Wet Phase Research Articles

Himalayan fir reveals moist phase during Little Ice Age in the Kashmir region of the western Himalayas

The Kashmir region in the western Himalayas is located in a transition zone between areas dominated by the South Asian Summer Monsoon (SASM) and the North Atlantic Oscillation (NAO). Currently being primarily influenced by westerly disturbances (WDs), the area is important to decipher teleconnections between these two important circulation systems for the assessment of past climate variability. We evaluated climate-growth relationships of Abies pindrow (Royle ex D. Don) and reconstructed April to June (AMJ) self-calibrated Palmer drought severity index (scPDSI) for the south Kashmir region during the period 1643–2016 CE. Our reconstructed scPDSI revealed a long wet phase during 1650–1816 CE, indicating the impact of the Little Ice Age (LIA) over the region, followed by prominent drier post-LIA episodes. The mid 18th century (1730–1760 CE) was the wettest period in the past four centuries, whereas the period 1817 to 1865 CE marked the driest phase. These phases are consistent with other precipitation reconstructions from the WD-dominated western and Trans-Himalayan regions, but inconsistant with summer precipitation reconstructions from the SASM-dominated Himalayan regions. A significant positive correlation between our scPDSI reconstruction and the North Atlantic Oscillation (NAO) for the wet phase of the LIA suggests that the NAO remained dominant in modulating the winter and spring precipitation at the study region. During the 19th and 20th centuries, scPDSI was either weakly or negatively correlated with the NAO index, indicating the influence of other atmospheric circulation systems in driving the spring/summer precipitation in the study area. This study, augmented with other moisture records, contributes to analyze the temporal and spatial extent of moisture variability in a regional perspective.

Dynamical influence of MJO phases on the onset of Indian monsoon

There is a need to understand the onset of monsoon dynamics as the date of onset of monsoon (DOM) is an important parameter in framing all the policy for the imminent season like crop choice, sowing schedule, disaster management, power distribution etc It is observed that the interannual variability of the DOM in India is about 7–8 days, making it more challenge to predict this at long lead. The MJO phases are linked with the different convection centres and hence, influences the global circulation process and the rainfall. In this paper the dynamical influence of the different phases of MJO are being quantified on DOM and its progress in continental India by using the multi-source atmospheric and oceanic parameters like wind structure, outgoing longwave radiation (OLR), sea surface temperature (SST). The linkage of the active and inactive phases of MJO along with the favourable conditions for DOM is obtained by using the pentad analysis of associated parameters in different clusters for both the wet and dry phases of MJO along with the strength for the period 1980–2018. Also the dynamics are studied for the early, normal and late onset years separately to understand the relation better. It is inferred that the wet (dry) phase leads to early (late) monsoon onset over Kerala (MOK) in India. To address the progress of monsoon the DOM in Rajasthan (MOR) is considered and the rainfall anomalies during MOK-MOR period are linked to the MJO phases. It is inferred that the wet MJO phase with negative OLR anomaly triggers the fast progress of monsoon over India. This understanding will surely help operational researchers and the NWP modellers for improving the methodologies for the advanced and accurate prediction of DOM.

Recovery of Pure Water, Salicylic Acid Crystals, and Paracetamol using PVDF-MWCNT Membranes by Membrane Distillation-crystallization

Membrane distillation-crystallization (MDC) is presented as a novel technique in the treatment of waste concentrated water which produces valuable crystals along with pure water. In the present study, multi-walled carbon nanotubes (MWCNT)/polyvinylidene fluoride (PVDF) flat sheet membranes were prepared via the wet phase inversion method and applied in MDC for the treatment of pharmaceutical waste. The pure and modified membrane surface properties are characterized with the help of SEM, FTIR, and contact angle measurement. The present work reported the effect of MWCNT content and feed temperature on the MDCperformance and measured pure water flux and pharmaceutical compounds recovery. The observed maximum permeate flux and crystal recovery for Salicylic acid system was 5.5 kg/m2h and 50%, respectively for PVDF+0.5% CNT membrane and 5 kg/m2h and 48%, respectively for pure PVDF. Also, for paracetamol system it was 3.9 kg/m2h and 41% for PVDF +0.5% CNT membrane and 3.5 kg/ m2h and 38% for pure PVDF. Obtained results show that MDC has good potential in treating pharmaceutical waste.

Tribocorrosive Aspects of Tungsten Carbide, Silicon Nitride, and Martensitic Steel under Fretting-like Conditions

Water-based lubrication faces the common challenge of component lifetime extension which is impaired by tribocorrosion due to material surface depassivation. However, such mechanisms in a pH-neutral and low-halide electrolyte require additional understanding. A ball-on-flat configuration study of hard-phase materials in a low amplitude–high frequency sliding contact against martensitic chromium steel with contact pressures around 200 MPa is presented. Under lubrication by purified water, tungsten carbide-based metal matrix composite (MMC) with NiCr binder and silicon nitride-based ceramic (SiAlON) against DIN/EN 1.4108 steel yielded coefficients of friction above unity. Wear scar enlargement led to fretting-like conditions with adhesion becoming the fundamental wear mechanism. A tribocorrosion-induced depletion of tungsten carbide and nickel was determined for MMC. SiAlON materials suffered extreme wear under the formation of abrasive SiO2, while heat-treated DIN/EN 1.4125 steel showed lower friction and wear, but also showed signs of hydrogen embrittlement. Results from accompanying single-material corrosion experiments could not satisfactorily explain the phenomena. Including galvanic interaction and the influence of contact geometry, a new tribocorrosion model for fretting conditions is proposed. It describes an expanding anodic belt located at the inner-most crevice position of an otherwise cathodically polarized material. Low conductivity of the electrolyte is seen as a key player in this process, while the galvanic situation between two materials in contact was shown to invert when water was substituted by a wet organic phase.

A 2600-yr multiproxy record for climate and vegetation reconstruction along the Mahanadi River delta, east coast of India

Understanding the impact of climate change on the vegetation cover in the past is crucial for predicting the future warming scenario and its consequences. The present study integrates biotic (palynological analysis) and abiotic proxy (sediment chemistry, clay mineral assemblages and grain size end member (EM) analysis) records in a chronologically constrained sedimentary sequence from the southeastern part of the Mahanadi River delta to reconstruct the hydroclimate since 2600 years. The Mahanadi delta sediments are primarily derived from felsic rock source possibly composed of granites or granulites. The dominance of herbaceous taxa, high aridity index and deposition of fine grain (EM1) sediment possibly suggest a relatively cold and dry climate in the study region during ~2600–2100 cal yr BP corresponding to the Iron Age Cold Period (IACP). Presence of diverse mangrove and tree taxa, deposition of coarser sediment (EM3) and relatively high abundance of secondary clay minerals possibly indicate high precipitation associated with the Roman Warm Period (RWP, ~2100–1800 cal yr BP). A decline in mangroves, dominance of herbaceous taxa and high deposition of fine grain (EM2) sediment from ~1800 to 1300 cal yr BP may indicate a relatively drier climate coinciding with the Dark Age Cold Period (DACP). High moisture index and an increased value of Rb/Sr during ~1300 cal yr BP may suggest a wet phase with the onset of the Medieval Climatic Anomaly (MCA) and later shifted to an arid climate during ~1100–800 cal yr BP. After ~800 cal yr BP, a sharp decline in all weathering indices and vegetation cover, dominance of illite indicates a relatively dry climate which could mark the Little Ice Age (LIA, ~800–300 cal yr BP). A small increase in the terrestrial flux, as well as the weathering indices after ~300 cal yr BP, may suggest the onset of recent warming.

METHODS FOR DETERMINING MICROCLIMATE PARAMETERS UNDER CLOTHES

When using the overalls, metabolic products accumulate under it - sweat in the form of a vapour-gas and wet phase. To increase productivity of workers and maintain a comfortable body ambience, that is, an optimal microclimate under special clothing, it is important to remove accumulated moisture and other metabolic products as soon as possible. The method for solving this problem should be aimed at normalizing the state of heat exchange by the human body, associated with the level of severity of labor and changes in the parameters of the external environment. The problem can be solved by improving the design of work-wear or the hygienic properties of the work-wear cloth. This article determines parameters of the ambience under special clothing made of a new fibrous gauze recommended for workers in the automotive industry and compares the findings. The level of comfort of the microclimate in special clothes made of gas with a new composition of fibers with increased hygienic properties, recommended for workers in assembly shops of automobile plants, has been maintained.

Geophysical sediment properties of a late Pleistocene loess–paleosol sequence, Chenarli, northeastern Iran

AbstractWe present stratigraphic, magnetic, diffuse reflectance spectrophotometric analyses, and chronologic data for the Chenarli loess–paleosol sequence in northeastern Iran. Eight loess units (LU) are identified, described, and constrained in time based on relative stratigraphy and luminescence dating from >130 ± 9.1 ka to ~9.8 ± 0.7 ka. Our data indicate that pedogenic magnetite/maghemite formation gives rise to magnetic enhancement in modern soil and paleosols. The top of LU 7 is demarcated by the well-developed last interglacial soil in which magnetic depletion occurred. We infer that magnetic depletion in this paleosol was produced by reducing conditions in a seasonally waterlogged soil during a warm and wet phase within Marine Isotope Stage (MIS) 5e. Units LU 6 to 1 record several episodes of dust accumulation and soil formation during the last glacial and Holocene. Increased dust accumulation rates occurred during middle-late MIS 3 and lasted into the late MIS 2, with a peak during the last glacial maximum (LU 2). These findings could be applicable to understanding magnetic enhancement/dissolution mechanism in the loess–paleosol sequences in study area. We infer paleoenvironmental changes in northeastern Iran relative to northern Iran, Eurasia, and China.

Inference of future bog succession trajectory from spatial chronosequence of changing aapa mires.

Climate change-driven vegetation changes can alter the ecosystem functions of northern peatlands. Several case studies have documented fen-to-bog transition (FBT) over recent decades, which can have major implications, as increased bog growth would likely cause cooling feedback. However, studies beyond individual cases are missing to infer if a common trajectory or many alternatives of FBT are in progress. We explored plant community and hydrology patterns during FBT of 23 boreal aapa mire complexes in Finland. We focused on mires where comparisons of historical (1940-1970) and new (2017-2019) aerial photographs indicated an expansion of Sphagnum-dominated zones. Vegetation plot and water chemistry data were collected from string-flark fens, transition zones with indications of Sphagnum increase, and bog zones; thus, in a chronosequence with a decadal time span. We ask, is there a common trajectory or many alternatives of FBT in progress, and what are the main characteristics (species and traits) of transitional plant communities? We found a pattern of fen-bog transitions via an increase in Sphagnum sect. Cuspidata (mainly S. majus and S. balticum), indicating a consistently high water table. Indicators only of transitional communities were scarce (Sphagnum lindbergii), but FBT had apparently facilitated shallow-rooted aerenchymatous vascular plants, especially Scheuchzeria palustris. Water pH consistently reflected the chronosequence with averages of 4.2, 3.9, and 3.8, from fen to transition and bog zones. Due to weak minerotrophy of string-flark fens, species richness increased towards bogs, but succession led to reduced beta diversity and homogenization among bog sites. Decadal chronosequence suggested a future fen-bog transition through a wet phase, instead of a drying trend. Transitional poor-fen vegetation was characterized by the abundance of Sphagnum lindbergii, S. majus, and Scheuchzeria palustris. Sphagnum mosses likely benefit from longer growing seasons and consistently wet and acidic conditions of aapa mires.

Westerly-monsoon variations since the last deglaciation from semi-arid Ladakh region, Trans Himalaya, India

The semi-arid Ladakh region in the Trans Himalaya forms an environmental boundary between North Atlantic and monsoon forcings. Its location in the transient setting of these two climate systems enables to attest slight changes in the dynamics of these components of atmospheric circulation. Variation in climatic conditions from 19.6 to 6.1 ka using multi-proxy investigation (mineral magnetism, stable carbon isotope, palaeoprecipitation, sediment grainsize end member analysis, clay mineralogy and TOC) is studied from Khalsi palaeolake deposit in Ladakh. Considering the inherent uncertainty of radiocarbon chronology, the present study provides millennial to multi-centennial scale resolution of climate variation from the sediment sequence. The results indicate cold arid climate influenced by Westerly circulation for the last 19.6 to 11.1 ka, thereafter from 11.1 to 7.5 ka, monsoon forcings dominated the climate of the region, following the orbitally controlled solar insolation that influenced the position of ITCZ and formed the key driver of the variability of these atmospheric circulations. A short wet phase from ∼17.4 to 16.5 ka within the dominant Westerly period is attributed to the early wet phase of two-fold H1 event. Westerly regained strength from 7.5 to 6.1 ka during the mid-Holocene coinciding with decreasing insolation, weakening monsoon and enhanced El Niño activities.

Effect of Polyvinylpyrrolidone on Polyvinylidene Fluoride/Hydroxyapatite- Blended Nanofiltration Membranes: Characterization and Filtration Properties.

The application of polyvinylidene fluoride (PVDF) as a filtration membrane is limited due to its hydrophobicity. This paper elaborated on the fabrication process of nanofiltration PVDF membrane incorporating various quantities of hydrophilic polyvinylpyrrolidone (PVP) and hydroxyapatite (HA) using a wet phase inversion method to improve its hydrophilicity. The membrane was fabricated by using the wet phase inversion method. It was then characterized in terms of water permeability, water contact angle, water content, surface energy, and surface porosity. Bacteria and Fe ions filtration was conducted to investigate the membrane filtration performance. The PVDF/PVP/HA-blended membrane showed the highest water permeability (6,165 LMH/Bar), water content (45.2 %), and surface energy (104.1 mN/m) when 2 wt.% of PVP was introduced into the base polymer PVDF. This fabricated membrane, labeled as PVP 2.0, also showed the lowest contact angle (64°) and the highest surface porosity (42%). Overall, the PVP introduction patents into the polymeric membrane doping solution potentially improves membrane hydrophilicity and permeability.

Precipitation variability, vegetation turnover, and anthropogenic disturbance over the last millennium in the Atacama highlands of northern Chile (19°S)

The Late-Holocene history of hydroclimatic variability in the Atacama Desert offers insights into the effects of precipitation and humans on ecosystems in one of the most extremely arid regions of the world. However, understanding the effects of regional precipitation variability in relation to local ecological stressors remains to be fully resolved. Here, we present a pollen-based qualitative precipitation reconstruction derived from fossil rodent middens recovered from two sites near Laguna Roja (LRO; n = 25) and Isluga (ISL; n = 15) in the Atacama highlands (19°S) of northern Chile. At LRO, the fossil pollen record shows multi-centennial hydroclimatic anomalies during the last millennium, with wetter than present phases at 1155–1130, 865–670, and 215–80 cal yrs BP, and similar to present conditions between 1005 and 880 cal yrs BP. In contrast, the ISL record shows a wet phase during 1115–840 cal yrs BP, suggesting that meso-ecological processes were as important in vegetation turnover as regional hydroclimate anomalies. Wetter conditions derived from LRO partially overlap with the Medieval Climate Anomaly (865–670 cal yrs BP) and with the latest part of the Little Ice Age (215–80 cal yrs BP). Furthermore, no strong anthropogenic signal was identified possibly related to the remote location of the records. Palynological diversity analyses evidence increasing diversification of plant communities during wet events at both sites. In correlation to existing regional hydroclimatic records from the Western Andes, our precipitation reconstruction verifies that centennial-scale changes in the strength of the South American Summer Monsoon (SASM) and partial influence of El Niño-like (ENSO) conditions drove vegetation turnover in the Atacama Desert during the last millennium.

Coevolution of Climate Change, Surface Properties, Vegetation Cover, and Drainage Network in a Loess Covered Area.

Arid and semi-arid areas are often regarded as highly sensitive to climate change. Average annual rainfall is usually regarded as the most important factor controlling soil moisture regime, water availability, and therefore various environmental variables. The present study deals with the ecology of an area located in the semi-arid area of Israel, where average annual rainfall is ~280 mm. The area is located in a loess covered area. The loess cover was deposited during a wet climatic phase. However, pedological and ecological data point to a desertification effect. Data obtained show that non-climatic factors, such as local surface properties, can exert a strong influence on the environment. In addition, the global models disregard the characteristics of the local rainfall regime, such as the distribution of rain intensities, and the duration of individual rain-showers during a rainstorm. Under the present rainfall regime about 85% of the rains are below 5 mm/hr,1, rainfall is also highly intermittent, limiting runoff generation, and infiltration depth. Under such conditions, a high evaporation rate leads to a soil salinization process.

A predictive model of frost formation on leaf surface and estimation of frost amount

The massive frost that occurs each year in autumn and spring across subtropical and temperate regions cause severe damage to horticultural crops, therefore, the research for frost formation and estimation of frost amount are important for monitoring and regulation of frost damage. In this study, a predictive model of frost formation on leaf surface with the interaction of wet air phase and frost phase was established by Euler multiphase flow model. According to the variation of phase volume fraction, the evolution process of frost under non-stationary conditions was simulated using Fluent calculations based on leaf surface frosting mechanism. In addition, the influence of different surface temperatures, air velocities and humidity on frost amount were investigated deeply during simulation by building frost amount measurement device combined with microscopic image processing. The results showed that the frost amount increased mainly with decreased surface temperature under time-varying conditions, and reduce the velocity or increase humidity also has a beneficial effect. The estimation of frost thickness fell within confidence intervals up to 90%, with overall deviations in frost mass ranging from −8.4% to 23.8%. Eventually, the model was demonstrated that it could provide an acceptable prediction of frost formation and estimate of frost amount.

No Signs of Long-term Greening Trend in Western Mongolian Grasslands

Trends for increased vegetation greenness based on satellite-derived data have been repeatedly published for the temperate grassland biome (including forest steppes) of eastern Inner Asia since 1982. Although this greening trend has been attenuated or partially reversed by drought in the early twenty-first century, linear increases in the Normalized Difference Vegetation Index (NDVI) or other parameters of vegetation greenness are nevertheless evident when the period since 1982 is regarded. However, the question arises whether these trends are part of a long-term trend driven by climate change, as simultaneously forests in the region show widespread drought-induced growth reductions and mortality outbreaks. Therefore, we hypothesized that the post-1982 greening trend was neither part of a long-term trend nor unprecedented. To test this hypothesis, we analyzed monthly maximum NDVI data from AVHRR time series and correlated these data with standardized tree-ring data of Larix sibirica from two regions of western Mongolia. We used linear regression to model the NDVI from tree-ring anomalies and to reconstruct the NDVI since 1940. These reconstructions show that the availability of satellite-based NDVI data coincidentally began during a dry period of low vegetation greenness in the early 1980s and was followed by a wet phase in the 1990s, producing the linear greening trend. No positive long-term trend in the reconstructed NDVI was observed from 1940 to 2010. This result rules out a recent climate change-driven greening trend for the grasslands and forest steppes of western Mongolia and calls into question its existence for all of eastern Inner Asia.

Convection and Clouds under Different Planetary Gravities Simulated by a Small-domain Cloud-resolving Model

In this study, we employ a cloud-resolving model to investigate how gravity influences convection and clouds in a small-domain (96 × 96 km) radiative–convective equilibrium. Our experiments are performed with a horizontal grid spacing of 1 km, which can resolve large (>1 km2) convective cells. We find that under a given stellar flux, sea surface temperature increases with decreasing gravity. This is because a lower-gravity planet has larger water vapor content and more clouds, resulting in a larger clear-sky greenhouse effect and a stronger cloud warming effect in the small domain. By increasing stellar flux under different gravity values, we find that the convection shifts from a quasi-steady state to an oscillatory state. In the oscillatory state, there are convection cycles with a period of several days, comprised of a short wet phase with intense surface precipitation and a dry phase with no surface precipitation. When convection shifts to the oscillatory state, the water vapor content and high-level cloud fraction increase substantially, resulting in rapid warming. After the transition to the oscillatory state, the cloud net positive radiative effect decreases with increasing stellar flux, which indicates a stabilizing climate effect. In the quasi-steady state, the atmospheric absorption features of CO2 are more detectable on lower-gravity planets because of their larger atmospheric heights. While in the oscillatory state, the high-level clouds mute almost all of the absorption features, making the atmospheric components hard to characterize.

Modeling the influence of chain length on secondary organic aerosol (SOA) formation via multiphase reactions of alkanes

Abstract. Secondary organic aerosol (SOA) from diesel fuel is known to be significantly sourced from the atmospheric oxidation of aliphatic hydrocarbons. In this study, the formation of linear alkane SOA was predicted using the Unified Partitioning Aerosol Phase Reaction (UNIPAR) model that simulated multiphase reactions of hydrocarbons. In the model, the formation of oxygenated products from the photooxidation of linear alkanes was simulated using a nearly explicit gas kinetic mechanism. Autoxidation paths integrated with alkyl peroxy radicals were added to the Master Chemical Mechanism v3.3.1 to improve the prediction of low-volatility products in the gas phase and SOA mass. The resulting gas products were then lumped into volatility- and reactivity-based groups that are linked to mass-based stoichiometric coefficients. The SOA mass in the UNIPAR model is produced via three major pathways: partitioning of gaseous oxidized products onto both the organic and wet inorganic phases, oligomerization in the organic phase, and reactions in the wet inorganic phase (acid-catalyzed oligomerization and organosulfate formation). The model performance was demonstrated for SOA data that were produced through the photooxidation of a homologous series of linear alkanes ranging from C9–C15 under varying environments (NOx levels and inorganic seed conditions) in a large outdoor photochemical smog chamber. The product distributions of linear alkanes were mathematically predicted as a function of carbon number using an incremental volatility coefficient (IVC) to cover a wide range of alkane lengths. The prediction of alkane SOA using the incremental volatility-based product distributions, which were obtained with C9–C12 alkanes, was evaluated for C13 and C15 chamber data and further extrapolated to predict the SOA from longer-chain alkanes (≥ C15) that can be found in diesel. The model simulation of linear alkanes in diesel fuel suggests that SOA mass is mainly produced by alkanes C15 and higher. Alkane SOA is insignificantly impacted by the reactions of organic species in the wet inorganic phase due to the hydrophobicity of products but significantly influenced by gas–particle partitioning.

An 1800-year oxygen-isotope record of short- and long-term hydroclimate variability in the northern neotropics from a Jamaican marl lake

Hydroclimate variability on multi-decadal timescales has been a prominent feature of the circum-Caribbean region over the common era, with marked dry intervals noted in particular for the period 800–950 CE coinciding with the Terminal Classic Period (the so-called Terminal Classic Drought: TCD) in Mesoamerica, and with the Little Ice Age from about 1500 to 1800 CE, linked to complex ocean-atmosphere interactions. Previous compilations of palaeoclimate reconstructions have revealed a clear precipitation dipole between northern and southern Mesoamerica over the common era, which is consistent with meteorological data and modelling experiments. However, patterns of variability elsewhere within the region are less well understood, although palaeoclimate records do point to spatial complexity. Here, we present a ∼sub-decadal-scale lake-sediment hydroclimate reconstruction based on ostracod-shell stable isotopes from Wallywash Great Pond, Jamaica, covering the past ∼1800 years, which fills a spatial gap in records for the region. Variations in δ18O values at this site are a proxy for changes in effective moisture and they reveal a marked wet phase over the Terminal Classic Period (TCP), suggesting that the precipitation dipole over northern and southern Mesoamerica may have an east to west component. This is supported by some previous studies, although additional sites are required from strategic localities within the region to confirm this. The Little Ice Age interval at Wallywash is drier than the TCP, although the signal is less clear than at some sites within the wider region, suggesting that regional complexity in hydroclimate has characterised this interval as well.

An evaluation of crustacean and rotifer diversity and composition in a temporary pond metacommunity: Comparing results from field samples and a hatching experiment

Abstract Many aquatic invertebrates that inhabit temporary ponds produce resting forms to overcome the dry period, building up the egg bank. When the wet phase returns, the resting forms hatch and the community is restored, and then pioneer species may have a major influence on how the pond community will assemble. We aimed to evaluate the diversity of an initial pond metacommunity by comparing the early active metacommunity collected in the field and the egg bank metacommunity (by carrying out a hatching experiment) of 32 Mediterranean temporary ponds. We hypothesised that both metacommunities would be similar but also that species turnover may play an important role, and that γ diversity would be similar with both approaches. After the identification and counting of rotifers and crustaceans in both metacommunities (i.e. the field vs. the experiment) we performed a Partial Triadic Analysis comparing the field metacommunity with those corresponding to each of the eight times the hatching experiment was checked for hatchlings. Furthermore, we compared the field and experimental metacommunities with a PROTEST analysis and identified the taxa responsible for differences between metacommunities with a SIMPER analysis. We assessed γ diversity using a size‐based rarefaction curve and an evenness profile and explored β diversity and its components (turnover and nestedness) for the two metacommunities. Our experimental results showed differences in the temporal pattern of emergence between groups of organisms, with copepods, rotifers, and anostracans appearing first, but ostracods and rotifers reaching the highest diversity at the end of the experiment. The active and experimental pioneer metacommunities were similar according to a Procrustes analysis. Nevertheless, β diversity was high in both metacommunities and the differences among ponds and between both assemblages were mostly explained by species turnover. Both the active and experimental pond metacommunities showed some exclusive species that may be more difficult to uncover with only one type of approach. Furthermore, the high β diversity observed indicates that each temporary pond is an important contributor to γ diversity in the metacommunity. These results show that hatching experiments provide information that is complementary to standard sampling of the active community, and consequently is a useful tool to uncover pond biodiversity.

Hydrogeotechnical Predictive Approach for Rockfall Mountain Hazard Using Elastic Modulus and Peak Shear Stress at Soil–Rock Interface in Dry and Wet Phases at KKH Pakistan

Predicting the susceptibility of rockfall mountain hazards for block-in-matrix soils is challenging for critical steep cuts. This research illustrates a hydrogeotechnical approach for the prediction of rockfall triggering by performing laboratory tests on low-cohesive-matrix soil collected from steep slopes with 85° to 88° angles at the Tatta Pani site, Karakorum Highway (KKH), and then real-scale moisture-induced rockfall was conducted on site for the validation of laboratory data. Laboratory data of forty quick direct shear tests on samples collected from the field depicted a 3-fold drop in peak shear stress (PS) at the soil–soil interface and a 9.3-fold drop at the soil–rock interface by varying the moisture content from 1% (taken as dry phase) to a critical laboratory moisture content (MC)LC of 21% (taken as wet phase). Similarly, a drop in the elastic modulus (ES) was observed to be 5.7-fold at the soil–soil interface and 10-fold at the soil–rock interface for a variation of moisture content from 1 % to 21% for the matrix with a permeability (k) range of 3 × 10−4 to 5.6 × 10−4 m/s, which depicts the criticality of moisture content for the rockfall phenomenon. The critical moisture content evaluated in laboratory is validated by an innovative field-inundation method for thirty-two moisture-induced real-scale forced rockfall cases, which showed the rock-block triggering at field dry density (γd)f and the critical field moisture content (MC)FC of the matrix ranging from 1.78 g/cm3 to 1.92 g/cm3, and 1.3% to 25.4%, respectively. Hydrogeotechnical relations, i.e., MC versus PS and ES, at the soil–rock interface are developed for the prediction of rockfall triggering. The proposed correlations may be helpful in the prediction of rockfall hazards by using expected rainfall in the field for disaster warning and landslide disaster prevention at ecological geotechnical engineering projects. The results revealed that the critical (MC)FC and (MC)LC are within 20%, depicting a good confidence level of the outcomes of this research.

The Role Played by the Bulk Hygroscopicity on the Prediction of the Cloud Condensation Nuclei Concentration Inside the Urban Aerosol Plume in Manaus, Brazil: From Measurements to Modeled Results

This work use observed and modeled data to trace a basic model that describes how the bulk chemical composition can be used to determine the aerosol size-dependency of hygroscopicity inside the urban aerosol pollution plume from Manaus, Brazil. The procedure is then used to predict the Cloud Condensation Nuclei (CCN) concentration (NCCN) from the Aerosol Size Distribution (ASD). The work briefly described hourly averaged data of ASD, Black Carbon size distribution (BCSD), Black Carbon mass concentration (BC), NCCN, and aerosol size hygroscopicity (κ) observed about 70 km downwind of the City of Manaus, inside the amazon rain forest, during 60 days of 2014, in the course of the rainy season. It uses a description of aerosol chemical composition obtained previously in the city of São Paulo, Brazil, as starting point to formulate a model that describes how particles in the pollution plume act as CCN as a function of their sizes and bulk chemical composition. A parameterization based on a polynomial fitting is proposed to determine BCSD from the BC. The measured and parameterized BCSD agree very well with more than 98% of the observed BCSDs, presenting a correlation coefficient larger than 0.9 with observation. The parameterized BC number concentration is also very well represented, with a correlation coefficient of 0.91 and a slope of 0.99 in comparison with observations. This work also studies how soot particles are incorporated in the CCN population and propose a parameterization to represent it. Simulations suggest that the larger BC particles are only partially incorporated as CCN and BC is a constraint to the fraction of aerosols that can act as CCN in all size ranges. The simulations also suggest that the incorporation of BC as CCN is probably only effective through coagulation in the presence of the wet phase. In addition, the work compares different strategies to predict observed NCCN from ASD. It is shown that the strategy presented can substantially improve the results of comparison of modeled and measured data from as bad as 2.14 ± 0.65 to as good as 1.02 ± 0.17. This study shows that the knowledge of the bulk chemical composition can be used to predict both the size-resolved chemical composition and mixing state, reducing the number of parameters needed to predict NCCN.