High quality GaN epitaxial layers were obtained with Al x Ga 1− x N buffer layers on 6H–SiC substrates. The low-pressure metalorganic chemical vapor deposition (LP-MOCVD) method was used. The 500 Å thick buffer layers of Al x Ga 1− x N (0≤ x≤1) were deposited on SiC substrates at 1025°C. The FWHM of GaN (0004) X-ray curves are 2–3 arcmin, which vary with the Al content in Al x Ga 1− x N buffer layers. An optimum Al content is found to be 0.18. The best GaN epitaxial film has the mobility and carrier concentration about 564 cm 2 V −1 s −1 and 1.6×10 17 cm −3 at 300 K. The splitting diffraction angle between GaN and Al x Ga 1− x N were also analyzed from X-ray diffraction curves.
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