We study nearest-neighbour correlation functions for the ground state of the supersymmetric XYZ spin chain with odd length and periodic boundary conditions. Under a technical assumption related to the Q-operator of the corresponding eight-vertex model, we show that they can be expressed exactly in terms of the Painlevé VI tau functions sn\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$s_n$$\\end{document} and s¯n\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${{\\bar{s}}}_n$$\\end{document} introduced by Bazhanov and Mangazeev. Furthermore, we give an interpretation of the correlation functions in terms of the Painlevé VI Hamiltonian.