Context. The latest Gaia data release in July 2022, DR3, in addition to the refinement of the astrometric and photometric parameters from DR2, added a number of important data products to those available in earlier releases, including radial velocity data, information on stellar multiplicity, and XP spectra of a selected sample of stars. Gaia has proved to be an important search tool for white dwarf stars, which are readily identifiable from their absolute G magnitudes as low luminosity objects in the Hertzsprung–Russell (H–R) diagram. Each data release has yielded large catalogs of white dwarfs, containing several hundred thousand objects, far in excess of the numbers known from all previous surveys (∼40 000). While the normal Gaia photometry (G, GBP, and GRP bands) and astrometry can be used to identify white dwarfs with high confidence, it is much more difficult to parameterize the stars and determine the white dwarf spectral type from this information alone. Observing all stars in these catalogs with follow-up spectroscopy and photometry is also a huge logistical challenge with current facilities. Aims. The availability of the XP spectra and synthetic photometry presents an opportunity for a more detailed spectral classification and measurement of the effective temperature and surface gravity of Gaia white dwarfs. Methods. A magnitude limit of G < 17.6 was applied to the routine production of XP spectra for Gaia sources, which would have excluded most white dwarfs. Therefore, we created a catalog of 100 000 high-quality white dwarf identifications for which XP spectra were processed, with a magnitude limit of G < 20.5. Synthetic photometry was computed for all these stars, from the XP spectra, in Johnson, SDSS, and J-PAS, published as the Gaia Synthetic Photometry Catalog – White Dwarfs (GSPC-WD). We took this catalog and applied machine learning techniques to provide a classification of all the stars from the XP spectra. We have then applied an automated spectral fitting program, with χ-squared minimization, to measure their physical parameters (effective temperature and log g) from which we could estimate the white dwarf masses and radii. Results. We present the results of this work, demonstrating the power of being able to classify and parameterize such a large sample of ≈100 000 stars. We describe what we can learn about the white dwarf population from this dataset. We also explored the uncertainties in the process and the limitations of the dataset.