Wide Operating Temperature Range Research Articles

Multifunctional visualized electronic skin based on a solvatochromic poly (ionic liquid) ionogel

The biological skins exhibit various fascinating visual functions, such as turning red in response to strain, whitening upon hydrogen peroxide stimulation, and changing color in accordance with the environment (octopus). Inspired by these phenomena, two kinds of multifunctional visualized electronic skin (e-skin) were designed and fabricated based on a novel poly (ionic liquid) ionogel. Herein, we reported a transparent and conductive poly (ionic liquid) ionogel (P(AAm-IL)) by photopolymerizing acrylamide (AAm) with 1-vinyl-3-butylimidazolium tetrafluoroborate (ionic liquid, IL) in ethylene glycol (EG). Interestingly, P(AAm-IL) displays a solvatochromic phenomenon, and typical hydrogen-bonding acceptor solvents like acetone, methanol, and nitromethane induce a whitening effect in it. Based on this ionogel, we fabricated multifunctional strain sensors integrated with the visualized chemical sensing ability. The discoloration mechanism of the chemical sensing was detailed studied. Furthermore, by combining the P(AAm-IL) ionogel with Lithium trifluoroethane sulfonate (LiTf), the blend P(AAm-IL)-Li ionogel exhibits enhanced stretchability (>4300 %), higher conductivity (1.44 × 10−2 S·m−1), good transparency (>80 %) as well as wide operating temperature range (−20 to 80 °C). A sandwich-structured e-skin (Polypyrrole/PAAm-IL-Li/CsPbBr3-TPU) exhibiting both electro-optical dual response to strain was successfully fabricated. The luminescent e-skin not only exhibits highly sensitive electrical responses but also demonstrates visible fluorescence changes in response to external strain variations. These multifunctional visualized e-skins demonstrate great potential for applications in chemical environmental monitoring robotics, wearable electronic devices, and human–computer interaction.

A multi-time-scale framework for state of energy and maximum available energy of lithium-ion battery under a wide operating temperature range

Lithium-ion batteries are one of the best choices as energy storage devices for self-powered nodes in wireless sensor networks (WSN) due to their advantages of no memory effect, high energy density, long cycle life, and being pollution-free after being discarded, ensuring that the sensor nodes maintain high power operation for a long time. An improved co-estimation framework for SOE and maximum available energy has been established, considering the problem of maximum available energy decay caused by temperature and battery charge-discharge rate, which can update the maximum available energy in real-time and reduce SOE errors caused by fixed energy values. A multi-timescale SOE and maximum available energy co-estimation framework is proposed to address the asynchronous and coupled characteristics of maximum available energy and SOE estimation, effectively reducing the algorithm's computational complexity. The proposed algorithm is experimentally verified according to the designed dynamic stress test conditions of lithium-ion batteries in WSN nodes. The experimental results show that smaller time scales can provide more accurate and reliable maximum available energy correction and higher SOE estimation accuracy, but the computational time cost is higher than that of larger time scales. To balance SOE estimation accuracy and algorithm computational complexity, the appropriate time scale should be selected based on the SOE estimation accuracy and time cost in practical battery management system working conditions.

Investigating the physical properties of lead-free halide double perovskites Cs2AgXBr6 (X = P, As, Sb) for photovoltaic and thermoelectric devices using the density functional theory

Lead-free halide double perovskites are promising materials for photovoltaic and thermoelectric applications due to their desirable functional features. In the present study, Wien2k ab-initio code based on the density functional theory (DFT) was employed to Cs2AgXBr6 (X = P, As, and Sb) to investigate their structural, electronic, mechanical, optical, and thermoelectric properties. The obtained results show that all compounds are mechanically stable. Both Cs2AgPBr6 and Cs2AgSbBr6 are ductile materials whereas Cs2AgAsBr6 is brittle. On the other hand, the atomic bonds of Cs2AgAsBr6 are stronger than those of the other two compounds, and its lattice structure is more rigid. Based on the hybrid functional (YS-PBE0) potential, the bandgap of Cs2AgXBr6 (X = P, As and Sb) was identified as indirect and have the values of 1.113, 1.517, and 1.672 eV, respectively. All compounds have high optical conductivity in the visible region and show the greatest absorption in the UV–visible region. Additionally, the positive values of Seebeck and Hall coefficients over the entire temperature range indicate the presence of hole-type charge carriers in these materials. The calculated thermoelectric Figure of Merit shows a broad plateau over the investigated temperature range which ensures stable efficiency over a wide operating temperature range. The present study demonstrates the potential of the investigated compounds to be utilized in photovoltaic and thermoelectric applications.

Itinerant ferromagnetism and room temperature giant magnetocaloric effect in (Mn0.6Fe0.4) (Ni0.5Co0.5) Si shape memory alloy

In this article, the feasibility of obtaining a magneto-structural coupling over a wide working temperature range of about 127 K (from 206.5 K to 333.5 K) with negligible thermal hysteresis in combination with the structural, microstructural, magnetic, and magnetocaloric properties of a 50 % Co-doped (at the Ni site) polycrystalline (Mn0.6Fe0.4) (Ni0.5Co0.5) Si (MFNCS-0.5) magnetic shape memory alloy (MSMA) has been thoroughly investigated. Along with leaf-like microstructure, at room temperature, the system shows a mixed phase of TiNiSi type low-temperature high-magnetic (ferromagnetic) orthorhombic martensite and Ni2In type high-temperature low-magnetic (paramagnetic) hexagonal austenite, with the dominance of the second one. To estimate the magnetocaloric effect (MCE) across the phase transition, the isothermal magnetic measurement technique has been employed. The merging of heating and cooling iso-field thermo-magnetization (M-T) curves, the presence of negligible thermal hysteresis in the MH curves, universal magnetic entropy curves, a proposed phenomenological model (across the Curie temperature), and the positive slopes of the Arrott plot (Banerjee criterion) show that the first-order structural and magnetic transition are coupled along with a second-order ferromagnetic to paramagnetic (FM → PM) phase transition (SOPT). By extrapolating the Arrott plot to the H/M = 0 axis the spontaneous magnetization value very close to 0 K, Ms(0), is found to be 71.92 emu/g (∼1.83 µB/f.u.). The linear dependency of MS2T on T2 below SOPT and the RWR (Rhodes–Wolhfarth ratio) = 4.29 > 1 indicate the long-range itinerant ferromagnetism in this alloy. A giant magnetic entropy change (ΔSm) of 25.77 J kg−1 K−1 and a refrigerant capacity (RC) of 472.83 J kg−1 are obtained at 6 T field. This observed magnetic refrigerant's key characteristics, including a giant magnetocaloric effect (MCE) near room temperature (RT), negligible thermal hysteresis loss, a wide operating temperature range of 127 K, and the use of cost-effective, non-toxic constituent elements, make it a suitable and very promising member for applications in solid-state refrigeration technology near RT.

Fabrication and capillary performance of multi-scale microgroove ceramic wicks via nanosecond laser irradiation for ultrathin ceramic heat pipes

Ultrathin ceramic heat pipes have great potential in solving the heat dissipation problems for power semiconductor devices with ever-increasing power density. Ceramic wick structures with superior capillary performance plays a decisive role in the heat transfer performance of the ceramic heat pipe. In the study, a multi-scale microgroove wick (MSMGW) prepared by laser irradiation is developed. The effects of laser scan pitch, laser fabrication parameters and ceramic material on the surface morphology, wettability and capillary performance of the MSMGW were investigated. The 66 μm thick ceramic wick proposed that consists of micron-sized microgrooves, nanoscale voids and material surface reconsolidation layers demonstrates remarkable capillary performance. The laser scan pitch, laser power, repetition frequency, and scanning speed have significant impacts on the surface morphology and capillary performance of MSMGW. The MSMGW with optimal parameters could reach capillary wicking height of 114 mm within 28 s and yield a capillary parameter (K/reff) of 1.49 μm. Moreover, MSMGW on the material of alumina with advantages of excellent machining property and technology maturity, and working fluid of DI water with high vaporization latent heat and wide operating temperature range, exhibits the maximum capillary performance, indicating its highly promising prospects for high-performance ultrathin ceramic heat pipes.

A low-temperature hydrogen sensor based on an acoustic topological material

Hydrogen, as a potential replacement for fossil fuels, exhibits promising application prospects and, meanwhile, demands hydrogen sensors with high performance due to flammability and explosivity. Currently, most of hydrogen sensors work based on sorption of hydrogen with hydrogen-sensitive materials. Thus, the sensitivities of the sensors decrease with operating temperature because the reaction between sensitive materials and hydrogen weakens. Here, we create a hydrogen sensor on the basis of an acoustic topological material, in which hydrogen can be detected by measuring the shift of the topological interface state. Owing to the absence of hydrogen sorption, the sensor possesses advantages of an extremely wide operating temperature range, a good linearity, a rapid and stable dynamic response, and a long life. It is demonstrated that the relative sensitivity of the sensor is a constant, which does not change with the operating temperature. This study opens an avenue to application of acoustic topological materials.

Enhanced piezoelectric and optical properties of tetragonal Sm‐doped Pb(In1/2Nb1/2)–Pb(Mg1/3Nb2/3)–PbTiO3 crystals

AbstractRelaxor ferroelectric single crystal Pb(In1/2Nb1/2)O3–Pb(Mg1/3Nb2/3)O3–PbTiO3 (PIN–PMN–PT) has received extensive research and attention due to its excellent piezoelectric, electromechanical, and other properties. In particular, tetragonal relaxor ferroelectric single crystals have shown greater application potential in high‐temperature devices due to their higher Curie temperature and better stability. However, the low piezoelectric performance of tetragonal crystals also greatly limits its application, and research on its optical properties is not sufficient. In this paper, the tetragonal phase Sm–PIN–PMN–PT single crystal was obtained by the Bridgman method, and its piezoelectric and electro‐optical properties are studied. At the same time, we gave a complete set of piezoelectric, dielectric, and elastic coefficient matrices. The results show that the crystal has excellent piezoelectric and electromechanical properties. The piezoelectric coefficient can reach 905pC/N, the electromechanical coupling coefficient k33 is 85%, and the kt is 72%. The transmittance of the sample polarized along [001] direction can reach 66%. The effective electro‐optical coefficient γc is 60 pm/V at room temperature and can reach 86 pm/V at 70°C. It has a wide operating temperature range and stable performance with frequency variation, which has certain reference significance for application in new electro‐optical devices.

Invar Effect in the Wide and Higher Temperature Range by Coherent Coupling in Fe‐Based Alloy

AbstractInvar alloys with zero thermal expansion (ZTE), isotropy, high operation temperature, and wide temperature range are of great significance in fields such as aerospace and modern industry. However, it is difficult to simultaneously meet the above characteristics in one material. The traditional methods like element or vacancies doping would increase the operation temperature but at the expense of ZTE behavior. Here, by the coherent coupling between two cubic phases, the isotropic ZTE metallic material with the higher cut‐off temperature (560 K) and a wide operation temperature range (ΔT = 200 K) is obtained in Fe2.75Co0.25PtB0.25. The operation temperature range is much higher than that of commercial Fe0.65Ni0.35 Invar alloy and meets the applications at elevated temperatures. High‐angle annular dark field images and synchrotron X‐ray diffraction prove that by the coherent interfacial coupling between the A1 and its coherent L12 nanodomains, the original negative thermal expansion or positive thermal expansion performances for them can be changed into the same ZTE performances. This thermal expansion regulation strategy realized by coherent coupling will lead to an innovative and significant revolution for ZTE design and promote its development and application.

An integrated single-shot spectrometer with large bandwidth-resolution ratio and wide operation temperature range

There has been a rapidly growing demand for low-cost, integrated single-shot spectrometers to be embedded in portable intelligent devices. Even though significant progress has been made in this area, two major problems are still remaining, namely the high temperature sensitivity and poor bandwidth-resolution ratio (BRR) that can’t meet the requirement of most applications. In this work, we present an integrated single-shot spectrometer relying on a silicon photonic circuit that has a footprint less than 3mm2, but could achieve broad operation bandwidth about 100 nm and high resolution up to 0.1 nm (with a BRR ~ 1000). Moreover, for the first time, we demonstrate an integrated spectrometer that could operate within a wide temperature range (between 10 and 70 degrees Celsius) without additional power consumption for temperature management.

Ge0.92Sn0.08/Ge multi-quantum-well LEDs operated at 2-μm-wavelength on a 12-inch Si substrate

The development of an efficient group-IV light source that is compatible with the CMOS process remains a significant goal in Si-based photonics. Recently, the GeSn alloy has been identified as a promising candidate for realizing Si-based light sources. However, previous research suffered from a small wafer size, limiting the throughput and yield. To overcome this challenge, we report the successful growth of GeSn/Ge multiple-quantum-well (MQW) p-i-n LEDs on a 12-inch (300-mm) Si substrate. To the best of our knowledge, this represents the first report of semiconductor LEDs grown on such a large substrate. The MQW LED epitaxial layer is deposited on a 12-inch (300-mm) (001)-oriented intrinsic Si substrate using commercial reduced pressure chemical vapor deposition. To mitigate the detrimental effects of threading dislocation densities on luminescence, the GeSn/Ge is grown pseudomorphically. Owing to the high crystal quality and more directness in the bandgap, enhanced electroluminescence (EL) integrated intensity of 27.58 times is demonstrated compared to the Ge LED. The MQW LEDs exhibit EL emission near 2 μm over a wide operating temperature range of 300 to 450 K, indicating high-temperature stability. This work shows that GeSn/Ge MQW emitters are potential group-IV light sources for large-scale manufacturing.

Fabrication of NiC2O4/PANI heterojunction structure on carbon cloth for neutral electrolyte supercapacitor application

Despite the wider potential windows and environmental friendliness provided by neutral electrolyte systems in supercapacitors, lower specific capacitance was often observed due to the absence of highly active pseudocapacitive reactions on the electrode surface. Introducing pseudocapacitive reactions from the electrode interior by constructing heterojunctions could be a promising solution to address this challenge. In this study, a NiC2O4/PANI heterojunction structure was constructed on carbon cloth using an in-situ method. The electrode exhibited excellent specific capacitance (1.70F cm−2 at 2 mA cm−2) and potential window (-0.5 V to 1.2 V). Impedance analysis and the two-probe IV method further confirm the presence and effectiveness of the heterojunction in enhancing the electrode's electrochemical performance. Additionally, this electrode also demonstrated outstanding cycling stability, reproducibility, and a wide operating temperature range. The successful development of the NiC2O4/PANI heterojunction structure on carbon cloth offered valuable insights into the design and fabrication of advanced supercapacitor applications.

Droplet freezing assays using a nanoliter osmometer

The ability to accurately record the temperature at which ice nucleation occurs is critical for studying biological ice nucleators. Several instruments have been designed and custom built to make such measurements, but they are not yet on the market. Here we reproducibly measure ice nucleation temperatures down close to the homogeneous nucleation temperature of −38 °C with a commercially available nanoliter osmometer, which we routinely use to assay the thermal hysteresis activity of antifreeze proteins. This instrument has both a wide operating temperature range and fine temperature control, while the oil immersion format on 12-well grids prevents droplet evaporation and surface nucleation events. The results obtained are consistent with those reported on other instruments in common use.

Haze-Suppressed Wideband Light Shutter from Near Ultraviolet to Infrared Rays Utilizing Electrophoretic Carbon Black Particles.

Carbon black (CB) particles that can absorb from near ultraviolet to infrared rays are well dispersed into an isotropic dielectric liquid and their optical properties can be kept even under exposure to sunlight over a long time. The shutter which controls the position of CB particles by electrophoretic force can be applied to switchable light shutters for windows in buildings and automobiles for the purpose of energy savings. Here, a wideband light shutter with three terminal electrodes is proposed, exhibiting excellent dark (transmittance ≈1.4%) and transparent state (transmittance >60%). The device operates at a low field intensity of about 1Vµm-1 to obtain transparent state and its wide temperature range operation from -50 to 120°C is confirmed while conventional liquid crystal-based shutter cannot perform such levels due to a limited temperature range in the nematic phase. In addition, haze is minimized in a transparent state by adopting an insulation layer over electrodes and a solution is found to keep a transparent state without applying power. It is believed that the proposed broadband shutter with fast response time could open a new chapter in switchable windows owing to its low power consumption and working in a wide temperature range.

In-situ prelithiation of electrolyte-free silicon anode for sulfide all-solid-state batteries

All-solid-state batteries (ASSBs) based on silicon (Si) anodes offer high energy density and safety, which are considered promising next-generation energy-storage systems. However, the large initial capacity loss of Si anodes greatly limits the practical capacity and rate performance of ASSBs. Herein, through the unique in-situ prelithiation of electrolyte-free Si anodes by using ultra-thin lithium (Li) foil, the Li6PS5Cl electrolyte-based ASSBs achieve significantly improved initial Coulombic efficiencies (ICEs). The results of three-electrode ASSBs confirm that the in-situ prelithiation strategy effectively improves the reversible delithiation capacity and solid-state Li kinetics of electrolyte-free Si anode. The full cells utilizing prelithiated Si anode and LiNi0.8Co0.1Mn0.1O2 (NCM811) cathode exhibit a remarkable energy density of 402 Wh kg−1 (based on the total mass of cathode and anode) at 0.1 C and achieve a wide operating temperature range between −30 and 50 °C. In addition, the bi-polar stacking cell with high-loading NCM811 cathode achieves a high cut-off voltage of 8.7 V and works stable for over 50 cycles. This practical prelithiation method presents substantial advantages to promote the development of ASSBs based on Si anodes with high ICEs and fast Li kinetics, offering a pathway to realize solid-state storages with high rates and high energy densities.

The Effect of Microwave Irradiation on the Synthesis of Graphene from Battery Waste on Capacitance Properties

Supercapacitor material is an alternative in energy storage. Supercapacitors are charge storage devices that have a high energy density, fast charge/discharge rates, long service life, wide operating temperature range, and are environmentally friendly. Graphene is a nanomaterial that can be used as a supercapacitor because it has high conductivity and a large surface area, but graphene can experience agglomeration so it can affect its capacitance properties. The microwave-assisted method can be used in the synthesis of graphene. Several microwave-based techniques are becoming more popular for producing graphene and altering it. Due to its quick, precise, uniform, and volumetric heating, microwave heating is a promising method for the thermochemical treatment and reduction of graphene oxide to graphene. This research aimed to examine the effect of microwave irradiation time on the capacitive properties of graphene synthesis as a supercapacitor. Graphene oxide (GO) can be reduced into graphene quickly and easily using microwave pulses lasting 15 to 30minutes to produce high-quality graphene fabrication. The characterization test was performed using UV-Vis, FTIR, SEM-EDX and cyclic voltammetry (CV). As a result, the optimum time is 25 minutes, and it showed an absorption peak at the 282 nm wavelength dan the CV analysis showed that the graphene has double capacitor properties with a specific capacitance of 140.7 F/g in 20 mV/s. Besides, the result of SEM indicated that graphene could be formed successfully. Its potential applications are also illustrated by emphasizing its usage as electrode material. Finally, its main challenges and prospects are considerably pointed out.

Energetic macroscopic representation of a mechanical compression-assisted hybrid thermochemical cycle exploiting low grade heat for cold applications

This paper describes an original model based on The Energetic Macroscopic Representation (EMR) to develop a control structure of an innovative compression-assisted hybrid thermochemical cooler driven by low-grade thermal energy. Hybrid thermochemical cooler with mechanical compression have a wider operating temperature range than conventional thermochemical processes. This makes it possible to exploit lower grade heat sources and/or produce cold at lower temperatures. In addition, the ability to control compressor speed increases thermochemical process controllability to respond to load or source variations. Nodal modeling of each process component is developed according to the EMR formalism. A parametric identification and validation of this process model is then carried out using experimental data. The deviation from the experimental data is lower than 1bar for the reactor, condenser and evaporator pressure, lower than 0.1 for the reaction advancement and lower than 2°C for the reactor wall temperature. The EMR model is then inverted to obtain a process control law for maintaining a cold room at -18°C. Despite the variation in cooling demand from a minimum of 100W to a maximum of 700W, the compressor's control structure was able to regulate its speed of rotation to maintain the cold room temperature at -18±0.5°C for 24h.

Fabrication of Gelatin-Derived Gel Electrolyte Using Deep Eutectic Solvents through In Situ Derivatization and Crosslinking Strategy for Supercapacitors and Flexible Sensors.

The facile fabrication of gel polymer electrolytes is crucial to the development of flexible electronics, and the use of natural polymers as sources has obtained great attention due to their abundant, low-cost, biodegradable, easy modification, and biocompatible features. In this article, a facile fabrication protocol to engineer gelatin into gel electrolytes was developed by taking the advantages of both deep eutectic solvent (DES) (including its good solubility to gelatin and satisfactory electrochemical properties) and rich active functional groups of gelatin, through in situ derivatization and crosslinking strategy. A double-crosslinked DES gel electrolyte was prepared with the dissolution of gelatin in choline chloride and alcohol-based DES and a further crosslinking with Fe3+ ions. The obtained DES gel presented outstanding mechanical properties, excellent ionic conductivity (up to 101-102 mS/cm), a wide operating temperature range (-40 to 80 °C), satisfactory self-healing property, and good degradability. Moreover, the obtained DES gel electrolyte was successfully applied to supercapacitors and flexible sensors, showing excellent electrochemical performance and strain-response properties. In a word, our study provides a facile protocol to engineer gelatin into gel electrolytes by using deep eutectic solvent, showing significant insights into the design and preparation of sustainable gel polymer electrolytes and having great application potential in next-generation high-performance flexible electronics.

High-Performance Lithium-Sulfur Batteries via Molecular Complexation.

Beyond lithium-ion technologies, lithium-sulfur batteries stand out because of their multielectron redox reactions and high theoretical specific energy (2500 Wh kg-1). However, the intrinsic irreversible transformation of soluble lithium polysulfides to solid short-chain sulfur species (Li2S2 and Li2S) and the associated large volume change of electrode materials significantly impair the long-term stability of the battery. Here we present a liquid sulfur electrode consisting of lithium thiophosphate complexes dissolved in organic solvents that enable the bonding and storage of discharge reaction products without precipitation. Insights garnered from coupled spectroscopic and density functional theory studies guide the complex molecular design, complexation mechanism, and associated electrochemical reaction mechanism. With the novel complexes as cathode materials, high specific capacity (1425 mAh g-1 at 0.2 C) and excellent cycling stability (80% retention after 400 cycles at 0.5 C) are achieved at room temperature. Moreover, the highly reversible all-liquid electrochemical conversion enables excellent low-temperature battery operability (>400 mAh g-1 at -40 °C and >200 mAh g-1 at -60 °C). This work opens new avenues to design and tailor the sulfur electrode for enhanced electrochemical performance across a wide operating temperature range.

Construction of high-rate performance sulfurized Poly(acrylonitrile) nanofibers cathodes for practical lithium–sulfur batteries via tellurium catalytic regulation

The rapid charge-discharge and wide operating temperature range are of great significance to the research of lithium-sulfur batteries. However, the poor electronic and ionic conductivity of sulfurized polyacrylonitrile limits the high-rate and low-temperature performance of lithium-sulfur batteries. In this work, a tellurium-doped sulfurized polyacrylonitrile nanofibers-based cathode material (Te0.02S0.98FPAN) is successfully fabricated by air-blow spinning for lithium-sulfur batteries. It is found that Te0.02S0.98FPAN maintained a high reversible specific capacity of 742 mAh·g−1composites after 200 cycles at a current density of 0.2 C (0.014% decay per cycle), whereas it provides a reversible specific capacity of 641 mAh·g−1composites after 500 cycles even at a large current density of 1.0 C (0.021% decay per cycle), manifesting its excellent high-rate performance. Moreover, Te0.02S0.98FPAN still maintained a high reversible specific discharge capacity of 586 mAh·g−1composites after 100 cycles at 0.2 C at a low temperature of 5.0 °C, confirming its wide operating temperature range. Both the eutectic accelerator (tellurium) and the one-dimensional nanofibrous structure greatly improve the migration rate and electron transport ability of Li+ ions, enhancing reaction kinetics and providing fast and stable migration channels for ions and electrons. Therefore, Te0.02S0.98FPAN has a higher oxidation-reduction reaction rate and less polarization. This study not only provides new ideas for the cathode design of lithium-sulfur batteries with high rate and wide temperature range, but also paves the way for the development of practical lithium-sulfur batteries. In particular, when tested in practical conditions of high areal loading (Te0.02S0.98: 5.0 mg cm−2) and lean electrolyte (E/Te0.02S0.98: 10 μL mg−1), this cathode delivers high reversible capacities of 725 mAh g−1 composite (0.1 C) and 663 mAh g−1 composite (0.2 C), demonstrating its great potential for future application.

Non-flammable solvent-free liquid polymer electrolyte for lithium metal batteries

As a replacement for highly flammable and volatile organic liquid electrolyte, solid polymer electrolyte shows attractive practical prospect in high-energy lithium metal batteries. However, unsatisfied interface performance and ionic conductivities are two critical challenges. A common strategy involves introducing organic solvents or plasticizers, but this violates the original intention of security design. Here, an electrolyte concept called liquid polymer electrolyte without any small molecular solvents is proposed for safe and high-performance batteries, based on the design of a room-temperature liquid-state brush-like polymer as the sole solvent of lithium salts. This liquid polymer electrolyte is non-flammable and exhibits high ionic conductivity (1.09 times 10−4 S cm−1 at 25 °C), significant lithium dendrite suppression, and stable long-term cycling over a wide operating temperature range ( ≥ 1000 cycles at 60 °C and 90 °C). Moreover, the pouch cell can resist thermal abuse, vacuum environment, and mechanical abuse. This electrolyte and design strategy are expected to provide enlightening ideas for the development of safe and high-performance polymer electrolytes.