Electric vehicles (EVs) and photovoltaics (PVs) are expected to be broadly adopted in future power systems. However, the temporal variability of EV load and PV production presents challenges for integrating them into the power grid. This study evaluates and assesses the synergies between EVs and PV systems to maximize solar energy utilization for EV load coverage. The configurations studied include EV charging via the national grid as a reference case (Case 1) and two solar energy harvesting options: EVs powered directly by vehicle-mounted PVs (Case 2) and EV chargers connected to residential PV installations (Case 3). These cases are evaluated across different urban environments with large EV fleets and dissimilar weather conditions: Berlin and Los Angeles. A customized operation profile based on the worldwide harmonized light-duty test cycle (WLTC) and a charge-right-away (CRA) strategy is used. Energy performance analysis is conducted through dynamic simulations using the Modelica language, with environmental and economic indices derived. Key findings highlight the superior performance of residential PV systems in both cities compared to current solar EV technologies, with both solutions offering significant benefits over the reference case. Cases 2 and 3 result in a 44% and 59% reduction in annual energy consumption, greenhouse gas emissions, and charging costs in Berlin, while in Los Angeles, the reductions are 67% and 98%. The average daily solar driving range reaches 20.3% in Berlin and 30.4% in Los Angeles.