In order to improve the wrinkle recovery of wool fabrics, various methods have been proposed, for example, incorporation of some bulky molecules, crosslinking with appropriate bifunctional compounds, and treatment with mercury(II) acetate and so on. In this paper, a new attempt for improving the wrinkle recovery of wool fabrics has been proposed, that is an introduction of much thiol(-SH) groups in the fabrics, considering the theory of wrinkle formation. The analysis of physical properties of the much -SH groups introduced wool fabrics, reveals that the wrinkle recovery and set property have been improved without any changes in weight, in color and handling. The sulfur content in the treated wool was found to be increased by analysing with X-ray fluorometry. This fact leads us to an conclusion that the wrinkle recovery mechanism of the present method might be based on the formation of disulfide(-SS-) groups in wool fabrics. As a comparison, we examined the wrinkle recovery mechanism by mercury(II) acetate treatment, and found that Hg ions could present as -S-Hg+ in the fabrics, which might eliminate the hydrogen bond.