Yangtze Block Research Articles

Geology, geochronology, geochemistry and Hf-Sr-Nd isotopes of the ‘green-bean rocks’ (felsic tuffs) in the western Yangtze Block, China: Implications for genesis and enrichment mechanism of Li

The widespread ‘green-bean rocks’ (GBRs) in the western Yangtze Block (YZB) are traditionally considered to be originally felsic volcanic tuff. These greenish or yellowish green GBRs are characterized by the presence of bean-like grains. Although the GBRs are enriched in Li in addition to K, the enrichment mechanism of Li during the formation process of GBRs remains controversial. Detailed petrography, scanning electron microscopy, X-ray diffraction, whole-rock geochemistry, U-Pb dating and Hf-Sr-Nd isotopes have been conducted on the GBRs from the Longmendong section in the western YZB to shed light on the genesis of GBRs, Li enrichment mechanism, and further exploration.The zircon and apatite from Longmendong GBRs yielded U-Pb ages of 247.2 ± 0.6 Ma and 247.0 ± 11.0 Ma, respectively. Longmendong GBRs show bull-rock (87Sr/86Sr)i ratios ranging from 0.72602 to 0.72948 and εNd(t) values between −9.8 and −10.4. Zircons have low εHf(t) values and old two-stage Hf model ages (TDM2) ranging from −16.1 to −7.4 and 1741 to 2285 Ma, respectively. Apatite grains display high (87Sr/86Sr)i ratios and low εNd(t) values in the range of 0.72225–0.72461 and −9.93–−11.18, respectively. The combined evidence from textures, mineral compositions, whole-rock geochemistry and Sr-Nd-Hf isotopic compositions indicates that the GBRs originated from felsic volcanic ashes that erupted along the Sanjiang Orogen. The magma of volcanic ashes was sourced from the remelting of ancient crust in response to the initial collision of Indochina-Yangtze Blocks during the closure of the eastern Paleo-Tethys Ocean. The apatite grains separated from GBRs show significantly low Sr and Eu contents (136–223 ppm and 4.23–6.53 ppm, respectively) and low (La/Sm)N (0.97–1.11) and (Sm/Yb)N (3.49–4.56) ratios, indicating that apatite crystallized earlier than the plagioclase and the original magma are highly evolved. The magma of GBRs originated from ancient crust with significant differentiation, facilitating the initial enrichment of Li during the magma evolution. On the other hand, the GBRs have elevated levels of K2O, MgO and clay minerals (e.g., illite and illite/smectite mixed layer minerals), which are proportional to the Li concentrations. This suggests that Li in the GBRs is adsorbed by clay minerals in ionic form and experience additional enrichment during the transformation from volcanic ashes into clay minerals. Furthermore, the GBRs in the northeastern Sichuan basin under a limited sedimentary environment have relatively higher Li concentrations, suggesting that continuous evaporation also positively contributed to Li enrichment in GBRs. Geographically, GBRs in the Sichuan basin are closely related to underground Li-rich brines hosted within the adjacent strata. Therefore, the widespread Li-rich GBRs in the western YZB not only hold promise as a potential Li resource, but also serve as a marker layer for the prospecting Li brines in the Sichuan basin.

The REY geochemistry of phosphorites during metamorphism of the Haizhou Group, NW Yangtze Block, China

Rare earth elements (REE including Y—REY) in phosphorites have been used widely as a proxy for seawater chemistry at the time of their formation. However, it is unclear whether metamorphism can lead to REE remobilization and alteration of primary seawater signatures recorded in phosphorites. In this study, we examine similarly aged metamorphosed phosphorite ore deposits from the northeastern margin of the Yangtze Block (Jinping and Xinpu ore sections), with contemporaneously deposited unmetamorphosed equivalents in the southwestern margin of the Yangtze Block (Weng'an ore section). New insights have been provided into the migration of rare earth elements and the redistribution of Zn and O isotopes in metamorphosed phosphorite, which suggests that the varying degrees of metamorphic fluid–rock reaction during the metamorphism process significantly reduced the δ18O value of phosphate (13.7‰ ± 2.2‰ of Jinping phosphate and 7.3‰ ± 1.8‰ of Xinpu phosphate) and added light Zn isotope. These metamorphic fluids were likely generated by the metamorphic dehydration of upper slab uplift during the plate subduction in the Triassic. The negative correlation between the O (and Zn) isotope compositions and REY contents in P-rich rocks suggests that REY were likely re-enriched during the recrystallization process of apatite. Preferential migration of LREE led to significant LREE and MREE enrichment in Haizhou metamorphosed P-rich rocks compared to Weng'an unmetamorphosed phosphorites.

Limited flexural control of fold-thrust belts on the Jurassic Sichuan Basin, South China

The northern part of the Jurassic Sichuan Basin has long been thought of as a foreland basin in relation to the post-collisional compression along the northern margin of the Yangtze block. However, the exact coupling mechanism between mountain building and basin formation remains unclear. Here, we integrate stratigraphic correlation, basin subsidence analysis and flexural simulation to quantitatively assess the extent to which the fold-thrust belts have controlled basin subsidence. Flexural backstripping of the stratigraphic record, spanning from 201 to 149 Ma, along two cross sections that are perpendicular to the Micangshan fold-thrust belt and the Dabashan fold-thrust belt, respectively, reveals a limited flexural control of mountain loading on basin subsidence. Owing to the short-wavelength nature of plate flexure, the basin-adjacent thrust belts exerted dominant control on basin subsidence only along its margin, with the width of the foredeeps not exceeding ca. 120 km, failing to drive subsidence in the forebulge and backbulge regions. Flexural modeling results suggest that crustal thickening was relatively weak during the Early to Middle Jurassic. This was followed by a more rapid and intense phase of crustal growth in the Late Jurassic, possibly extending into the earliest Early Cretaceous. Compared to the Micangshan region, the Dabashan region has experienced more intense compression during the Late Jurassic. Additionally, our results reveal spatial variations in plate rigidity along the northern margin of the Yangtze block, with greater plate stiffness in the Dabashan region. The presence of residual subsidence, an anomalous long-wavelength subsidence component corrected for both basin-adjacent thrust loading and associated sediment loading, highlights the necessity for an additional driving mechanism for basin subsidence. This residual subsidence was likely dynamic subsidence induced by the flat subduction of the Paleo-Pacific plate (the Izanagi plate) beneath East Asia as the flat slab progressively migrated inland.

Seismic evidence for collisional tectonics of the North China and Yangtze blocks in the Tongbai-Dabie orogenic belt

The Tongbai-Dabie orogenic belt was formed in the Middle to Late Triassic through continental collision between the North China Block and the Yangtze Block. To reveal the collisional tectonics of the two blocks, we apply teleseismic tomography to study the 3-D P-wave velocity structure down to 400 km depth beneath the Tongbai-Dabie orogenic belt using 37,251 first P-wave arrival times of 1423 teleseismic events recorded at 99 seismic stations in the study region. Our tomography reveals three obvious high-velocity anomalies. One is dipping southward beneath the Tongbai-Dabie orogenic belt, reflecting the southward subduction of the North China Block. The second is visible down to 100 km depth beneath the eastern Tongbai-Dabie orogenic belt, which reflects the Yangtze Block. The third appears at depths of 300–400 km, which is interpreted as the retained broke-off paleo-Tethyan oceanic slab. On the basis of our tomographic results and previous findings, we propose a two-stage subduction model showing that the Yangtze Block subducted northward in the Triassic, and then the North China Block subducted southward in the Jurassic beneath the Tongbai-Dabie orogenic belt.

Fluctuation in redox conditions and the evolution of early Cambrian life constrained by nitrogen isotopes in the middle Yangtze Block, South China

AbstractThe Ediacaran–Cambrian (E-C) transition (∼542–517 Ma) witnessed the rapid evolution of Cambrian animals, which was accompanied by carbon cycling anomalies and a significant increase in the concentration of oxygen in Earth’s atmosphere. The mechanisms stimulating the evolution of complex eukaryotes, however, remain problematic, especially concerning the link between biological evolution and contemporaneous changes in the oceanic environment. In this study, integrated δ13Ccarb–δ13Corg–δ15N compositions were analysed from the YD-4 core samples to understand redox fluctuations and nitrogen cycling of the middle Yangtze Block across the E-C transition. Two negative δ13Ccarb excursions (N1 and N2) and a positive δ13Ccarb excursion (P1) are identified from the studied samples and are supposedly of primary origin. Constrained by of the U-Pb age, biolithology and pattern of isotopic variation, N1, P1 and N2 are comparable to the Basal Cambrian Carbon Isotope Excursion (BACE), Zhujiaqing Carbon Isotope Excursion (ZHUCE) and Shiyantou Carbon Isotope Excursion (SHICE). We interpreted the decreased δ15N values in this study as resulting from intensified atmospheric nitrogen fixation driven by enhanced denitrification associated with expanded marine anoxia, as well as partial ammonium assimilation, while increased δ15N values suggest weakened denitrification associated with an amplified oxic water mass. The temporal coincidence of N1 and N2, with two episodes of negative δ15N excursions, and of P1, with a positive δ15N excursion, suggests that variable oceanic redox conditions and nitrogen bioavailability may have influenced the evolution of the Cambrian eukaryote-dominated community.

Detrital Zircon Geochronology and Provenance of Metasedimentary Rocks from the Susong Complex Zone in the Dabie Orogen

AbstractThe Susong complex zone is a relatively low‐grade metamorphic unit located in the southern part of the Dabie orogen and preserves a variety of metasedimentary rocks, mostly with epidote–amphibolite facies. However, their depositional age, provenance and tectonic setting of sedimentary protolith remain controversial due to the lack of fossils, precise dating and integrated geochemical investigation. This study has conducted whole‐rock elemental, and zircon U‐Pb SHRIMP dating and Lu‐Hf isotope analyses on three types of representative metasedimentary rocks including garnet‐bearing mica‐quartz schist, graphite‐muscovite‐quartz schist and dolomitic marble from the Susong complex zone. The U‐Pb SHRIMP dating data indicate that the sedimentary protolith of these rocks have the maximum depositional ages of less than 840–750 Ma and have various sedimentary provenances. In combination with zircon Lu‐Hf isotope compositions, the provenance of the metasedimentary rocks in the region is for the first time documented to be mainly derived from four groups of magmatic rocks formed at ∼2.5 Ga, ∼2.0 Ga, ∼1.4 Ga and ∼0.8 Ga in response to four episodes of igneous activity in the northeastern margin of the Yangtze Block. The conventional geothermobarometry combined with rare metamorphic zircon ages indicate that the studied rocks underwent the Late Triassic continental subduction‐related metamorphism with peak epidote–amphibolite facies conditions at P = 0.34–0.91 GPa and T = 427–532°C. In addition, results of the elemental contents (i.e., La, Ce, Th and ΣREE) and ratios (i.e., Eu/Eu* and LaN/YbN) suggest that the protoliths of the metasedimentary rocks were mainly shales, wackes and limestones, most probably related to the Rodinia supercontinent rifting along the northern margin of the Yangtze Block during the Neoproterozoic.

Age, provenance and tectonic setting of the Tonian–Cryogenian clastic successions in the northwest Bikou terrane, NW Yangtze Block, Central China

Studies on the widely-exposed Neoproterozoic geological records in the Bikou terrane (northwestern Yangtze Block, Central China) have produced different tectonic models (e.g., arc, rift and ridge settings), confusing the relationships between the Bikou and Yangtze blocks in the Neoproterozoic. In addition to the Neoproterozoic Bikou Group igneous rocks and Hengdan Group sedimentary strata which have been well investigated, clastic sedimentary records in the westernmost regions are also crucial for understanding the Neoproterozoic tectonic evolution of the terrane. Here, we target a 3000 m-thick siliciclastic outcrop section along the Bailongjiang River and conduct sedimentological, petrographic, elemental geochemical and zircon U-Pb geochronological analyses to constrain depositional time, sediment provenance and tectonic settings. The outcrop indicates an overall coarsening-upward sedimentary succession, from deep-water sequences to ice-water sequences with dropstone textures. Two volcanic tuffaceous rocks from the basal and middle parts of the succession were dated as 773.2 ± 5.9 Ma and 758.0 ± 8.7 Ma, respectively. The upper parts are characterized by thick, continuous, poorly-sorted glacial diamictites and are conformably overlain by Ediacaran strata. We contend that these diamictites are most likely equivalents to the widespread Cryogenian strata in the Yangtze Block. While provenance analysis results demonstrate felsic bedrock-dominated source terranes with minor mafic contributions, the dropstone gravel components, sandstone petrography and heavy mineral compositions and fine-grained sedimentary rock element concentrations are evidently variable vertically, revealing temporal variations in sediment source-to-sink systems in this region during the late Tonian–Cryogenian. We suggest that the late Tonian deposits were most likely fed by proximal mixed sources with continental arc-related and recycled orogenic terranes, whereas the Cryogenian deposits were dominated by detritus from recycled orogenic terranes. Climate change during the Neoproterozoic glacial-interglacial cycles also played a crucial role in the variable deposit compositions by regulating sediment transport agents and abilities. We favor that the Bikou terrane connected with the Yangtze Block under convergent settings during the early-middle Neoproterozoic and was subsequently under extensional settings. Such findings are a significant step in our understanding of the role of the Yangtze Block in global Neoproterozoic tectonic and climatic frameworks.

Locating the Yangtze Block in Nuna: Constraints from age and isotopic data from Paleoproterozoic sedimentary rocks in the Phan Si Pan Zone, northwest Vietnam

New U-Pb ages and Hf isotopic data for detrital zircons from the late Paleoproterozoic sedimentary rocks (Suoi Chieng Formation) in the Phan Si Pan Zone of northwest Vietnam constrain their depositional ages, provenance, and tectonic setting. The weighted average age of the youngest coherent zircon population is 1769 ± 31 Ma (MSWD = 1.3, n = 8), which provides a maximum depositional age for the Suoi Chieng Formation. The detrital zircons obtained from six Paleoproterozoic samples exhibit various ages, showing multiple magmatic and metamorphic events. The detrital zircon age pattern shows that magmatic activities in the source areas occurred at 2650 Ma, 2350–2150 Ma, and 2050 Ma, as well as minor activities at 2850 Ma, 1850 Ma, and 1780 Ma. Additionally, a prominent metamorphic age peak is observed around ca. 1850 Ma, while a few metamorphic zircons exhibit ages ranging from 2600 to 2500 Ma and 2100 Ma. This pattern indicates that the primary source of these zircons is the local basement rocks of the Phan Si Pan Zone and SW Yangtze. However, contributions from other adjoining cratonic blocks are also possible and these likely included the Rae craton of North Laurentia. Our new data verifies and expands earlier results, showing that the SW Yangtze and north Yangtze have distinct Archean-Paleoproterozoic crustal evolutionary histories prior to their assembly in the late Paleoproterozoic. Regional correlations based on detrital zircon spectra, stratigraphic and tectono-thermal histories show strong similarities between the SW Yangtze and the Rae craton of north Laurentia throughout the Paleoproterozoic, suggesting the proximity of the two blocks before or during the formation of the Nuna supercontinent. We further suggest that the north Yangtze adjoined southern Siberia in the Archean to late Paleoproterozoic as supported by their identical tectono-thermal histories and detrital zircon age spectra. In combination with published data, we propose that the Yangtze Block was located between north Laurentia and south Siberia during the Nuna assembly.

Neoproterozoic slab window in the western Yangtze Block, South China: Evidence from adakitic granodiorites, gabbro-diorites and high-K granites in the Panxi arc belt

Neoproterozoic igneous rocks are widespread along the margins of the Yangtze Block and record key information on the tectonic evolution of the South China Craton. In this paper, we present a comprehensive study of zircon U-Pb ages, whole-rock geochemistry and Sr-Nd-Hf isotopes on the Neoproterozoic granodiorites, gabbro-diorites, and high-K granites in the western Yangtze Block. The granodiorites, gabbro-diorites and high-K granites were dated at 848 ± 5.3 Ma, 824 ± 5.1 Ma and 819 ± 1.5 Ma, respectively. The granodiorites have high Sr (567 ∼ 607 ppm) contents and Sr/Y (84.4 ∼ 88.0) ratios and low alkalis (Na2O + K2O = 4.3 ∼ 4.9 wt%) and Y (6.6 ∼ 7.1 ppm) and Yb (0.7 ∼ 0.9 ppm) contents, similar to typical adakitic rocks. They show low MgO (0.9 ∼ 1.3 wt%), Cr (15.2 ∼ 26.7 ppm) and Ni (3.6 ∼ 4.4 ppm) contents and positive εNd(t) (+1.7 to + 4.2) and εHf(t) (+3.0 to + 8.2) values. The parental magmas for granodiorites were generated by partial melting of thickened juvenile mafic lower crust. The gabbro-diorites are characterized by the enrichment in LREEs, significantly negative Nb, Ta and Ti anomalies, and positive εNd(t) (+2.2 to + 4.2) and εHf(t) (+5.8 to + 10.4) values. They are inferred to be derived from partial melting of lithospheric mantle modified by subduction-related fluids. The high-K granites display high Zr + Nb + Ce + Y (208 ∼ 366 ppm) and alkali (Na2O + K2O = 7.6 ∼ 8.4 wt%) contents, high 10000*Ga/Al (2.31 ∼ 2.64) ratios and zircon saturation temperatures, similar to A-type granites. We suggest that these granites were formed by the partial melting of felsic crustal materials under low pressure and high temperature conditions. The association of granodiorites, gabbro-diorites and high-K granites indicates Neoproterozoic oceanic slab subduction in the western Yangtze Block. We suggest that a subducting oceanic slab window can account for Neoproterozoic magmatism in the western Yangtze Block.

Precambrian Tectonic Affinity of Hainan and Its Evolution from Columbia to Rodinia

The assembly and break-up of supercontinents have been hot research topics in international earth sciences because they represent a breakthrough in reconstructing the history of continental evolution and deepening the theory of plate tectonics, which is of indispensable importance to the development of earth sciences. With the continuous enrichment of paleomagnetic, paleontological, chronological, and geochemical data in the last two decades, the evolution of the supercontinent from Columbia to Rodinia has gradually gained unified understanding, and the reconstruction of the major plates within the supercontinent has basically been constrained. In contrast, the reconstruction of microplates, such as South China, Tarim, and Kabul, is controversial and has now become a popular topic and frontier area of supercontinent reconstruction. Hainan lies at the southern tip of South China, and a few Proterozoic units are exposed on the island. At present, Hainan is often taken as a part of the Cathaysia Block. However, due to the lack of exposed Mesoproterozoic igneous and supercrustal rocks in Cathaysia, the reconstruction model of the Cathaysia Block and even the South China Craton based solely on Mesoproterozoic units in Hainan are distinct from those based on units in the Yangtze Block and younger Proterozoic units within the Cathaysia Block, which makes the paleoposition of the South China Craton controversial. In this paper, we provide new detrital zircon U–Pb age data for the Baoban Complex, Hainan, together with the available data to comment on the affinities between Hainan and the Yangtze and Cathaysia Blocks in the Proterozoic, and on this basis, we can reconstruct the South China Craton within the Proterozoic supercontinents.

A new age, provenance and tectono-sedimentary setting of the middle Dengying Formation of the terminal Ediacaran in the western Yangtze Block, South China

The widespread terminal Ediacaran Dengying Formation in the western Yangtze Block, South China, is dominated by thick marine dolomite successions deposited in shallow-water platform environments. However, a distinctive succession of mixed clastic and carbonate rocks occurs widely in the middle Dengying Formation, representing sedimentary environment variations. The absolute age of the mixed sedimentary succession is poorly constrained, and tectonic and sedimentary settings remain controversial. In this study, we report a new zircon U–Pb age of 547.3 ± 4.8 Ma from a volcanic ash bed intercalated within a mudstone succession (ca. 40–100 cm thick) in the middle Dengying Formation in the western Yangtze Block. This age is consistent with previously published ages of the middle Dengying Formation or its equivalents in the Yangtze Block and in other blocks worldwide. Field investigations show that the mudstone succession overlies above an unconformity resulted from the lower Dengying Formation weathering and shows a deepening upwards depositional succession representing a period of transgression. Mineralogical analyses show that the mudstones are composed of clay minerals (ca. 68.7%, illite and illite/smectite mixed layers), quartz (24.2%) and minor K-feldspar, indicating a high compositional maturity. Redox sensitive element results (e.g., Mo and U) indicate an increasing anoxic setting upwards. Both elemental geochemical and Lu-Hf-O isotopic analyses suggest that the siliciclastic sediments were moderately weathered (average CIA = 71) and were derived from felsic-intermediate rocks, such as granites and granodiorites (or geochemically-equivalent rocks). We suggest that the mixed sedimentary succession represents as a short-lived, regionally-correlated sea level change event, rather than a tectonic uplift event. Our geochemical data reveal that the mudstone succession accumulated most likely in a passive margin setting, supporting the proposition that the Yangtze Block was located on the periphery of the Gondwana supercontinent during the Ediacaran Period.

Precambrian tectono-magmatic evolution of the western margin of the Yangtze block, South China: evidence from zircon U-Pb-Lu-Hf isotopes, REE and trace elements of Yuanmou-Miyi complexes

ABSTRACT Here new evidence of the isotope geochronology and the geochemistry from the Yuanmou-Miyi complexes reveal the Precambrian tectono-magmatism geodynamic process in the study area. The Yangtze Block basement with 1.81- ~1.77 Ga and negative ε Hf(t) values of −7.8 to −0.7 corresponded to the assembly of the Columbia-supercontinent. However, the rifting magmatic event of ~ 1.70 Ga, which caused the continental crust extension-thinning in the study area, may exert influence on the subduction-magmatism in the Grenvillian period. The Yuanmou-Miyi complexes of 1.19- ~1.00 Ga are characterized by (La/Sm)N＞1, depletion in HFSEs, negative anomalies of Nb-Ta, and enrichment of LILEs, which show a genetic link with the subduction-magmatism. The temporal tendency that the magmatism from Yuanmou to Miyi gradually became younger, may be responsible for the subducting direction. The subduction caused the reactivation of the Anninghe-Lvzhijiag fault zone, and created the rupture windows of the subduction slab, leading to upwelling of the deep magma. These granitoids were derived from the partial melting of the mantle wedge, while the small-scale gabbro dikes intruded into the granitoids were likely spillover products from the asthenosphere mantle melts through the rupture windows.

Early to Middle Jurassic sedimentation within the northern Sichuan Basin in response to exhumation of the South Qinling orogenic belt, central China

The northern Sichuan Basin of central China is an important region for investigating the continent-continent convergence that resulted from the closure of the Palaeo-Tethys Ocean. The Early-Middle Jurassic sediments of this basin record the palaeogeography, palaeoenvironments and tectonic evolution of the southern Qinling orogenic belt, especially the Dabashan thrust belt. Detailed sedimentological investigations, coupled with provenance analyses using zircon UPb geochronology, demonstrate that during Early Jurassic times, conglomerate megafan facies extended across the northern Sichuan Basin into the Micangshan area deformed by South Dabashan thrusting and reached even as far as the Mianlue suture belt. These megafan deposits were mainly reworked from the Silurian sediments of the North Dabashan thrust belt (also called the South Qinling orogenic belt), north of the Mianlue suture. These conglomerates record the initial thrust-driven uplift and exhumation of the Qinling orogenic belt that rapidly followed the diachronous closure of the Mianlue oceanic basin. Moreover, our results show that the detrital materials of meandering stream, lacustrine and braided river delta facies that accumulated in the Middle Jurassic mainly originated from the southern Qinling orogenic belt, Mianlue suture zone and northern South China block, suggesting the southward progradation of the Dabashan fold-thrust belt onto the northern Yangtze block and the southward migration of the basin centre. These findings support a model in which the Early to Middle Jurassic evolution of the northern Sichuan Basin may have been triggered by East Asian convergence.

LA–ICP–MS U–Pb geochronology and geological significance of two types of monazite in the Xinjiazui gold deposit, northwestern margin of Yangtze Block, China

The newly discovered Xinjiazui gold deposit situates on the northwestern margin of the Yangtze Block, China. Previously, the absolute age of gold metallogenesis in this area has yet to be well defined due to the lack of suitable dating minerals, significantly hindering the study of ore genesis and metallogenesis of gold deposits. This study presents high precision in-situ laser ablation-inductively coupled plasma-mass spectrometry (LA–ICP–MS) U–Pb ages of monazite to address this issue. Two types of monazite have been found in this deposit, with Type 1 developed in the sedimentary diagenetic stage and Type 2 formed in the ore-forming stage. Type 1 monazite collected from carbonaceous slate is symbiotic with framboidal pyrite in a skeletal texture. It exhibits a high total amount of rare earth elements (REE) and low Y, Th, and U contents, indicating a low-grade metamorphic origin. In contrast, Type 2 monazite from the auriferous quartz vein is intergrown with hydrothermal mineral assemblages including free gold, Au-bearing pyrite and arsenopyrite, ankerite and sericite, suggesting a hydrothermal origin. The monazite (Type 1) LA–ICP–MS 206Pb/238U age is 460.8 ± 7.0 Ma, representing the sedimentary age of the host rock. A combination of lithologic associations and geochemical characteristics indicates that the Ordovician strata (O2ch) are important surrounding rocks in the Xinjiazui gold deposit. Additionally, the forming ages of monazite symbiotic with free gold in the auriferous quartz–sulfide veins range from 206.4 to 207.4 Ma, representing the gold mineralization age of the Xinjiazui deposit. Field geological observation shows that the vertical vein wall of columnar quartz crystals grows inward in the auriferous quartz–sulfide vein geodes and the euhedral granular sulfides develop in geodes. Therefore, this study proposes that the tectonic system changed from compression to extension in the late orogenic period with the closure of Paleo-Tethys and gold mineralization occurred in the Back-Longmenshan tectonic belt.

Provenance and paleogeography of the Early Paleozoic basin in the northern Yangtze Block: Constraints from detrital zircon U-Pb-Hf data

The Proto-Tethys was a significant post-Rodinia breakup ocean that eventually vanished during the Paleozoic. The closure timing and amalgamation history of numerous microblocks within this ocean remain uncertain, while the Early Paleozoic strata on the northern margin of the Yangtze Block archive valuable information about the evolution of the Shangdan Ocean, the branch of the Proto-Tethys. By comparing the detrital zircon U-Pb-Hf isotopic data from Cambrian, Ordovician, and Silurian sedimentary rocks in the northern Yangtze Block with adjacent blocks, it was found that detrital zircons in Cambrian strata exhibit a prominent age peak at ∼ 900–700 Ma, which indicates that the primary source of clastic material in the basin was the uplifted inner and margin regions of the Yangtze Block. In the Silurian, abundant detrital material from the North Qinling Block was transported to the basin due to the continuous subduction and eventual closure of the Shangdan Ocean. This process led to two distinct age peaks at ∼500–400 Ma and ∼900–700 Ma, indicating a bidirectional provenance contribution from both the North Qinling Block and the Yangtze Block. This shift demonstrates that the initial collision between these two blocks occurred no later than the Silurian. The northern Yangtze Basin transitioned from a passive continental margin basin in the Cambrian to a peripheral foreland basin in the Silurian. Major blocks in East Asia, including South Tarim, North Qilian, North Qinling, and North Yangtze, underwent peripheral subduction and magmatic activity to varying degrees during the late Early Paleozoic, signifying the convergence and rapid contraction of microplates within northern Gondwana and the Proto-Tethys Ocean. These findings provide new insights on the tectonic evolution of the Proto-Tethys Ocean.

The Early–Middle Triassic Supervolcano in the Yangtze Block, South China and associated obstacles to biotic recovery

The end–Permian mass extinction was one of the major global crises spanning the entire Early Triassic or longer. Eruptions of volcanos were one of the factors that delayed the biotic recovery after this event. Supervolcano eruptions can cause catastrophic effects on global environment, climate, and life. Here we investigate the tuff layers from Early–Middle Triassic boundary in the Yangtze Block and identify a supervolcano eruption event. The zircon U–Pb ages of the section–Langdai, section–Daijiagou and section–Longmendong tuff samples are 247.1 ± 1.9 Ma, 247.6 ± 2.0 Ma and 247.7 ± 1.7 Ma, respectively. These ages mark the Olenekian–Anisian boundary. The zircon grains from the tuff layers have negative εHf(t) (−15.3 to −0.8), two–stage Hf model (TDM2) ages (1.7 to 2.2 Ga) and display high–δ18O values (mostly > 10‰). Clay minerals and quartz dominate the rock composition. The whole rock compositions show that the tuff layers were derived from magma of intermediate to felsic composition, which formed by the remelting of Paleoproterozoic materials of continental crust. The volcanic eruption site is located in the Jinshajiang–Ailaoshan–Song Ma suture zone in the southwestern margin of the Yangtze Block. A combination of the closure of the Paleo–Tethys Ocean Basin and the collision of the Indochina Block and South China contributed to the eruption, which was a supervolcano eruption under the active continental margin arc settings. We speculate that this supervolcano eruption might have contributed to the delayed biotic recovery after the end–Permian mass extinction.

Paleo‐ to Mesoproterozoic Tectono‐Magmatic Events Recorded in the Huwan Complex from the Dabie Orogen, Central China: Evidence from Petrology and U‐Pb Geochronology

AbstractTo better understand the Paleo‐ to Mesoproterozoic tectonic evolution of the Dabie Orogen in the northern margin of Yangtze Block, we present geochronological data for metasedimentary and metavolcanic rocks in the Huwan complex. A total of 385 detrital zircon LA‐ICP‐MS analyses for metasedimentary rocks yielded three 207Pb/206Pb age populations: 1.50–1.80 Ga, 1.81–1.87 Ga and 1.93–2.0 Ga, providing a maximum depositional timing of ca. 1.50 Ga; while metafelsic volcanic gneisses yielded protolith U‐Pb ages of 1893 ± 54 Ma. The peak ages are remarkably consistent with the tectonothermal events that occurred in the northern Yangtze Block, indicating the presence of Paleo‐ to Mesoproterozoic magmatism in the Dabie Orogen. The age range of 1.93–2.0 Ga correlates with the Paleoproterozoic collision; the age range of 1.81–1.87 Ga coincides with the period of the post‐orogenic extension; and the age range of 1.50–1.80 Ga is interpreted to associate with an extensional regime. Zircon cores with age of 1732–1965 Ma have εHf(t) values ranging from –11.70 to –2.47, indicating that juvenile crust involved in their magma sources. Owing to the similar age spectra, we proposed that the nucleus of the Dabie Orogen was close to the Yangtze Block since the Paleoproterozoic. The Huwan complex has an intimate affiliation to the Yangtze Block, and implies multiple orogenic cycles. It was not only experienced the Paleo‐Tethys ocean subduction and collision, but also recorded Paleo‐ to Mesoproterozoic tectono‐magmatic events in the Dabie Orogen.

Paleo-Mesoproterozoic meta-basalts within the Caiziyuan-Tongan accretionary complex in the southwestern Yangtze Block, South China: Evidence for the breakup of the Nuna supercontinent

Paleo-Mesoproterozoic meta-basalts within the Caiziyuan-Tongan accretionary complex in the southwestern Yangtze Block, South China: Evidence for the breakup of the Nuna supercontinent

Biotic recovery after the Late Ordovician Mass Extinction Event: insights from ichnofossils of the middle–upper Yangtze Block, South China

ABSTRACT The timing and pattern of biotic recovery after the Late Ordovician Mass Extinction (LOME) are highly controversial. Here, we conducted a systematic investigation on ichnofossils from the lower Silurian succession of the northwestern Hunan province, middle-upper Yangtze Block, South China. Biotic recovery of marine benthic ecosystems after the LOME was analysed and discussed for the first time using multiple ichnofossil proxies. The vertical distribution and evolutional trends of trace fossil assemblages suggest that biotic recovery was significantly delayed by the widespread anoxia during the latest Hirnantian to middle Aeronian. The recovery displays a stepwise pattern and reached a relatively high stage during the late Aeronian, although a full recovery was generally not achieved during this interval as proposed elsewhere before. There is a sharp decrease in all trace fossil proxies across the Aeronian-Telychian boundary, indicating a resetting of biotic recovery back to initial stages, most likely linked to a re-onset of anoxia in shallow marine settings during the late Aeronian Event. Subsequent recovery generally followed the patterns of late Aeronian, but was hampered by a low nutrient supply during early Telychian. By the beginning of middle Telychian, a full recovery was achieved, ca. 8.8 Ma after the second pulse of the LOME.

From arc accretion to within-plate extension: Geochronology and geochemistry of the Neoproterozoic magmatism on the northern margin of the Yangtze Block

Early Neoproterozoic arc magmatism and arc accretion processes are fundamental issues in reconstructing the Rodinia supercontinent. In this study we present new data of zircon U-Pb geochronology, Hf-O isotopes and whole-rock geochemistry for the magmatic rocks (including 12 felsic volcanic rocks, 3 granodioritic intrusions, 8 basaltic extrusive rocks and 12 gabbroic intrusions), which are spatially independent, in the Dahongshan area on the northern margin of the Yangtze Block. The investigated intermediate-felsic rocks are dated at ca. 970 Ma, ca. 885–865 Ma, ca. 840–830 Ma and ca. 810–790 Ma by in situ ion probe and laser zircon U-Pb dating methods. The mafic rocks are dated at ca. 870 Ma by in situ ion probe. Combined with previous age data, our new geochronology results suggest continuous magmatic activities from ca. 970 Ma to ca. 790 Ma in the Dahongshan area with a magmatic flare-up at ca. 840 Ma. The ca. 970–840 Ma mafic rocks, as well as the contemporaneous intermediate-felsic rocks, show enrichments in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) and depletions in high-field strength elements (HFSEs), representing arc-related tectonic settings. Zircon grains from these rocks generally have positive εHf(t) values from +7.3 to +14.7 and slightly elevated δ18O values from +5.59 to +6.89, indicating a dominant juvenile source with minor supracrustal incorporation. In contrast, the ca. 830–790 Ma mafic rocks are characterized by E-MORB- (enriched mid-ocean ridge basalt) and OIB- (oceanic island basalt) like and the contemporaneous felsic rocks show characteristics of A2-type granites, implying a within-plate extension environment. Zircon grains from the ca. 830–790 Ma felsic rocks display broad εHf(t) values from −5.7 to +15.3 and low mantle δ18O values from +3.81 to +6.11, implying multiple magma sources for their generation and the imprinting of high-temperature hydrothermal alteration. The relative contributions of the mature crustal component in the Dahongshan magmas decreases from 10–20 % in the ca. 970–840 Ma felsic rocks to 0–10 % in the ca. 830–790 Ma felsic rocks. The Neoproterozoic magmatic activity on the northern margin of the Yangtze Block recorded an integrated evolution from accretion of previous oceanic arc (ca. 970–870 Ma) at ca. 870–840 Ma to within-plate extension (ca. 830–790 Ma) in response to the convergence and divergence of the supercontinent Rodinia.