X-ray Fluorescence Analysis Research Articles

Late Holocene geochemical signature of inter reef mixed sediments on the northeastern Brazilian outer shelf

The northeastern outer shelf in Brazil is a complex ecotone that holds significant information on Holocene sedimentary processes and evolution. X-ray diffraction (XRD), X-ray fluorescence (XRF), and scanning electron microscopy/energy dispersive spectrometry (SEM/EDS) were employed to investigate bioclastic sedimentary facies and patches of relict siliciclastic sands. Radiocarbon dating (AMS) indicates that the carbonate sediments and corals formed in the past millennium. The sediment samples were divided into two groups using a multivariate analysis of XRD and XRF. The first group consists of siliciclastic materials, characterized by Si, Al, Fe, K, Zr, and Ti, and has low levels of carbonate and organic matter. The second, bioclastic and mixed facies, has a high carbonate content and exhibits elevated concentrations of Ca, Sr, and Mg, indicating authigenic processes. The EDS data revealed that the shells predominantly consisted of Cl, Cu, Al, Fe, and Ca. The terrigenous sites are detached from the coastal sources and are mainly located within the reef areas of the outer shelf. The erosion processes in these areas were inefficient to eliminate the siliciclastic sediments. This deposit trapped in inter reef sediments holds the key to understanding the timing and interactions between past coastal processes, shelf valley incision, and reef evolution during the Late Holocene transgression.

Cellulase gene expression in the thermophilic Thermomyces lanuginosus isolated from compost

Thermophilic fungi are superlative microorganisms for enzyme production, especially cellulase, and their using in biotechnological applications is due to their stability at utmost temperatures. In the current investigation, we isolated six genera encompassing six fungal species and one species variety from 30 samples of compost at 45 °C and 55 °C. Thermomyces lanuginosus was the most rampant species. The colony diameter of T. lanuginosus ranged from 2.8 to 4.3 cm at 45 °C on yeast-starch agar (YpSs) medium with white or greyish-brown mycelia. Fifteen isolates of T. lanuginosus were cellulase producers with variable competencies with a C/Z range of 1.09–1.38 cm. Fascinatingly, the clear zone diameter was much bigger when using Iodine than those obtained using Congo red. T. lanuginosus isolate no. 33 produced substantial amounts of cellulase on the four used media: Corncob (CC), Corncob treated with NaOH (C-NA), Yeast Peptone Dextrose (YPD), and CarboxyMethyl Cellulose (CMC) with the highest activity on CC; 143.9 μg/min, also cellulase gene expression levels of cel6Aq, cel7Aq, and bgl3Aq genes exhibited higher fold changes in the CC condition (7.26-fold, 11.51-fold, and 3.39-fold, respectively). X-ray fluorescence (XRF) analysis revealed the presence of 11 minerals with higher concentrations in CC than in C-NA. Supplementation of corncob medium with rosemary essential oil (CR) completely inhibited cellulase production. It adversely affected the growth, and changes in conidia, which were depicted using a scanning electron microscope (SEM). Interestingly, the conidia appeared much bigger than other media, and the large conidia diameter was 10.2–12.1 μm.

Industrial manufacturing method and characterization of Ayurvedic marine drugs: mother pearl, cowry, coral and pearl

Introduction: Ayurvedic marine drugs derived from mollusc shells and coral are regularly used by Ayurvedic physicians to treat several disease conditions like acid peptic disease, irritable bowel syndrome, osteoporosis, etc. However, standard operating procedures for manufacturing these drugs and their complete characterization have not been published in the Ayurvedic Formulary and Ayurvedic Pharmacopeia of India to date. Methods: Present study describes the traditional manufacturing process and thorough characterization using classical and advanced analytical tools. The raw materials characters, in-process parameters, and finished product specifications have been elaborated to develop monographs. Especially, the identity and purity of raw coral and pearl were checked by Raman Spectroscopy and Energy Dispersive X-ray Fluorescence analysis. Results: In the finished product analysis, the X-Ray Diffraction study revealed that incineration after trituration with Aloe barbadensis leaf pulp or rose water converted the aragonite phase of calcium carbonate into calcite phase in mother pearl, cowry, and pearl while the calcite form of raw coral was retained. The prominent bands around 1390, 870, and 712 cm−1 detected by Fourier Transform-Infrared Spectroscopy and mass loss between 39–44% (w/w) revealed by thermogravimetric analysis confirmed the carbonate form of these calcium-based drugs. The finished products were very fine grayish-white powders constituted by irregularly shaped nano-micro particulate calcium carbonate exhibiting particle size between 600 nm (D10 value) to 1.2 µm (D90 value). Conclusion: The quality control and assurance achieved in this study may be further utilized by the pharmaceutical industries to manufacture quality marine drugs and conduct efficacy studies.

Influence of the clay fractions from various horizons on the radiation shielding parameters of an Arenosol

Abstract This study examines the effects of the chemical composition of the clay fraction of various soil horizons on radiation shielding parameters. X-ray fluorescence (XRF) analysis did not reveal significant differences in the concentration of the most abundant oxides (Al2O3, SiO2, Fe2O3) among the various horizons. Consequently, the mass attenuation coefficient did not vary among the horizons in terms of the photon energies studied (15 keV–10 MeV). The mean free path (MFP), half-value layer (HVL) and tenth-value layer (TVL) did not differ for energies up to 100 keV. However, at higher energies, these parameters were mainly influenced by the differences in the densities of the soil horizons. The effective atomic number did not differ across the horizons for the various photon energies, nor did the mass attenuation coefficient. It is shown that slight differences in the chemical composition of the clay fraction of soil horizons do not affect radiation shielding parameters (MFL, HVL, TVL) for low photon energies (<500 keV). Density is more important for radiation shielding than the chemical composition of the various horizons of the same soil type for higher energies (>100 keV); hence, compacting the clay fraction might be more efficient for radiation shielding purposes at higher energies.

In situ determination of soybean leaves nutritional status by portable X-ray fluorescence: An initial approach for data collection and predictive modelling

X-ray fluorescence (XRF) analyses are fast, clean, non-destructive, and compatible with on-field operations, which are some advantages over traditional determinations using coupled plasma optical emission spectroscopy (ICP-OES). The aim of this study was to advance in situ XRF approaches for assessing the nutritional status of soybean leaves (i.e., P, S, K, Ca, Mn, Fe, Cu and Zn). More specifically, we propose a protocol to ensure accuracy of in-field analysis and then evaluate the predictive performance of XRF via different data modelling strategies for macro- and micronutrient determination. Therefore, the XRF sensor dwell time of 60 s and the maximum time of 5 min were determined for the analysis of the leaves after leaf abscission, taking into account the influence of moisture loss on the signal intensity of the lighter elements. Regarding the predictive performance of XRF data for nutrients determination, multiple linear regression (MLR) models resulted in lower root mean square errors (RMSE) for P (433 mg kg−1), S (204 mg kg−1) and K (1957 mg kg−1); Partial least squares regression (PLS) for Ca (519 mg kg−1); and simple linear regression (SLR) for Mn (9 mg kg−1), Fe (18 mg kg−1), Zn (5 mg kg−1). The different modelling strategies exhibited equivalent RMSE for Cu (2 mg kg−1). These prediction errors are within a ±20% range, demonstrating that the in situ protocols developed in this research are useful for predicting the nutrients concentration in soybean leaves. Our study shows the possibility of using the in situ XRF sensor for the rapid and practical nutrients determination in soybean leaves, presenting good potential as a crop diagnosis tool.

Polarization X-Ray Fluorescence Analysis by Milliwatt X-ray Tube

Polarization X-Ray Fluorescence Analysis by Milliwatt X-ray Tube

Sustainable treatment of boron from oilfield produced water for optimum recovery using zirconium chloride oxo-precipitation

This study focuses on the recovery of boron from oilfield-produced water employing the chemical oxo-precipitation method. Zirconium chloride was used to recover boron as a sustainable approach. The study aimed to optimize the parameters to achieve the highest possible boron recovery. It also sought to investigate the impact of operating parameters, including pH, time, oxidizing agent, and dosage of the precipitant, on boron recovery. The optimal operating conditions were optimized through response surface methodology (RSM). A comparative study was conducted with barium chloride (chemical oxo-precipitation) and calcium hydroxide (conventional precipitation). The results indicated that the highest boron recovery was achieved at 97% by utilizing chemical oxo-precipitation with zirconium chloride. Meanwhile, barium chloride and calcium hydroxide recovered boron at 89% and 88%, respectively. The precipitates were characterized by Fourier transform infrared (FTIR), x-ray fluorescence (XRF), scanning electron microscopy (SEM), and energy dispersive x-ray spectroscopy (EDX). The XRF and EDX characterization analysis confirmed the highest boron recovery at 97% with zirconium chloride. SEM showed that zirconium chloride precipitated visible amorphous insoluble solids. The chemical-oxo-precipitation procedure outperforms barium chloride and calcium hydroxide precipitation. The zirconium chloride oxo-precipitation method was proved to be a greener solution for boron recovery.

Properties of biocoal briquettes from mesoporous coals and rice husk and their effects on environmental pollution

This work assessed some properties and effects of biocoal briquettes on environmental pollution compared with utilising coal alone. A mixture of coal fines and rice husks was prepared, with cassava starch gel as a binder, before compaction in a briquetting machine and drying with a solar dryer. Samples of the coal fines, rice husk, cassava flour and briquettes were analysed for their elemental and oxide concentrations via an energy-dispersive X-ray fluorescence analyser. The heat fuels were analysed for their thermal behaviour via thermogravimetric analyser (TGA), whereas the specific surface area, pore size and pore volume were determined using a Brunner–Emmett–Teller (BET) analyser. The conversion of the tested coals to biocoal briquettes resulted in a reduction in the level of arsenic in the briquettes. Additionally, the sulphur level decreased from 1.96 to 1.11% in the Okobo-Enjema briquettes and from 1.78 to 0.90% in the Onyeama briquettes. However, the levels of manganese increased from 0.04 to 0.22% in the Okobo-Enjema briquettes and from 0.04 to 0.21% in the Onyeama briquettes. Thermogravimetric analysis at different heating rates revealed that derivative weight loss increased with increasing heating rate, from 4.4% at 10 °C/min to 5.5% at 20 °C/min. BET analysis revealed that the briquettes had larger pore diameters, volumes and specific surface areas than did the coal samples. The coal samples have greater propensity to pollute the environment as the amount of potentially hazardous elements in the samples is greater than in their biocoal briquettes.

Harnessing hazardous wastes: the production, characterization, and performance of controlled low strength materials using common effluent treatment plant sludge

India's rapid industrialization has led to an increase in waste generation, necessitating efficient disposal methods. This research addresses this challenge by exploring the use of Common Effluent Treatment Plant (CETP) sludge, a hazardous waste, in the production of Controlled Low-Strength Materials (CLSM). The study aims to mitigate the environmental impacts associated with CETP sludge disposal while providing a sustainable solution. To assess the feasibility of this approach, an experimental program was conducted with variations in the mix ratio of CETP sludge and slag sand, a byproduct of steel production. The properties of the produced CLSM, such as flowability and unconfined compressive strength (UCS), were thoroughly examined using Scanning Electron Microscopy, X-ray Diffraction, and X-ray Fluorescence analyses. The results reveal that the CLSM produced with CETP sludge and slag sand exhibits promising performance, with excellent flowability and UCS values ranging from 1.8 to 5.5 MPa. This research underscores the potential of waste materials in creating sustainable and environmentally friendly construction materials, contributing to effective waste management practices and sustainable industrial growth.

New data about the provenance of the Early Eneolithic copper artefacts from western Lesser Poland

Abstract The Early Eneolithic period in Lesser Poland is represented by the Lublin-Volhynian culture and the Wyciąże-Złotniki group. For both of them, the main cultural references were the Middle Copper Age groups from the Carpathian Basin (the Bodrogkeresztúr, the Hunyadihalom-Lažňany, the Balaton-Lasinja cultures, as well as the Ludanice, and the Bajč-Retz-Gajary groups). One of the most important indicators of the Transcarpathian influence was the use of various copper objects by local communities and their deposition in graves. A set of seventeen objects, mostly from well-dated grave contexts, was analysed to establish the provenance of the copper artefacts used in western Lesser Poland. This set included artefacts discovered in Złota Grodzisko I and Grodzisko II, Książnice 2, Koniecmosty, Kraków-Wyciąże 5 and Kraków-Cło 7. Energy dispersive X-ray fluorescence analysis was used to study the chemical compositions, while lead isotope ratios were determined using a inductively coupled plasma mass spectrometer (HR-MC-ICP-MS). In addition, some of the objects were visually inspected under a digital microscope to determine how they were made and used. As a result of this analytical programme, it was possible to establish that both Lesser Poland groups used the same copper distribution networks. Initially (c. 4050–3950 BC), the copper originated from the mines in Serbia that at the time were controlled, as suggested in the literature, by the peoples of the Bodrogkeresztúr culture, and also from the mines in the Slovak ore Mountains, linked to the Ludanice group. It appears, however, that from c. 3950 BC onwards, the only source of metal for the production of copper objects used by the inhabitants of western Lesser Poland were the mines located in the Slovak Ore Mountains. This research also suggested that, while around 3950–3800 BC, there was a marked regression in the production and use of copper artefacts in the Carpathian Basin, in the area of western Lesser Poland there was an increase in the use and, most likely, local production of original copper jewellery.

Development of cement slurries with additives of nanoclay particles for the construction of oil wells at elevated temperatures

Relevance. Strength decrease is a phenomenon that becomes more pronounced as the temperature rises above 110°C. It is characterized by significant chemical and microstructural changes that Portland cement undergoes at high temperatures. Adding silica particles (SiO2) to cement can significantly increase cement resistance to strength reduction when the temperature exceeds 110°C. Nanoclays are currently used in the cement industry to increase the strength of the cement matrix due to their ability to fill capillary micropores and due to their relatively small particle size. Aim. To investigate the effect of adding nanoparticles (nanoclay) to Saudi grade G cement on compressive and tensile strength, and cement stone permeability under high temperature conditions (300°С). Objects. Six samples of cement mortars with different concentrations of nanoclay, cement stones from, tested after 7 and 28 days of hardening at 25 and 300°C. Methods. Cement chemical composition was evaluated by the X-ray fluorescence method with the WORKSTN-V Olympus Vanta X-ray fluorescence analyzer. Cement physical composition was evaluated by the method of ray diffraction on the Mastersizer 2000 laser particle size analyzer. The test of the grouting stone samples was carried out in accordance with ISO 10426-2:2003 on a hydraulic press 65-L1132. The tensile strength of the samples by the Brazilian method was tested in accordance with ASTM D 3967-08 standard on a hydraulic press 65-L1132. The permeability of the samples was determined by single-phase stationary filtration at a facility for studying the filtration and capacitance properties of the PIK-OFP-UCH core in accordance with ISO 10426-2:2003. Results. The data obtained showed that cement destruction at extremely high temperatures can be avoided by using nanoclay (up to 3% by weight of cement). The microstructure of the cement matrix was significantly affected due to the aggregation of nanoparticles when more than 3% of nanoclay was added. All rheological characteristics of the cement slurry were improved by the addition of nanoclay particles.

New Discovery of Natural Zeolite-Rich Tuff on the Northern Margin of the Los Frailes Caldera: A Study to Determine Its Performance as a Supplementary Cementitious Material.

The release of Neogene volcanism in the southeastern part of the Iberian Peninsula produced a series of volcanic structures in the form of stratovolcanoes and calderas; however, other materials also accumulated such as large amounts of pyroclastic materials such as cinerites, ashes, and lapilli, which were later altered to form deposits of zeolites and bentonites. This work has focused on an area located on the northern flank of the San José-Los Escullos zeolite deposit, the only one of its kind with industrial capacity in Spain. The main objective of this research is to characterize the zeolite (SZ) of this new area from the mineral, chemical, and technical points of view and establish its possible use as a natural pozzolan. In the first stage, a study of the mineralogical and chemical composition of the selected samples was carried out using X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray fluorescence (XRF), and thermogravimetric analysis (TGA); in the second stage, chemical-qualitative and pozzolanicity technical tests were carried out at 8 and 15 days. In addition, a chemical analysis was performed using XRF on the specimens of mortars made with a standardized mixture of Portland cement (PC: 75%) and natural zeolite (SZ: 25%) at the ages of 7, 28, and 90 days. The results of the mineralogical analyses indicated that the samples are made up mainly of mordenite and subordinately by smectite, plagioclase, quartz, halloysite, illite, and muscovite. Qualitative chemical assays indicated a high percentage of reactive silica and reactive CaO and also negligible contents of insoluble residues. The results of the pozzolanicity test indicate that all the samples analyzed behave like natural pozzolans of good quality, increasing their pozzolanic reactivity from 8 to 15 days of testing. Chemical analyses of PC/SZ composite mortar specimens showed how a significant part of SiO2 and Al2O3 are released by zeolite while it absorbs a large part of the SO3 contained in the cement. The results presented in this research could be of great practical and scientific importance as they indicate the continuation of zeolitic mineralization beyond the limits of the San José-Los Escullos deposit, which would result in an increase in geological reserves and the extension of the useful life of the deposit, which is of vital importance to the local mining industry.

Biogenic Origin of Fe-Mn Crusts from Hydrothermal Fields of the Mid-Atlantic Ridge, Puy de Folles Volcano Region

Ferromanganese formations are widespread in the Earth’s aquatic environment. Of all the mechanisms of their formation, the biogenic one is the most debatable. Here, we studied the Fe-Mn crusts of hydrothermal fields near the underwater volcano Puy de Folles (rift valley of the Mid-Atlantic Ridge). The chemical and mineralogical composition (optical and electron microscopy with EDX, X-ray powder diffraction, X-ray fluorescence analysis, Raman and FTIR spectroscopy, gas chromatography—mass spectrometry (GC-MS)) and the magnetic properties (static and resonance methods, including at cryogenic temperatures) of the samples of Fe-Mn crusts were investigated. In the IR absorption spectra, based on hydrogen bond stretching vibrations, it was concluded that there were compounds with aliphatic (alkane) groups as well as compounds with double bonds (possibly with a benzene ring). The GC-MS analysis showed the presence of alkanes, alkenes, hopanes, and steranes. Magnetically, the material is highly coercive; the blocking temperatures are 3 and 13 K. The main carriers of magnetism are ultrafine particles and X-ray amorphous matter. The analysis of experimental data allows us to conclude that the studied ferromanganese crusts, namely in their ferruginous phase, were formed as a result of induced biomineralization with the participation of iron-oxidizing and iron-reducing bacteria.

The Role of Metal Nanoparticles in the Pathogenesis of Stone Formation.

The process of stone formation in the human body remains incompletely understood, which requires clinical and laboratory studies and the formulation of a new endogenous, nanotechnological concept of the mechanism of origin and formation of crystallization centers. Previously, the mechanism of sialolithiasis was considered a congenital disease associated with the pathology of the ducts in the structure of the glands themselves. To date, such morphological changes of congenital nature can be considered from the position of the intrauterine formation of endogenous bacterial infections complicated by the migration of antigenic structures initiating the formation of crystallization centers. The present work is devoted to the study of the morphology and composition of stones obtained as a result of surgical interventions for sialolithiasis. Presumably, nanoparticles of metals and other chemical compounds can be structural components of crystallization centers or incorporated into the conditions of chronic endogenous inflammation and the composition of antigenic structures, in complexes with protein and bacterial components. X-ray microtomography, X-ray fluorescence analysis, scanning transmission electron microscopy and microanalysis, mass spectrometry, and Raman spectroscopy were used to study the pathogenesis of stone formation. Immunoglobulins (Igs) of classes A and G, as well as nanoparticles of metals Pb, Fe, Cr, and Mo, were found in the internal structure of the stones. The complex of antigenic structures was an ovoid calcified layered matrix of polyvid microbial biofilms, with the inclusion of metal nanoparticles and chemical elements, as well as immunoglobulins. The obtained results of clinical and laboratory studies allow us to broaden the view on the pathogenesis of stone formation and suggest that the occurrence of the calcification of antigenic structures may be associated with the formation of IgG4-associated disease.

Late Holocene morphosedimentary and palaeoenvironmental study of the Middle Drâa river basin (southeastern Morocco)

The alluvial filling of the middle basin of the Drâa River (southeastern Morocco) has recorded hydrogeomorphological responses to environmental changes. A systematic study of the Holocene fluvial terraces along an upstream-downstream section of about a hundred kilometers, combined with a sedimentary multiproxy study, was carried out on the alluvial archives of the Drâa's river. The stratigraphic field studies, combined with granulometric and geochemical X-ray Fluorescence analyses and radiocarbon dating, enable us to propose, for the first time, a reconstruction of the major stages in the morpho-hydrodynamic and paleo-environmental evolution of the middle Drâa river over the past 3500 years. Our results highlight six morpho-hydrodynamic and paleoenvironmental phases. Between 3500–2700 and 1800–1600 cal BP, the Drâa river was highly active, associated with torrential activity, reflecting arid climatic conditions. The lack of sedimentary record observed between 2800 and 2350 cal BP points either to a phase of erosion, or to a minimal and discontinuous activity that left no traces in the studied archives. The periods 2350–1800 (Roman Warm Period) and 1600–550 cal BP (Medieval Climate Anomaly) are characterized by strong fine and more regular alluviation punctuated by episodes of low energy of the Drâa floodplain, sometimes favoring fluviosols development that showed similar characteristics in the three outcrops studied. Finally, from 550 cal BP the fluvial records generally shows signs of anthropization, marked by the formation of anthrosols characteristic of fluvial oasis construction, and associated with the presence of ceramics and hearths, in which eolization features are frequent. The comparison of Drâa evolution in a broader paleohydrological and climatic context, integrating other Moroccan studies and regional data, shows solid connection with the river, lakes, and marine archives from the southern Mediterranean to the Western Sahelian steppe zones, revealing a clear response of this large hydrosystem to regional climatic variations.

Hierarchical organization and skilled workforces for constructing the Tartessic earthen building at Casas del Turuñuelo (Guareña, Spain)

This article presents the results of the geoarchaeological study of earthen building materials used in a Tartessic public building at Casas del Turuñuelo. The construction dates back to the fifth century BCE and is one of the monumental buildings of Tartessic culture, characterized by its complex architecture, prestige goods, and intentional destruction after a feast and animal sacrifice. We applied an integrated methodology combining macro and micro approaches to investigate earthen construction processes, such as techniques, labour organization, workers’ specialization, and environmental exploitation. The sample mainly consists of mudbricks, but we also include other forms of earthen materials such as mud plasters, mud mortars, and geological soils for comparison. In total, 64 samples from different building parts were studied through X-ray fluorescence, X-ray diffraction, thin-section petrography, and CHN analyses. The results reveal that the workforce involved in the construction process used different resources and presented different skill levels, but was centrally planned and organized. This study reflects on the communities’ knowledge of the environment, the logistic effort and technical skill employed in the building process, and the existence of strong political structures capable of managing the erection of the complex Tartessic buildings.

Ore Characteristics and Distribution Based on Geological and Geophysical Features of the Tambang Sawah Low Sulfidation Epithermal Gold Prospect in Lebong District, Sumatra Island, Indonesia

Sumatra is recognized as one of the Indonesian islands with a big potential for mineral deposits particularly along the belt known as Neogene Sumatra gold axis. However, the publication of the gold resources is still restricted as regional/district scale maps or limited in some locations and internal company reports, hence, a detailed study on deposit scale remains limited. This study aims to document the deposit geology, ore characteristics and geophysical features of the Tambang Sawah prospect at Lebong district, Sumatra Island. The study was done by geological mapping, sampling, and analyzing of selected samples by petrographic, ore microscopic, X-Ray Diffraction, micro X-Ray Fluorescence and various geochemical analyses to identify ore characteristics. The geophysical survey was carried out using geomagnetic and induced polarization. Ore mineralization is manifested by various alteration types such as argillic, propylitic, and silicification, which suffered andesitic breccia and granite host-rocks. Gold mineralization is in the form of quartz veins with typical opening space filling textures such as colloform, crustiform, cockade, moss, comb, and brecciated. The main sulfides consist of pyrite, chalcopyrite, covelite, sphalerite and galena. Gold commonly occurs as free grains. Highest grade gold of up to 21.3 ppm is associated with colloform and cockade-crustiform quartz veins. Geophysical surveys indicate that gold mineralization is associated with low geomagnetic anomaly areas. The 3D modelling of the IP survey reveals that the ore mineralization may occur at 75m depth. Two target areas located at the northeastern and southwestern portions are recommended for a follow-up detailed exploration based on the mapped ore geology, ore characteristics, and geophysical anomalies.

Analysis of Cobalt Distribution and Co-Ni Correlation in Nickel Laterite Zonation in Tropical Region

Cobalt is a key metallic element required in the manufacture of lithium-ion batteries in the electric car industry, which has led to increased demand for cobalt globally. Cobalt is found associated with laterite nickel deposits but generally at lower levels. This study aims to analyze the distribution of cobalt in the laterite zone, determine cobalt-rich zones, determine cobalt-forming minerals in the limonite, saprolite and bedrock zones. As well as determining the average cobalt content in each nickel laterite zone, and determining the correlation between Co and Ni in the laterite zone. The research methodology was carried out by conducting petrographic analysis on bedrock samples to determine cobalt-forming minerals. Furthermore, X-Ray Diffraction analysis was carried out on limonite and saprolite zone samples to determine the mineral content and cobalt-forming minerals. Furthermore, conduct X-Ray Fluorescence analysis at 12 drill points to determine the percentage of cobalt elements in each laterite zone. Based on the research results, it is known that the distribution of cobalt at 12 drill points has levels in the limonite zone ranging from 0.05-0.12% Co, saprolite zone 0.02-0.05% Co, and the bedrock zone ranges from 0.01-0.04% Co. So it can be concluded that the highest cobalt distribution is in the limonite zone and the average cobalt content in the limonite zone is 0.082%; saprolite zone is 0.029%; and bedrock zone is 0.02%. The mineral identified as the cobalt-forming mineral in the bedrock samples in the study area is the mineral antigorite. The Co-Ni correlation coefficient values range from 0.01 to 0.22.

Inorganics and Printing Image Analysis by Micro X-ray Fluorescence Analysis in Base Paper and Printed Ink

Inorganics and Printing Image Analysis by Micro X-ray Fluorescence Analysis in Base Paper and Printed Ink

Eco-friendly synthesis and antibacterial potential of chitosan crosslinked-EDTA silver nanocomposite (CCESN)

This study presents a novel and eco-friendly approach for synthesizing silver nanocomposite at room temperature. The method utilizes chitosan derived from snail (Archachatina marginata) shell waste crosslinked with EDTA as a combined reducing and capping agent. The existence of silver nanoparticles in the composite was confirmed by transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffractometry (XRD), energy dispersive X-ray (EDX), energy dispersive X-ray fluorescence (EDXRF) and thermogravimetric analysis (TGA). The TEM, SEM, XRD, and analyses revealed that the silver nanoparticle has a face-centered cubic structure with an average size of 45.30 nm respectively. EDX and EDXRF showed characteristic silver peaks confirming the formation of silver nanoparticles in the composite while TGA indicated that silver nanoparticles contributed to good thermal stability of the composite. The formation of silver nanoparticles was indicated by a brown color transformation and an ultraviolet visible (UV Vis) absorption peak at 435 nm. The synthesized nanocomposite demonstrated promising antibacterial activity against both Staphylococcus saprophyticus DSM 18669 and Escherichia coli O157 strains, with S. saprophyticus showing higher susceptibility. This highlights the potential of chitosan-EDTA silver nanocomposites as alternative antimicrobial agents.