of the deciduous teeth to bending and torsion tests with the boundary conditions according to ISO 3630-1 specifications. ResultsIn the bending analysis, Pro AF baby files were found to withstand the complete bending tests without yielding with a maximum von Mises stress of 1366 MPa, and Kedo SG, Neoendo Pedoflex file exhibited maximum von Mises stress of 2296 MPa, 1971 MPa. Under torsion tests Kedo SG exhibited maximum stress distribution, while Neoendo Pedoflex and Pro AF baby files exhibited similar stress distribution. ConclusionPro AF baby file effectively withstood the rigorous 45 -degree bending examination without experiencing yielding, while Kedo SG file exhibited higher flexibility. Under torsional resistance test, all the three instruments exhibited similar stress distribution under the yield limit. In summary, the mechanical behaviour (bending and torsion) of pediatric rotary file systems were influenced by design of the files.

Evaluating chickpea varietal performance under different levels of phosphorus application

Chickpea, a vital legume crop, faces yield limitations due to factors like climatic conditions, nutrition deficiency in soil etc. Therefore, the knowledge of adoptive varieties to prevailing climatic conditions and enhancement yield by nutrient management is essential. The present investigation was carried out to assess the effect of varying levels of phosphorus on growth and yield of chickpea, at Agricultural Research Farm of SGRR University, Dehradun during Rabi season of 2022-23. The treatments of experiment comprise two chickpea varieties viz., PG-186 (V1) and Type 9 (V2) and five levels of phosphorus application i.e., 0, 15, 30, 45 and 60 kg P2O5/ha which were replicated thrice in factorial randomize design. The growth and yield parameters were recorded during different crop growth stages to get the response of treatments. The recorded data shows that the variety Type 9 perform better than variety PG-186 in most of the growth and yield attributing characters. Among the phosphorus doses the application of 45 kg P2O5/ha was perform best among all other treatments. The interaction effects of variety Type 9 with 45 kg P2O5/ha (V2T4) showed maximum growth and yield attributing characters over the other treatment combinations like plant height (46.66 cm), number of branches per plant (5.67), dry matter accumulation in plant (30.67 g), 1000 seeds weight (140.00 g) and seeds yield per hectare (14.30 q/ha). Based on experimental findings it can be concluded that variety Type 9 with application of 45 kg P2O5 /ha is best among all other treatments for higher yield of chickpea at Doon valley of Uttarakhand.

Finite element analysis of distraction osteogenesis with a new extramedullary internal distractor

Distraction osteogenesis (DO) is a bone regenerative maneuver, which is conventionally done with external fixators and, more recently, with telescopic intramedullary nails. Despite the proven effectiveness, external approaches are intrusive to the patient’s life while intramedullary nailing damages the growth plates, making them unsuitable for pediatric patients. An internal DO plate fixator (IDOPF) was developed for pediatric patients to address these limitations. The objective of this study was to test the hypothesis that the IDOPF can withstand a partial weight bearing scenario and create a favorable mechanical microenvironment at the osteotomy gap for bone regeneration as the device elongates. A finite element model of a surrogated long bone diaphysis osteotomy fixation by means of the IDOPF was created and subjected to axial compression, bending and torsion. As the osteotomy gap increased from 2 mm to 20 mm, under compression, The average axial interfragmentary strains decreased from 2.33% to 0.35%. Stress increased from 179 MPa to 281 MPa at the contact interfaces of the telescopic compartments, which exceeded the endurance limit of stainless steel (270 MPa) but was below its yield limit (415 MPa). These results demonstrate, that the IDOPF can withstand a partial load bearing scenario and provide a stable biomechanical environment conductive to bone healing. However, high contact stresses at the telescopic interfaces of the device are likely to cause wear, as is frequently reported in telescopic fixators. This study is a step towards refining the IDOPF design for clinical use.

Load transfer model and failure prevention measures of a mechanical-type anchorage for anchor cable in deep roadway

In this paper, the load transfer mechanism of a mechanical-type anchorage is analyzed and studied. The stress distribution on the surface of the anchor cable is clarified, and the means of mechanical analysis and Abaqus finite element method are used. Results indicated there is no stress concentration, and the peak value indicated by the anchor cable appears near the loading end, and the peak value is about 60 MPa larger than the tensile strength. The results of the tensile test show that the failure mode of the anchor cable is the necking fracture of the steel wires, which indicates that the steel reaches the yield limit stress. The anchor efficiency of mechanical-type anchorage is high, which can effectively exert the tensile strength of anchor cable. In deep mine roadway, two failure modes of anchor cable are summarized when mechanical-type anchorage is used. Including shear failure and slippage failure under dynamic action. Aiming at the shear failure behavior, a new type of anchorage was invented, including the self-aligning and shear resistance functions of the anchor cable, and an experiment was carried out. Results indicated anti-shear anchorage can effectively solve the problem of anchor cable failure caused by shear. For the problem of anchor cable slippage failure under dynamic action. The parameters affecting the stability of mechanical-type anchorage are analyzed by means of theoretical analysis and numerical simulation. Results indicated reducing the bevel angle of wedge and barrel, the difference angle between them, and increasing the friction coefficient μ between wedge and barrel can increase the stability of mechanical-type anchorage. The research content of this paper can provide reference for the design of mechanical-type anchorage in similar underground engineering.

Structural Model of Spatially and Plane Reinforced Medium from Rigid-Plastic Anisotropic Materials with Different Yield Limits under Tension and Compression

Structural Model of Spatially and Plane Reinforced Medium from Rigid-Plastic Anisotropic Materials with Different Yield Limits under Tension and Compression

Strategic behaviour in the mean field Ising game

The properties of the mean field version of the Ising game of far-sighted agents on a complete graph are considered. General evolution equation for arbitrary yield of simultaneously decision-making agents is derived. Analytical expressions demonstrating strategic stiffening/cooling in the limits of small and large yield of simultaneously decision-making agents are derived.

Microstructure, wear and residual stresses of selective laser melting AlSi10Mg solid cylinder

Advanced industrial processing technique selective laser melting (SLM) can handle various materials. Although titanium alloys are the main material used in SLM, aluminium alloys may be employed in the future. However, producing aluminium alloys is more complicated. This work uses SLM to make an AlSi10Mg solid cylinder. The aim is to study the mechanical properties and microstructure of products. Layer thickness increases defects; thus, research advises avoiding it. The optical microscope study proved the conduction melting process's stability and hole-freeness. EDX mapping and SEM were used to compare the chemical makeup of as-cast and SLM materials. An unusual microstructure showed consistent alloying component distribution. Investigations examine wear, hardness and residual stresses. Extreme hardness was found. The component has evenly distributed compressive residual stresses within material yield limits.

Evaluation of the fatigue life of AISI 347 specimens with small notches based on local strain considerations

The use of materials data for cyclic loading determined on unnotched specimens to predict the fatigue life of notched components has a long tradition, specifically when it comes to nuclear engineering. The basic principle is that the material behaviour of the unnotched specimens can be transferred to what the material is exposed to be in a notch root. This principle has been proven for large notches. However, what happens when the notch is relatively small? Can the fatigue life still be predicted on the grounds of what has been considered as the local strain or Neuber approach? A key reference in that regard is the Neuber equation or generally the load versus notch stress, notch strain – or any combination of those – relationship. In a larger study, unnotched and notched specimens from the metastable austenitic steel AISI 347 have been tested and characterized providing a database that may give some answers to the question raised above.The unnotched specimens considered here had a cross-section diameter of 10 mm while the notch radii of the notched components were only 0.5 and 0.35 mm, respectively. Notch radii of such dimensions will easily reach a fully plastic condition once the material has exceeded the yield limit, because the difference in load between yield start in the notch and full plastification is relatively small. This fully plastic state exceeds the validity of the Neuber equation and requires respective corrections. In this paper it is shown how such corrections can be obtained through a finite element analysis and how this applies to the cases mentioned above.

Investigations on diamond rotary rolling treatment induced gradient microstructure and its effects on mechanical properties

Surface and subsurface gradient microstructures play a significant role in mechanical properties. To obtain gradient microstructures, a surface strengthening method, namely diamond rotary rolling treatment (DRRT), was proposed in this study. Varied gradient microstructures in 316 L stainless steel were obtained through different DRRT processing parameters. The micro-hardness distribution along the gradient microstructure was tested. The resulting gradient micro/nanostructures in terms of grain size, dislocation density and phase transformation were characterized and evaluated with electron backscatter diffraction (EBSD), transmission electron microscopy (TEM) and X-ray diffraction (XRD) analyses. The corresponding mechanical properties were investigated by slow strain rate test. The results showed that the DRRT could introduce a gradient hardening layer on the surface, accompanied by a gradient distribution of nano-grains, ultrafine grains, fine grains and coarse grains extending from the surface to the material interior. Besides, the gradient microstructure was associated with martensitic phase transformation, slip and dislocation. Compared to milled and untreated specimens, the DRRT-treated specimens exhibited a significant increase in yield strength and reduced ductility. Particularly, a well-designed DRRT process can enhance the yield limit while preserving higher ductility. Additionally, a quantitative relationship between the overall yield strength and the hardness distribution of the gradient microstructure was established.

Kinetic analysis and stability evaluation of femoral neck fracture with internal fixation based on gait rehabilitation training

To explore the biomechanical effects of different internal fixation methods on femoral neck fractures under various postoperative conditions, mechanical analyses were conducted, including static and dynamic assessments. Ultimately, a mechanical stability evaluation system was established to determine the weights of each mechanical index and the evaluation scores for each sample. In static analysis, it was found that the mechanical stability of each model met the fixation requirements post-fracture. During the healing process, the maximum stress on the hollow nail slightly increased, and stress distribution shifted from multi-point to a more uniform single-point distribution, which contributes to fracture healing and reduces the risk of stress concentration. In dynamic analysis, resonance points frequently occurred at low frequencies. With increasing walking speed, the maximum stress increased significantly. At slow speeds, the maximum stress approached the material's yield limit. Under cyclic dynamic loading, the number of cycles barely met the requirements of the healing period, and increasing walking speed may lead to fatigue fractures. The evaluation model established in this study comprehensively considers different mechanical performances in static and dynamic analyses. Based on various mechanical analyses and evaluation systems, the applicability of internal fixation treatment plans can be assessed from multiple dimensions, providing the optimal simulated mechanical solution for each case of femoral neck fracture treatment.

Research on the Isolation of Endophytic Fungi from Papaya and the Prevention of Colletotrichum gloeosporioides.

Endophytic fungi can be used as a source of herbal antioxidants to overcome the limitations of low yield and lengthy growth cycles associated with using plants as raw materials for antioxidant production. Papaya fruit is often susceptible to infection by Colletotrichum gloeosporioides after harvest, leading to postharvest rot. Endophytic fungi were extracted with ethyl acetate, and the initial screening concentration was 100 mg/L. Seven strains were identified, with scavenging rates exceeding 50% and strong antioxidant activity. The IC50 values in DPPH and ABTS free radical scavenging assays ranged from 19.72 to 84.06 mg/L and from 14.34 to 64.63 mg/L, respectively. Strain Y17 exhibited robust antioxidant activity (IC50 < 20 mg/L) and was identified as Penicillium rolfsii (MT729953) through ITS sequencing. Treatment of papaya fruit wounds with a fermentation broth of strain Y17 significantly inhibited the infection and colonization of anthracnose pathogens, resulting in a slowed disease incidence rate. This promoted the activity of protective enzymes, such as CAT, POD, and SOD, in the papaya fruit and slowed down the rate of MDA accumulation. This strain, which was found to have antioxidant activity in this study, has the potential to control anthracnose in papaya and has value in terms of further development and utilization.

Ultrafast Scintillator Based on Zirconium‐Doped Cesium Zinc Chloride Single Crystals and Their Charge Carrier Dynamics

AbstractScintillators have been widely used for high‐energy radiation imaging. It is in great demand and challenge to develop scintillator materials with fast decay time, high scintillation light yield, and low detection limit for high‐resolution imaging applications such as time‐of‐flight positron emission tomography. However, it is still a challenge to develop the ultrafast carrier dynamics to achieve 100% ultrafast decay time with high scintillation light yield. To meet the demand, a series of component‐tunable Cs2ZnCl4: x%Zr single crystals as promising ultrafast scintillators is successfully developed. With 8% of Zr‐dopant (Cs2ZnCl4: 8%Zr), the single crystal exhibits high light yield (28000 photons MeV−1) and low detection limit (51 nGy s−1) under X‐ray excitation. Photo‐induced transient absorption signals on sub‐nanosecond and nanosecond scales ensure almost 100% fast decay time (≈3 ns) in nanoseconds under γ‐ray excitation. In particular, the different radiative transition processes are achieved under ultraviolet and high‐energy radiation due to the tunable carrier dynamics from the shallow trapped state to the self‐trapped exciton (STE) state.