Wufeng Formation Research Articles

Rock physics model for velocity—pressure relations and its application to shale pore pressure estimation

Acoustic wave velocity has been commonly utilized to predict subsurface geopressure using empirical relations. Acoustic wave velocity is, however, affected by many factors. To estimate pore pressure accurately, we here propose to use elastic rock physics models to understand and analyze quantitatively the various contributions from these different factors affecting wave velocity. We report a closed-form relationship between the frame flexibility factor (γ) in a rock physics model and differential pressure, which presents the major control of pressure on elastic properties such as bulk modulus and compressional wave velocity. For a gas-bearing shale with abundant micro-cracks and fractures, its bulk modulus is much lower at abnormally high pore pressure (high γ values) where thin cracks and flat pores are open than that at normal hydrostatic pressure (low γ values) where pores are more rounded on average. The developed relations between bulk modulus and differential pressure have been successfully applied to the Upper Ordovician Wufeng and Lower Silurian Longmaxi formations in the Dingshan area of the Sichuan Basin to map the three-dimensional spatial distribution of pore pressure in the shale, integrating core, log and seismic data. The estimated results agree well with field measurements. Pressure coefficient is positively correlated to gas content. The relations and methods reported here could be useful for hydrocarbon exploration, production, and drilling safety in both unconventional and conventional fields.

Palaeoenvironmental Evolution Based on Elemental Geochemistry of the Wufeng-Longmaxi Shales in Western Hubei, Middle Yangtze, China

The organic-rich shales found in the Wufeng–Longmaxi Formation are typically deposited in oxygen-deficient reducing environments. One of the primary sources of debate revolves around the question of whether the anoxic bottom water found in these shales is either euxinic or ferruginous, and this matter remains unresolved. Previous studies have mostly focused on the Wufeng–Longmaxi Formation as a whole in order to understand the key factors that control organic matter accumulation (OMA). However, research on OMA for each member, including the Wufeng Formation (WF), the lower Longmaxi Formation (LLM), and the upper Longmaxi Formation (ULM), has been insufficient. This paper aims to investigate the palaeoenvironmental conditions and OMA mechanisms of the Wufeng–Longmaxi shales in western Hubei by integrating data on total organic carbon (TOC) content, mineral compositions, major and trace elements, and iron speciation. The results indicate that the Wufeng–Longmaxi shales were deposited under highly restricted hydrographic conditions, except for relatively open and upwelling conditions in the upper WF. Silica in the upper WF was primarily biogenic origin and not hydrothermal. Ferruginous conditions were the primary redox conditions for organic-rich shales except for minor formations in the lower LLM that were deposited under euxinic conditions. Due to the tectonic uplift caused by the Kwangsian Orogeny in the upper LLM, the palaeoenvironment was characterized by a warmer and wetter climate, high terrigenous influx, oxic conditions, and low productivity as the result of the insufficient nutrients caused by the weak upwelling, leading to the turnover of graptolite biozones from LM5 to LM6. The factors influencing OMA changed vertically. TOC contents have a highly positive correlation with Al content, indicating that terrigenous influx was the main factor affecting OMA in the WF, which significantly differed from patterns found in other regions. This suggests that the sedimentation rate of organic matter was higher than the terrigenous dilution rate during the WF stage. The combination of redox conditions and productivity were the main factors affecting OMA in the LLM, while terrigenous influx was the key factor controlling OMA in the ULM, resulting in the dilution of organic matter. Regions in the eastern Yiling block, which are close to the Qinling Ocean, show better prospects for shale gas exploration. This research will further facilitate the development of shale gas in this area.

Palaeoenvironment evolution and organic matter enrichment mechanisms of the Wufeng-Longmaxi shales of Yuanán block in western Hubei, middle Yangtze: Implications for shale gas accumulation potential

The deposition of black shale is influenced by several factors, including organic matter input, which is controlled by primary productivity; preservation, which is governed by redox conditions and deposition rates; and dilution, which is controlled by terrigenous input. However, determining the individual contribution of these factors to organic matter enrichment (OME) is complex due to significant variations in palaeodepositional conditions across different regions. In this study, we aimed to investigate the palaeoenvironmental conditions and OME mechanisms in the Wufeng-Longmaxi Formation in western Hubei by integrating data on total organic carbon (TOC) content, mineral compositions, and major and trace elements. We also examined the rapid variations in the palaeoenvironment, which led to the mass extinction in the Late Ordovician. Our findings indicate that dolomite siltstone and silty dolomite are present in the Guanyinqiao Formation (GYQ), which differs from other regions. The silica in the Wufeng-Longmaxi Formation has a mainly nonhydrothermal origin, while the upper Wufeng Formation (WF) has an entirely biogenic source. The organic-rich shales were primarily deposited in a warm and humid climate with low terrigenous input, low salinity, dysoxic conditions, and moderate to high palaeoproductivity due to moderate to strong upwelling. The GYQ serves as a transitional section from the WF to the Longmaxi Formation, which was characterized by a cold climate, oxic conditions, weak upwelling, and deposition in a strongly restricted setting, potentially leading to the mass extinction. Overall, OME was primarily dominated by preservation, with factors that influenced OME changing vertically. Palaeoproductivity, combined palaeoproductivity and palaeoredox conditions, and palaeoredox conditions were the main controlling factors in the WF, the Lower Longmaxi Formation (LLMX), and the Upper Longmaxi Formation (ULMX), respectively. Additionally, the Huangling basement, a submarine high, and the Xuefeng uplift's uplift and compression played important roles in OME. However, shale gas exploration prospects in the study area are limited due to the thinness of the organic-rich shales, oxic to dysoxic conditions, and relatively low palaeoproductivity.

Seismic prediction of shale reservoir quality parameters: A case study of the Longmaxi–Wufeng formation in the WY area

Shale is a crucial natural gas resource, attracting global exploration and development interest. China has abundant shale gas resources that will drive future oil and gas exploration advances by increasing reserves and production. The WY shale gas field is the most productive and has the greatest potential for exploration and development. This study analyzed high-quality shale logging response characteristics and drilling logging, seismic, and analytical test data in the WY area to establish a rock physical model of seismic attribute parameters and shale reservoir quality parameters. Seismic elastic parameters were converted into indicators that directly reflect shale reservoir quality, such as total organic carbon (TOC), high-quality reservoir thickness, porosity, brittleness index, and crack development strength. Corresponding regression equations were established to predict quality parameters.The results showed that shale reservoir quality parameters have a good correlation with seismic parameters. The TOC distribution ranged from 2% to 5% in the study area and was generally high in the north but low in the south. The high-quality shale reserve had a thickness of over 40 meters, and except for the northwest region, the porosity was nearly over 4%. The overall brittleness of the study area was favorable, and the brittleness index was over 35%, which is suitable for network fractures formation in subsequent fracturing operations. The anisotropy of shale in S1l1I was small, and the overall fractures were underdeveloped in the study area. Drilling verifications showed that the prediction results of the quality parameters of high-quality shale reservoirs were consistent with actual drilling test results with high reliability. This study provides guidance for comprehensive prediction of sweet spots and subsequent fracturing and well location deployment.In summary, this study provides valuable insights into shale gas exploration and development in the WY area by establishing a rock physical model, predicting quality parameters, and offering guidance for fracturing and well location deployment.

Organic matter accumulation mechanisms in the Wufeng-Longmaxi shales in western Hubei Province, China and paleogeographic implications for the uplift of the Hunan-Hubei Submarine high

Organic matter accumulation exhibits different distribution patterns in time and space and tends to be controlled by many factors. This study investigated the mechanisms that control the accumulation of organic matter in the Xianfeng area of western Hubei Province, South China through sedimentological and geochemical analyses of wellbore samples. The results showed that the total organic carbon (TOC) content, mineral content, and elemental geochemical data of the Wufeng-Longmaxi Formations varied significantly with depth. Based on the sharp changes in the vertical profiles of the TOC content, Gamma-ray, and numerous geochemical parameters, as well as regional stratigraphy, this study divided the section from the Upper Ordovician Wufeng Formation to Lower Silurian Longmaxi Formation into six units (W1, W2, GYQ, L1, L2, and L3). The TOC content was positively correlated with redox proxies (DOPT, VEF, and MoEF) and primary productivity proxies (CuEF and NiEF), and negatively correlated with terrigenous input proxies (Al, K, and Ti). The correlation coefficients suggest that the primary factors affecting organic matter accumulation are redox conditions and paleoproductivity, while terrigenous input is a secondary controlling factor. This study proposed an organic matter accumulation model based on the organic matter characteristics, lithofacies, sedimentary environment, and geological setting of the study area. During the deposition of Unit W1, organic matter was well-preserved owing to the anoxic bottom water environment resulting from strong water mass restriction. During the deposition of Unit W2, the rising sea level led to the development of anoxic-euxinic bottom water conditions, and the joint influence of nutrients from upwelling in the open sea and volcanic eruptions enhanced productivity, resulting in the most intense accumulation of organic matter. Unit GYQ had low TOC content due to low productivity despite anoxic conditions. During the deposition of Unit L1, the uplift of the Hunan-Hubei Submarine High caused the depocenter to shift westward and the sea level in this area to drop, resulting in suboxic bottom water and relatively low productivity in the surface water layer. During the deposition of Unit L2, the regional sea level drop resulted in increased input and dilution of terrigenous clasts, thus leading to low TOC content. During the deposition of Unit L3, continuously enhanced terrigenous input due to climate warming and sea level drop became the major factor controlling the organic matter accumulation. In summary, the main factors controlling the organic matter accumulation differed significantly at different evolutionary stages. Compared with the Jiaoshiba area, the Xianfeng area in western Hubei experienced continuously increased terrigenous input, a less reductive water mass, a significant decrease TOC content, and a westward shift of the depocenter since the early stage of the Longmaxi Formation deposition. These changes may be related to the intense uplift of the Hunan-Hubei Submarine High triggered by the Kwangsian Orogeny. These results provide important implications for the understanding of the accumulation of organic matter in the Wufeng-Longmaxi Formations and paleogeographic changes.

Development model and identification of evaluation technology for Wufeng Formation–Longmaxi Formation quality shale gas reservoirs in the Sichuan Basin

In 2012, China's first national shale gas demonstrations areas were set up in the Sichuan Basin. After 10 years' construction and practice, the giant marine shale gas area of 10 × 1012 m3 level is built up in the Sichuan Basin, and shale gas steps into a new stage of large-scale benefit exploration and development. In order to systematically summarize the achievements in shale gas exploration and development and provide guidance and reference for the exploration and development of deep shale gas and shale oil & gas in other areas, this paper systematically summarizes the main characteristics, development models and key identification and evaluation technologies for quality reservoirs of Wufeng Formation–Longmaxi Formation shale gas by analyzing the electric property, lithofacies, reservoir parameters and microscopic porosity of key wells in the basin. And the following research results are obtained. First, biogenetic siliceous shale, calcareous shale and mixed shale are main lithofacies types in quality shale gas reservoirs, and they are formed in the environment of semi-deep and deep water continental shelf. Their lateral distribution is controlled by the paleogeomorphology and their vertical development is influenced by provenance, redox condition and paleo productivity. They are 25–90 m thick. Second, in the quality shale gas reservoirs develop organic pores, inorganic pore and microfractures (including lamina/bedding fractures), among which, organic pore is one of the main reservoir spaces and microfracture is not only indispensable reservoir space, but also production pathway. The reservoir space of shale gas is overall micro-nano pore, and macropores play an important role in shale gas enrichment. Third, three development models of quality reservoir are established, including sedimentary type, diagenesis type and reworking type. The sedimentary type is the foundation. Multiple quality reservoirs are developed in the high U/Th interval of graptolite belt at the bottom of Longmaxi Formation, and their thickness is mainly controlled by paleogeomorphology and especially greater in the depression area. The diagenesis type is divided into three forms, i.e., syngenetic-early diagenetic rigid support, middle-late diagenetic mineral-organic matter transformation, and overpressure relief compaction. The reworking type is dominated by quality reservoirs with microfractures. Fourth, the core technologies for identifying and evaluating quality shale gas reservoir include large-size core and rock slice observation, high-accuracy rock mineral identification, experimental gas content test and simulation, SEM microscopic characterization, 3D microscopic pore reconstruction, comprehensive geophysical interpretation and prediction and big data analysis. In conclusion, nearly 10 years' research and practice achievements in demonstration area construction can deepen the understanding on domestic quality shale gas reservoirs, promote the effective development of the theories and technologies related to shale gas reservoirs, improve the prediction accuracy of shale gas sweet spot zones/intervals, and expand the shale gas exploration and development achievements of demonstration areas.

Depositional-diagenetic process and their implications for pore development of Wufeng-Longmaxi shales in the Jiangdong block, Fuling shale gas field, SW China

Depositional environment and diagenesis are important factors affecting pore characteristics, whereas how differential depositional and diagenetic processes affect pore development and preservation in shale remains controversial. In this study, based on geochemical analysis, low-temperature gas (including N2 and CO2) physisorption, core observation, thin section and field emission-scanning electron microscopy, the influences of various paleoenvironmental conditions and diagenetic pathways on pore development of the Wufeng and Longmaxi Formations are investigated. The results indicate that paleoenvironmental conditions determine primary mineral composition and content of organic matter, resulting in the various shale lithofacies. Subsequently, minerals in different shale lithofacies experienced various diagenetic events and evolution pathways, finally affecting pore generation and evaluation. Three system tracts, including transgressive systems tract (TST), early highstand systems tract (EHST) and late highstand systems tract (LHST) are identified in the Wufeng and Longmaxi Formations. Siliceous shale, mainly deposited in the TST, contains large amounts of biogenic authigenic quartz and abundant organic matter. Authigenic quartz aggregates effectively inhibit compaction and protect abundant pores. The contents of extrabasinal components increase during the EHST, while biogenic quartz and organic matter decrease to mainly develop mixed shale. Insufficient microcrystalline authentic quartz and high content of clay minerals lead to higher degree of compaction in mixed shale than siliceous shale, resulting in fewer residual pores. In contrast, clay minerals in clay-rich shale, deposited in the LHST, undergo strong compaction and illitization of smectite during diagenesis, resulting in strong deformation and loss of primary pores. As a result, higher amount of OM pores is generated and preserved in the organic-rich siliceous shales from the bottom of Wufeng and Longmaxi Formation, and gradually decreases in the mixed shale, while clay-rich shale in the upper section of the Longmaxi has the lowest amount of pore volume.

Theory and practice of unconventional gas exploration in carrier beds: Insight from the breakthrough of new type of shale gas and tight gas in Sichuan Basin, SW China

Unconventional gas in the Sichuan Basin mainly includes shale gas and tight gas. The development of shale gas is mainly concentrated in the Ordovician Wufeng Formation–Silurian Longmaxi Formation, but has not made any significant breakthrough in the Cambrian Qiongzhusi Formation marine shale regardless of exploration efforts for years. The commercial development of tight sandstone gas is mainly concentrated in the Jurassic Shaximiao Formation, but has not been realized in the widespread and thick Triassic Xujiahe Formation. Depending on the geological characteristics of the Qiongzhusi Formation and Xujiahe Formation, the feedback of old wells was analyzed. Then, combining with the accumulation mechanisms of conventional gas and shale gas, as well as the oil/gas shows during drilling, changes in production and pressure during development, and other characteristics, it was proposed to change the exploration and development strategy from source and reservoir exploration to carrier beds exploration. With the combination of effective source rock, effective carrier beds and effective sandstone or shale as the exploration target, a model of unconventional gas accumulation and enrichment in carrier beds was built. Under the guidance of this study, two significant results have been achieved in practice. First, great breakthrough was made in exploration of the silty shale with low organic matter abundance in the Qiongzhusi Formation, which breaks the traditional approach to prospect shale gas only in organic-rich black shales and realizes a breakthrough in new areas, new layers and new types of shale gas and a transformation of exploration and development of shale gas from single-layer system, Longmaxi Formation, to multi-layer system in the Sichuan Basin. Second, exploration breakthrough and high-efficient development were realized for difficult-to-produce tight sandstone gas reserves in the Xujiahe Formation, which helps address the challenges of low production and unstable production of fracture zones in the Xujiahe Formation, promote the transformation of tight sandstone gas from reserves without production to effective production, and enhance the exploration and development potential of tight sandstone gas.

Principal characteristics of marine shale gas, and the theory and technology of its exploration and development in China

The exploration and development theory and technology of marine shale gas with shallow burial depth of 3500 m in South China has become mature after more than 10 years of practice. In order to continuously promote the exploration and development of shale gas in China, based on the research results of many scholars, combined with production practice, the main characteristics of marine shale gas in China and the main theory and technology of exploration and development are further summarized. The results show that: (1) The basic characteristics of marine shale gas in southern China are marine deep-water shelf deposition, and organic-rich shale is distributed continuously in a large area; The organic matter is stored in situ after high thermal maturity gas generation, and the gas content of shale is affected by late tectonic activity; The reservoir space is dominated by nano-scale pores, and the reservoir is super-tight and ultra-low permeability, which has no natural productivity without well stimulation; Bedding and natural fracture affect the productivity of shale gas wells; The mechanical properties of shale rock determine the effect of horizontal wells. In the early stage of well production, the production rate is high and the decline is fast, while in the middle and late stage, the rate is low but the production cycle is long. (2) Based on the above characteristics, the theory of “sweet spot” and “sweet interval” of shale gas and the theory of effective development of artificial gas reservoir are established, that is, the sedimentary and tectonic interaction forms the “sweet area” or “sweet spot” of marine shale gas. Gas productivity is determined by geological and engineering factors, so the “sweet spot” must be found to develop. By constructing artificial gas reservoir through “making an artificial high permeability area, and reconstructing a seepage field”, the effective development of ultra-tight and low permeability shale gas reservoirs can be realized. It is the most effective technique for shale gas development to accurately create “transparent geological body” of reservoirs based on geology-engineering integrated evaluation technology and establish artificial gas reservoir through multi-stage fracturing technology. (3) The overpressure area in the southern Sichuan Basin is the “sweet area” for shale gas development. The “sweet interval” of the lower Silurian Longmaxi Formation with a thickness of 3–5 m and high brittle-rich organic matter is the optimal “golden target” for horizontal wells. (4) The development leapfrog from the first generation to the second generation has been realized by the key technology of multi-stage fracturing of horizontal wells. The EUR per well of Upper Ordovician Wufeng Formation and Longmaxi Formation in southern Sichuan has increased from 0.5 × 108 m3 in the initial stage to 1.0 × 108–1.2 × 108 m3 at present with a buried depth of shallower than 3500 m. (5) The effective area favorable for shale gas development in southern Sichuan is 2.0 × 104 km2, and it is estimated that the proven geological reserves of shale gas can reach 10 × 1012 m3. It is preliminarily predicted that the shale gas production in China will exceed 300 × 108 m3 in 2025 and reach 400 × 108 m3 in 2035.

Comparison and Verification of Gas-Bearing Parameter Evaluation Methods for Deep Shale Based on the Pressure Coring Technique

Gas-bearing properties, such as gas-in-place (GIP) content and adsorbed gas ratio (AGR), have drawn considerable attention because they are essential for shale gas resource evaluation and sweet spot forecasting. The above-mentioned metrics have been determined using a variety of approaches, but they lack systematic comparison and accuracy verification, particularly for deep shale gas, where conventional methods frequently fall short. A total of 30 shales were taken for the investigation utilizing pressure and conventional coring methods from Wufeng and Longmaxi Formations in the Sichuan Basin, China. For pressure coring samples, we developed the experimental protocols and a GIP content classification scheme that categorizes the GIP content into four categories: lost gas (estimated using the temperature-corrected pressure-holding ratio), extracted gas from depressurization, degassed gas, and residual gas. The four pressure coring samples from well Y206 with measured GIP content range from 2.84 to 5.58 m3/tonne, with an average of 4.72 m3/tonne. In contrast to the calculated GIP content of the pressure coring samples, the validity of the current GIP content evaluation methodologies has been confirmed. The comparison results demonstrate that the GIP content assessed using the United States Bureau of Mines (USBM) method is frequently underestimated for samples from conventional coring and notably overstated for samples from pressure coring. The polynomial fitting method dramatically overestimated the GIP content. With its accurate time-dependent boundary conditions and strict theoretical foundation, the simplified carbon isotope fractionation (s-CIF) model exhibits the highest level of accuracy in determining GIP content. Additionally, the s-CIF model can find yet another crucial parameter of AGR. Shale samples from well Y206 had an average AGR of 20.4% but a range from 12.2 to 33.2%. The examination of the influencing factors demonstrates that the lost gas ratio, AGR, and diffusion coefficient are responsible for controlling the calculation error of the USBM method. The lost gas ratio prior to core retrieval increases with decreasing AGR (or increasing diffusion coefficient), which increases the computation error of the USBM method.

Experimental study on mechanical properties and fracture characteristics of shale layered samples with different mineral components under cyclic loading

In shale plays, the in-situ effective stress is continuously being perturbed because of the production which impacts field operations. Therefore, mechanical properties of the formation and its response to stress field changes, with respect to mineral variations, is of great significance for the proper design of horizontal drilling and hydraulic fracturing. In this paper, clay-rich, calcareous and siliceous black shales are classified based on their XRD analysis, from the Wufeng and Longmaxi Formations in the Sichuan Basin of the Upper Yangtze Plate. Uniaxial quasi-static and cyclic loading tests, acoustic emissions, and CT scanning are combined to study mechanical behavior and fracturing mechanisms of the shale layer samples that own different mineral components. The results show that the strength and deformation response of the samples is a function of their mineral composition. The damage from cyclic loading is gradually accumulated in the samples which ultimately leads to fatigue and sample failure. The compressive strength of the samples under cyclic loading is lower than in the uniaxial quasi-static conditions. Furthermore, the fracturing of rock under uniaxial quasi-static loading mainly occurs after the peak strength is achieved while in cyclic loading, when a certain stress level is reached, fracturing begins, the damage accumulates up to the peak stress and the rock suddenly fails. Based on CT images from the samples after rupture, failure modes of the clay-rich, calcareous and siliceous black shales mainly constitute extensional and shear fractures, with some conjugate shearing. In comparison with uniaxial quasi-static loading, the fracture volume of the clay-rich, calcareous and siliceous black shales after cyclic loading increases by 12.2%, 25.9% and 32.9%, respectively. Overall, this study explains how cyclic loading that can be applied in the field via changing the injection pressure and other stimulation parameters, can effectively improve the complexity of the shale fracture network and lead to higher productivity of the formation.

Sedimentary facies, lithofacies paleogeography, and an evaluation of the Ordovician sequences in the Sichuan Basin, southwest China

Ordovician strata in the Sichuan Basin occur in formations of varying thicknesses. Deposited in intracratonic and craton margin depressions of the Yangtze Block, these strata are rarely exposed in the basin with poorly described facies types and multiple controversies in sequence stratigraphy, which can lead to inaccurate interpretations of depositional settings and paleogeography. We studied outcrops, samples, and thin sections, and conducted interpretations of the environment of deposition and sequence stratigraphy as well as the lithofacies paleogeographic characteristics of different depositional stages of Ordovician units. Macroscopic facies (08) and their associated microfacies (14) were identified from outcrops and thin sections. The depositional environments of the carbonate rocks were interpreted using the standard microfacies types (SMF) of Flügel (2010) as a reference. The Ordovician units in the Sichuan Basin were divided into three 2nd-order sequences, including two complete cycles (SSQ1 and SSQ2) and one semi-cycle (SSQ3), and further subdivided into ten 3rd-order sequences (SQ1-SQ10). Ordovician units were partitioned into seven formations: the Tongzi, Honghuayuan, Meitan, Shizipu, Baota-Linxiang, and Wufeng formations. Based on the variation characteristics of the carbon-13 isotope (δ13C) curve, two large cycles of sea-level rise and fall were detected in the study area. An extensional rifting event occurred in the basin during the first cycle (Lower Tongzi Formation to Early/Middle Meitan Formation). The basin was in a compressive stage during the second cycle (Late Meitan Formation to Late Wufeng Formation). The Early Ordovician Tongzi and Honghuayuan formations were deposited in shallow water. During the deposition of these units, shoal facies occurred in the platform margin. Afterward, rimmed carbonate platforms occurred in the platform margin with a fauna mainly composed of brachiopods, echinoderms, trilobites, bryozoans, and algae. The Middle Ordovician Meitan Formation is characterized by increased clastic components deposited in continental shelf environments with graptolite and trilobite fossils. The Late Ordovician Baota Formation is marked by the development of slope facies deposited in carbonate ramp environments with cephalopod and trilobite fragments. The Late Ordovician Wufeng Formation was deposited in deep water shelf settings characterized by graptolite fossils. Tectonic activities and relative sea-level change mainly controlled the paleogeographic pattern and the evolution of the Sichuan Basin. The results presented in this study provide valuable insights and fill a significant gap in facies analysis, sequence stratigraphic division, and paleogeography of Ordovician units in the Sichuan Basin.

Geochemical Characteristics and Organic Matter Accumulation of Wufeng-Longmaxi Shales in the Southeast of the Sichuan Basin of South China

The Upper Ordovician Wufeng Formation and Lower Silurian Longmaxi Formation black shales are the critical targets for shale gas exploration in the Sichuan Basin of South China. The enrichment of organic matter (OM) in shale is the basis for the generation of large-scale shale gas; however, its controlling factors in Wufeng-Longmaxi shales are still under debate, and few studies have focused on the edge of the Sichuan Basin. Based on the mineral composition, total organic carbon (TOC), and systematic inorganic geochemistry analysis of 72 core samples from Wufeng and Longmaxi formations in Well Xike 1, southeastern Sichuan Basin, the sedimentary conditions (palaeoclimate, palaeoredox, and palaeoproductivity) were reconstructed, and the controlling factors of OM enrichment were identified. The mineral compositions are dominated by quartz, clay minerals, calcite, and feldspar, associated with minor dolomite, pyrite, and anhydrite. The TOC contents (0.31%-6.84%, avg. 2.22%) show an upward decreasing trend from the Wufeng Formation to Longmaxi Formation. The chemical index of alteration (CIA) ranges from 65 to 71 (avg. 69), indicating warm and humid climate with moderate weathering. The diagrams of Al2O3-TiO2, TiO2-Zr, Zr/Sc-Th/Sc, La/Th-Hf, and La-Th-Sc jointly indicate the contribution from felsic and intermediate rock weathering. The P/Al, Cu/Al, and Ni/Al ratios suggest that marine paleoproductivity was relatively high in the Wufeng Formation and relatively low to moderate in the Longmaxi Formation. The V/Cr, V/Sc, U/Th, MoEF/UEF, and Corg/P ratios indicate that the bottom water was anoxic during the Wufeng Formation deposition and then fluctuating dysoxic and/or oxic in the overlying Longmaxi Formation. The TOC content was positively correlated with productivity proxies (P/Al, Cu/Al, and Ni/Al) as well as redox proxies (U/Th, V/Cr, MoEF/UEF, and Corg/P), indicating that the OM accumulation in Wufeng-Longmaxi shales is mainly controlled by high productivity and anoxic bottom water conditions.

Differential sedimentary mechanisms of Upper Ordovician-Lower Silurian shale in southern Sichuan Basin, China

The Wufeng-Longmaxi Formations are the focus of shale gas exploration in China. Their sedimentation is affected by global and regional geological events, and the resulting heterogeneity hinders the expansion of exploration results. This study combines logging, mineralogy, and geochemistry to reconstruct the sedimentary mechanisms of shale in the southern Sichuan Basin and discusses its implications for exploration. The shale can be divided into third-order sequences, in which the Wufeng Formation and lower Long-1 Member are transgressive systems tracts (TST1 and TST2), and the Guanyinqiao Member and the middle-upper Long-1 Member are highstand systems tracts (HST1 and HST2). Volcanic eruption and glaciation evolution are the driving factors of the sedimentary environment during the TST. The area is in a cold-warm climate, characterized by anoxic conditions, slow sedimentation, booming productivity, and low terrigenous influx, thereby depositing four types of siliceous shale. The siliceous shale is rich in biogenic microcrystalline quartz and high TOC, which are the keys to becoming the “sweet spot” of shale gas. Microcrystalline quartz fills the intergranular pores to support the entire pore network framework. The organic matter undergoes thermal evolution to produce abundant organic matter pores, which constitute the main place for adsorbed gas and free gas. For the highstand systems tract, HST1 is the product of the peak of glaciation, mainly composed of calcareous shale and carbonate rocks. The sedimentation of HST2 is affected by turbidity currents and violent orogeny. The area is in a warm climate, characterized by high terrigenous influx, dysoxic-oxic conditions, medium productivity and rapid sedimentation rates. The lithofacies gradually changed from siliceous shale to mixed shale and argillaceous shale. Excessive clay minerals and low TOC make it difficult for HST2 to realize the commercial development of shale gas.

The Origin of the Black Shale Series and Bentonites from the Wufeng Formation in the Southwestern Upper Yangtze: Implications for the Convergence of the Yangtze and Cathaysia Blocks in the Late Ordovician

AbstractEarly Paleozoic black organic sediments and bentonites occur widely in the craton basin within the Yangtze block and are generally believed to be genetically related to a specific tectonic setting on the cratonic boundary. However, the intimate relationship between their origins and the dynamic mechanisms are unclear, as exemplified by the genesis of the black shale series and bentonites from the Wufeng Formation during the Ordovician–Silurian transition (OST). In order to reveal the relationship between the Wufeng Formation and the convergence of the Yangtze and Cathaysia blocks (i.e., the intracontinental Kwangsian Orogeny), two stratigraphic sections respectively in Zhaotong area (Northeast Yunnan) and Puyi area (Northwestern Guizhou) that were located in the semi‐restricted inner Yangtze Sea during the OST were systematically studied, on the basis of whole‐rock geochemical composition, pyrite δ34S (δ34Spy), total organic carbon (TOC), stable Sr isotope, pyrite framboid size distribution and zircon U‐Pb age, trace elements. The evidence shows that the paleo‐oceanic environment changed significantly at the turn of the early–late Katian and formed the black shale series in the Wufeng Formation. These acritarch assemblages were formed in the transition process of the Upper Yangtze Basin from passive continental margin basin to foreland basin during this interval. Based on previous research on the genetic relationship between black shale series and plate tectonic movement, a basin‐mountain evolution model suitable for South China in the Late Ordovician is presented. The two bentonites in the Wufeng Formation with U‐Pb ages of 445.5 ± 0.8 Ma and 441.9 ± 2.4 Ma primarily originated from the intermediate–acid volcanic eruption during the collision and convergence between the Yangtze and Cathaysia blocks in the Late Ordovician, the provenance region probably being located in the Jiangnan orogenic belt. Thus, we believe that the appearance of the black shale series and bentonite in the Wufeng Formation at the turn of the early–late Katian may represent the initiation of basin‐mountain transformation and the Kwangsian Orogeny in South China, which provides important evidence for the collision and convergence of the Yangtze and Cathaysia blocks in the Late Ordovician.

Late Ordovician-Early Silurian extension of the northern margin of the Upper Yangtze Platform (South China) and its impact on organic matter accumulation

Breakthroughs in shale gas exploration in the Upper Ordovician-Lower Silurian strata of the Upper Yangtze Platform have attracted interest in its sedimentary-tectonic evolution, but the tectonic background of the northern margin of the Upper Yangtze Platform remains unclear. In this paper, the Wufeng-Longmaxi formations on the northern margin of the Upper Yangtze Platform were investigated. Based on geochemical and mineralogical analyses of the tuffs/K-bentonites of the Wufeng Formation and the barite in the Longmaxi Formation, as well as previous research results, it was concluded that the northern margin of the Upper Yangtze Platform was in an extensional tectonic background during the Late Ordovician-Early Silurian. Detailed analysis revealed that, (1) the U–Pb zircon age of the tuff in the Bajiaokou section in South Qinling is 443.91 ± 0.92 Ma. The Zr/TiO2–Nb/Y diagram of the tuffs/K-bentonites indicates that their protoliths were alkaline-subalkaline basalt and andesite series rock. Based on the Th–Hf/3-Ta, Th–Tb*3-Ta*2, and TiO2–Nb/3-Th diagrams, there are undiscovered intraplate tension calc-alkaline basalts in the northern Yangtze Platform or the southern Qinling region, which provided volcanic clastic materials to the Ziyang, Lan'gao, Chengkou, Yichang and other regions. (2) Scanning electron microscopy revealed that the barite crystals in the Longmaxi Formation exhibit dissolution features and have a large particle size. Energy spectrum analysis of these barite crystals revealed that they have C, O, S, and Ba contents of 8.48 wt%, 22.98 wt%, 13.09 wt% and 55.44 wt%, so they are speculated to have been formed via cold methane seep genesis in a weak extensional tectonic setting. The 87Sr/86Sr ratios of the barite revealed that different types of barite were simultaneously formed in this area under the influences of hydrothermal and cold methane seeps. (3) The analysis of the heavy minerals in the Lower Silurian strata in the Bajiaokou section revealed that the provenance in the South Qinling area changed significantly during the late Early Silurian. Based on the above analyses, the northern margin of the Upper Yangtze Platform was in an extensional tectonic setting during the Late Ordovician-Early Silurian. The distribution of the total organic carbon content indicated that the extensional tectonic background provided good conditions for the enrichment and preservation of organic matter. The results of this study provide an understanding of the regional sedimentary-tectonic pattern and evolution of the Yangtze Platform during this period, as well as a reference for future shale gas exploration in this region.

Complex Resistivity Anisotropy Response Characteristics of Wufeng-Longmaxi Formation Shale in Southern Sichuan

Electrical exploration has become an important means of shale gas reservoir exploration and evaluation, and is expected to play a key role in the later stages of reservoir fracturing and development. At present, the research on the electrical response characteristics of shale gas reservoirs and their relationship with reservoir parameters is extensive and in-depth, but there is little research on their complex resistivity anisotropy characteristics and influencing factors, which restricts petrophysical modeling and reservoir parameter prediction, and reduces the reliability of shale gas exploration and reservoir evaluation by electromagnetic methods. In this paper, shale samples from the Longmaxi Formation and the Wufeng Formation of shale gas wells in southern Sichuan were collected, the complex resistivity of 34 shales in bedding direction and vertical bedding direction were measured, and the induced polarization (IP) parameters of shales were extracted by inversion. The electrical anisotropy response characteristics under different temperature and pressure conditions were analyzed, and the influencing factors and laws of complex resistivity anisotropy of shales were revealed. Combined with the test results of shale porosity and permeability, the evaluation model of resistivity, polarizability and porosity and permeability parameters was established. The research results have formed a set of testing methods and analysis techniques for electrical anisotropy of shale reservoirs, which are mainly based on complex resistivity parameter testing. It is helpful to understand the electrical anisotropy characteristics of shale gas reservoirs in southern Sichuan; this will provide the theoretical and physical basis for shale gas reservoir evaluation and fracturing monitoring by electrical exploration.

Development Characteristics and Distribution Patterns of Fractures in the Wufeng-Longmaxi Formation Shale in the Southwestern Sichuan Basin, China

Abstract As the important storage space and main seepage channel of the shale gas reservoirs, fractures control the migration, enrichment, and preservation of shale gas. Therefore, studying the development characteristics of fractures within shale is the key to the exploration and development of shale gas reservoirs. Based on core observation, microscopic thin section examination, field-emission scanning electron microscopy (FE-SEM) analysis, and three-dimensional seismic attribute analysis, this paper studies the development characteristics and distribution patterns of fractures in the Wufeng-Longmaxi Formation shale in the southwestern Sichuan Basin. The results show the following: (1) Both macrofractures and microfractures are developed in the Wufeng-Longmaxi Formation shale in the study area. On the macroscale, horizontal bedding fractures, low-angle slip fractures, vertical shear fractures, and high-angle fractures are mainly developed; on the microscale, intergranular fractures, intragranular fractures, abnormally high-pressure fractures, hydrocarbon generation shrinkage fractures, bedding fractures, etc. are mainly developed. These fractures of different scales work together to create an intricate fracture system within the shale. (2) Based on the 3D seismic attribute analysis, the distribution patterns of fractures was studied in the research area. It was found that nearly east-west-trending and nearly south-north-trending large faults were mainly developed in the Wufeng Formation and the Long-11 submember, with accompanying small faults and secondary fractures. From the bottom boundary of the Wufeng Formation to the top boundary of the Long-11 submember, the fault development shape is unchanged, and the secondary fractures are developed gradually densely, showing the characteristics of a zonal distribution in the entire study area. From the bottom boundary of the Wufeng Formation to the top boundary of the Long-11 submember, the development of microfractures shows variation in different zones. Microfractures are mainly developed around large faults, and the development range of microfractures decreases from bottom to top, but the development of microfractures is gradually intensive. The microfractures are densely distributed from the central to the southern part of the study area (gradually from convergence to divergence), are sparsely distributed in the western part of the study area, and are densely and widely distributed in the northern, northeastern, and northwestern parts of the study area. The research results can provide some guidance for the prediction of shale gas sweet spots in this area, which is beneficial to the further exploration and development of marine shale gas in this area.

Characteristics and Enrichment Genesis of the Platinum Group Elements (PGEs) in Organic Rich Shale of the Wufeng and Longmaxi Formations of Upper Ordovician and Lower Silurian in the Sichuan Basin

The petrology, mineralogy, elemental geochemistry, biology and PGEs characteristics of the black shale of the Wufeng and Longmaxi Formations in the CN outcrop of the Sichuan Basin are studied in this paper. The distribution and change in PGEs at different horizons are summarized, and the reasons for PGEs enrichment are discussed. The results show that the PGEs in the organic-rich shale segment are obviously enriched, which is positively correlated with the Total Organic Carbon (TOC) content and has a Pt–Pd distribution characteristic. δEuN, Pd/Pt, (Pt + Pd)/(Os + Ru + Ir), etc., and SiO2–Al2O3 and It/Pt–Pd/Pt discrimination diagrams, indicate that they are not extraterrestrial sources, nor are they the origins of normal seawater deposition but they are related to hydrothermal deposition. The enrichment process of PGEs is relatively complicated and is controlled by the impact of the sedimentary environment in the restricted basin. The anoxic water environment and organic-rich environment are the main factors of PGEs enrichment. PGEs and TOC have a good positive correlation and can be used as index parameters for sedimentary environments and organic matter enrichment.

Petrological and geochemical characteristics of the Ordovician–Silurian black shale in eastern Sichuan and western Hubei, South China: Differential sedimentary responses to tectonism and glaciation

During the Ordovician–Silurian transition period, the Yangtze area experienced significant environmental changes, which were recorded by the widely distributed black shale of the Upper Ordovician Wufeng and Lower Silurian Longmaxi formations. However, the petrological and geochemical analyses of the Upper Ordovician-Lower Silurian black shale in Well JY1 (eastern Sichuan Basin) and Well YY2 (western Hubei Province) drill cores show that there are some significant differences with respect to lithology, thickness, and geochemical characteristics despite the long-term similar variation trend in petrology and geochemistry. This may suggest some major environmental changes and their differential influence on black shale deposition in the Yangtze area. Based on the analyses of lithology, total organic carbon (TOC), MoEF, and UEF, four long-term sedimentary cycles (one for the Wufeng Formation and three for the Longmaxi Formation) were identified in Well JY1. In Well YY2, only three long-term sedimentary cycles can be recognized (one for the Wufeng Formation and two for the Longmaxi Formation). Different from the gradual increase of the geochemical proxies (such as TOC, MoEF, and NiEF) followed by an abrupt decrease in the Wufeng Formation, these proxies of the Silurian sedimentary cycles in both wells exhibit an abrupt increase at the base followed by a gradual decrease, showing that controlling mechanisms for the Lower Silurian black shale deposition in the study areas were different from those of the Upper Ordovician black shale. However, the black shale of each Silurian cycle in Well JY1 is much thicker than that in Well YY2. Compared with the thick silty mudstone developed in Well JY1 during the Rhuddanian–Aeronian transition, there is a stratigraphic gap in Well YY2 except for a thin calcareous dolostone formed in a strongly restricted environment. These differences indicate that tectonism and glacial eustasy should be the key factors for black shale development, but their influences on the deposition of the Lower Silurian black shale varied between eastern Sichuan Basin and western Hubei province. Since the early Rhuddanian stage, continuous tectonic subsidence in eastern Sichuan Basin promoted the development of thick black shale, while a persistent tectonic uplift in western Hubei Province led to the formation of thin black shale. Meanwhile, the study areas experienced a significant sea-level drop related to intensified glaciation during the Rhuddanian–Aeronian transition, which is recorded by the low chemical index of alteration (CIA) values in both wells. This resulted in the formation of a stratigraphic gap in western Hubei Province and the deposition of thick silty mudstone in eastern Sichuan Basin. Moreover, abrupt increases in CIA, TOC, MoEF, and NiEF observed in the lower part of the Aeronian black shale in the two wells suggest that eastern Sichuan Basin and western Hubei Province experienced a significant sea-level rise during the early Aeronian stage, which may be related to a global warming event. Subsequently, eastern Sichuan Basin and western Hubei Province both suffered a significant tectonic uplift related to the Kwangsian Movement leading to the termination of the Aeronian black shale formation. However, the thickness variations of the Aeronian black shale in the two study areas indicate that remarkable geomorphological differences persisted in these two areas until the middle Aeronian stage. Thus, this study not only reveals differences of the Upper Ordovician-Lower Silurian black shale in eastern Sichuan Basin and western Hubei Province, but also interprets the causes of these differences, which provide new data and perspectives for the understanding of global paleoclimate and sea-level changes during the Ordovician–Silurian transition.