Recent extreme hurricanes caused a huge loss in damages to critical civil infrastructure. To estimate hurricane wind loading on structures, spectral methods are widely used to generate neutral atmosphere boundary layer winds, which however are limited to describe extreme wind fields that are non-stationary and more turbulent. To overcome this limitation, a high-fidelity high-resolution computational model is developed to simulate hurricane wind field with detailed physics. A large eddy simulation (LES) solver is developed using a sub-grid-scale model based on open source program OpenFOAM. The simulated wind field is validated through comparison with observations. The generated wind field is applied to analyze structural response of a power transmission system. The proposed hurricane boundary layer (HBL) model and a neutral atmosphere boundary layer (ABL) model are compared in tropical storm and category-3 hurricane scenarios. Compared with the HBL model, the ABL model doesn’t consider the mesoscale terms and overestimates the crosswind velocity and the turbulent kinetic energy (TKE) near the ground. As a result, the ABL model overestimates the dynamic responses of the wires and towers. The developed HBL model captures the main characteristics of hurricane wind and is applicable for modeling civil infrastructure exposed to hurricanes at a large scale.