It is well known that the electron motion in the external electromagnetic field is described by the relativistic Dirac equation. In this case, in the Foldy–Wouthuysen representation, the Hamiltonian includes the terms corresponding to the interaction of the particle magnetic moment with a magnetic field (∼ (1/m)(σH)) and the terms which are interpreted as a spin-orbit coupling (∼ (σ/m2){(p−eA)×E)). Apart from these constituents the Hamiltonian includes the Darwin term (∼ (1/m) divE) [1]. Such a description is in good accordance with the experimental data. It was shown by Bargman [2] that it is possible to introduce the particle spin in the nonrelativistic quantum mechanics by performing the central extension of the Galilei group. In connection with this Bargman result the problem of finding the motion equations, which are invariant with respect to the extended Galilei group G, arises naturally. Such a problem has been considered in [3–5]. The equations obtained in [5] have redundant components and, besides, these equations do not describe the spin-orbit and the Darwin couplings if one makes the replacement pμ → πμ = pμ − eAμ in them. The aim of this note is to find such motion equations for a particle with spin which are invariant relative to the group G, have no redundant components and describe the spin-orbit and the Darwin couplings of the particle with the field. It is reached by the supposition that the free nonrelativistic particle Hamiltonian has two energy signs just as the Dirac Hamiltonian. This is equivalent to the requirement that the theory (equations) be invariant under such a transformation:
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