Wufeng Formation Research Articles

Enlightenment of calcite veins in deep Ordovician Wufeng–Silurian Longmaxi shales fractures to migration and enrichment of shale gas in southern Sichuan Basin, SW China

The relationship between fracture calcite veins and shale gas enrichment in the deep Ordovician Wufeng Formation–Silurian Longmaxi Formation (Wufeng–Longmaxi) shales in southern Sichuan Basin was investigated through core and thin section observations, cathodoluminescence analysis, isotopic geochemistry analysis, fluid inclusion testing, and basin simulation. Tectonic fracture calcite veins mainly in the undulating part of the structure and non-tectonic fracture calcite veins are mainly formed in the gentle part of the structure. The latter, mainly induced by hydrocarbon generation, occurred at the stage of peak oil and gas generation, while the former turned up with the formation of Luzhou paleouplift during the Indosinian. Under the influence of hydrocarbon generation pressurization process, fractures were opened and closed frequently, and oil and gas episodic activities are recorded by veins. The formation pressure coefficient at the maximum paleodepth exceeds 2.0. The formation uplift stage after the Late Yanshanian is the key period for shale gas migration. Shale gas migrates along the bedding to the high part of the structure. The greater the structural fluctuation is, the more intense the shale gas migration activity is, and the loss is more. The gentler the formation is, the weaker the shale gas migration activity is, and the loss is less. The shale gas enrichment in the core of gentle anticlines and gentle synclines is relatively higher.

Organic matter enrichment in shale deposited proximal to paleo-uplifts and its impact on shale gas exploration

Much of the global exploration and development of shale gas is focused on organic-rich shale deposited in basin or slope/basin margin settings. There is a clear need to assess the degree to which organic-rich shale deposited in other settings, notably proximal to paleo-uplifts, are promising shale gas prospects. Organic-rich sediments that accumulated proximal to paleo-uplifts are recognized globally and include the Cambrian Niutitang Formation, Ordovician-Silurian transition “hot shales”, and modern sediments of the Black Sea. Though the subject of recent research efforts, much remains to be learned of the mechanisms of organic matter enrichment of fine-grained sediment deposited adjacent to paleo-uplifts. Our study focuses on the Ordovician Wufeng Formation that accumulated proximal to uplifted areas of the Upper Yangtze platform. Though the TOC content of the analyzed Wufeng Formation samples recovered from near the paleo-uplifts is less than that of Wufeng samples collected from basin or slope/basin margin settings, average TOC value of the former can still reach more than 2%. Wufeng Formation shale deposited proximal to paleo-uplifts accumulated under conditions of medium to high paleoproductivity, elevated terrigenous clastic input and sedimentation rate, and oxic-suboxic water column conditions. Principal component analysis suggests that the factor most critical to organic matter enrichment of Wufeng deposits proximal paleo-uplifts was paleo-redox conditions. The TOC abundance in Wufeng Formation shale deposited during late Katian stage is higher than that of shale deposited during Hirnantian stage. It was at the Hirnantian stage that the paleo-uplifts became most active in association with the Kwangsian Orogeny resulting in diminished paleoproductivity and preservation conditions as reflected in the reduced organic matter abundance of associated shale. Uplift of the paleo-uplift of the Yangtze Platform, a manifestation of the Kwangsian Orogeny during the Ordovician-Silurian transition, appears to have been largely responsible for spatial and temporal distribution differentiation of organic matter abundance of the Wufeng Formation of the Upper Yangtze Platform. Results of the present study contribute supplementary information regarding the mechanism of organic matter enrichment in shale and can provide guidance for shale gas exploration and development in geologically similar regions.

Micropore Structure of Deep Shales from the Wufeng–Longmaxi Formations, Southern Sichuan Basin, China: Insight into the Vertical Heterogeneity and Controlling Factors

The microscopic pore throat structure of shale reservoir rocks directly affects the reservoir seepage capacity. The occurrence and flow channels of shale gas are mainly micron–nanometer pore throats. Therefore, to clarify the microstructural characteristics and influencing factors of the deep organic-rich shales, a study is conducted on the marine shale from the Upper Silurian to Lower Ordovician Wufeng–Longmaxi Formation in the southern Sichuan Basin. Petrographic lithofacies division is carried out in combination with petro-mineralogical characteristics, and a high-resolution scanning electron microscope, low-temperature nitrogen and low-temperature carbon dioxide adsorption, and micron-computed tomography are used to characterize the mineral composition and pore structure qualitatively and quantitatively, upon which the influencing factors of the microstructure are further analyzed. The results show that with the increase in burial depth, the total organic carbon content and siliceous mineral content decrease in the Wufeng formation to Long-11 subsection deep shale, while clay mineral content increases, which corresponds to the change in sedimentary environment from anoxic to oxidizing environment. Unexpectedly, the total pore volume of deep shale does not decrease with the increase in burial depth but increases first and then decreases. Using total organic carbon (TOC), siliceous mineral content showed a good correlation with total pore volume and specific surface area, with correlation coefficients greater than 0.7, confirming the predominant role of these two factors in controlling the pore structure of deep shales. This is mainly because the Longmaxi shale is already in the late diagenetic stage, and organic matter pores are generated in large quantities. Clay minerals have a negative correlation with the total pore volume of shale, and the correlation coefficient is 0.7591. It could be that clay minerals are much more flexible and are easily deformed to block the pores under compaction. In addition, the longitudinal heterogeneity of the deep shale reservoir structure in southern Sichuan is also controlled by the thermal effect of the Emei mantle plume on hydrocarbon generation of organic matter and the development of natural microfractures promoted by multistage tectonic movement. Overall, the complex microstructure in the deep shales of the Longmaxi Formation in the southern Sichuan Basin is jointly controlled by multiple effects, and the results of this research provide strong support for the benefit development of deep shale gas in southern Sichuan Basin.

A world-class source rock in southern China formed during the periods from Katian to Rhuddanian: Biostratigraphic distribution, depositional model and shale gas potential

Typical outcrops and shale gas wells from the upper Ordovician (Katian and Hirnantian) Wufeng Formation to the lower Silurian (Rhuddanian) Longmaxi Formation in the Sichuan Basin of southern China were selected to investigate the shale quality and shale gas potential. The chronostratigraphy was studied based on the graptolite biozones and well logging. The sedimentary environment, depositional facies, biostratigraphic distribution, depositional model and lithological characteristics were characterized. Organic-rich shale primarily developed in the late Katian to the early–middle Rhuddanian. Two organic-rich shale depocentres were identified in the southern and eastern-north-eastern Sichuan Basin. The spatial distribution of organic-rich shale of different graptolite biozones was determined and showed gradual migration northwest. The depocentre of the Dicellograptus complexus Biozone to the Cystograptus vesiculosus Biozone was controlled by paleo-uplift and a submarine high. The black shale typically lacks some graptolite biozones, and even if it is fully developed, the thickness of organic-rich shale is thin and has a poor shale gas source potential. The control effect of the graptolite biozone on shale-gas-enrichment helps to evaluate the shale-gas-enriched and productive intervals accurately. This study characterises the organic-rich shale distribution in the Sichuan Basin and helps in assessing organic-rich shale and identifying sweet spots of shale gas potential.

Organic Matter of the Wufeng–Longmaxi Formation Shales Using Scanning Electron Microscopy

Fine-grained organic matter (OM) particles are commonly widely dispersed in shale deposits. However, carrying out investigations of pores hosted by OM particles and the nature of grain interactions in OM particles and associated detrital grains using optical microscopy is difficult at best. Scanning electron microscopy (SEM) is much better suited for characterizing the microstructure of dispersed OM particles and has found wide application in the study of unconventional oil and gas systems. Scanning electron microscopy was used to define the types of OM contained in marine shale deposits of the Wufeng and Longmaxi Formations spanning the Ordovician–Silurian transition in South China. Of particular interest was the development of OM-hosted pores and the identification of the factors that controlled their formation. The dominant OM type contained in the studied deposits is pyrobitumen, with subordinate graptolitic OM and sparse OM of unknown origin. Pyrobitumen is present in four forms, including pore fillings among authigenic quartz grains, within framboidal pyrite, and between authigenic clay grains and massive material. Diagenetic alteration has given rise to OM pores of differing morphology, size, and time of formation. Common small, equisized circular or oval OM pores are most developed and appear to have formed in association with the generation of hydrocarbons. Shale deposits containing abundant pyrobitumen filling interparticle pores among authigenic quartz crystals display robust reservoir and fracturing capacity. A sedimentary environment appears to have been the main factor affecting the type of OM and the nature of its association with detrital and authigenic minerals. Results of this study demonstrate that a sedimentary environment is a primary requisite for the formation of highly prospective/high-yielding hydrocarbon shale reservoir deposits.

Sedimentary Environment and Organic Accumulation of the Ordovician–Silurian Black Shale in Weiyuan, Sichuan Basin, China

The sedimentary environment and organic matter enrichment relationship of the Upper Ordovician Wufeng Formation black shale, Guanyinqiao mudstone, and Lower Silurian Longmaxi Formation black shale in the Sichuan Basin of Weiyuan are analyzed using geochemical methods such as organic carbon, sulfur, major elements, and trace elements. The experimental results illustrate that the upper section of the Wufeng Formation and the lower section of the Longmaxi Formation are organic matter enrichment layers. The presence of P indicates a high productivity level in the Sichuan Basin from the Late Ordovician to the Early Silurian. In addition, indicators such as V/Cr, Ni/Co, and S/C suggest that the Wufeng Formation was deposited under anoxic reductive conditions, that the ice age Guanyinqiao segment was in an oxygen-rich to oxygen-poor environment, and that the Longmaxi Formation was in a sulfidic environment. Mo/TOC indicates that the Wufeng Formation shale was controlled by a restricted basin and that the Guanyinqiao segment and the Longmaxi Formation were in a medium-to-weak retention environment. The weak correlation of TOC with P/Al and Al indicates that the level of primary productivity and terrigenous detritus had a minor effect on the organic matter enrichment of the Wufeng and Longmaxi Formation black shale. Conversely, the positive correlation of TOC with V/Cr and Ni/Co illustrates that the anoxic reductive sedimentary environment is the main factor affecting the organic matter enrichment of the Wufeng and Longmaxi Formation black shale. Based on these studies, the development model of organic-rich shales of the Ordovician–Silurian in Weiyuan, Sichuan Basin is proposed. This paper may provide a reference for shale gas exploration in the Wufeng–Longmaxi Formation and a sedimentary response to the major geological events of Ordovician–Silurian.

An optimization method for equivalent bulk permeability of gas shale matrix with crushed samples and re-recognition of the influence of pressure and particle size

The pressure decay (or gas expansion) test with crushed samples has been used to evaluate the matrix permeability of shale and other low-permeability rock for many years. However, there still exist uncertainties relating to particle size and equilibrium pressure. The existing late-stage curve fitting method has the advantage of easy calculation, but the assumption that gas enters particles with a single permeability value is not generally applicable for shale samples, and late-stage analysis may lead to underestimation. This study proposes an optimization method to determine the equivalent bulk permeability that ensures the smallest sum of squares of errors between the forward-predicted pressure decay curve and the measure one. Both the optimization and curve fitting method are applied to two shale samples from the Ordovician Wufeng Formation of two wells in the Sichuan Basin, China with improved apparatus and testing procedures. The optimization method is superior to the curve fitting method in the repeatability and regularity on the change of apparent permeability with pressure. A strong linear relationship between apparent permeability and coefficient of compressibility is established between 3 and 12 bars. The variation of permeability with particle size is more diverse than that is commonly understood and might be nonmonotonic, depending on the change of pore structure during crushing. Change of apparent permeability with pressure (non-Darcy feature) is proposed as a criterion of whether pore structure has changed significantly. It is suggested to measure the variation of permeability with pressure and particle size to obtain a more comprehensive understanding of matrix permeability and pore structure.

Geochemical Characteristics of Elements and Main Controlling Factors of Organic Matter Enrichment in Shale from Wufeng Formation to Submember Long-11 in Southern Sichuan

A total of 70 shale samples from seven core holes, namely, N203, N208, N209, N210, N211, N215 and N217, in Changning area, south Sichuan, were analyzed for major and trace elements. Based on an analysis of longitudinal variation characteristics of major and trace elements, the REDOX conditions, paleoproductivity, relative sea level height and terrigenous detrital injection amount of gas-bearing shale in Wufeng Formation–Submember Long-11 in the Changning area were studied. And, the main controlling factors of organic matter enrichment in Wufeng Formation–Submember Long-11 were discussed. The results show the following: (1) Trace elements Mo, U, Ba and Ni are relatively enriched in the shale of Wufeng Formation–Submember Long-11 in the Changning area, while the Co element is deficient. The flat distribution pattern of rare earth in Wufeng Formation–Submember Long-11 shows that the shale deposits are weakly influenced by terrigenous materials. The amount of terrigenous injection in Wufeng Formation is higher than that in Submember Long-11, and the amount of terrigenous injection increased gradually from the lower part of Bed Long-111 to the lower part of Bed Long-114. (2) The REDOX environment discrimination indexes such as U/Th, Ni/Co, V/Sc and δU show that the water REDOX conditions of Wufeng Formation–Submember Long-11 in the Changning area have changed many times during the shale sedimentary period, and the overall REDOX conditions are dominated by an anaerobic environment. The REDOX indexes at the boundary between Long-111 and Wufeng Formation are relatively small and in the oxidizing environment range. The REDOX index from Bed Long-111 to Bed Long-114 decreases gradually, and the anaerobic environment of Bed Long-111 and Bed Long-112 gradually changes to the oxygen-poor environment of Bed Long-113; and, the REDOX index of Bed Long-114 is the lowest, which is generally oxygen rich. (3) Organic matter enrichment in Wufeng Formation Submember Long11 in the Changning area is mainly controlled by REDOX conditions. Low terrigenous injection and a relatively high sea level have positive effects on organic matter enrichment, but there is no obvious relationship between the paleoproductivity and organic matter enrichment.

Prediction of Marine Thin Shale Gas Reservoir with Seismic Phase-Controlled Nonlinear Stochastic Inversion

Due to the complicated interference sources and low signal-to-noise ratio of seismic records, conventional seismic inversion methods are difficult to accurately identify shale gas reservoirs with a thickness of less than 10 m. This presents great challenges to shale gas exploration and development in China. Seismic phase-controlled nonlinear stochastic inversion (SPCNSI) is related to the heterogeneity of underground media. With the constraints of the stratigraphic sequence or seismic facies models, the minimum value between the seismic model and seismic record can be solved through iterative processes. Based on the solved acoustic velocity in formation, the constraints for SPCNSI can be formed with the matching relationship between target layers and different sequences in three-dimensional space. The prediction resolution of an unconventional reservoir can be effectively improved by combining logging, geological and seismic information. The method is suitable for predicting thin shale gas reservoirs in complex geological structures. In this study, SPCNSI was developed to predict the thin-layer marine shale gas reservoir in the southeast of Chongqing; the horizontal and vertical distribution characteristics were proven in the Longmaxi Formation and the Wufeng Formation; thin layers with a thickness of less than 7 m were also discovered. According to the results, three sets of potential development areas were determined by the inversion method, and the accuracy and reliability of the method were verified by logging and productivity testing.

Anisotropic mechanical behavior of ultra-deep shale under high in-situ stress, a case study in the Luzhou block of the southern Sichuan Basin, China

The safe and efficient development of ultra-deep shale gas deeper than 4500 m is closely related to the comprehensive evaluation of the mechanical behavior, brittleness and anisotropy characteristics of reservoir rocks under in-situ stress conditions. However, the above-mentioned information about ultra-deep shale is rarely reported. This study aims to fill this gap by systematically investigating the mechanical and anisotropic characteristics of cores, with 0° and 90° bedding orientations, from different layers in the vertical depth of 4900–4930 m, under confining pressure of 110 MPa. Furthermore, a new brittleness index with three parts related to brittle failure, i.e., the energy storage performance in the pre-peak stage, the performance of elastic energy used to maintain the post-peak failure, and the severity of the energy released during the post-peak stage, all of which are physically meaningful, was proposed. Subsequently, the index was validated and applied to the brittleness evaluation of ultra-deep reservoir rocks. The brittleness was evaluated in the following descending order: black shale of Longmaxi Formation ＞ gray-black shale of Wufeng Formation ＞ limestone of Baota Formation. Overall, the Wufeng- Longmaxi Formation shale still exhibits brittle failure under such high confining pressure, while the Baota Formation limestone exhibits quasi-ductile failure, which is consistent with the phenomenological behavior of cores. Further, various experimental techniques have been employed to study the brittle and quasi-ductile failure mechanisms of reservoir rocks. The anisotropy evaluation results show that the anisotropy degree of the mechanical and brittleness parameters corresponding to the deep formation is significantly lower than that of the shallow formation. The anisotropy degree of strength and deformation parameters (Young's modulus, Poisson's ratio) is closely related to the content of quartz and clay minerals, respectively. The above results are expected to provide data support and theoretical guidance for the development of deep and ultra-deep shale gas in the southern Sichuan region of China.

The Intensification of Prolonged Cooling Climate-Exacerbated Late Ordovician–Early Silurian Mass Extinction: A Case Study from the Wufeng Formation–Longmaxi Formation in the Sichuan Basin

The Late Ordovician–Early Silurian period was a significant transitional phase in geological history and has garnered global interest. This study focuses on the black shale series of the Wufeng Formation–Longmaxi Formation of the Upper Ordovician–Lower Silurian period in the Sichuan Basin. Based on the logging curves and lithological characteristics of the Yucan-1 Well, 46 black shale samples were collected from the target layer section for clay mineral XRD (46 samples) analysis and whole-rock XRF (14 samples) analysis. The results indicate that three third-order sequences (SQ1, SQ2, and SQ3) are present in the Wufeng Formation–Longmaxi Formation of the Yucan-1 Well, and two subfacies and three microfacies were identified. In conjunction with the characteristics as well as the characteristic parameters of whole-rock oxide and clay mineral content ((I/C), (S + I/S)/(I + C), CIA, CIA-error, CIW, PIA, MAP, and LST), the Wufeng Formation–Longmaxi Formation of the Yucan-1 Well is divided into three intervals. Interval I is the Wufeng Formation. During this interval, weathering intensity, surface temperature, and precipitation gradually decreased, while the climate shifted from warm and humid to cold and dry. This corresponds to two pulse-type biological extinction events and represents an interval of increasing organic carbon burial. Interval II encompasses the bottom-middle part of the Longmaxi Formation. Weathering intensity, surface temperature, and precipitation were characterized by smooth, low values. Subsequently, the climate was predominantly cold and dry. This was the primary interval of organic carbon enrichment. Interval III extends from the upper part to the top of the Longmaxi Formation. Weathering intensity, surface temperature, and precipitation gradually increased. The climate transitioned from cold and dry to warm and humid. Organic carbon burial gradually decreased, while sea levels dropped. This indicates that climate cooling was the primary controlling factor for this biological extinction event. In combination with previous divisions of graptolite zones in the Yucan-1 Well, it is postulated that this biological extinction event may primarily have been pulse extinction. The continuous cooling of the climate in the later period led to the continuous extinction of organisms that survived the disaster. Until approximately 438.76 Ma at the top of the Longmaxi Formation, the climate environment recovered to pre-extinction conditions, with a transition to a warm and humid climate again.

Geochemistry and mineralogy of the Upper Ordovician Wufeng formation, Southwestern China: Implications for Paleoclimate construction

Wufeng Formation shale is an important source rock of unconventional hydrocarbons in the Lower Paleozoic shales of Sichuan Basin. However, the study on its provenance and paleoclimate is still relatively limited. In this study, mineralogical and geochemical data of the shales from the Upper Ordovician Wufeng Formation in southwestern China has been used to interpret the provenance and conditions of weathering and paleoclimate. The Wufeng shales have intermediate to high SiO2 (57.72–82.38 wt. %, av. = 68.84 wt. %) and Al2O3 (5.26–16.17 wt. %, av. = 10.62 wt. %), are rich in transition metal elements (i.e. V, Ni, Cu, Co and Cr) and Y as well as moderate depletion in Na2O and Sr, relative to the concentrations of the upper continental crust (UCC). In the chondrite-normalized (CN) rare earth elements (REE) distributions, these rocks display light REE (LREE) enrichment (La/YbCN = 6.69–12.63, av. = 9.28), flat heavy REE (HREE) (Gd/YbCN = 1.35–2.41, av. = 1.70), and clearly negative Eu anomalies (Euan = 0.50–0.66, av. = 0.58), showing similar characteristics with the CN post-Archean Australian Average Shales (PAAS). Wufeng Formation shales are immature composition without evident recycling sediments, and they are originated from an intermediate-felsic igneous source composed of tonalite–trondhjemite–granodiorite (TTG), granitic and andesitic igneous rocks. The chemical weathering conditions of studied shales decreased from moderate to low in the provenance region, suggesting a gradual cooling trend of the climate at Late Ordovician Thus, this article will be helpful to discern the provenance and variations of chemical weathering conditions and paleoclimate of Wufeng Formation shales.

Intensive geological alteration and gas accumulation in Longmaxi Formation shales at moderate and great depths: A case study of the Luzhou area in the southern Sichuan fold zone, China

In recent years, significant efforts have been directed towards extracting deep shale gas (SG) in Luzhou. Understanding the factors influencing the accumulation and preservation of SG in the section extending from the Upper Ordovician Wufeng (WF) Formation (Fm) through the Lower Silurian Longmaxi (LMX) Fm is crucial for its large‐scale, profitable development. The shale layers in the LMX Fm located in the Luzhou‐Zigong area in the southern part of the Sichuan Basin have undergone unique geological processes, including deep deposition, intensive uplift, erosion and deformation. The Luzhou block, situated in the low‐fold zone in southern Sichuan between the southern slope of the paleo‐uplift in central Sichuan and the down‐warping fold zone in south‐eastern Sichuan, was studied using seismic, well‐log, drilling and core analysis and test data to understand its tectonic, sedimentary, reservoir and fracture characteristics and identify the principal factors controlling gas accumulation in this area. The study found that SG in the Luzhou block is primarily distributed in the WF Fm through the Longyi1sub‐member. Class I continuous reservoirs, 2.6–20.3 m in thickness, are mainly found in the Longyi11–13sublayers and those with large continuous thickness produced high yields during tests. Gentle anticlinal zones and wide, gentle tectonic structures with relatively high‐pressure coefficients have formed in this area. High‐angle fractures (HACs) in this area tend to accumulate free gas and, therefore, facilitate the accumulation and production of SG. The study concludes that the continuous thickness of Class I reservoirs and natural HACs controlled by the centre of the deep‐water continental shelf are the primary factors controlling SG accumulation in the Luzhou block.

Carbon isotope evidence for shale gas preservation conditions and large methane release over million years: A case study of shale gas reservoirs of Wufeng and Longmaxi Formations in the Sichuan Basin

Although carbon isotope reversal and its reasons in shale gas reservoirs have been widely recognized, the application of the reversal is yet to be investigated. A study on high-maturity shale from Wufeng and Longmaxi Formations in the Sichuan Basin not only reveals the relationship between the degree of isotopes inversion and the production capacity (e.g., estimated ultimate recovery (EUR)) of the gas well but also indicates the preservation conditions of shale gas reservoirs. (1) Although there are differences in gas isotopes in different shale gas reservoirs, the isotope fractionation of shale gas is small during the production stage of gas wells, even when the wellbore pressure drops to zero. The main cause of the difference in carbon isotopes and their inversion degree can be the uplift time during the Yanshan period and the formation pressure relief degree of shale gas reservoirs in distinct structural positions. Thus, carbon isotope inversion is a good indicator of shale gas preservation condition and EUR of shale gas wells. (2) The degree of carbon isotope inversion correlates strongly with shale gas content and EUR. The calculation formula of shale-gas recoverable reserves was established using Δδ13C (δC1-δC2) and EUR. (3) The gas loss rate and total loss amount can be estimated using the dynamic reserves and isotopic difference values of gas wells in various shale gas fields, which also reflects the current methane loss, thereby demonstrating great potential for evaluating global methane loss in shales.

Determination of adsorption parameters in shale gas resource/reserve calculation: Case study of Wufeng Formation–Longmaxi Formation in the Sichuan Basin

In the calculation of shale gas resources/reserves, isothermal adsorption parameters are mainly determined by dry sample data at the laboratory temperature, and the regression effect of total organic carbon content (TOC) isothermal adsorption parameters is poor. Based on the physical significance of key parameters in Langmuir and Henry adsorption models, the problems in determining the isothermal adsorption parameters in the calculation of shale gas reserves/reserves are analyzed by taking the marine shale in the Upper Ordovician Wufeng Forming–Lower Silurian Longmaxi Formation in the Sichuan Basin as an example. Based on a large number of measured isothermal adsorption data, the effects of TOC, temperature and water saturation on the shale gas adsorption parameters are analyzed. The influence model of TOC, temperature and water saturation on isothermal adsorption parameters of shale gas is established, and a novel method for calculating the adsorption parameters of shale gas from under experimental conditions to original reservoir conditions is proposed. The results are obtained as follows. First, there are problems in the calculation of shale gas resources/reserves, such as poor and contradictory fitting relation between isothermal adsorption parameters and TOC, difficulty in the conversion of Van't Hoff equation, and difficulty in direct application of water saturation (Sw) in resource/reserves calculation. Second, the problem of poor direct fitting relation between Langmuir pressure (pL) and TOC is solved by integrating the Langmuir adsorption model with the Henry adsorption model and by establishing a new parameter – Henry constant a for methane adsorption capacity of shale. Third, when Sw<40%, the Langmuir volume (VL) is linearly negatively correlated with Sw; when Sw<20%, a is constant relatively; by establishing the relationship between the normalized absolute adsorption capacity and Sw (<50%) under the pressure exceeding 30 MPa, the effect of Sw on the isothermal adsorption capacity can be calculated. Fourth, the in-situ stress in the Wufeng Formation–Longmaxi Formation shale reservoir affects the adsorption capacity of shale. For shale reservoirs with the same TOC, the higher the in-situ stress, the smaller the VL and a values. Under high pressure (>30 MPa), the effect of Sw on the methane adsorption capacity of shale shows a similar trend, and the effect of water molecules on the adsorption capacity on shale pore surface is constant. It is concluded that the proposed novel method for determining the isothermal adsorption parameters of shale with different TOC, temperature and water saturation conditions provides a technical support for the accurate calculation of shale gas resources/reserves and contributes to the scientific development of shale gas industry.

Control Model of Organic Shale Enrichment by Terrigenous Weathering in Wufeng Formation–Longmaxi Formation, Southeast Sichuan, China

The relationship between the Late Ordovician–Early Silurian sedimentary system, weathering, paleoclimate, and primary productivity in the Yangzi region is not well understood. In this study, by analyzing the sedimentation cycle and major trace elements of the Youc well 2 in the southeast Sichuan Basin, the coupling relationships of weathering indicators, terrigenous debris input indicators, paleoclimate, redox condition indicators, U-Mo covariance model, Mo/TOC relationship, and paleoproductivity indicators are investigated. The results show that single-well logs delineate four third-order sedimentary sequences (SS1, SS2, SS3, and SS4), two sedimentary subfacies, and four sedimentary microfacies in the Wufeng Formation–Longmaxi Formation. The weathering degree is stronger at the bottom where the climate shifts from warm–wet to cold–dry, and the seawater is in an oxidic–anoxic–oxidic–anoxic environment. While the primary productivity and material source input decreases gradually in the middle and upper part, the climate becomes dry and cold, and the seawater is in an anoxic–oxidic environment. Thus, a rock enrichment model for the organic matter shale of the Wufeng Formation–Longmaxi Formation in southeast Sichuan has been established. This provides more information on the control factors concerning organic matter enrichment and their interactions.

Lithofacies Types and Physical Characteristics of Organic-Rich Shale in the Wufeng-Longmaxi Formation, Xichang Basin, China.

The shale of the Upper Ordovician Wufeng Formation and the Lower Silurian Longmaxi Formation in the Xichang Basin is the main replacement horizon for the shale gas exploration being conducted in the Sichuan Province, except for the Sichuan Basin. The fine identification and classification of the types of shale facies are important for shale gas exploration and development evaluation. However, the lack of systematic experimental studies on rock physical characteristics and micro-pore structures leads to a lack of physical evidence for the comprehensive prediction of shale sweet spots. Therefore, the present study used different means, such as core observation, total organic carbon content (TOC), helium porosity measurement, X-ray diffraction analysis, and mechanical properties analysis, in combination with the analysis of the whole rock mineral composition and characteristics of shale, for the identification and classification of the lithofacies of the shale layer, the systematic petrology and hardness measurement of the shale samples with different lithofacies, and discussion of the dynamic and static elastic properties of the shale samples and the control factors. It was revealed that nine types of lithofacies existed in the Wufeng Formation- the Long11 sub-member in the Xichang Basin, among which moderate organic carbon content-siliceous shale facies, moderate organic carbon content-mixed shale facies, and high-organic carbon content-siliceous shale facies were the best lithofacies with the optimum reservoir conditions, providing sufficient space for shale gas accumulation. The siliceous shale facies mainly developed organic pores and fractures, and the pore texture was excellent overall. The mixed shale facies mainly developed intergranular pores and mold pores, with a preference toward pore texture. The argillaceous shale facies mainly developed dissolution pores and interlayer fractures, and the pore texture was relatively poor. The geochemical characteristics of the organic-rich shale samples with TOC > 3.5% revealed that the sample was composed of microcrystalline quartz grains as the rock support framework, while the intergranular pores were located between the rigid quartz grains, which exhibited hard pores in the analysis of their mechanical properties. In the relatively organic-poor shale samples with TOC < 3.5%, the quartz source was mainly terrigenous clastic quartz, and the sample was composed of plastic clay minerals as the rock support skeleton, while the intergranular pores were located between argillaceous particles, which exhibited soft pores in the analysis of their mechanical properties. The difference in the rock fabric of the shale samples resulted in an ″initial increase followed by a decrease″ trend of velocity with quartz content, with the organic-rich shale samples exhibiting low velocity-porosity and velocity-organic matter content change rate, and the two kinds of rocks were easier to distinguish in the correlation diagram of the combined elastic parameters such as the P-wave impedance-Poisson ratio and the elastic modulus-Poisson ratio. The samples dominated by biogenic quartz exhibited greater hardness and brittleness, while the samples dominated by terrigenous clastic quartz exhibited lower hardness and brittleness. These results could serve as a basis for logging interpretation and seismic ″sweet spot″ prediction of high-quality shale gas reservoirs in Wufeng Formation-Member 1 of the Longmaxi Formation.

Enrichment characteristics of deep shale gas in tectonically complex regions of the southeastern sichuan basin, China

In recent years, breakthroughs have been made in deep shale gas exploration in the Wufeng-Longmaxi formations in the complex tectonic region of the Sichuan Basin and southeastern margin, indicating promising prospects for exploration and development. This study focuses on the Nanchuan area of the complex tectonic region of the southeastern Sichuan Basin margin, using data from drilling wells and experimental analysis tests to investigate deep shale gas enrichment characteristics, particularly the effects of changes in the formation environment such as formation temperature and pressure on deep shale gas enrichment. The study concludes that: (1) The dominant sedimentary phase zone is the basis for hydrocarbon formation in shale gas reservoirs, with the Wufeng Formation–the first member of Longmaxi Formation in the study area—formed in a deep-water shelf sedimentary environment with high-quality shale development, which provides favorable material conditions for the formation of shale gas reservoirs. (2) Organic carbon content controls the degree of development of nanoscale organic matter pores, and the high-pressure-ultra-high-pressure environment helps maintain pores and improve the physical properties of deep shale. (3) Deep shale gas exhibits typical geological characteristics of high temperature, high ground stress, and exceptionally low permeability. The study finds the influence of temperature on the adsorption capacity of shale is more significant than that of pressure, and deep shale gas is primarily free gas. High pressure can slow down or inhibit gas flow, which is beneficial to shale gas preservation. (4) Gas diffusion is complex, with high temperature increasing the diffusion of gas, aggravating the migration and escape of gas, while high pressure can slow down or inhibit gas flow, which is beneficial to shale gas preservation. (5) The burial depth and pressure coefficient show a positive correlation, and the burial depth has a more significant effect on the pressure coefficient of syncline shale gas, indicating that preservation conditions of deep syncline shale gas reservoirs are becoming better. Residual syncline core with larger depths, inner-sag uplift, and slopes with reverse faults can be favorable targets for shale gas exploration in complex tectonic zones.

Differences of Organic Matter Types of High Maturity Marine Organic-Rich Shale from Wufeng-Longmaxi Formation: Implication for Shale Gas “Sweet Spots” Prediction

Based on the identification of visual kerogen assessment, a subdivision method of organic matter types was proposed. Combined with GR curve, the distribution was further studied, the relationship between shale reservoir parameters and organic matter types was analyzed, and the significance was discussed. The results show that the kerogen types of organic rich shale in the lower part of Wufeng-Longmaxi Formation in the south of the Sichuan Basin are mainly of type I, II1a and II1b, while type II2 and type III are not developed. In Wufeng Formation, the shale organic matter is mainly of type II1a and II1b. From Long111 to Long114, the shale displays a trend of “Type I-II1b-II1a-II1b”. Type I was characterized by higher TOC, porosity and gas bearing capacity of shale reservoirs than the other organic matter. The reservoir parameter of type II1a was better than type II1b, indicating that the organic matter type control on the quality of shale reservoirs. Type difference is closely related to the bio-precursors component, among which type I and type II1a are related to the content of planktonic algae, while type II1b is related to the content of benthic algae. This study provides a good reference for the subdivision of marine shale organic matter types and the evaluation and prediction of gas bearing properties.

Rock physics model for velocity—pressure relations and its application to shale pore pressure estimation

Acoustic wave velocity has been commonly utilized to predict subsurface geopressure using empirical relations. Acoustic wave velocity is, however, affected by many factors. To estimate pore pressure accurately, we here propose to use elastic rock physics models to understand and analyze quantitatively the various contributions from these different factors affecting wave velocity. We report a closed-form relationship between the frame flexibility factor (γ) in a rock physics model and differential pressure, which presents the major control of pressure on elastic properties such as bulk modulus and compressional wave velocity. For a gas-bearing shale with abundant micro-cracks and fractures, its bulk modulus is much lower at abnormally high pore pressure (high γ values) where thin cracks and flat pores are open than that at normal hydrostatic pressure (low γ values) where pores are more rounded on average. The developed relations between bulk modulus and differential pressure have been successfully applied to the Upper Ordovician Wufeng and Lower Silurian Longmaxi formations in the Dingshan area of the Sichuan Basin to map the three-dimensional spatial distribution of pore pressure in the shale, integrating core, log and seismic data. The estimated results agree well with field measurements. Pressure coefficient is positively correlated to gas content. The relations and methods reported here could be useful for hydrocarbon exploration, production, and drilling safety in both unconventional and conventional fields.