The increasing demand for wearable devices and mobility platforms has garnered the importance of multifunctional components that integrate various features. To achieve this multifunctionality, the carbon-based two-dimensional nanomaterial Mxene (Ti₃C₂Tx) has been explored in various studies including smart textiles, owing to its high electrical conductivity, hydrophilicity, and abundance of functional groups. But the limitations of MXene applications are its low mechanical durability and flexibility, as well as its vulnerability to moisture and washing, which restrict its use in wearable smart textiles. In this study, we developed a novel type of multifunctional smart textile that incorporates energy harvesting, electromagnetic interference (EMI) shielding, flame resistance, and Joule heating. By integrating these functions, the synergy between them could maximize the benefits of the smart textile. MXene, polyvinyl alcohol (PVA), and polyacrylic acid (PAA) were cross-linked through sonication and a vortex generator, and this mixture was vacuum-filtered onto Hanji, a traditional Korean paper, to create a fiber with an asymmetric structure via a simple yet efficient process. Various analytical techniques confirmed the successful cross-linking of MXene/PVA/PAA (MPP), ensuring the fabrication of MXene/PVA/PAA-Hanji (MPP-H) textiles. Structural integrity and stable interfaces were confirmed through a series of experiments, and the performance of the multifunctional capabilities was evaluated.In terms of the functionalities, The MPP-H fiber demonstrated the capability to generate power for over 1 h with the application of a small amount of electrolyte solution, producing a power density of approximately 100 µW/cm³. Additionally, it exhibited a high shielding effectiveness per unit thickness (SE/t) of up to 437 dB/mm within the X-band frequency range (8.2–12.4 GHz), indicating excellent shielding performance relative to its thickness. With an absorption shielding rate exceeding 90%, the developed textile was proven to be an absorption-based shielding material. Furthermore, the MPP-H displayed superior thermal and mechanical properties, including excellent flame retardancy, rapid Joule heating, durability through wash tests, and sonication resistance, making it practical for real-world applications.The MPP-H textile efficiently integrates multiple functionalities into a single material, making it a promising candidate for next-generation wearable devices and mobile technologies.
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