We present the results of our QCD analysis of the recent CCFR data for the structure function xF3(x,Q2) of the deep-inelastic neutrino-nucleon scattering. The analysis is based on the Jacobi polynomials expansion of the structure functions. The concrete results for the parameter Λ(4)MS and the shape of quark distributions are determined. At the reference scale |Q02|; = 3GeV2 our results are in satisfactory agreement with the ones obtained by the CCFR group with the help of another method. The Q02-dependence of the Gross-Llewellyn Smith sum rule is extracted in the wide region of high-momentum transfer. Within systematical uncertainties the results obtained are consistent with the perturbative QCD predictions. We reveal the effect of the discrepancy between our results and the analysed perturbative QCD predictions at the level of the statistical error bars. The importance of taking account, in our procedure, of the next-next-to-leading approximation of the moments of the structure function xF3(x,Q2) is stressed.