White LED Light Research Articles

Photodynamic inactivation of multidrug-resistant bacteria in wastewater effluent using green phytochemicals as a natural photosensitizer

The control of multidrug-resistant bacteria (MDRB) is a great challenge in the 21st century. Photodynamic treatment (PDT) is one of the promising approaches to control MDRB. In the process, powerful oxidants such as reactive oxygen species (ROS) are produced, which cause cytotoxic damage and cell death of bacteria. This study examined a new and environment-friendly strategy for the photodynamic inactivation of two MDRB (Escherichia coli and Staphylococcus aureus) and total coliform (TC) in wastewater effluent using two phytochemicals, pyrogallol (PGL) and terpinolene (TPN), along with white and blue light-emitting diode (LED) light. Fourier-transform infrared spectroscopy (FTIR) of the phytochemicals confirmed the presence of different phenolic and aromatic compounds, which can enhance the generation of ROS alongside inactivating the bacterial cells. In the PDT process, white LED light was more active in controlling MDRB than blue LED light. After 80 min irradiation with white LED light (17 mW/cm2), the MDRB bacteria were eradicated completely at a minimum inhibitory concentration (MIC) dose (0.156 mg/mL for E. coli and 0.078 mg/mL for S. aureus) of PGL. In addition, light intensity was an important parameter in photodynamic disinfection. The TC in the secondary effluent was inactivated completely by both phytochemicals after 60 min of exposure to white LED light with an intensity of 80 mW/cm2. The photosensitizing activity of phytochemicals was analyzed by a bactericidal and imidazole-RNO assay. These assays showed that PGL contributed to the generation of •OH radicals, whereas TPN produced 1O2 in the PDT process. Transmission electron microscopy (TEM) confirmed bacterial cell disruption after treatment. Overall, PDT using the phytochemicals as PS is a sustainable approach to control the MDRB and TC in wastewater successfully.

M6L12 Nanospheres with Multiple C70 Binding Sites for 1O2 Formation in Organic and Aqueous Media.

Singlet oxygen is a potent oxidant with major applications in organic synthesis and medicinal treatment. An efficient way to produce singlet oxygen is the photochemical generation by fullerenes which exhibit ideal thermal and photochemical stability. In this contribution we describe readily accessible M6L12 nanospheres with unique binding sites for fullerenes located at the windows of the nanospheres. Up to four C70 can be associated with a single nanosphere, presenting an efficient method for fullerene extraction and application. Depending on the functionality located on the outside of the sphere, they act as vehicles for 1O2 generation in organic or in aqueous media using white LED light. Excellent productivity in 1O2 generation and consecutive oxidation of 1O2 acceptors using C70⊂[Pd6L12], C60⊂[Pd6L12] or fullerene soot extract was observed. The methodological design principles allow preparation and application of highly effective multifullerene binding spheres.

LED light-induced enhanced photocatalytic hydrogen evolution on Au@TiO2 core–shell modified by nitrogen doping and reduced graphene oxide

This study focused on the large band gap of TiO2 for its use as a photocatalyst under light emitting diode (LED) light irradiation. The photocatalytic activities of core–shell structured Au@TiO2 nanoparticles (NPs), nitrogen doped Au@TiO2 NPs, and Au@TiO2/rGO nanocomposites (NCs) were investigated under various light intensities and sacrificial reagents. All the materials showed better photocatalytic activity under white LED light irradiation than under blue LED light. The N-doped core–shell structured Au@TiO2 NPs (Au@N–TiO2) and Au@TiO2/rGO NCs showed enhanced photocatalytic activity with an average H2 evolution rate of 9205 μmol h−1g−1 and 9815 μmol h−1g−1, respectively. All these materials showed an increasing rate of hydrogen evolution with increasing light intensity and catalyst loading. In addition, methanol was more suitable as a sacrificial reagent than lactic acid. The rate of hydrogen evolution increased with increasing methanol concentration up to 25% in DI water and decreased at higher concentrations. Overall, Au@TiO2 core–shell-based nanocomposites can be used as an improved photocatalyst in photocatalytic hydrogen production.

Light-Induced Anti-Bacterial Effect Against Staphylococcus aureus of Porphyrin Covalently Bonded to a Polyethylene Terephthalate Surface.

Antimicrobial photodynamic inactivation represents a promising and potentially greener alternative to conventional antimicrobials, and a solution for multidrug-resistant strains. The current study reports the development and characterization of tetra-substituted diazirine porphyrin covalently bonded to polyethylene terephthalate (PET) and its use as an antimicrobial surface. The diazirine moiety on the porphyrin was activated using a temperature of 120 °C, which initiated a C–H insertion mechanism that irreversibly functionalized the PET surface. Activation of the surface with white LED light in phosphate-buffered saline (PBS) led to singlet oxygen generation, which was detected via the degradation of 9,10-anthracenediylbis(methylene)dimalonic acid (ADMA) over time. The bactericidal effect of the 1O2-producing surface against Staphylococcus aureus was determined qualitatively and quantitatively. The growth of the pathogen beneath porphyrin-functionalized PET coupons was reduced; moreover, the PET coupons resulted in a 1.76-log reduction in cell counts after exposure to white LED light for 6 h. This is a promising material and platform for the development of safer antimicrobial surfaces, with applications in healthcare, food packaging, marine surfaces, and other surfaces in the environment.

Machine Learning to Predict Junction Temperature Based on Optical Characteristics in Solid-State Lighting Devices: A Test on WLEDs.

While junction temperature control is an indispensable part of having reliable solid-state lighting, there is no direct method to measure its quantity. Among various methods, temperature-sensitive optical parameter-based junction temperature measurement techniques have been used in practice. Researchers calibrate different spectral power distribution behaviors to a specific temperature and then use that to predict the junction temperature. White light in white LEDs is composed of blue chip emission and down-converted emission from photoluminescent particles, each with its own behavior at different temperatures. These two emissions can be combined in an unlimited number of ways to produce diverse white colors at different brightness levels. The shape of the spectral power distribution can, in essence, be compressed into a correlated color temperature (CCT). The intensity level of the spectral power distribution can be inferred from the luminous flux as it is the special weighted integration of the spectral power distribution. This paper demonstrates that knowing the color characteristics and power level provide enough information for possible regressor trainings to predict any white LED junction temperature. A database from manufacturer datasheets is utilized to develop four machine learning-based models, viz., k-Nearest Neighbor (KNN), Radius Near Neighbors (RNN), Random Forest (RF), and Extreme Gradient Booster (XGB). The models were used to predict the junction temperatures from a set of dynamic opto-thermal measurements. This study shows that machine learning algorithms can be employed as reliable novel prediction tools for junction temperature estimation, particularly where measuring equipment limitations exist, as in wafer-level probing or phosphor-coated chips.

Effect of White LED Light on the Growth of Apple Seedlings in Controlled Environment System

Plant growth in a controlled environment system is highly dependent on the availability of light. The light-emitting diode (LED) is capable of providing the needed quality and quantity of light for the plant. The purpose of this study was to determine the effect of white LED light intensity on the growth of in vitro propagated apple (M-9) seedlings in a controlled environment system. Seedlings were grown for 30 days under five different white LED light intensities: 100–500 (L1), 250–500 (L2), 500–500 (L3), 250–250 (L4), and 100–100 (L5). Our findings indicate that seedlings treated with L3 grew substantially taller than seedlings treated with L1, L2, or L5. The number of leaves, stem diameter, shoot fresh weight, root fresh weight, and shoot dry weight of L3 treated seedlings were considerably greater than those growing in other treatments. Furthermore, root length, root dry weight, chlorophyll content, and photosynthesis rate were considerably increased in the L3 treatment group compared to the L5 treatment group. However, there was no significant difference in the stomatal conductance or transpiration rate of apple seedlings between the light treatments. Moreover, a positive correlation was seen between stomatal conductance and transpiration rate. These results suggest that light intensity PPFD 500-500 were favorable for the initial growth of in vitro propagated apple seedlings.

Long-term effects of artificial nighttime lighting and trophic complexity on plant biomass and foliar carbon and nitrogen in a grassland community.

The introduction of artificial nighttime lighting due to human settlements and transport networks is increasingly altering the timing, intensity, and spectra of natural light regimes worldwide. Much of the research on the impacts of nighttime light pollution on organisms has focused on animal species. Little is known about the impacts of daylength extension due to outdoor lighting technologies on wild plant communities, despite the fact that plant growth and development are under photoperiodic control. In a five‐year field experiment, artificial ecosystems (“mesocosms”) of grassland communities both alone or in combination with invertebrate herbivores and predators were exposed to light treatments that simulated street lighting technologies (low‐pressure sodium, and light‐emitting diode [LED]‐based white lighting), at ground‐level illuminance. Most of the plant species in the mesocosms did not exhibit changes in biomass accumulation after 5 years of exposure to the light treatments. However, the white LED treatment had a significant negative effect on biomass production in the herbaceous species Lotus pedunculatus. Likewise, the interaction between the white LED treatment and the presence of herbivores significantly reduced the mean shoot/root ratio of the grass species Holcus lanatus. Artificial nighttime lighting had no effect on the foliar carbon or nitrogen in most of the grassland species. Nevertheless, the white LED treatment significantly increased the leaf nitrogen content in Lotus corniculatus in the presence of herbivores. Long‐term exposure to artificial light at night had no general effects on plant biomass responses in experimental grassland communities. However, species‐specific and negative effects of cool white LED lighting at ground‐level illuminance on biomass production and allocation in mixed plant communities are suggested by our findings. Further studies on the impacts of light pollution on biomass accumulation in plant communities are required as these effects could be mediated by different factors, including herbivory, competition, and soil nutrient availability.

Preferences of Dairy Cattle for Supplemental Light-Emitting Diode Lighting in the Resting Area.

Simple SummaryThe effects of light exposure on dairy cattle milk production are well known, whereas aspects of light quality and potential benefits on dairy production and health are currently undetermined. We developed a supplemental lighting system (i.e., in addition to existing natural and artificial light in the facility) to provide light to cows while lying down. This study assessed dairy cow preferences for three colours of light-emitting diode lighting in the free-stall area. Cows did not prefer lying down under any of the light-emitting diode light options provided. Our results suggest that short-term use of supplemental light-emitting diode lighting in the stall area was not avoided by cows and lays the groundwork to study various aspects of light-emitting diode light, including the quality (wavelength), intensity, and duration of exposure.Light from the environment is important for vision and regulating various biological processes. Providing supplemental lighting in the stall area could allow for individually targeted or group-level control of light. This study aimed to determine whether dairy cattle had preferences for short-term exposure to white (full-spectrum) light-emitting diode (LED) light or no LED light, yellow-green or white LED light, and blue or white LED light in the stall area. In total, 14 lactating cows were housed in a free-stall pen with unrestricted access to 28 stalls. LED light was controlled separately for each side of the stall platform. Two combinations of light were tested per week, and each week consisted of three adaptation days and four treatment days. Lying behaviour and video data were recorded continuously using leg-mounted pedometers and cameras, respectively. Preference was assessed by the amount of time spent lying and the number of bouts under each light treatment. No differences occurred between treatments within each week for daily lying time and number of bouts. Similarly, no differences occurred between treatments within each time period. Further controlled studies of long-term exposure to different LED wavelengths and intensities are required to determine potential benefits on metabolic processes.

Effect of Use of Different Light Spectrum on Growth Performance and Color Brightness Level of Tiger Barb (Puntius tetrazona)

This study aims to evaluate the effect of light spectrum on growth performance and brightness level of tiger barb (Puntius tetrazona). The research was conducted in January – March 2022 at the Laboratory of Aquatic Animal Physiology, Faculty of Fisheries and Marine Sciences, Padjadjaran University. This study used an experimental method of Completely Randomized Design (CRD) with five treatments and three replications. The treatment consisted of five treatments, namely control (without LED lights), white LED lights (B), red (C), green (D) and blue (E) lights with 12 hours of irradiation. The treatment was given for 60 days. Parameters observed included growth in length and absolute weight, color brightness level, survival rate and water quality (temperature, pH and DO). The results of the study for 60 days of maintenance showed that the best growth parameter was the red LED light treatment with an absolute length growth of 0.57 cm and an absolute weight growth of 0.49 g. The best color quality parameter for tiger barb (Puntius tetrazona) was obtained in the red LED light treatment with an increase in the color score in the Toca color finder (TCF) reaching 1.7 on the body; 2,3 on the pectoral fins; and 2.4 on the tail. The water quality parameter values are in normal conditions (temperature ranges from 27.3-27.9 ◦C; DO ranges from 4.2-5 mg/l; and pH ranges from 6.97-7.65;) so that it is good for the survival rate of tiger barb, namely 100%.

Adding UVA and Far-Red Light to White LED Affects Growth, Morphology, and Phytochemicals of Indoor-Grown Microgreens

White light emitting diodes (LED) have commonly been used as a sole light source for the indoor production of microgreens. However, the response of microgreens to the inclusion of ultraviolet A (UVA) and/or far-red (FR) light to white LED light remains unknown. To investigate the effects of adding UVA and FR light to white LEDs on plant biomass, height, and the concentrations of phytochemicals, four species of microgreens including basil, cabbage, kale, and kohlrabi were grown under six light treatments. The first three treatments were white LED (control) and two UVA treatments (adding UVA to white LED for the whole growth period or for the last 5 days). Another three treatments consisted of adding FR to the first three treatments. The total photon flux density (TPFD) for all six light treatments was the same. The percentages of UVA and FR photons in the TPFD were 23% and 32%, respectively. Compared to white LEDs, adding UVA throughout the growth period did not affect plant height in all the species except for basil, where 9% reduction was observed regardless of the FR light. On the contrary, the addition of FR light increased plant heights by 9–18% for basil, cabbage, and kohlrabi, regardless of the UVA treatment, compared to white LED. Furthermore, regardless of UVA, adding FR to white LEDs reduced the plant biomass, total phenolic contents, and antioxidant concentrations for at least one species. There was no interaction between FR and UVA on all the above growth and quality traits for all the species. In summary, microgreens were more sensitive to the addition of FR light compared to UVA; however, the addition of FR to white LEDs may reduce yields and phytochemicals in some species.

Strain release of formamidinium-cesium perovskite with imprint-assisted organic ammonium halide compensation for efficient and stable solar cells

Residual lattice strain in halide perovskites has been recognized as a key factor that affects device efficiency and stability of perovskite solar cells (PSCs). Here, we reveal that the escape of organic ammonium halide and their inhomogeneous distribution after thermal annealing could cause severe residual strain in intrinsic thermal stable formamidinium-cesium (FACs) perovskite films. Thus, we develop an imprint-assisted organic ammonium halide compensation strategy for residual lattice strain relaxation. We demonstrate the residual lattice strain is well-released after post-treatment, along with further perovskite grain growth/coalescence, crystallinity improvement, and defect repair. As a result, the strain-free PSCs with nickel oxide based inverted architecture exhibit a power conversion efficiency as high as 21.30% and the corresponding encapsulated devices retain 98% of their initial efficiencies at 45 °C under 1-sun equivalent white-light light-emitting diode array illumination with maximum power point tracking in the ambient environment for 1000 h.

Enhancing the Microstructure of Perovskite‐Inspired Cu‐Ag‐Bi‐I Absorber for Efficient Indoor Photovoltaics

Lead-free perovskite-inspired materials (PIMs) are gaining attention in optoelectronics due to their low toxicity and inherent air stability. Their wide bandgaps (≈2eV) make them ideal for indoor light harvesting. However, the investigation of PIMs for indoor photovoltaics (IPVs) is still in its infancy. Herein, the IPV potential of a quaternary PIM, Cu2 AgBiI6 (CABI), is demonstrated upon controlling the film crystallization dynamics via additive engineering. The addition of 1.5vol% hydroiodic acid (HI) leads to films with improved surface coverage and large crystalline domains. The morphologically-enhanced CABI+HI absorber leads to photovoltaic cells with a power conversion efficiency of 1.3% under 1 sun illumination-the highest efficiency ever reported for CABI cells and of 4.7% under indoor white light-emitting diode lighting-that is, within the same range of commercial IPVs. This work highlights the great potential of CABI for IPVs and paves the way for future performance improvements through effective passivation strategies.

Effect of Photoblastism on Rice Morphogenesis and Seedling Development

The effect of continuous light and complete dark period on seed germination to first leaf emergence was examined in BRRIdhan71 and BRRIdhan81 in controlled environment at 22 ± 2 ᵒC and 82± 2 % of relative humidity, with or without supplemental LED white light. In the dark, BRRIdhan71 had a germination rate of 97 percent and BRRIdhan81 had a germination rate of 57 percent. Germination was 92 percent in BRRIdhan81 and 77 percent in BRRIdhan71 under photoblastic conditions (Light). The dark and light treatments had a noticeable impact on the percentage of seeds that germinated. Coleoptile was longer in dark than light in BRRIdhan71. In both rice varieties, the light and dark treatments had little effect on the first leaf length, although the first leaf breadth increased noticeably in BRRIdhan81. The growth condition had an impact on root length, seedling fresh weight, and dry weight. Germination percent, coleoptile length, prophyll length, first leaf length, and root length all decreased in BRRIdhan71, whereas germination percent, first leaf length, first leaf breadth, seedling freash, and dry weight all increased significantly in BRRIdhan81.The findings imply that BRRIdhan71 and BRRIdhan81, in particular, responded to photoblastic treatment and predominantly possess photoblastic biocomponents in seed, which affect germination and subsequent growth phases. Rice seed during germinate in the field will light stress if photoblastism is not considered during the development and release of rice varieties for different seasons, such as Aman and Boro, because light affects seeding photomorphogenesis differently in different growth environments.
 Environ. Sci. & Natural Resources, 13(1&2): 43-49, 2020

A Novel Preparation of Special-Shaped Phosphors-in-Glass by Gel Casting with Isobam for High-Power WLEDs Lighting.

Phosphors-in-glass (PiGs) regarded as a promising phosphor-converter for white light emitting diodes (WLEDs) is being researched widely. However, there are few reports on the effect of changing the shape of PiGs on the color rendering index (CRI) and heat dissipation of WLEDs. In this paper, gel casting with Isobam was first attempted in preparing special-shaped PiGs successfully. It exhibited that 76 wt.% was the optimum solid content based on the rheological properties of slurry and the shrinkage of green bodies. The sintering rate should be kept at a low speed and glass transition temperature (Tg) of glass powders must be higher than sublimation temperatures (Ts) of APS and Isobam. The CRI of PiGs was increased by about 27% after changing the shape of PiGs from cylinder to dome. Most importantly, operating temperature also reduced effectively the increase of the surface area of PiGs. Therefore, changing the shape of PiGs by gel casting with Isobam is a creative way for high-power WLEDs lighting.

Charge effect of water-soluble porphyrin derivatives as a prototype to fight infections caused by Acinetobacter baumannii by aPDT approaches

In the last decade, Acinetobacter baumannii has emerged as a pathogen associated with infections in intensive care units worldwide, especially due to its ability to resist an extensive list of antibiotics. In this context, porphyrins have emerged as an important strategy in photodynamic therapy, since they are a group of tetrapyrrolic compounds with important photochemical and photobiological activities. In this study, the antimicrobial photodynamic activity of meso-tetra(4-N-methyl-pyridyl)porphyrin (H2TMePyP+ ) and meso-tetra(4-sulfonatophenyl)porphyrin (H2TPPS‒ ) was evaluated against A. baumannii by minimum inhibitory concentration (MIC), anti-biofilm activity, and the interaction with antibiotics after exposure to white-light LED irradiation. The cationic derivative H2TMePyP+ was more potent (MIC = 0.61 µM) than H2TPPS‒ , with anti-biofilm activity and increased the antimicrobial activity of ciprofloxacin and amikacin. Given these findings, the tetra-cationic porphyrins can be assumed as prototypes to optimize and develop new agents by promoting oxidative stress and inducing free radical production.

Multicolor Phosphate Glasses for Potential White LED Lighting and X‐Ray Detections

AbstractThough widely applied in light‐emitting diode (LED) lighting and X‐ray detection, respectively, rare‐earth ions doped phosphor and scintillating single crystals still face many challenges in practicalities, like aging of package material and difficulty to construct tiny array structure. Using phosphate glass as the host is quite beneficial for solving these problems while enabling distinguished luminescence. Therefore, Eu3+ and Tb3+ doped phosphate glasses which, respectively, show strong red/green emissions are researched. Superior thermal stabilities (78.69% and 89.35% emission intensities remain at 150 °C) and high internal quantum efficiencies (87.3% and 68.6%) are found to guarantee the excellent photoluminescence performances. The brilliant X‐ray excited luminescence properties are demonstrated by general 19.49% and 34.74% integrated emission intensities of that of commercial Bi4Ge3O12 single crystal scintillator with the change of X‐ray power. Meanwhile, Tb3+ doped scintillating fiber is drawn. Finally, excited by 380 nm LED, color manipulation and white light generation are achieved in LEDs with a structure of stacked emitting layers (mainly Eu3+ and Tb3+ doped phosphate glasses). Many of the as‐constructed white LED's performance parameters are much better than the commercial white LED. These results show that Eu3+ and Tb3+ doped phosphate glasses possess promising potential in LED lighting and X‐ray detections.

Environmental-friendly lead-free chiral Mn-based metal halides with efficient circularly polarized photoluminescence at room temperature

In recent years, chiral organic-inorganic hybrid metal halides have attracted more and more attention from researchers. However, most chiral metal halides are based on toxic Pb elements. In this work, we first successfully prepared a pair of lead-free manganese-based metal halide enantiomers (R/S-1-PPA) 2 MnBr 4 (R/S-1-PPA=R/S-1-Phenylpropan-1-amine). Under the excitation of 365 nm UV light, (R/S-1-PPA) 2 MnBr 4 exhibited bright green emission, which can be attributed to the spin-forbidden d-d transition of Mn 2+ . In addition, the decay lifetimes were as high as 32.57 μs and 33.60 μs for (R-1-PPA) 2 MnBr 4 and (S-1-PPA) 2 MnBr 4 , respectively. (R/S-1-PPA) 2 MnBr 4 showed notable circular dichroism (CD) signals and displayed highly efficient circularly polarized photoluminescence (CPPL) at room temperature with the large g lum of − 0.01 and 0.008, respectively. The high g lum enables them to be a series of very promising materials for the development of chiral optoelectronic devices based on chiral hybrid metal halides. Finally, the white LED device constructed with (R-1-PPA) 2 MnBr 4 also showed a wide color gamut, as high as 107% of NTSC, and a "warm" white light-correlated color temperature of 6883 K, which indicated it has good competitiveness in the application of white light LED devices. • We synthesized a pair of Pb-free Mn-based chiral metal halides (R/S-1-PPA) 2 MnBr 4 . • The halides emitted green CPPL, with g lum of − 0.01 and 0.008 at room temperature. • The g lum represent the maximum of the reported Mn-based metal halides.

Performance Assessment of Smart Dynamic Controller for Variable CCT White LED Light Source - A SVM Based Approach

Performance Assessment of Smart Dynamic Controller for Variable CCT White LED Light Source - A SVM Based Approach

Influence of Different Light-Emitting Diode Colors on Growth and Phycobiliprotein Generation of Arthrospira platensis.

Light-emitting diodes (LED) can be utilized as tailorable artificial light sources for the cultivation of cyanobacteria such as Arthrospira platensis (AP). To study the influence of different LED light colors on phototrophic growth and biomass composition, AP was cultured in closed bioreactors and exposed to red, green, blue, or white LED lights. The illumination with red LED light resulted in the highest cell growth and highest cell densities compared to all other light sources (order of cell densities: red > white > green > blue LED light). In contrast, the highest phycocyanin concentrations were found when AP was cultured under blue LED light (e.g., order of concentrations: blue > white > red > green LED light). LED-blue light stimulated the accumulation of nitrogen compounds in the form of phycobiliproteins at the expense of cell growth. The results of the study revealed that exposure to different LED light colors can improve the quality and quantity of the biomass gained in AP cultures.

Nonstoichiometric LaO0.65F1.7 Structure and Its Green Luminescence Property Doped with Bi3+ and Tb3+ Ions for Applying White UV LEDs.

Red–green–blue phosphors excited by ultraviolet (UV) radiation for white light LEDs have received much attention to improve the efficiency, color rendering index (CRI), and chromatic stability. The spectral conversion of a rare-earth ion-doped nonstoichiometric LaO0.65F1.7 host was explored with structural analysis in this report. The nonstoichiometric structure of a LaO0.65F1.7 compound, synthesized by a solid-state reaction using La2O3 and excess NH4F precursors, was analyzed by synchrotron X-ray powder diffraction. The crystallized LaO0.65F1.7 host, which had a tetragonal space group of P4/nmm, contained 9- and 10-coordinated La3+ sites. Optical materials composed of La1−p−qBipTbqO0.65F1.7 (p = 0 and 0.01; q = 0–0.2) were prepared at 1050 °C for 2 h, and the single phase of the obtained phosphors was indexed by X-ray diffraction analysis. The photoluminescence spectra of the energy transfer from Bi3+ to Tb3+ were obtained upon excitation at 286 nm in the nonstoichiometric host lattice. The desired Commission Internationale de l’Eclairage (CIE) values of the phosphors were calculated. The intense green La0.89Bi0.01Tb0.1O0.65F1.7 phosphor with blue and red optical materials was fabricated on a 275 nm UV-LED chip, resulting in white light, and the internal quantum efficiency, CRI, correlated color temperature, and CIE of the pc LED were characterized.