Properties Of Wheat Starch Research Articles

The effects of D-allulose on the gelatinization and gelling properties of wheat starch

D-Allulose, with its low calorie content and sweetness comparable to sucrose, has gained significant attention from researchers as an ideal substitute for sucrose. Here, we investigated the effects of D-allulose on the physicochemical properties and texture of wheat starch. The gelatinization results showed that D-allulose (D-allulose: wheat starch = 1:1 w/w) increased the pasting temperature (56.4 to 65.2 °C) and transition enthalpy (7.9 to 9.0 J/g) of wheat starch systems, and the impact was significantly lower than that of other commonly used small-molecule sugars (sucrose, fructose, glucose). In addition, rheological, texture, and X-ray diffraction analyses confirmed that the addition of D-allulose improved the hardness, gumminess, and recrystallization of retrograded wheat starch gels. Microstructure analysis indicated that the addition of D-allulose enhanced the structural density of wheat starch system, thereby significantly slowing down the retrogradation of wheat starch. D-allulose exhibited unique properties, promoting the gelatinization of wheat starch and delaying its retrogradation. These results will help to promote the wide application of D-allulose in starchy foods with special physiological functions.

Effect of Ethanol Extract of Tea on the Physicochemical, Retrogradation Characteristics, and Digestion Properties of Wheat Starch

AbstractThe effects of ethanol extract of tea (EET) on the physicochemical properties, microstructure, and digestibility of wheat starch (WS) are investigated. Aging degree, solubility, swelling degree, Springness of gel, thermodynamic properties, X‐ray diffraction, infrared spectroscopy, Scanning electron microscopy (SEM), and digestibility of WS by adding different ratios of EET are analyzed. The changes of EET on WS‐related properties are evaluated comprehensively. The results show that the addition of EET reduces the enthalpy of recovery and inhibits the recovery of WS. At the same time, XRD diffraction shows that the addition of EET reduces the crystallinity of WS. At the same time, the addition of EET also decreases the content of rapidly digestible starch (RDS) in WS and increases the content of slowly digestible starch (SDS) and resistant starch (RS). In conclusion, EET can inhibit the retrogression of WS and can also be used as a potential source of RS additives.

The Influence of Yeast Inoculated on the Structural and Physicochemical Properties of Wheat Starch during Ganmianpi Fermentation

AbstractGanmianpi is a traditional snack in China that has traditionally been produced through natural fermentation of wheat starch slurry. However, natural fermentation occurs spontaneously and lacks control, thereby an alternative yeast‐inoculated fermentation method is proposed for the industrialization of Ganmianpi production. This study aims to investigate the impact of yeast‐inoculated fermentation on the structural and physicochemical properties of wheat starch and elucidate the underlying mechanism. The findings reveal that yeast fermentation significantly affects the properties of wheat starch, varying with the fermentation time. Yeast‐inoculated fermentation leads to surface erosion of the starch granules and a significant reduction in amylose content, double helicity, gelatinization enthalpy, and relative crystallinity of wheat starch. Specially, yeast‐inoculated fermentation alters starch chain proportions, with a decrease in chain A and an increase in chains B1, B2, and B3. Ganmianpi produced from wheat starch exhibits decreased hardness, springiness, and chewiness, and sensory evaluation suggests an optimal fermentation time of 18 h for Ganmianpi production. Overall, this study provides valuable theoretical support for the industrial production of Ganmianpi and promotes the standardized production of fermented starch‐based foods.

Integrative experimental and computational analysis of the impact of KGM's polymerization degree on wheat starch's pasting and retrogradation characteristics

This study investigated the influence of Konjac Glucomannan (KGM) with varying degrees of polymerization (DKGMx) on the gelatinization and retrogradation characteristics of wheat starch, providing new insights into starch-polysaccharide interactions. This research uniquely focuses on the effects of DKGMx, utilizing multidisciplinary approaches including Rapid Visco Analysis (RVA), Differential Scanning Calorimetry (DSC), rheological testing, Low-Field Nuclear Magnetic Resonance (LF-NMR), and molecular simulations to assess the effects of DKGMx on gelatinization temperature, viscosity, structural changes post-retrogradation, and molecular interactions. Our findings revealed that higher degrees of polymerization (DP) of DKGMx significantly enhanced starch's pasting viscosity and stability, whereas lower DP reduced viscosity and interfered with retrogradation. High DP DKGMx promoted retrogradation by modifying moisture distribution. Molecular simulations revealed the interplay between low DP DKGMx and starch molecules. These interactions, characterized by increased hydrogen bonds and tighter binding to more starch chains, inhibited starch molecular rearrangement. Specifically, low DP DKGMx established a dense hydrogen bond network with starch, significantly restricting molecular mobility and rearrangement. This study provides new insights into the role of the DP of DKGMx in modulating wheat starch's properties, offering valuable implications for the functional improvement of starch-based foods and advancing starch science.

Effects of deamidated gluten protein on wheat starch properties and rheological properties of starch-gluten dough

To further investigate the interaction between starch and gluten protein, deamidated gluten protein with varying degrees of organic acid (citric acid) was mixed with wheat starch in various proportions, and the solubility, pasting, and rheological properties of the blend flour were investigated. The solubility of the sample powder increased significantly as the deamidated protein content increased. The gelatinization results also demonstrated that the deamidated protein content increased the peak viscosity, trough viscosity gradually decreased, and peak viscosity time shortened. The results of the rheological measurement revealed that the elastic modulus (G′), viscous modulus (G″), and creep recovery of the mixed flour showed regular changes with the continuous change of the mixed powder proportion. Furthermore, consistent alterations were observed in the effects of proteins with varying degrees of deamidation in the same proportion on farinaceous characteristics. FTIR analysis of the gluten protein revealed that the primary secondary structures were the β-sheet and β-turn; different levels of damage were observed.

Analysis of the impact of drying on common wheat quality and safety

Mycotoxin contamination in grain has been an ongoing concern in the world. Wheat, as a staple crop in China, is particularly notable for its mycotoxin contamination. The main mycotoxins in wheat include deoxynivalenol (DON) and its derivates, zearalenone (ZEN) and aflatoxin B1 (AFB1). After harvest, drying process is an effective technique and a necessary step to ensure the long-term safe storage of wheat. In this study, the moisture content, the concentrations of total fungi and main mycotoxins in post-harvest wheat of three wheat growing areas in the North China Plain were examined, and the effect of different drying methods on wheat quality was evaluated. The results showed that 87.5% of wheat samples were simultaneously contaminated with two or more mycotoxins. Due to the pre-harvest heavy rainfall, the moisture content, the levels of total fungi and mycotoxins in wheat samples of Liaocheng city were significantly higher compared to other regions. Moreover, the effects of different drying methods on the starch gelatinization and viscosity properties of wheat were investigated. The results showed that both natural air drying and dryer drying altered the crystal structure within starch particles and affected the gelatinization and viscosity properties of wheat starch. However, there is no significant difference between the wheat samples treated with two drying methods.

Effect of dielectric barrier discharge (DBD) plasma treatment on physicochemical and 3D printing properties of wheat starch

In recent years, the focus has shifted towards carbohydrate-based hydrogels and their eco-friendly preparation methods. This study involved an investigation into the treatment of wheat starch using dielectric barrier discharge (DBD) plasma technology over varying time gradients (0, 2, 5, 10, 15, and 20 min). The objective was to systematically examine the impact of different treatment durations on the physicochemical properties of wheat starch and the suitability of its gels for 3D printing. Morphology of wheat starch remained intact after DBD treatment. However, it led to a reduction in the amylose content, molecular weight, and crystallinity. This subsequently resulted in a decrease in the pasting temperature and viscosity. Moreover, the gels of the DBD-treated starch exhibited superior 3D printing performance. After a 2-min DBD treatment, the 3D printed samples of the wheat starch gel showed no significant improvements, as broken bars were evident on the surface of the 3D printed graphic, whereas DBD-20 showed better printing accuracy and surface structure, compared to the original starch without slumping. These results suggested that DBD technology holds potential for developing new starch-based gels with impressive 3D printing properties.

Effect of atmospheric pressure plasma jet on the structure and physicochemical properties of wheat starch.

The effect of atmospheric pressure plasma jet (APPJ) with different discharge power (0, 400, 600, and 800 W) on the structure and physicochemical properties of wheat starch were evaluated in this study. After APPJ treatments, significant declines in peak viscosity, breakdown viscosity, and final viscosity of wheat starch pasting parameters were observed with increase of plasma treatment power. Being treated with discharge power of 800 W, the PV and BD value of wheat starch paste significantly dropped to 2,578 and 331 cP, respectively. Apparently, APPJ could raise the solubility of wheat starch, while reduce the swelling capacity, and also lower the G' and G″ value of wheat starch gel. Roughness and apparent scratch was observed on the surface of the treated wheat starch granules. Although APPJ treatment did not alter wheat starch's crystallization type, it abated the relative crystallinity. APPJ treatment might be useful in producing modified wheat starch with lower viscosity and higher solubility.

Changes in the pasting and rheological properties of wheat, corn, water caltrop and lotus rhizome starches by the addition of Annona montana mucilage

Annona montana mucilage (AMM) is a novel mucilage with unique but limited information. This study investigated the effects of AMM addition on the pasting and rheological properties of wheat starch (WS), corn starch (CS), water caltrop starch (WCS), and lotus rhizome starch (LRS). The addition of AMM generally increased the pasting temperature and peak viscosity, but reduced the setback value of all starches to varying degrees, and the initiation of viscosity-increase for cereal starch/AMM systems during pasting occurred at lower temperatures, accompanied with a distinctive two-stage swelling process as well as lower peak and final hot paste viscosity at 50 °C. AMM significantly increased the pseudoplasticity and entanglement of the systems to varying degrees (LRS > WS > WCS > CS). Under a constant shear rate of 50 s−1, the consistency level was found to fall in honey-like for cereal starch/AMM groups, and honey-like to extremely thick levels for WCS and LRS/AMM groups. Except for the WCS/AMM systems, the storage and loss modulus as well as tanδ increased with increasing AMM concentration. Short-term retrogradation of starch at 4 °C was pronouncedly retarded by the addition of AMM for WS, CS and WCS groups, but was less affected for LRS group.

Effects of the Ethanolic Extract of Onion Peel on the Physicochemical Properties of Wheat Starch

AbstractThe objective of this study is to examine the interactions between wheat starch (WS) and ethanol extract of onion peel (EEOP) at varying concentrations (1.0%, 2.5%, 5.0%, and 10.0%) during the process of gelatinization, and to assess the impact of these interactions on the physicochemical and retrogradation characteristics of wheat starch. In contrast to the control group, the incorporation of EEOP results in a reduction in retrogradation, an increase in solubility, and an increase in the swelling degree of wheat starch. Furthermore, the addition of the EEOP effectively hinders the retrogradation process of wheat starch. The incorporation of EEOP has the potential to decrease the enthalpy associated with starch retrogradation. Accordingly, the addition of 10% EEOP results in a decrease of 43.6% in the enthalpy of starch retrogradation in wheat starch after a storage period of 15 days, as compared to the control group. In addition, the incorporation of an enzyme known as EEOP has the potential to reduce the occurrence of crystallization in the process of starch retrogradation. Hence, the incorporation of EEOP may impede the regression of WS.

Effect of fibers on starch structural changes during hydrothermal treatment: multiscale analyses, and evaluation of dilution effects on starch digestibility.

Dietary fibers (DFs) may influence the structural, nutritional and techno-functional properties of starch within food systems. Moreover, DFs have favorable effects on the digestive system and potentially a lower glycemic index. These potential benefits may change depending on DF type. Starch processed in the presence of soluble and insoluble fibers can undergo different structural and functional changes, and the present study investigated the effects of short-chain and long-chain inulin and cellulose on the structural and digestive properties of wheat starch. The combined use of differential scanning calorimetry, Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) provided insights into the structural changes in starch and inulin at different levels. Short-chain and long-chain inulin had higher water retention capacity and a potential to limit starch gelatinization. The FTIR results revealed an interaction between starch and inulin. Scanning electron microscopy analysis showed morphological changes in starch and inulin after the hydrothermal treatment. Cellulose fiber was not affected by the hydrothermal treatment and had no influence on starch behavior. The structural differences observed through XRD, FTIR and scanning electron microscopy analyses between starch with and without inulin fibers did not significantly impact starch digestibility, except for the dilution effect caused by adding DFs. The present study highlights the importance of utilizing different analytical tools to assess changes in food samples at different scales. Although short-chain and long-chain inulin could potentially limit starch gelatinization, the duration of the heat treatment (90 °C for 10 min) was sufficient to ensure complete starch gelatinization. The dilution effect caused by adding fibers was the primary reason for the effect on starch digestibility. © 2024 The Authors. Journal of The Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.

Structural characteristics and paste properties of wheat starch in natural fermentation during traditional Chinese Mianpi processing

Fermentation plays a crucial role in traditional Chinese mianpi processing, where short-term natural fermentation (within 24 h) is considered advantageous for mianpi production. However, the influence of short-term natural fermentation on the properties of wheat starch is not explored yet. Hence, structural characteristics and paste properties of wheat starch during natural fermentation were investigated in this study. The findings revealed that fermenting for 24 h had a slight effect on the morphology of wheat starch but significantly decreased the particle size of starch. Compared to native wheat starch, the enzyme activity produced during fermentation may destroy the integrity of starch granules, resulting in a lower molecular weight but higher relative crystallinity and orderliness of starch. After 24 h of natural fermentation, higher solubility and swelling power were obtained compared to non-fermentation. Regarding paste properties, fermented starches exhibited higher peak viscosity and breakdown, along with lower final viscosity, tough viscosity, and setback. Furthermore, the hardness, gel strength, G', and G" decreased after fermentation. Clarifying changes in starch during the short-term natural fermentation process could provide theoretical guidance for improving the quality and production of short-term naturally fermented foods such as mianpi, as discussed in this study.

Physicochemical properties, structural properties and gels 3D printing properties of wheat starch

The relationships between the physicochemical properties of wheat starch and the characteristics of 3D printing were studied by extracting wheat starch from three kinds of wheat flour with different gluten contents. The results showed that wheat starch extracted from high-gluten wheat flour (MS) and medium-gluten wheat flour (ZS) exhibited more accurate printing and better quality than wheat starch extracted from low-gluten wheat flour (JS). ZS had moderate final viscosity and setback value, indicating good extrusion performance and high elasticity. Therefore, the printing quality of ZS was the best, with obvious and unbroken printing lines. The 3D-printed sample made from ZS had dimensions closest to the designed CAD model. Additionally, there were no significant differences in the functional groups of native starch, gelatinized starch, and post-3D-printed starch among the three types. ZS exhibited the most regular microstructure. Therefore, wheat starch extracted from medium-gluten wheat flour was determined to be the most suitable for 3D printing. This research could provide a new theoretical basis for the application of wheat starch in 3D-printed food and offer new technical support for practical production.

Effect of Bletilla Striata Polysaccharide on the Pasting, Rheological and Adhesive Properties of Wheat Starch.

A combination of starch and hydrocolloids is a facile method for physically modifying native starch. Bletilla striata polysaccharide (BSP) is a glucomannan with various applications in the food and cosmetic industries as a thickening agent. This study focused on investigating the impact of BSP on the pasting, rheological and adhesive properties of wheat starch (WS). Results from a Rapid Visco-Analyzer (RVA) revealed that the addition of BSP (below 0.2%) resulted in increases in peak viscosity, breakdown and setback values. However, for the addition of BSP at a higher concentration (0.3%), the opposite trend was observed. Rheological measurements indicated that the presence of BSP increased the viscoelastic properties of WS-BSP gels. TGA results demonstrated that the presence of BSP promoted the thermal stability of starch. FTIR results indicated the short-range order structure decreased at low addition concentrations of BSP (0.05% and 0.1%) and increased with higher BSP addition concentrations (0.2% and 0.3%). SEM observation showed that the BSP improved the hydrophilic property of starch gels and decreased the size of pores in the starch gels. Further, the mechanical properties of paper samples unveiled that the present of BSP in starch gels obviously increased its bonding strength as an adhesive.

Retrogradation inhibition of wheat starch with wheat oligopeptides.

Starch staling greatly reduces the cereal products quality, and the staling retardation becomes a focus in current research. The effect of wheat oligopeptide (WOP) on anti-staling properties of wheat starch (WS) was studied. Rheology property indicated that WOP reduced WS viscosity, showing more liquid-like behavior. WOP improved the water holding capacity, inhibited swelling power, and reduced the hardness of WS gels, which decreased from 1200 gf to 800 gf compared with the control after 30days storage. Meanwhile, the water migration of WS gels were also reduced with WOP incorporation. The relative crystallinity of WS gel with 1% WOP was reduced by 13.3%, and the pore size and the microstructure of gels was improved with WOP. Besides, the short-range order degree reached the lowest value with 1% WOP. In conclusion, this study explained the interaction between WOP and WS, which was beneficial to the application of WOP in WS-based food.

Effects of sugar beet pectin on the pasting, rheological, thermal, and microstructural properties of wheat starch

The effects of addition of sugar beet pectin (SBP) on the pasting, rheological, thermal, and microstructural properties of wheat starch (WS) were investigated. Results revealed that SBP addition significantly increased the peak viscosity, trough viscosity, breakdown value, final viscosity, and setback value of WS, whereas decreased the pasting temperature. SBP raised the swelling power (from 13.44 to 21.32 g/g) and endothermic enthalpy (ΔH, from 8.17 to 8.98 J/g), but decreased the transparency (from 9.70 % to 1.37 %). Regarding rheological properties, WS-SBP mixtures exhibited a pseudo-plastic behavior, and SBP enhanced the viscoelasticity, but decreased the deformability. Particle size distribution analysis confirmed that SBP promoted the swelling of WS granules. Fourier-transform infrared spectroscopy results suggested that the interactions between SBP and WS did not involve covalent bonding, and the formation of ordered structure was inhibited by SBP addition. Additionally, scanning electron microscopy observation found that the gel network of WS-SBP mixtures became more irregular, pore size gradually decreased, and the wall became thinner as the SBP concentration increased. These results indicated that SBP is a promising non-starch polysaccharide that can enhance the processing properties of WS.

Superheated steam treatment of soft wheat on the physicochemical properties and structure of wheat starch

AbstractSoft wheat grains were treated with superheated steam (SS) at 165 and 190°C, respectively for 1–5 min to understand the changes in the structures and properties of wheat starch following SS treatment. The damaged starch contents, amylose ratio, gelatinization properties, surface morphology, viscosity, and crystalline structure of the starch in wheat flour were determined. Damaged starch content, amylose ratio, and starch viscosity significantly increased after SS treatment. The onset temperature (To) and peak temperature (Tp) of wheat starch increased with the extending of treatment time, while an opposite variation trend was observed for (Tc − To). Additionally, the gelatinization enthalpy (ΔH) decreased after 3–5 min of SS treatment. Starch aggregation was observed in scanning electron microscopy (SEM) graphs. Compared to traditional heat treatment methods, SS treatment of wheat grains may be preferable for modifying the starch properties of soft wheat since much time and energy could be saved.Practical ApplicationThe physicochemical properties and structure of soft wheat starch significantly affect the quality of cakes made with soft wheat flour. After SS treatment of wheat kernels, the amylose ratio and damaged starch content in wheat starch significantly increased. Moreover, gelatinization properties and starch viscosity of wheat starch were also significantly affected. The changes in physicochemical properties were mainly due to the changes in the structure of starch granules and starch molecules. The above results in the physicochemical properties and structure of starch led to the increase in the viscosity and gas retention capacity of cake batter, which might be the reason why the specific volumes and texture of cakes could be improved after SS treatment of wheat. This research verified SS treatment may be preferable for improving cake quality compared to traditional heat treatment methods, which promotes the application of SS in wheat process engineering.

Starch Fine Molecular Structure Is the Driving Factor for Starch Gelatinization Property in Both Wheat Flour and Wheat Dough

AbstractThe thermal properties of dough are critical for eating and processing quality of wheat flour‐based products. Although the gelatinization properties of wheat starch or flour as affected by starch molecular structures have been investigated, it remains largely unexplored how starch structures determine the gelatinization properties of wheat dough. The gelatinization properties of 10 wheat flours and corresponding doughs with distinct starch fine molecular structures are thus investigated. A parabolic relationship is observed between amylose content and gelatinization temperatures of both wheat flour and dough. Amylopectin molecular size is positively correlated while amylose molecular size negatively correlates with gelatinization onset and peak temperatures of wheat flour. Amylose molecular size is negatively correlated with gelatinization temperatures of wheat dough. Possible mechanisms are further discussed. These results provided first associations between starch molecular structures and thermal properties of wheat dough, and their difference compared to those from wheat flour, which can help the food industry select suitable wheat varieties with improved dough quality.

Influence of Persian Gum and Almond Gum on the Physicochemical Properties of Wheat Starch.

In this study, the influence of different levels (0.1, 0.2, and 0.3% w/w) of Persian gum or almond gum were incorporated into wheat starch, and their influences on water absorption, freeze-thaw stability, microstructure, pasting, and textural properties were investigated. The SEM micrographs revealed that the addition of hydrocolloids to starch leads to the formation of denser gels with smaller pores. The water absorption of starch pastes was improved in the presence of gums, and samples containing 0.3% almond gum had the highest water absorption. The rapid visco analyzer (RVA) data showed that the incorporation of gums significantly affected the pasting properties by increasing the pasting time, pasting temperature, peak viscosity, final viscosity, and setback and decreasing breakdown. In all the pasting parameters, the changes caused by almond gum were more obvious. Based on TPA measurements, hydrocolloids were able to improve the textural properties of starch gels, such as firmness and gumminess but decreased the cohesiveness, and springiness was not affected by the incorporation of gums. Moreover, the freeze-thaw stability of starch was enhanced by the inclusion of gums, and almond gum exhibited better performance.

Characterization of Starch Physicochemical Properties and Grain Transcriptome Reveal the Mechanism for Resistant Starch Accumulation

Understanding the physicochemical properties of starch during grain development and the mechanism for resistant starch (RS) accumulation will provide useful information for improving the RS content of wheat. The grains from wheat mutant lines with high RS contents and their corresponding wild-type control were analyzed to characterize the structural and physicochemical properties of wheat starch. A transcriptomic analysis was used to analyze the differentially expressed genes (DEGs) involved in RS accumulation. The results showed that the RS content increased with grain development, along with the total starch content, but a larger increase was observed in the middle and later stages of grain filling. The X-ray diffraction peak intensity and relative crystallinity of starch exhibited the lowest and highest values at 10 days after anthesis, respectively. Regarding the thermal properties of starch, the peak temperature and conclusion temperature generally decreased with grain development; however, the enthalpy values showed no apparent regularity. Compared to control cultivar ZM22, the RS639 and RS683 lines with high RS contents showed high amylose contents and high relative crystallinity and a large proportion of 2.0~9.8 µm starch granules. Furthermore, the transcriptomics analysis revealed that the average relative expression of the glucan-branching enzyme (GBE) α-1,4 glucan phosphorylase (Pho) and starch synthase (SS) in ZM22 was 2.47-, 2.70-, and 2.56-fold higher than that in RS639, respectively; which indicates that the downregulation of the expression of genes encoding GBE, Pho, and SS in wheat grain promotes the accumulation of RS.