The wick performance is a crucial metric for ensuring the reliable and efficient operation of vapor chambers (VCs) away from dry-out. To enhance the performance of VC, a pitcher plant inspired enhanced wick characteristic dual-height microgrooves (DHMW) was fabricated on 6063 aluminum alloy by one-step picosecond laser texturing without chemical modification. This study describes the two-step capillary behavior of DHMW by high-speed camera and infrared camera. The effects of minor rib number, groove height ratio, length scale, and test liquids (water, acetone, ethanol) on the capillary performance were investigated. When using water as the working fluid, the DHMW achieved a K/Reff of 1.182 µm, which was about 71.3 % larger than that of normal microgroove wicks due to the liquid propagation effect and the flow resistance reduction effect. Furthermore, the maximum K/Reff could reach 1.819 µm of the sample with a minor rib depth of about 70 μm. However, the wetting results showed that the droplets of acetone and ethanol tend to spread laterally after contact with the surface, which is unfavorable for the formation of hierarchical transport in the DHMW. This study demonstrates that laser texturing is an effective and controllable method for the complex shaping of grooved aluminum wicks, with the potential to improve the heat transport capability of VCs.