The extended ultraviolet (XUV) disks of nearby galaxies show ongoing massive-star formation, but their parental molecular clouds remain mostly undetected despite searches in CO(1-0) and CO(2-1). The recent detection of 23 clouds in the higher excitation transition CO(3-2) within the XUV disk of M83 thus requires an explanation. We test the hypothesis introduced to explain the non-detections and recent detection simultaneously: The clouds in XUV disks have a clump-envelope structure similar to those in Galactic star-forming clouds, having dense star-forming clumps (or concentrations of multiple clumps) at their centers, which predominantly contribute to the CO(3-2) emission and are surrounded by less dense envelopes, where CO molecules are photo-dissociated due to the low-metallicity environment there. We utilized new high-resolution ALMA CO(3-2) observations of a subset (11) of the 23 clouds in the XUV disk of M83. We confirm the compactness of the CO(3-2)-emitting dense clumps (or their concentrations), finding clump diameters below the spatial resolution of 6-9 pc. This is similar to the size of the dense gas region in the Orion A molecular cloud, a local star-forming cloud with massive-star formation. The dense star-forming clumps are common between normal and XUV disks. This may also indicate that once the cloud structure is set, the process of star formation is governed by the cloud's internal physics rather than by external triggers. This simple model explains the current observations of clouds with ongoing massive-star formation, although it may require some adjustment, for example including the effect of cloud evolution, to describe star formation in molecular clouds more generally.