When a horizontal axis wind turbine rotor works under yawed condition, a cyclic variation of Angle of Attack (AOA) at blades will causes dynamic stall phenomenon and accordingly increases the fatigue load. In order to relate the yawed condition with dynamic stall characteristic, a 3D and time-accurate Computational Fluid Dynamics (CFD) is used for the simulations of flow-field and dynamic stall characteristic on the National Renewable Energy Laboratory (NREL) Phase VI wind turbine rotor at yaw 30 degrees. The local AOA and airfoil aerodynamics, i.e., lift coefficient Cl and drag coefficient Cd, are computed based on CFD results. The results show that the horizontal component of yawed inflow and unsteady flow around sections of blade will delay the formation of separation vortex and also the occurrence of stall. The dynamic load accompanied with dynamic stall phenomenon is significantly increased on blade, and the hysteresis characteristic of airfoil lift and drag is more remarkable at the inboard blade sections. The derived results are helpful to develop more reliable aerodynamic models for wind turbine design codes, and also can provide theoretical guidance for the optimal design of a wind turbine.