X-ray Diffraction Measurements Research Articles

Study of Pr doped nanocrystalline LiCoO2 cathode material for spintronic and energy storage applications: A theoretical and experimental analysis

In this study, Pr3+ substituted LiCoO2 lithium-rich cathode materials were prepared using the sol-gel auto-combustion technique to enhance cycling performance. LiCo1-xPrxO2 samples having Pr concentrations x = 0.00–0.10 were synthesized. X-ray diffraction (XRD) showed a rhombohedral structure with space group R-3m, further verified by the Rietveld refinement. Field emission scanning electron microscopy (FESEM) revealed the presence of distinct and well-defined submicron-scale grains. FTIR spectroscopy confirmed Co–O stretching bonds within 590–560 cm−1 and revealed peaks at around 560–590, 830–860, and 1320-1480 cm−1, which could be attributed to the electrochemical performance of Pr-doped species. Moreover, EDX spectroscopy confirmed the typical elemental peaks of only Co, Pr, and O, confirming the required phase presence. The cyclic voltammetry showed improved reversibility and stability due to Pr doping. The first-principles computations were performed using the lattice constant extracted from XRD measurements. The pure LiCoO2 with a semiconducting nature became half-metallic due to Pr doping (LiCo0.84Pr0.16O2). The magnetic properties indicate that LiCoO2 and LiCo0.84Pr0.16O2 exhibit positive magnetic order, which shows that these are suitable candidates for spintronic applications. The pure LiCoO2 revealed intercalation voltages of 4.10–2.73V and a theoretical capacity 40–203 mAh/g. Meanwhile, for LiCo0.84Pr0.16O2, the intercalation voltages and theoretical capacity improved to 4.42–2.85 V and 42 to 211 mAh/g, respectively. The combined experimental and theoretical study suggests that Pr-doped LiCoO2 is suitable for spintronic applications and energy applications such as composite cathodes.

Superconducting properties and electronic structure of CuAl2-type transition-metal zirconide Fe1-xNixZr2

CuAl2-type transition-metal (Tr) zirconides are a superconductor family, and the Tr-site element substitution largely modifies its transition temperature (Tc). Here, we synthesized polycrystalline samples of Fe1-xNixZr2 by arc melting. The crystal structure and the superconducting properties were studied through synchrotron X-ray diffraction, magnetic susceptibility, electrical resistivity, and specific heat measurements. Bulk superconductivity was observed for 0.4 ≤ x ≤ 0.8, and the highest Tc of 2.8 K was observed for x = 0.6. The obtained superconductivity phase diagram exhibits a dome-shaped trend, which is similar to unconventional superconductors, where magnetic fluctuations are essential for superconductivity. In addition, from the c/a lattice constant ratio analysis, we show the possible relationship between the suppression of bulk superconductivity in the Ni-rich compositions and a collapsed tetragonal transition.

Chemical properties of peat micro particles modified asphalt.

This study investigated the chemical properties of peat microparticles modified asphalt (Pt.M.A.). The originality of the study resides in the examination of the chemical characteristics of peat microparticles (Pt.) modified asphalt (Pt. M.A.) utilising FTIR, SEM, SFE, and XRD methodologies. This encompasses Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), surface free energy (SFE), and X-ray diffraction (XRD). Initially, FTIR examined the functional groups of both unaltered and altered asphalt binders. The SEM images reveal improved compatibility, showcasing superior diffusion of the modifier across the asphalt. A further critical factor is that improved adhesion properties, according to the SFE study, indicate that modified binders generally offer more SFE compared to unmodified binders. The XRD measurements revealed a semi-crystalline structure in the Pt. modifier and an amorphous structure in the basal asphalt binder. The integration of Pt. into the asphalt cement resulted in modifications to the phases of both constituents, culminating in the emergence of a new semi-crystalline phase inside the modified asphalt binder. These data suggest that peat microparticles (Pt.) can improve the efficacy of asphalt binders by enhancing compatibility, adhesion, and resistance to ageing.

Pressure-induced superconductivity and phase transition in PbSe and PbTe

Abstract The IV-VI semiconducting chalcogenides are a large material family with distinct physical behavior. Here, we systematically investigate the effect of pressure on the electronic and crystal structure in PbSe and PbTe by combining high-pressure electrical transport and synchrotron x-ray diffraction (XRD) measurements. The resistivity of PbSe and PbTe changes dramatically under high pressure and a non-monotonic evolution of ρ(T) is observed. Both PbSe and PbTe are found to undergo semiconductor-metal transition upon compression and show superconductivity under higher pressure. The structural evolutions from the Fm-3m to Pnma phase and then to the Pm-3m phase in PbSe are verified by the x-ray diffraction. The present findings reveal the internal correlation between the structural evolution and the physical properties in lead chalcogenides.

Hierarchical Intercalation of Solvated Tetrafluoroborate Anions into Graphite Electrodes: The Case Studies of Methyl Acetate and γ-Butyrolactone Solutions.

Intercalation of anions unlocks graphite as a positive material in energy storage devices, and the performance could be affected by solvents in solutions. In this context, it is vital to investigate the role of solvents in anion intercalation. Herein, a hierarchical intercalation phenomenon, in which different graphite intercalation compounds are generated in the same solution, is studied in lithium tetrafluoroborate (LiBF4) solutions of carboxylate ester solvents γ-butyrolactone (GBL) and methyl acetate (MA). The evolution modes of the graphite cathode structure during electrochemical intercalation and deintercalation are discussed via in situ X-ray diffraction (XRD) measurements. Based on this, the relationship between GICs and potentials, together with concentrations, is compared in detail. Furthermore, various graphite materials with different surface properties are applied to adjust the anions' solvation status inside graphite sheets.

Pitting corrosion resistance of tempered N08825 alloy in the inner layer of bimetallic composite pipe

Pitting corrosion resistance of N08825 alloy in the inner layer of bimetallic composite pipe SA210A/N08825 tempered at 570∼720 ℃ was investigated in NH4Cl solution by scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical measurement techniques. The M23C6 precipitates, observed at the grain boundaries of inner layer alloy 825, exhibit a temperature-dependent behavior during tempering at 570∼720 ℃. The quantity of M23C6 precipitates and the pitting corrosion resistance change with the tempering temperature. When the tempering temperature increases from 570 to 660 ℃, the quantity of M23C6 precipitates increases, with the pitting potential (Ep) decreasing from about 499 ± 8.6 to 354 ± 6.7 mVSCE, the passive current density (ip) increases from about 1.9 ± 0.2 to 2.45 ± 0.3 μA cm-2, and the average number of pits on the specimen surface rises from 3 to 7. Conversely, when the tempering temperature increases from 660 to 720 ℃, the quantity of M23C6 precipitates decreases, leading to the Ep increases from about 354 ± 6.7 to 394 ± 14.6 mVSCE, the ip decreases from about 2.45 ± 0.3 to 2.34 ± 0.4 μA cm-2, and the average number of pits on the specimen surface decreases from 7 to 6. There is a strong relationship between the M23C6 precipitates and the pitting corrosion resistance. As the quantity of M23C6 precipitates increases, it results in the expansion of Cr-depleted zones on the specimen surface, the rise of passive film defects, and a subsequent reduction in the pitting corrosion resistance of inner layer alloy 825.

Effect of Ag–Te alloys on pH sensitivity of Ag2O–TeO2 glass/stainless steel enamel

Glass pH sensors are unsuitable for in vivo biomedical, clinical, or food applications because of brittleness of glass, the difficulty in measurement of small volumes and complex matrices, and the need for calibration. Herein, a novel enamel reference electrode for pH sensors is developed using a binary xAg2O·(100–x)TeO2 glass/stainless steel (SUS) electrode. Subsequently, the effects of Ag2O content on the precipitated crystalline phases and pH sensitivity of Ag2O–TeO2 glass/SUS electrodes are examined. The results indicate that the xAg2O·(100–x)TeO2 glass/SUS samples exhibit relatively low pH sensitivity. The pH sensitivities of the samples can be classified into two distinct groups. The first group, comprising samples with an Ag2O content of 25 mol% or more, exhibits a pH sensitivity higher than 10 %. The second group, comprising samples with an Ag2O content of 22 mol% or less, exhibits a pH sensitivity of less than 10 %. The pH sensitivity tends to decrease with increase in stutzite fraction in Ag–Te alloys. Results of X-ray diffraction measurements and transmission electron microscopy observations indicate that the hessite and stutzite Ag–Te alloys, which are minor and conductive, are the primary contributors to the low pH sensitivity observed. Moreover, the pH sensitivity of xAg2O·(100–x)TeO2/SUS is observed to be between those of the Ag–Te alloy and the Ag2O–TeO2 glass matrix. We propose occurrence of an electrical shunt should occur between the Ag–Te alloy and the Ag+-ion conductive Ag2O–TeO2 glass matrix. Regarding xAg2O·(100–x)TeO2 glass/SUS, the 20Ag2O·80TeO2 glass/SUS to 21Ag2O·79TeO2 glass/SUS compositions represent promising candidates as for KCl-leakage-free reference electrodes for pH sensors.

A laboratory nondestructive instrument for joint X-ray diffraction and fluorescence measurements of material in a vial

This paper presents an innovative laboratory instrument equipped with high-energy tungsten target X-ray source and a cadmium telluride (CdTe) detector, designed to perform simultaneous X-ray diffraction (XRD) and X-ray fluorescence (XRF) analyses of materials in vials. By using the instrument we successfully captured fluorescence signals from cerium (Ce), erbium (Er), tungsten (W), and bismuth (Bi) in samples housed in vials made of 6061 aluminum (1 mm thick), 304 stainless steel (0.5 mm thick), and brass (0.5 mm thick). In addition, XRD signals from cerium oxide (CeO2) and bismuth oxide (Bi2O3) powders were captured in glass (0.5 mm thick) and 6061 aluminum (1 mm thick) vials. The experiment results reveal that the fluorescence signal also appears in the XRD patterns. The fluorescence analysis enriches the diffraction analysis by offering complementary insights that enhance the information of the overall material characterization. This instrument greatly improves inspection efficiency and enriches inspection information by performing diffraction and fluorescence measurements simultaneously.

Green Synthesis of Pleurotus Eryngii-Derived Nanomaterials for Phytopathogen Control.

Growing concerns over the human health and environmental impacts of conventional fungicides, coupled with the escalating challenge of microbial resistance, have fueled the search for sustainable biocontrol strategies against plant pathogens. This study reports, for the first time, the green synthesis and characterization of a novel, eco-friendly nanomaterial, designated Pleurotus eryngii-Lecithin-Chitosan Nanomaterial (PEELCN), derived from P. eryngii extract (PEE), lecithin (L), and chitosan (C). The structural attributes of PEELCN were elucidated using Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Thermogravimetric Analysis (TGA), X-ray Diffraction (XRD), and zeta potential measurements, confirming the successful formation of a stable and uniform nanostructure. The antifungal activity of PEELCN, and PEE, was assessed against five economically important phytopathogenic fungi: Neoscytalidium dimidiatum, Alternaria alternata, Verticillium dahliae, Bipolaris sorokiniana, and Fusarium oxysporum. Both PEE and PEELCN exhibited significant inhibitory effects on the mycelial growth of V. dahliae, B. sorokiniana, and N. dimidiatum, with varying degrees of efficacy. The differential antifungal activity suggests a species-specific mode of action. The findings highlight the promising potential of PEELCN as a sustainable, biocompatible, and cost-effective nanofungicide for the management of plant diseases, with the potential for development into a commercially viable biofungicide for sustainable agriculture.

Synthesis of MgO nanoparticles via the sol-gel method for antibacterial applications, investigation of optical properties and comparison with commercial MgO

Magnesium oxide nanoparticles (MgO-NPs) were synthesized using the solution-gelation (sol-gel) technique. For comparison, US Research Nanomaterials, Inc has supplied MgO with very high purity and used without further purification. Both nanoparticles were subjected to X-ray diffraction (XRD) pattern analysis for structural investigation. The XRD measurements showed an incredibly crystalline cubic structure. Morphological studies were carried out using scanning electron microscopy (SEM) measurements to examine the nanoparticles’ size and shape. SEM analysis of the synthesized sample’s morphology revealed a flake-like shape, while a spherical-like structure was observed in the case of the commercial MgO. Using X-ray peak broadening analysis, the Scherrer method was used to assess the crystallite size. A substantial correlation was found between the Scherrer formula and the average particle size of the MgO-NPs, which was determined through SEM analysis. The energy gap calculations were ascertained by plotting the photon energy utilizing the Tauc equation with the measurements of UV–visible absorption spectroscopy. Both nanoparticles were used against the bacterial activity of Streptococcus and Serratia bacteria. The results showed that synthesized nanoparticles exhibited greater effectiveness against bacterial activity than commercial ones.

Alternative Treatments for Zirconium Oxide to Compare Commonly Used Surface Treatments to Determine Which Has the Least Effect on the Phase Transformation.

Traditional mechanical processing of zirconium leads to an unfavorable transformation, from a metastable tetragonal phase to a monoclinic phase (t→m), which weakens the structure of the material and subsequently leads to damage to the prosthetic restoration. The aim of this research is to compare commonly used surface treatments to determine which has the least effect on t→m. Thirty cylindrical samples made of sintered zirconium were divided into six groups based on the following treatments: polishing, grinding, sandblasting, chemical etching, laser structuring or dry plasma etching. After surface treatment, the samples were subjected to the following tests: X-Ray Diffraction, microscopic examination, surface wettability and surface roughness measurements. Chemical etching, laser structuring and plasma etching significantly reduce the content of the monoclinic phase. All surface treatments significantly reduced the final amount of the monoclinic phase. However, chemical etching did not provide sufficient surface roughness. Both laser and plasma processing offer the advantage of creating structural patterns on the surface of elements. However, as plasma etching requires a mask to obtain the appropriate pattern on the surface, it seems that laser processing offers more and varied structuring possibilities. Laser structuring is easier to control and more economical than the other methods.

Multi-Noncentrosymmetric Polar Order in 2D Hybrid Lead Chloride with Broadband Emission and High-Temperature Second-Harmonic Generation Switching.

Two-dimensional lead halide perovskites represent a fascinating class of hybrid semiconductors for solar cell, light-emitting, nonlinear optical (NLO), and ferroelectric applications. A notable subset within this category is luminescent ferroelectrics, which have garnered considerable attention for their potential in integrated photoelectronic devices. In this study, we employed an organic amine halogenation strategy (also referred to as halogen engineering), which is renowned for its efficacy in inducing polar order through crystal engineering. Consequently, we synthesized a layered Ruddlesden-Popper (RP) lead chloride comprising 3-chloropropylammonium cations (CPA+), with the chemical formula CPA2PbCl4. This compound features as many as four temperature-dependent crystal phases, with phase transitions observed at T1 = 353.1 K (343.9 K), T2 = 211.7 K (208.6 K), and T3 = 182.0 K (178.2 K) in the heating (cooling) cycles. Employing a multitechnique approach─including thermal analysis, X-ray diffraction, dielectric and pyroelectric current measurements, Raman spectroscopy, and second-harmonic generation (SHG) studies─we determined the mechanisms of the structural phase transitions. Our findings demonstrate polar order of phase II (space group Cmc21), phase III (space group Pna21), and phase IV (space group Pca21), while also confirming the centrosymmetric nature of phase I (space group Cmce). X-ray diffraction data revealed that the I to II PT is of a ferroelectric nature, devoid of ferroelastic strain, a conclusion further supported by pyroelectric measurements. CPA2PbCl4 features negative linear thermal expansion and broadband emission, which transitions to white light above 180 K. Remarkably, CPA2PbCl4 also demonstrates high-temperature SHG on-off switching with a high contrast ratio of 300:1 along with good switching stability, as evidenced by SHG cycling studies at heating/cooling rates ranging from 5 to 50 K/min. This SHG study also sets new standards for the field of SHG switching by providing a method to quantify the thermal responsiveness of SHG-switchable materials using the treq (time requirement) parameter. Overall, our findings show that the halogenation strategy has led to the discovery of a rare example of an RP perovskite exhibiting coexistence of white-light emission, SHG on-off thermal bistability, ferroelectricity, and negative linear thermal expansion.

High transparent glass of germanate-borate-tellurite modified by different concentration of bismuth oxide for optical and radiation shielding applications

The current investigation studied one of the high-density heavy metal oxides (Bi2O3) having density = 8.9 g/cm³, which was utilized to improve structural and optical features of the B2O3–TeO2-GeO2-MgO glass system. Three high transparent glasses with a chemical formula of 35B2O3–20TeO2-10GeO2-35MgO-xBi2O3 (x = 5, 10, and 15 mol %) were fabricated by melting at 1100 °C for 20 min and annealing at 400 °C for 5 h. X-ray diffraction measurements for the Bi5 sample, containing 5 mol % Bi2O3, were obtained at the range of 10°–80° to inspect the structural characteristics of the made glasses. Optical absorption was employed and recorded for Bi5, Bi10, and Bi15 samples at wavelength range 300–1000 nm to examine the optical properties, including optical band gap. Using Makishima and Mackenzie methods, the mechanical features of the glass samples were assessed. Nuclear library ENDF/B-VI.8 is coupled to the MCNP-5 code and is used to study and simulate the prepared Bi glass sample shielding parameters. The ionizing absorption properties for the prepared Bi5, Bi10, and Bi15 samples were found to be changed because of many circumstances like the photon energy (Eγ, MeV), and chemical compositions (Bi2O3 content (mol. %). The increased layer thickness of glass between 25 and 200 mm enhances the RPE values at 0.6 MeV over the range of 16.31–50.93 % (Bi5 glass sample), 18.68–56.26 % (Bi10 glass sample), and 20.80–60.66 % (Bi15 glass sample).

A Spin-Labeled Derivative of Gossypol

Gossypol and its derivatives arouse interest due to their broad spectrum of biological activities. Despite its wide potential application, there is no reported example of gossypol derivatives bearing stable radical functional groups. The first gossypol nitroxide hybrid compound was prepared here via formation of a Schiff base. By this approach, synthesis of a gossypol nitroxide conjugate was performed by condensation of gossypol with a 4-amino-TEMPO (4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl) free radical, which afforded the target product in high yield. Its structure was proven by a combination of NMR and EPR spectroscopy, infrared spectroscopy, mass spectrometry, and high-resolution mass spectrometry. In addition, the structure of the gossypol nitroxide was determined by single-crystal X-ray diffraction measurements. In crystals, the paramagnetic Schiff base exists in an enamine–enamine tautomeric form. The tautomer is strongly stabilized by the intra- and intermolecular hydrogen bonds promoted by the resonance of π-electrons in the aromatic system. NMR analyses of the gossypol derivative proved that in solutions, the enamine–enamine tautomeric form prevailed. The gossypol nitroxide at micromolar concentrations suppressed the growth of tumor cells; however, compared to gossypol, the cytotoxicity of the obtained conjugate was substantially lower.

Shish-kebab formation in the micro-injection molding of polyethylene: In-situ synchrotron small angle X-ray scattering study

The structural formation and evolution in high density polyethylene (HDPE) during the micro-injection molding process were investigated as a function of the mold temperature and injection speed utilizing an in situ synchrotron small angle X-ray scattering (SAXS) technique in conjunction with a portable micro-injection molding setup. It was found that shish-kebab structures were formed in all cases. The beginning of occurrence of shish is not much affected by the mold temperature, but the onset of the formation of kebab crystals is strongly dependent on the mold temperature. This mold temperature dependence of the kinetics of shish-kebab formation is attributed to the interplay between the crystallization rate in the outer layer and the formation rate of the shish-like structure, which was further evidenced by the multilayered structure of molded samples via ex situ microfocus scanning SAXS and wide angle X-ray diffraction (WAXD) measurements. On the other hand, the injection speed affects the long period of oriented lamellae and the dimension of the shish-like structure only slightly but influences the kinetics of structural formation evidently. The larger the injection speed, the earlier occurrence of oriented lamellae and shish formation is observed.

Effect of Tungsten Doping on the Properties of Titanium Dioxide Dye-Sensitized Solar Cells

Tungsten-doped TiO2 thin films were prepared by sol–gel method on fluorine-doped tin oxide-coated substrates as working electrodes of dye-sensitized solar cells. The influences of different W doping (0, 2, 4, 6, and 8 at%) on the microstructure, optical, and photovoltaic properties of the W-TiO2 thin-film DSSCs were studied by the measurement of X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller (BET) analysis, and electrochemical impedance spectroscopy (EIS). An optimal DSSCs performance was observed with a 6 at% W-doped TiO2 thin film, resulting in a Voc of 0.68 V, a Jsc of 20.2 mA/cm2, an FF of 68.6%, and an efficiency (η) of 9.42%. The efficiency of DSSCs with 6 at% W-doped TiO2 photoanode improved by 75%. This is because the 6 at% W-doped TiO2 thin film increases the specific surface area and electron transfer rate.

New Ibuprofen Cystamine Salts With Improved Solubility and Anti-Inflammatory Effect.

Two novel ibuprofen cystamine salts (IBU-CYS 1 and IBU-CYS 2) are synthesized by coupling the anion of ibuprofen with cystamine dihydrochloride in 1 : 1 and 2 : 1 ratio to improve the solubility and bioavailability of ibuprofen. The salts are characterized by 1HNMR, FT-IR and UV-Vis spectroscopy, differential scanning calorimetry (DSC), thermogravimetry (TGA, DTA) and X-ray diffraction measurements. IBU-CYS 1 and IBU-CYS 2 show higher solubility (6.11 and 7.81 mg/mL) compared to ibuprofen (0.04 mg/mL) in water. IBU-CYS2 was encapsulated into 2-hydroxyethyl methacrylate: poly (ethylene glycol) acrylate hydrogels for enhanced delivery. The in vitro studies in PBS (pH 7.4) indicate that the salts are effective in relieving inflammatory responses induced by lipopolysaccharide in RAW264.7 macrophage cells (nitrite inhibition percentages of IBU-CYS 1, IBU-CYS 2 and ibuprofen: approximately 34.29, 27.03 and 31.50 respectively) while indicating no cytotoxicity. Therefore, these salts may be promising candidates for the development of effective formulations of this drug.

Corrosion failure analysis of steel tubes operating in mining installations: Metallurgical, chemical and mechanical investigations

AbstractCorrosion of steel tubes represents a major challenge for various industries, leading to significant economic and environmental impacts, such as material losses, operational interruptions and safety risks. This study focuses on the metallurgical, chemical and mechanical characterization of corroded steel tubes operating in mining installations using metallographic analysis, X-ray diffraction (XRD), SEM-EDS studies, chemical analysis and micro-hardness measurements. The results reveal the existence of a considerable extent of corrosion, of which, the main corrosion products are magnetite – 72% and goethite – 18.1 associated with corrosion. The corroded tubes measured 0.128% carbon, against 0.23% in new tubes, indicating a loss in weight and mechanical strength properties. The observed tensile strength for the new tubes was 481 MPa while the same for the corroded tubes was to a large extent lower. Furthermore, metallographic examination indicates that indeed the structure is ferrite pearlite as to the composition. This study indicates that 304 L or 316 L stainless steels may be utilized which have better corrosion-protecting coatings thus prolonging service life and reducing maintenance activities.

Probabilistic risk assessment method considering machining-induced random residual stress

The aero-engine disks inevitably have manufacturing-induced anomalies and machining-induced random residual stress (RS) in localized and critical areas, which cause a severe threat to the safety of the aircraft. Traditional structural design of the disks fails to establish a quantitative correlation between the machining process and the failure risk. Therefore, this paper proposes a probabilistic model considering random RS to quantify the influence of machining RS subjected to low-cycle fatigue. The RS dispersion is quantified using a scaling parameter, obtained by X-ray diffraction measurements and orthogonal cutting simulations. The crack life database under varying RSs is established for efficient probability calculations. Results show that the coefficient of variation (COV) of the RS on the same machined surface with the same processing parameters is 7.62 % in the local area and 13.74 % in the whole machined surface. The risk results show that the probability of failure (POF) considering the deterministic RS is 2–4 % lower than the POF without RS, owing to the extension of fatigue life by compressive RS. Furthermore, the POF considering the random RS is almost the same (difference <0.6 %) as the POF considering the deterministic RS because the depth of the machining RS is around 0.2 mm. The proposed method predicts the POF more accurately and is thus valuable for the safety assessment of an aero-engine titanium disk.

Optical properties and energy transfer of Tm3+ single-doped and Tm3+-Tb3+ co-doped transparent glass-ceramics containing NaGd(MoO4)2 single phase

Tm3+ single-doped and Tm3+-Tb3+ co-doped SiO2–B2O3–Na2O–ZnO–MoO3-Gd2O3 glasses were successfully prepared by the melt-quenching process. X-ray diffraction and transmittance measurements were used to determine that the optimal heat treatment regime consisted of crystallization at 620 °C for 5 h and transparent glass-ceramics containing the NaGd(MoO4)2 single phase were obtained. The characterization results by SEM confirmed that the size of the crystals precipitated in the glass matrix was on the nanometer level. The effects of different contents of Tm2O3 on the luminescent properties of glass-ceramics in this system were explored. The results showed that the emission peak at 453 nm (1D2→3F4) had the highest intensity when Tm2O3 was doped with 0.5 mol% under the wavelength at 359 nm excitation. In addition, with the gradual increase of Tb2O3 contents, the luminescence colour of the Tm2O3–Tb2O3 co-doped glass-ceramics gradually shifted from blue to green. This indicates its potential application in blue-green light display technologies and various other areas. The experimental results of the water resistance stability of the samples show that the co-doped glass-ceramic still has good luminescence stability after being immersed in water, which provides further favourable support for its application.