Yb Contents Research Articles

East–west-trending tearing of the Indian slab beneath the eastern Tibetan Plateau: Insights from Eocene–Oligocene potassic adakite-like granites in western Yunnan

Large-scale Eocene–Oligocene potassic adakite-like granites predominantly occur between 25° N and 27° N, north of the Ailaoshan suture in western Yunnan, eastern Tibetan Plateau. However, limited interpretations of their spatial characteristics hinder our understanding of the tectonic evolution in this region. Herein, we present new petrographic analyses, zircon UPb ages, whole-rock major and trace element compositions, SrNd isotopic data and zircon Hf isotopic mapping for these granites. Zircon UPb ages indicate that the adakite-like granites were emplaced at approximately 37.1–33.6 Ma. These granites exhibit high-K calc-alkaline compositions, enriched light rare earth elements and significant depletion in heavy rare earth elements, characterised by high Sr contents (667–1795 ppm), Sr/Y ratios (35–158) and La/Yb ratios (13–62), alongside low Y (8.2–23.3 ppm) and Yb (0.71–1.13 ppm) contents. The adakite-like granites possess high initial 87Sr/86Sr ratios (0.70596–0.70687) and low εNd(t) values (−5.73 to −0.65), with two-stage depleted mantle model ages (TDM2) ranging from 1.3 to 0.9 Ga. Their zircon εHf(t) values range from −5.1 to +0.7, with Neoproterozoic TDM2 ages of 1.4–1.1 Ga. Notably, these adakite-like rocks in western Yunnan exhibit an eastward decrease in zircon εHf(t) and whole-rock εNd(t) values. By integrating these findings with the Hf isotopic mapping results, we suggest spatial heterogeneity in lower crustal composition in western Yunnan. The lower crust in the western Yangtze block comprises Neoproterozoic arc roots, while the lower crust of the Simao block represents a superposition of Neoproterozoic and Permian–Triassic arc roots. Based on the abrupt changes in angle and depth of the eastward-subducting Indian slab, along with the spatial characteristics of the Eocene–Oligocene magmatism, we propose that east–west-trending tearing of the subducted Indian slab occurs along approximately 26° N beneath the eastern Tibetan Plateau.

Electrochemical studies of ytterbium doped Cu/Co nanoparticles synthesized by green fabrication using Callistemon viminalis leaves extract

AbstractBACKGROUNDUtilization of phytochemicals for the preparation of metal oxides nanocomposites has been proven to be a best alternate of chemical synthesis methods. Here, we have extracted, isolated and characterized the phytochemicals of Callistemon viminalis plant extract and utilized them as biofuel in the synthesis of Cu/Co and doped Cu/Co nanoparticles. Callistemon viminalis has been shown to have reducing and stabilizing properties. The plant extracts contain a variety of bioactive substances, including tannins, vitamins, amino acids, saponins, inositol, alkaloids, flavonoids, and terpenes. The use of plant extracts in the synthesis of NPs is a quick, dependable, nontoxic, benign, environmentally friendly, and cost‐effective method. Thus, in the present work, the Callistemon viminalis leaves extract a synthesis of Cu/Co nanoparticles and ytterbium doped Cu/Co nanoparticles, and these nanoparticles were characterized by optical properties (UV), Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X‐rays diffraction (XRD), and electrochemical application.RESULTSSynthesis of Cu/Co nanoparticles and ytterbium doped Cu/Co nanoparticles at room temperature have been successfully done using Callistemon viminalis aqueous leaf extract. Products were confirmed by conducting UV‐ visible spectrophotometry, FTIR, SEM, and XRD confirming the formation of cubic shaped Cu/Co nanoparticles of average diameter of 14 nm. The aqueous leaf extract acted as a capping agent and the existence of organic functional groups were confirmed by FTIR. Upon varying the Yb content in Cu/Co, the particle's size obtained from SEM showed a decrease in size. The band gap energies were also reduced with Yb doping. The stability of the produced NPs was investigated using linear sweep voltammetry LSV on this special and innovative metal oxide electrode. The LSV analysis has shown an elevation in the scan rate detection with an increase in voltage. 55.6 μA current was detected at 10 V for Cu/Co NPs. Ytterbium doped nanoparticles have shown 471.3 μ current voltage value at scan rate of 10 V. Observed value of current of synthesized Cu/Co NPs was 5.7 μA and the observed current of doped Yb(Cu/Co) was 12.5 μA. The increase in current values of dopant Cu/Co nanoparticles is due to the higher pore volume and surface area of copper, which promotes the transfer of electrons, so the current density is greater of the doped material than the composite NPs. The electrical resistivity of Cu/Co nanoparticles has shown a decline with elevation in current indicating its semiconducting nature.CONCLUSIONIn summary, biologically synthesized Cu/Co and ytterbium doped Cu/Co nanoparticles at room temperature have been successfully synthesized based on the greener approach using Callistemon viminalis aqueous leaf extract. The utilization of the Callistemon viminalis plant‐mediated approach, which makes the procedure more affordable and environmentally benign than chemical synthesis, is one of the study's major contributions. © 2024 Society of Chemical Industry (SCI).

Geochronology and petrogenesis of Early Mesozoic Rb-mineralized granitic rocks from the Liuzhangshan Rb, West Qinling Orogen Belt, China

ABSTRACT The newly discovered Liuzhangshan (LZS) Rb deposit is a large granite-type deposit in the West Qinling Orogenic Belt (WQOB), spatially associated with biotite monzogranite. Previous research has focused on the geological characteristics and metallogenic conditions of the LZS Rb deposit; however, its geochronology and petrogenesis remain unclear. In this study, monazite U-Pb dating of biotite monzogranite in the LZS deposit yielded a U-Pb age of 200.8 ± 0.9 Ma via laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Combined with the age of magmatic rocks in the WQOB, we propose a potential mineralization event related to Rb around 200 Ma in the WQOB. The biotite monzogranite belongs to weakly peraluminous, high-K calc-alkaline serious, containing high SiO2, Na2O, K2O, and low FeO, MgO, CaO, and P2O5. Compared with primitive mantle and relatively unfractionated granodiorites found in the WQOB, the biotite monzogranite enriched in Rb, Th, U, and Pb, deleted in Ba, Sr, and Ti, and showed negative Eu anomalies, a high Rb/Sr ratio, and a low K/Rb ratio, an ∑REE of 31.3 ppm, an LREE/HREE ratio of 6.48, a LaN/YbN ratio of 2.59, an Mg# of 4.15, and a crystallization temperature of 760°C, the biotite monzogranite also had a high differentiation index (DI = 98.2), apparent tetrad effect (TE 1,3 = 1.12 ~ 1.15), characteristic of highly fractionated I-type granite. Monzoite from the biotite monzogranite in the LZS deposit has negative εNd(t) values ranging from −12.45 to −11.17, and TDM1 of 1569 ~ 2018 Ma, indicating that the LZS biotite monzogranite originated from the partial melting of a Mesoproterozoic ancient basement material, with a minor contribution from mantle-derived melts. Highly differentiated, low Sr and Yb contents, Sr/Yb ratios, and low crystallization temperature magma facilitated the enrichment of Rb.

Improving mechanical properties of Mg–Zn-Nd-Zr alloy by low alloying with Yb and corresponding strengthening mechanisms

This study was aim to explore the possibility of adding Yb element to Mg–6Zn-3Nd-0.5Zr alloy to develop a commercial high-strength Mg alloy under the condition of low rare earth content. A systematic investigation was conducted and it was shown that the phase compositions were changed by the Yb addition (0–2 wt%). The Mg–Zn phases disappeared while a new phase, (Nd,Yb)Zn2, were formed. The volume fractions of precipitates increased with increasing Yb content. Due to the extra precipitation through the process of extrusion, the volume fractions of precipitates of as-extruded alloys were slightly higher than that of the as-cast alloys. All as-extruded alloys displayed the same strong fiber texture with the (10 1‾ 0) perpendicular and the [1‾ 100] parallel to the extrusion direction. The Yb addition improved the DRX degree, but has little effect on grain orientations, and adjusted the texture intensities by influencing DRX process. When the Yb content is 1.0 wt%, the alloy showed best mechanical properties, with the yield strength and ultimate tensile strength of 400 MPa and 407 MPa. The high strength is the result of the combined effects of excellent grain boundary and texture strengthening.

Anatomy and genesis of the world’s largest carbonate-hosted Zn-Pb deposit: New insights from ore characteristics, Zn-Pb-C-O isotopes, and trace element constraints of the Huoshaoyun deposit, Karakorum Range, Xinjiang

The Huoshaoyun deposit in the Karakorum area of NW China is the world’s largest zinc-lead carbonate ore deposit. Here we investigate the genesis of the mineralization based on multiproxy investigations. The deposit contains zinc-lead carbonate and sulfide minerals, with smithsonite (Smt), cerussite (Cer), and sulfides accounting for 85%, 10%, and 5% of the total lead and zinc resources, respectively. Three ore-forming stages, involving Smt, Cer, and sulfides ores were summarized. The Smt mineralization is characterized by veined, massive, and stratified Smt forming horizontal sedimentary layered ore and vertical feeder veins similar to the SEDEX-type deposits. The sulfide and Cer veins display typical hydrothermal characteristics and are superimposed on the massive Smt ores. The Smt ores show high Li, Be, Cr, Y, Ba, Nd, Yb, and Zr contents, whereas the Cer veins have extremely high Sr contents (up to 3814–9174 ppm) and low Zr contents (less than 0.01 ppm). Galena and sphalerite show higher Cd concentrations compared to Smt and Cer ores.The Smt ores differ with different spatial locations, with Smt ores formed at the vent have δ66Zn values of +0.15‰ to +0.21‰, the massive Smt formed close to the vent show a value of +0.13‰, and those formed away from the vent show a value of 0.05‰, all values being close to 0. The sulfides have δ66Zn values of −0.09‰ to +0.04‰. The C-O isotopes of Smt ores are similar to both altered and unaltered host limestone, suggesting that the limestone was a potential source for carbon and oxygen. Quartz with veined Smt shows magmatic signatures with δ18OVSMOW of +1.14‰ to +2.23‰, high Pb (115–401 ppm) and Zn concentrations (390–997 ppm), whereas quartz associated with sulfide has meteoric fluid signature with the lowest δ18OVSMOW (−14‰ to −10.7‰), low Pb (11.6–49.0 ppm) and Zn (18.1–72.8 ppm) concentrations. The temperature of equilibration computed based on oxygen isotope fractionation between Smt and coeval quartz indicate a dual source with that of quartz derived from an aqueous fluid, whereas the source for Smt might involve CO2 or HCO3−.We trace multiple metallogenic stages for this deposit including exhalation, hydrothermal deposition, and fault-controlled sulfide vein formation. The largest orebody (III-1) preserves a 16 Mt reserve of Zn and was formed by crust-mantle interaction at ca. 195 Ma in the early development of the Linjitang post-arc rift system. Fluid convection, zinc enrichment driven by granitic magma, volcanic activity, and karst alteration induced by acid rain in a lagoonal environment promoted ore enrichment.

Improved thermoelectric properties in solid state microwave of Zn1-xYbxSb compound by Yb for Zn substitution

In this research, the Zn-Yb-Sb materials in the form Zn1-xYbxSb; x = 0.02 to 0.8, were composed by a solid-state microwave method. These samples were examined to determine the crystal structure by XRD analysis, which indexed to the orthorhombic phase. The dominant peak (112) had a clearly shift in Bragg angle from 28.536° to 28.784° with increasing Yb content. The Yb content (x) effects on the thermoelectric properties (TE) was measured at the temperature reach to 500 K. Increased the Yb content (the sample with x = 0.8) in Zn1-xYbxSb caused an increase in the Seebeck coefficient (486 μV/K at 433 K) and a decrease in each of the hole concentration (3.02 × 1021 cm−3) and the electrical conductivity (5320 S/m). Ascribing to the increased Seebeck coefficient, the higher value of the power factor measured in this research was 1257 μW/mK2 at 473K for the sample of Zn0.92Yb0.08Sb (x = 0.08).). These experimental results suggest that a clear idea of the application of the Zn1-xYbxSb for TE modules.

Petrogenesis of K-rich and high-mg adakitic rocks in the North Dabie terrane, China: products of early cretaceous orogenic collapse

ABSTRACT Understanding orogenic collapse is key to comprehending the evolution of continental collision orogens. The Dabie orogen is a collapsed continental collision orogen that provides an ideal window for revealing orogenic collapse. Here, we conduct fieldwork, whole-rock geochemistry, and zircon U-Pb dating of the Daoshichong pluton in the North Dabie terrane to elucidate the collapse mechanism of the Dabie orogen. The Daoshichong pluton is composed of quartz monzodiorite and mafic microgranular enclaves (MMEs) with an Early Cretaceous (~130 Ma) crystallization age. The Daoshichong pluton is strongly deformed and ductile, displaying a gneissic structure. The quartz monzodiorites are K-rich and high-Mg adakitic rocks. They contain 60.2–63.3 wt.% SiO2 and have high K2O (2.88–3.42 wt.%) and MgO (2.08–3.04 wt.%) contents with relatively high Mg# values (44.4–49.3). They exhibit high Sr (673–819 ppm) and low Y (11.4–20.9 ppm) and heavy rare earth elements (e.g. Yb: 0.94–1.87 ppm) contents, resulting in high Sr/Y (35.1–72.0) and (La/Yb)N (15.7–36.1) ratios. The MMEs exhibit geochemical characteristics similar to those of the Early Cretaceous mafic – ultramafic rocks of the Dabie orogen. They have low SiO2 contents (48.1–51.9 wt.%) and high MgO contents (3.27–5.62 wt.%) with high Mg# values (47.3–51.2). They also exhibit relatively high Ni (16.6–63.6 ppm), Cr (30.5–164.6 ppm), Y (18.2–25.8 ppm) and Yb (1.50–1.94 ppm) contents and high Sr/Y ratios (53.7–109.5). Evidence from fieldwork and geochemistry distinctly indicates magma mixing during magma evolution between the MMEs and the quartz monzodioritic host. Thus, the Daoshichong quartz monzodioritic host and the MMEs can be interpreted as a mixture of mantle-derived magma and over-thickened lower continental crust-derived adakitic melt. Previous studies suggest that the Early Cretaceous (~130 Ma) high-Mg adakite-like rocks are distributed only along the eastern margin of the Dabie orogen (i.e. along the Tan – Lu Fault). This study is the first to report a homochronous (~130 Ma) K-rich and high-Mg adakite-like pluton in the core of the Dabie orogen. Our results suggest that a whole delamination of the over-thickened orogenic root caused the orogenic collapse, subsequently triggering crust – mantle interactions, dome structure, and magmatism in the Dabie orogen.

Petrogenesis and Metallogenesis of Late Cretaceous Adakites in the Nuri Large Cu-W-Mo Deposit, Tibet, China: Constraints from Geochronology, Geochemistry, and Hf Isotopes

The Gangdese metallogenic belt in Tibet is an important polymetallic metallogenic belt formed during the subduction of the Neo-Tethys Ocean and subsequent India–Asia collision. Adakitic rocks are widely distributed in this belt and are considered to be closely related to porphyry–skarn Cu-Mo polymetallic mineralization. However, the petrogenesis and geodynamic setting of the Late Cretaceous adakites in the Gangdese belt remain controversial. In this study, we focus on the quartz diorite in the Nuri Cu-W-Mo deposit along the southern margin of the eastern Gangdese belt. LA-ICP-MS zircon U-Pb dating yields a Late Cretaceous age of 93.6 ± 0.4 Ma for the quartz diorite. Whole-rock geochemistry shows that the quartz diorite possesses typical adakitic signatures, with high SiO2, Al2O3, and Sr contents, but low Y and Yb contents. The relatively low K2O content and high MgO, Cr, and Ni contents, as well as the positive zircon εHf(t) values (+6.58 to +14.52), suggest that the adakites were derived from the partial melting of the subducted Neo-Tethys oceanic slab, with subsequent interaction with the overlying mantle wedge. The Late Cretaceous magmatic flare-up and coeval high-temperature granulite-facies metamorphism in the Gangdese belt were likely triggered by Neo-Tethys mid-ocean ridge subduction. The widespread occurrence of Late Cretaceous adakitic intrusions and associated Cu mineralization in the Nuri ore district indicate a strong tectono-magmatic-metallogenic event related to the Neo-Tethys subduction during this period. This study provides new insights into the petrogenesis and geodynamic setting of the Late Cretaceous adakites in the Gangdese belt, and has important implications for Cu polymetallic deposit exploration in this region.

Evidence from adakitic rocks for a switch in magmatic source at ca. 460 Ma in the Karamaili Ocean of East Junggar, NW China

Early Paleozoic magmatism can preserve critical geological records related to subduction-accretion in the Central Asian Orogenic Belt (CAOB). Here, we report new geochemical, geochronological and isotopic results for diorites-granitoids in the Karamaili region of East Junggar, Northwest China. These rocks record high Sr, but low Y and Yb contents, with high Sr/Y ratios but low La/Yb ratios, and can be divided into low-silica adakite and high-silica adakite. All samples are with typical features of subduction-related magmas and show relatively juvenile Sr, Nd and Hf isotopic ratios. Zircon LA-ICP-MS UPb ages are between 468 ± 4 Ma and 441 ± 5 Ma. The low-silica adakite has relatively high Mg# and Cr, Co and Ni contents, implying a possible mantle origin. The Hongliuxia diorite (low-silica adakite) has relatively high Th contents and Th/Yb ratios, but records lower ɛNd(t) (+4.1) and ɛHf(t) (+8.9 − +12.2) values than those of the granitoids (high-silica adakite), implying the low-silica adakite was influenced by the subduction of sediments. The low-silica adakite likely originated from partial melting of a mantle wedge, metasomatized by subduction-related fluids and sediments, whereas the high-silica adakite was likely derived from partial melting of juvenile mafic lower crust. There is little involvement of garnet in the magma source, consistent with fluid-flux melting at pressures between 10 and 12.5 kbar (corresponding to 30–40 km depth). We suggest that the increase in Nd and Hf isotopic ratios at ∼460 Ma may imply that subduction began to retreat at this time in the Karamaili Ocean during evolution of the CAOB.

Geochemistry and geochronology of the TTG-sanukitoid suite in the Zhulagou area: Constraints on the Neoarchean crustal evolution of the western North China Craton

The Archean basement in the Yinshan Block of the western North China Craton consists of a variety rock of assemblage, including TTG (tonalite-trondhjemite-granodiorite) rocks and some dioritic gneiss (sanukitoid). Understanding the petrogenesis of these rocks is crucial for comprehending the late Neoarchean crustal evolution of the western North China Craton. This study provides a new geochronological, geochemical, and Sr-Nd-Pb-Hf isotopic data for the TTG-sanukitoid suit that was newly identified in the Zhulagou area. The late Neoarchean TTG gneisses were emplaced around 2.54–2.50 Ga, while dioritic gneiss was emplaced between 2.53 and 2.50 Ga. The TTG gneisses exhibit high SiO2 (64.46–72.24 wt%) and Al2O3 (13.37–16.48 wt%) contents, relatively elevated (La/Yb)N and Sr/Y ratios, as well as low Y and Yb contents. They display variable εHf(t) (+0.94 to +3.57) and εNd(t) (−1.02 to +0.82) values, with relatively low Pb isotopic compositions, suggesting that they were derived from the partial melting of a thickened mafic lower crust. On the other hand, dioritic gneiss shows moderate SiO2 (58.05–61.87 wt%) content, high MgO (2.62–4.06 wt%), Al2O3 (14.42–18.44 wt%) and Cr contents, but relatively low (La/Yb)N values, showing geochemical affinity to the Archean sanukitoids. The dioritic gneiss exhibits variable εHf(t) values (−2.29 to +5.56) and εNd(t) (−2.05 to +2.02), with relatively low Pb isotopic compositions. Furthermore, the presence of amphibolite xenoliths, along with the high Mg# contents (36.84–53.49), indicating the addition of mantle-derived components to its source region. Therefore, the formation of the dioritic gneiss is primarily attributed to partial melting of the thickened (mafic) lower crust and the addition of mantle material. By combining previous studies with the new data presented in this study, we propose that a late Neoarchean tectonic regime involving a mantle plume is the most favorable explanation for the two major magmatic events in the Yinshan Block. Firstly, the earlier pulse/stage of mantle plume resulted in the ∼2.7 Ga thickened (mafic) lower crust and a limited amount of TTG rocks. Subsequent pulse/stage of mantle plume triggered partial melting of pre-existing thickened (mafic) lower crust and generated 2.54–2.50 Ga TTG rocks and dioritic gneiss.

Petrogenesis of late Early Cretaceous adakitic rocks in the offshore Bohai Bay Basin, Eastern China, and tectonic implications

ABSTRACT Adakitic rocks provide important data on Early Cretaceous magmatism and the tectonic setting of the eastern North China Craton. This study reports new data on adakitic alkali rhyolites in the offshore Bohai Bay Basin, eastern China. The eruption age of the rhyolites is represented by a weighted mean206Pb/238U age of 114.4 Ma. The geochemical characteristics of the samples are similar to those of adakitic rocks, with high Sr (307–1686 ppm) and low Y (3.18–11.3 ppm) and Yb (0.30–1.39 ppm) contents, as well as high Sr/Y (40–70) ratios. Moreover, the samples show relatively uniform εNd(t) values (−15.48 to −16.51) and older TDM2 values (2253–2170 Ma). These geochemical features indicate that they were mainly derived from partial melting of the lower continental crust. Amphibole rather than garnet is the main residual phase in the source, indicating that the magma originated from the normal lower crust (<40 km) rather than from the thickened lower crust. Our data, along with regional geology, lead us to suggest that the lithosphere was being stretched and thinned before ca. 114 Ma in the eastern North China Craton, and the region was already under an intraplate tectonic setting associated with a large mantle wedge at ca. 114 Ma. The tectonic regime was triggered by the rollback of the Paleo-Pacific Plate during the late Early Cretaceous.

Petrogenesis of early-middle jurassic igneous rocks in the Central Jilin Province, NE China: implications for the early subduction of the Paleo-Pacific ocean and crustal growth

ABSTRACT Crustal growth is closely associated with the oceanic subduction process, although the precise mechanism involved remains poorly constrained. Northeast (NE) China is an important component of the largest accretive orogenic belt worldwide – Central Asian orogenic belt. Its accretionary process was dominated by the Paleo-Asian and Paleo-Pacific Oceans; thus, NE China can provide a promising insight to explore this complex mechanism. We report new geochronological, geochemical and Hf isotopic compositions of the igneous rocks found in the Central Jilin Province, NE China. The geochronological results reveal that these igneous rocks were formed during 174.7 − 167.7 Ma (i.e. Early−Middle Jurassic). The quartz diorite and monzogranites from the northeastern margin of the North China Craton have high Sr (314 − 757 ppm) content, (La/Yb)N (7.11 − 29.9) and Sr/Y (41.50 − 157) ratios, low Y (2.03 − 12.97 ppm) and Yb (0.30 − 1.34 ppm) contents, exhibiting adakitic features. Coupling with their significant negative εHf(t) values (−32.51 to − 5.45), we propose that these igneous rocks were originated from the partial melting of an ancient thickened lower crust. In contrary, the syenogranite, granite porphyry, and porphyritic monzogranite from the Zhangguangcai and Jiamusi blocks are characterized by high K calc-alkaline, low MgO (0.03 − 0.88 wt.%), Zr + Nb + Ce + Y (141 − 462 ppm) contents and Sr/Y (0.93 − 17.40) ratios, indicating an affinity of I−type granite. In view of their positive εHf(t) values (5.41 to 9.47), we suggest that they were originated from the partial melting of a juvenile lower mafic crust. Despite they have different magma sources, all the Jurassic igneous rocks exhibit typical geochemical signatures associated with subduction, such as enriched in large ion lithophile elements and depleted in high field strength elements. Considering the spatial-temporal distribution of coeval igneous rocks within the region, we propose that the Early Jurassic is the early subduction of the Paleo-Pacific Ocean. The Jurassic igneous rocks can be divided into two categories, one with high Sr/Y ratios and negative Hf isotope, and the others with low Sr/Y ratios and positive Hf isotope, which may indicate that crustal architecture in subduction zone has a significant effect on continental crustal growth and reworking in NE China.

High thermoelectric performance in polycrystalline Yb3Ge5 thin films

The development of eco-friendly thin-film thermoelectric generators for microenergy harvesting applications is highly desired. Ge-based materials have recently attracted significant research interest because of their superior performance at room temperature as human-compatible thermoelectric constituents. We examined the synthesis of Yb3Ge5 thin films and assessed their thermoelectric properties, considering the exceptional ability of Yb as a heavy metal to scatter phonons. The components of the resulting thin film were strongly dependent on the Yb/Ge deposition ratio and the subsequent annealing temperature. An increase in the Yb content augmented the formation of Yb2O3, whereas an increase in the Ge content facilitated the formation of Ge crystals. These trends were more evident at higher annealing temperatures. By controlling the YbGe composition, a power factor of 1470 µW m−1 K−2 was obtained at an annealing temperature of 700 °C, along with a low thermal conductivity of 3.1 W m−1 K−1. Machine-learning-facilitated data analysis revealed that the high power factor originated from Yb3Ge5. Notably, the power factor reached 1370 µW m−1 K−2 even at a temperature of 500 °C, causing the expansion of heat-resistant plastic films. Thus, we established the impressive potential of Yb3Ge5 as a suitable material for eco-friendly thin-film thermoelectric generators.

Cretaceous magmatism in the northern Lhasa Terrane: Implications for the tectonic evolution and crustal growth tempos of central Tibet

The subduction and demise of an ocean plate are generally recognized as essential processes that result in the reworking and maturation of the continental crust. The northern Lhasa Terrane in central Tibet represents the forefront of the Lhasa-Qiangtang collision belt following the closure of the Bangong-Nujiang Ocean. Thus, it is a pivotal location to study the transition processes from oceanic lithosphere subduction to continental collision as well as pertinent crustal growth mechanisms. Here, we present zircon U-Pb dating, whole-rock major and trace element and Sr-Nd isotope, and zircon Hf isotope and trace element data of the Mendang igneous complex, Baingoin County, northern Lhasa Terrane. Geochronological results show that the granodiorites, trachydacites, and rhyolites in the Mendang igneous complex formed at ca. 122−116 Ma, 97 Ma, and 73 Ma, respectively. The Early Cretaceous granodiorite samples are peraluminous with high SiO2, Al2O3, and K2O contents, and moderate A/CNK (molar ratio of Al2O3/[CaO + Na2O + K2O]) values, which are similar to those of typical felsic peraluminous I-type granites. The granodiorites are characterized by enrichment in light rare earth elements and large ion lithophile elements (e.g., Rb) and depletion in high field strength elements (e.g., Nb, Ta). They also show the most enriched whole-rock Sr-Nd [(87Sr/86Sr)i = 0.7072−0.7078; εNd(t) = −7.60 to −5.08] and zircon Hf [εHf(t) = −4.46 to +1.02] isotope compositions, indicating that the Early Cretaceous granodiorites were likely derived from an ancient basement under a subduction setting. The trachydacites have uniform SiO2, high Al2O3, Sr contents, and Sr/Y values, and low Y and Yb contents, belonging to adakitic rocks. They show more depleted whole-rock Sr-Nd [(87Sr/86Sr)i = 0.7065−0.7066; εNd(t) = −0.56 to −0.22] and zircon Hf [εHf(t) = 4.36−7.84] isotopes than the granodiorites, suggesting that the trachydacites may have generated from partial melting of the juvenile thickened lower continental crust. The rhyolites have the highest SiO2 and K2O contents in the Mendang igneous complex, and significant depletion of Ba, Sr, Eu, P, and Ti. They have slighter more enriched whole-rock Nd [εNd(t) = −3.71 to −1.16] and zircon Hf [εHf(t) = 1.03−4.31] isotope compositions than the trachydacites. These features suggest that the rhyolites were highly fractionated products of the crustal melts. Whole-rock Sr-Nd and zircon Hf isotopes of the Mendang igneous complex show a kink trend from enrichment to depletion and then transfer to enrichment again, signifying an increased contribution of juvenile materials in the northern Lhasa Terrane toward progressively replacing the ancient lower crust and accumulating to newly formed crust. The estimated crustal thickness beneath the northern Lhasa Terrane shows a sharp increase from the Early to Late Cretaceous and peak at ca. 97 Ma, whereas it largely decreases in the Late Cretaceous. Integrated with previous studies, we propose that the formation of the Mendang igneous complex (122−73 Ma) elaborately documents the regional tectonic transition from oceanic lithosphere subduction to demise as well as continental crustal differentiation and maturation. The rollback and breakoff of the southward subducted Bangong-Nujiang oceanic slab in the Early Cretaceous initiated diverse magmatism in the northern Lhasa Terrane. During the early Late Cretaceous, the widespread adakitic and Mg-rich magmatism was attributed to the delamination of the thickened lithosphere following the final amalgamation of the Lhasa and Qiangtang Terranes. In the late Late Cretaceous, post-collisional extension induced the formation of the rhyolites in the northern Lhasa Terrane. The growth and destruction of the continental crust had certain tempos from the oceanic lithosphere subduction to continental post-collision stage.

Whole-Rock and Apatite Geochemistry of Late Triassic Plutonic Rocks in the Eastern Songpan-Ganzi Orogenic Belt: Petrogenesis and Implications for Tectonic Evolution

Abstract To constrain the late Triassic tectonic evolution of the Songpan-Ganzi orogenic belt, we present new whole-rock and in situ apatite geochemistry for plutonic rocks in its eastern margin. The Taiyanghe pluton can be classified into two rock types: dioritic and granitic rocks. The former exhibits low SiO2 and MgO contents but high Al2O3, Th, LREE contents, and Th/Yb and Th/Nb ratios, as well as low Ba/La and Ba/Th ratios and enriched Sr-Nd isotopic compositions, which, together with apatite geochemistry and Nd isotopes, indicate that they were derived from low degrees of partial melting of lithospheric mantle metasomatized by sediment-derived melts. The latter is characterized by high Sr and low Y and Yb, with elevated Sr/Y and (La/Yb)N ratios, implying an adakitic affinity. Notably, their similar Sr-Nd isotopic compositions indicate an origin from partial melts of a newly underplated lower crust. The Maoergai granitic rocks, characterized by high Sr and low Y and Yb contents with high Sr/Y and (La/Yb)N ratios, are indicative of adakitic rocks. In combination with the enriched whole-rock Sr-Nd isotopes and the apatite Nd isotopic data, we suggest that they were generated by the partial melting of the ancient thickened mafic lower crust. The Markam and Yanggonghai felsic granitoid rocks are peraluminous and similar to typical S-type granitoids, indicating an origin from remelting of the Triassic metasedimentary rocks. Based on the temporal-spatial relationship of the late Triassic plutonic rocks in the orogenic belt, we suggest that these rocks were formed in association with the roll-back and subsequent break-off of a subducted slab of the Paleo-Tethys Ocean. During the subduction, the formation of the Maoergai adakitic rocks was triggered by slab roll-back, whereas the magmatic “flare up” (ca. 216–200 Ma) was likely caused by slab break-off. This indicates that the final closure of the Paleo-Tethys Ocean happened in the end of the Triassic or Early Jurassic.

Pervasive Neoarchean melting of subducted sediments generating sanukitoid and associated magmatism in the North China Craton, with implications for the operation of plate tectonics

Abstract The Mesoarchean to Neoarchean period (ca. 3.0–2.5 Ga) is the most important stage during the emergence and evolution of plate tectonics. However, plate subduction at this time may have been less stable and perhaps more susceptible to the lubrication effect of sediments than the modern counterpart. Such predictions have not yet been verified by field-based investigations. In this work, we identified two types of rock units (i.e., sanukitoids and associated adakitic suites, exposed in the Eastern Hebei Complex of the North China Craton) and illustrated their petrogenesis and tectonic context through field, geochronologic, geochemical, and isotopic investigations. Laser ablation–inductively coupled plasma–mass spectrometry zircon U-Pb analyses suggest that the two magmatic suites formed within a relatively short time span of ca. 2596–2544 Ma and ca. 2559–2533 Ma, respectively. The sanukitoids are composed of meta-andesites and diorite porphyrites and characterized by relatively high MgO (3.94–5.62 wt%), Mg# (50–61), Cr (73–343 ppm), and Ni (37–111 ppm) values. The adakitic rocks are composed of granodiorite-granite gneisses and have relatively high Sr (316–1001 ppm) and low Y (7–13 ppm) and Yb (0.83–1.37 ppm) contents, and relatively high Sr/Y (36–89) and La/Yb (16–45) ratios. Rocks from both suites exhibit depletions of Nb, Ta, and Ti and have similar Sr-Nd-Hf-Zn isotopes: variable (87Sr/86Sr)i (0.7002–0.7053), weakly positive εNd(t) (+0.3 to +1.7) and εHf(t) (+1.8 to +6.8), and slightly heavy δ66Zn (0.30‰–0.36‰). These geochemical characteristics indicate that the sanukitoids were derived from the melting of subducted sediments followed by melt-mantle interaction, whereas the adakitic rocks were produced by direct partial melting of subducted plate (including tonalite-trondjhemite-granodiorite melts) under a garnet stability field with minor sediments. Such distinct magmatic rock associations, together with the coeval charnockites and tholeiites with diverse compositions in the adjacent area, can be best explained by a slab breakoff model. Further, events associated with slab breakoff are likely to represent a transition of a quasi-plate tectonic regime, characterized by multiple, continuous, and stagnant attempts to start the modern-style subduction on Earth. In addition, the emergence of sanukitoids and associated magmas symbolized the onset of supracrustal recycling into the mantle. Combined with the Nd-Hf-Zn isotopes of diverse magmatic rocks in the North China Craton that are comparable to other Precambrian magmatic rock suites worldwide, we suggest that supracrustal recycling symbolized the onset of plate tectonics since ca. 3.0 Ga, and by inference played a key role in the development of subduction-driven plate tectonics in addition to Earth’s secular cooling.

Effect of ytterbium on hardness and color of titanium nitride thin films

Yb mononitride (YbN) has a B1 (NaCl-type) structure similar to the structure of titanium nitride (TiN), which makes it a candidate for use in new hard coating materials via solid-solution hardening. Ternary system (Ti–Yb–N) thin films with various Yb contents were prepared on Si substrates by pulsed laser deposition, and compositional analysis confirmed that the resultant films contained the expected elements. Phase identification revealed that the ternary nitride (Ti1−x Yb x )N thin films were all single-phase thin films that comprised YbN in TiN as a solid solution in the form of a B1- (Ti1−x Yb x )N phase. Although the hardness of the Ti–Yb–N thin films could be increased to a certain degree compared with that of a pure TiN thin film, the improvement was not significant. A change in the optical properties of the (Ti1−x Yb x )N thin films was indicated by a change in their color from gold to copper to silver with increasing x. This effect could make such thin films suitable for use as decorative coatings that are resistant to oxidation.

Genesis and tectonic setting of an Early Palaeozoic skarn in the East Kunlun Orogenic Belt, China: constraints from adakitic rocks and garnet megacrysts

ABSTRACT The East Kunlun Orogenic Belt (E-KOB) in the northern Tibet Plateau has undergone a long multi-stage history of drifting, accretion, and collision of the Proto- and Palaeo-Tethyan oceans. It has been addressed a trench-arc-back-arc basin system of the Proto-Tethys in the E-KOB, and the tectonic history of this major ocean has been well constrained by previous studies. However, the evolution of the back-arc basin still remains unclear. In this study, the Yugusayi monzodiorite, quartz-bearing syenite, and gradually contacted skarn rocks characterized by garnet megacrysts, in the North Qimantagh Belt were investigated. To reveal the tectonic setting and skarnization mechanism, geochemical and geochronological studies were conducted on the intrusions and garnet skarn, and the elemental compositions of the garnet megacrysts were also analysed. These monzodioritic rocks have high MgO (6.87–8.31 wt.%), Sr and La contents, low Y and Yb contents, and relatively high La/Yb (31–55) and Sr/Y (41–51) ratios, resembling to high-Mg adakites. They display right-sloping chondrite-normalized REE patterns, enriched in LILEs, and depleted in Ti with significant Nb-Ta troughs, which are similar to those of continental arc rocks. Zircons from monzodiorite and skarn samples have contemporaneous U-Pb ages of 459 ± 3 Ma and 454 ± 4 Ma with εHf(t) values of − 8.53 to − 4.64 and − 7.7 to + 12.8, respectively. In addition, the chemical zoning garnet megacrysts are composed mainly of grossular and andraditic grossular, and are characterized by spoon-shaped REE patterns. Based on our new data and the regional geology, it can be concluded that the Yugusayi intrusive rocks formed in a subduction-related tectonic setting and resulted in the skarnization. These data not only provide key constraints on the initial subduction of the Qimantagh back-arc basin’s oceanic crust, but also offer a unique opportunity to explore the Caledonian skarnization in the Qimantagh Belt.

Meso-Neoproterozoic tectonic-thermal events in the Qaidam Block, NW China and their geological significance: Constraints from drill cores geochronology and geochemistry studies

As a micro-continent lying at the junction of the North China, Yangtze, and Tarim Cratons in northwest China, the composition and tectonic-thermal history of the Qaidam Block not only are crucial for determining its tectonic attribute and relationships with surrounding cratons, but also can provide key constraints on convergence, fragmentation, and paleogeographic reconstruction of Columbia and Rodinia. In this study, systematic petrology, geochemistry, and zircon U–Pb–Hf isotope analyses were conducted on newly discovered Meso-Neoproterozoic granitic rocks from drill cores in the Qaidam basin and three stages granitic magmatism at ca. 1420 Ma, ca. 900 Ma and 780–750 Ma are yielded. The ca. 1420 Ma granitic rocks exhibit characteristics of highly fractionated I-type granites, with high Yb but low Sr contents, low Sr/Y and La/Yb ratios, high zircon saturation temperatures (774–831 ℃), and positive εHf(t) values (–0.04 to +11.35) with TDM2 values of 2178–1468 Ma, suggesting that they were mainly derived from the ancient crust with mantle magma input under an extensional setting. The ca. 900 Ma granitic rocks have high A/CNK values (1.01–1.21) and variable zircon εHf(t) values (–1.93 to + 6.58) with TDM2 ages between 1402 and 1910 Ma, indicating they are S-type granites formed by partial melting of sedimentary rocks in thickened crust. The ca. 780–750 Ma granites have high Zr + Nb + Ce + Y contents, 10000* Ga/Al ratios, and crystallization temperatures (mean = 808 ℃), belonging to the A1-type granite formed in a continental rift setting.Combined with the previous researches, the Meso-Neoproterozoic tectonic-thermal events in the Qaidam Block can be divided into three stages, 1.8–1.1 Ga, 1.0–0.9 Ga and 850–750 Ma, corresponding to the fragmentation of Columbia, and the assembly and breakup of Rodinia, respectively. Comparing the Qaidam Block with the surrounding blocks and the major cratons in Columbia and Rodinia, it is considered that the Qaidam Block was splited from the Tarim Craton and they may have occupied an interior position in Columbia but a peripheral position in Rodinia, connecting to the India and East Antarctica.

Paleoproterozoic crustal evolution of the Tarim Craton, NW China: Constraints from geochronology and geochemistry of orthogneisses and granitic veins in the Xingdi region of the Quruqtagh Block

The Archean–Paleoproterozoic basement rocks, exposed in the Xingdi region of the Quruqtagh Block, provide a great opportunity to characterize the early crustal evolution of the Tarim Craton and reconstruct the Columbia supercontinent. Here we report zircon U–Pb ages, Lu–Hf isotope compositions, and bulk-rock geochemical data of orthogneisses and granitic veins from the Xingdi region of the Quruqtagh Block in the northeastern margin of the Tarim Craton. The orthogneisses formed in the late Neoarchean to early Paleoproterozoic (2504 ± 33 Ma, 2419 ± 24 Ma and 2450 ± 27 Ma), and were metamorphosed in the late Paleoproterozoic (1789 ± 43 Ma and 1748 ± 35 Ma). The orthogneisses have relatively high Sr (312–710 ppm) contents, and low Y (5.3–13.8 ppm) and Yb (0.46–1.10 ppm) contents, resulting in high Sr/Y (32–118) and La/Yb (17–64) ratios that are characteristics of adakites. The relatively high Mg# (49–55) and depleted zircon Hf isotope characteristics (positive εHf(t), with TDM2 of ca. 2.5–2.8 Ga) indicate that the orthogneisses crystallized from partial melting of garnet-bearing amphibolite in a subduction environment. The granitic veins that intrude the orthogneisses formed during the late Paleoproterozoic (1760 ± 25 Ma), which is roughly contemporaneous with the metamorphic ages of the orthogneisses; the granitic veins are characterized by extremely high SiO2 (>80 %), enrichments in Rb, Ba and U, and depletions in Nb and Ta. It is inferred that the granitic veins formed by in situ anatexis of the orthogneisses during the late Paleoproterozoic. Based on the zircon ages with Hf isotope compositions, it is evident that the continental crust in the Xingdi region of the Tarim Craton largely formed between 2.5 and 2.8 Ga and was reworked at ca. 1.8 Ga; this evolutionary history is similar to that of the Dunhuang Block. Comparison of the Paleoproterozoic tectono-thermal events in the different terranes of the Tarim Craton, it is suggested that the Tarim Craton is composed of discrete terranes that detached from different ancient cratonic nuclei prior to the late Paleoproterozoic, and assembled within the Columbia supercontinent respectively.