AbstractGlass windows are an important part of indoor‐to‐outdoor wireless communication channels, but the transmission loss of the normal glass limits the quality of the radio frequency (RF) signals, especially for the transverse‐electric (TE) polarized waves incident at large angles due to the impendence mismatch. Although some design methods for wide‐angle high RF transmission (WHRT) have been proposed recently, they can only work in a single frequency band. Here, an optically transparent metasurface is presented to realize high RF transmissions for dual polarizations in dual bands (2.2–3.2 and 4.4–5.2 GHz) and wide incidence angles (0–80°). The central frequencies of the two bands can be tuned independently by changing the structural parameters. A theory based on the transmission line (TL) model is proposed to explain the mechanism of the design, and a prototype is fabricated by using flexible printed circuit technology. The measured results of the prototype have good agreement with numerical calculations and full‐wave simulations. The design is expected to be beneficial to improve the quality of wireless signals in 5G systems.