Wet Conditions Research Articles

Design, Fabrication, and Evaluation of 3D Biopotential Electrodes and Intelligent Garment System for Sports Monitoring.

This study presents the development and evaluation of an innovative intelligent garment system, incorporating 3D knitted silver biopotential electrodes, designed for long-term sports monitoring. By integrating advanced textile engineering with wearable monitoring technologies, we introduce a novel approach to real-time physiological signal acquisition, focusing on enhancing athletic performance analysis and fatigue detection. Utilizing low-resistance silver fibers, our electrodes demonstrate significantly reduced skin-to-electrode impedance, facilitating improved signal quality and reliability, especially during physical activities. The garment system, embedded with these electrodes, offers a non-invasive, comfortable solution for continuous ECG and EMG monitoring, addressing the limitations of traditional Ag/AgCl electrodes, such as skin irritation and signal degradation over time. Through various experimentation, including impedance measurements and biosignal acquisition during cycling activities, we validate the system's effectiveness in capturing high-quality physiological data. Our findings illustrate the electrodes' superior performance in both dry and wet conditions. This study not only advances the field of intelligent garments and biopotential monitoring, but also provides valuable insights for the application of intelligent sports wearables in the future.

Glycidyl methacrylate co-polymer emulsion-based heat and water-resistant wood adhesive

This work aims to add an epoxy-ended co-monomer to polyvinyl acetate (PVAc) emulsion adhesive-based wood adhesive to improve its resistance to heat and moisture. Here, glycidyl methacrylate (GMA), vinyl neodecanoate (VeoVa), and vinyl acetate (VAc) emulsion copolymers have been created and evaluated as wood adhesives. To prepare the emulsion-based adhesive samples, a polyvinyl alcohol (PVA) solution, aluminium chloride solution, preservatives, and a plasticizer are added. Following that, the poly(VAc–VeoVa–GMA) based adhesive sample is compared with the VAc, VeoVa, and methyl methacrylate (MMA) (poly(VAc-VeoVa-MMA)) co-polymer-based adhesive. Tensile shear strength of wood joints under dry and wet conditions was tested in compliance with EN 204-205 standard to assess the adhesives’ performance. The EN 14257 standard, which defines the shear stress of wood joints at 80 °C, was used to assess the heat resistance of the wood adhesives. Tests on the hardness of films confirmed the results of differential scanning calorimetry, which indicated that the glass transition temperature in the GMA-based adhesive was significantly higher than in the MMA-based adhesive. After 6 h of bonding, EN 204 shows that the tensile shear strength of a GMA-based adhesive increased by 15.56% in a dry environment, by 16.67% in a wet environment and 37.84% heat resistance when compared to a co-polymer-based adhesive based on MMA. The approach that was developed provides a simple and useful way of developing adhesives with enhanced heat, water, and bonding strength resistance.

Assessing the influence of nano graphene oxide application in mitigating the adverse effects of runoff pH on the moisture susceptibility of asphalt concretes

The specifications of runoff entered the pavement has an essential role in the severity of moisture damage of asphalt concretes. Changing the pH of runoff has a negative impact on moisture damage and intensifies this damage in asphalt concretes. Accordingly, in this study, the impact of nanographene oxide (NGO) as a contaminant adsorbent and bitumen modified to decrease the destructive impacts of acidity changes in runoff has been investigated. For this purpose, limestone and siliceous aggregates, PG 64–16 bitumen, and NGO in two different contents (0.3 % and 0.5 % of the weight of bitumen) were utilized. To asses the strength of asphalt concretes with different runoff pH conditions, hydrochloric acid and sodium oxide were used to simulate acidic and basic runoffs, respectively. The indirect tensile strength (ITS) of asphalt concretes in different environmental states was tested to compare the severity of moisture sensitivity. Moreover, the surface free energy (SFE) elements of bitumen and aggregates were calculated utilizing the Wilhelmy Plate (WP) and the Universal Sorption Device (USD), respectively. The parameters of SFE theory were used to assess the mechanisms of water damage potential. The SFE results showed that NGO decreased the debonding energy (DE) of the mixtures. Changes in DE in neutral environments were minor, but with the polarization of environmental conditions, especially in basic states, these changes intensified. The application of NGO improved the total bitumen SFE, which reduced the possibility of moisture sensitivity as a cohesive failure. The results of mechanical methods indicated that the use of NGO in specimens with limestone and siliceous aggregate increased the indirect tensile strength ratio (TSR) in moisture conditions with different degrees of acidity. The mechanical experiment results also confirmed the SFE method's results that the effect of using NGO on increasing the TSR index at pH equal to 7 was minor, and it was intensified in acidic and basic waters.

Pore-scale simulation of H2-brine system relevant for underground hydrogen storage: A lattice Boltzmann investigation

Underground hydrogen (H2) storage in saline aquifers is a viable solution for large-scale H2 storage. Due to its remarkably low viscosity and density, the flow of H2 within saline aquifers exhibits strong instability, which needs to be thoroughly investigated to ensure safe operations at the storage site. For the first time, we develop a lattice Boltzmann model tailored for pore-scale simulations of the H2-brine system under typical subsurface storage conditions. The model captures the significant contrast of fluid properties between H2 and brine, and it offers the flexibility to adjust the contact angle to suit varying wetting conditions. We show that the snap-off is enhanced in a system with a high capillary number and a small contact angle. These conditions lead to a low recovery factor, which is unfavorable for H2 production from the aquifer. Moreover, the relative permeability curves, computed from the simulation results, exhibit distinct behaviors for H2 and brine. In the case of the wetting phase, the relative permeability can be quantified using the quadratic expression, whereas for the non-wetting phase, the relative permeability exhibits a nearly linear behavior, and saturation alone appears insufficient to characterize the relative permeability at large saturations of non-wetting phase. This implies that different formula for liquid and gas phases may be employed for continuum-scale simulations.

Preparation of cellulose/activated carbon cells: application to the adsorption of cobalt from stagnant waters

Abstract A cellulose/activated carbon combined material is prepared and tested for the adsorption of Co(II) from stagnant waters. This material is easily prepared using two different homemade activated carbons as adsorbents and sanitary paper as cellulose source. Cellulose/activated carbon cells so prepared are thoroughly characterized using multiple methods including optical imaging, tensile tests in dry and wet conditions, thermogravimetric analysis and Fourier transform infrared spectroscopy. Afterwards, they are tested for the adsorption of Co(II) from stagnant waters solutions. The results showed that the prepared cells offer good mechanical resistance; the optical microscopy images showed the dispersion of activated carbons grains between cellulose fibres while spectral analysis revealed that the activated carbons keep their chemical properties in the cells. When tested and compared to activated carbons alone for the retention of Co(II) from stagnant waters solutions, the cellulose/activated carbon cells gave better adsorption ratios for both activated carbons (up to double). This study shows an easy way to enhance the efficiency of activated carbons by dispersing their grains within cellulose fibres. Thus the added value of this work is ease of preparation, non-use of harmful chemicals and the economic aspect.

Engineered Robust Hydrophobic/Hydrophilic Nanofibrous Scaffolds with Drug-Eluting, Antioxidant, and Antimicrobial Capacity.

Multifunctional nanofibrous architectures have attracted extensive attention for biomedical applications due to their adjustable and versatile properties. Electrospun fabrics stand out as key building blocks for these structures, yet improving their mechanobiological and physicochemical performance is a challenge. Here, we introduce biodegradable engineered hydrophobic/hydrophilic scaffolds consisting of electrospun polylactide nanofibers coated with drug-eluting synthetic (poly(vinyl alcohol)) and natural (starch) polymers. The microstructure of these composite scaffolds was tailored for an increased hydrophilicity, optimized permeability, water retention capacity of up to 5.1 g/g, and enhanced mechanical properties under both dry and wet conditions. Regarding the latter, normalized tensile strengths of up to 32.4 MPa were achieved thanks to the improved fiber interactions and fiber-coating stress transfer. Curcumin was employed as a model drug, and its sustained release in a pure aqueous medium was investigated for 35 days. An in-depth study of the release kinetics revealed the outstanding water solubility and bioavailability of curcumin, owing to its complexation with the hydrophilic polymers and further delineated the role of the hydrophobic nanofibrous network in regulating its release rate. The modified curcumin endowed the composites with antioxidant activities up to 5.7 times higher than that of free curcumin as well as promising anti-inflammatory and bacteriostatic activities. The cytocompatibility and cell proliferation capability on human dermal fibroblasts also evidenced the safe use of the constructs. Finally, the fabrics present pH-responsive color-changing behavior easily distinguishable within the pH range of 5-9. Thus, these designs offer a facile and cost-effective roadmap for the fabrication of smart multifunctional biomaterials, especially for chronic wound healing.

Genomic insights into redox-driven microbial processes for carbon decomposition in thawing Arctic soils and permafrost.

As the Arctic warms, thawing permafrost unlocks carbon, potentially accelerating climate change by releasing greenhouse gases. Our research delves into the underlying biogeochemical processes likely mediated by the soil microbial community in response to the wet and anaerobic conditions, akin to an Arctic summer thaw. We observed a significant shift in the microbial community post-thaw, with fermentative bacteria like Firmicutes and Bacteroidota taking over and switching to different fermentation pathways. The dominance of iron and sulfate-reducing bacteria likely constrained methane production in the thawing permafrost. Slow-growing microbes outweighed fast-growing ones, even after thaw, upending the expectation that rapid microbial responses to dominate after permafrost thaws. This research highlights the nuanced and complex interactions within Arctic soil microbial communities and underscores the challenges in predicting microbial response to environmental change.

Dynamic response, durability, and carbon footprint analysis of the marl clay treated with sodium lignosulfonate as a sustainable-environmentally friendly approach

In the current study, the marl clay was improved by different contents of sodium lignosulfonate (NLS) and cured at different times and then, all samples were subjected to Bender Element (BE), Unconfined Compressive Strength (UCS), and Brazilian Tensile Strength (BTS) tests considering two different dry condition (DC) and wet condition (WC). The durability of the samples was further controlled by a special technique, namely the soaking test. The carbon footprint analysis was undertaken for a low-volume trench project to address the sustainability benefits associated with replacing cement and lime as traditional stabilizers with NLS. The results show that the reuse of NLS as a non-traditional alternative for stabilizing marl soil can play an influential role in improving dynamic parameters as well as sustainable development. It has been observed that the CO2 emission decreases up to 5.6 and 4.4 times compared to lime and cement, respectively. Additionally, the use of NLS enhances the UCS by 249%, BTS by 208%, and small strain shear modulus by 117%. Furthermore, reducing the adverse effects of the WC on soil properties, among others, was the main finding of utilizing the NLS in marl stabilization with curing time. NLS-treated marl samples were able to preserve the integrity of their particles even after being soaked in water for a period of 3 weeks. In contrast, the particles of the untreated sample started to disintegrate within a few seconds of initiating the soaking test. Finally, possible equations correlating the dynamic and static moduli were reported in this study.

Assessing crop yield and water balance in crop rotation irrigation systems: Exploring sensitivity to soil hydraulic characteristics and initial moisture conditions in the North China Plain

Multiple cropping is an effective measure to enhance the intensity of land use. The North China Plain is one of China’s most important grain production areas, with 70 % of the arable land under double rotation of winter wheat and summer maize. The allocation of irrigation water between two crop seasons depends on soil water flow and crop water consumption. This is because the amount of moisture left in the soil at the end of one season affects how much moisture is in the soil at the beginning of the next season. As a result, the amount of crops produced and the amount of water needed for irrigation are influenced by the initial soil moisture conditions and the soil’s hydraulic properties. This study aims to analyze how various factors affect crop yield when faced with water scarcity. The factors considered include initial soil moisture condition, soil texture, and irrigation scheduling. The simulation results indicate that, in most cases, initial soil moisture conditions have a more significant impact on crop yield than soil hydraulic characteristics. The impact of irrigation can differ based on the irrigation method and availability of water. Hence, when distributing irrigation water over a year, it is crucial to consider the soil’s water transport between two crop cycles to achieve the ideal full and deficit irrigation in a crop rotation system. Additionally, a joint optimal irrigation plan can significantly reduce the adverse effects of unfavorable soil hydraulic characteristics. Moreover, the optimal irrigation strategy can enhance crop water productivity and food security simultaneously.

Soil and weed management effects on floral hemp (Cannabis sativa L.) production and cannabinoid content

AbstractMany floral hemp (Cannabis sativa L.) growers rely on tillage and black plastic mulch to prepare soil for transplants, warm the soil, and control weeds. However, plastic waste and its high cost to growers drive the need for research to assess alternative weed and soil management practices. Experiments were conducted at two Maine locations in 2021 and 2022 to compare cover crop soil and weed management systems on hemp production, cannabinoid concentrations, and yield. Experimental treatments included (1) tilled raised bed‐black plastic mulch, (2) biweekly cultivation, (3) no weed control, and (4) mowed no‐till mowed winter rye (Secale cereale L. Aroostook). Experimental sites received twice the 30‐year monthly average rainfall in July and September 2021 leading to poorer production versus typical 2022 long‐term average rainfall. Ice damage reduced winter rye biomass in 2022 at University of Maine Rogers Farm, leading to several significant year by location and year by weed management interactions. Hemp grown in the no‐till winter rye mulch developed more slowly, produced lower yields, and had higher weed densities than cultivated or black plastic mulch treatments. Plant size, yield, and cannabinoid content were generally equivalent where weeds were controlled. Raised bed‐black plastic soil and weed management were most effective under excessively wet conditions to reduce soil moisture and improve drainage. Cannabinoid concentrations did not increase under high weed pressure, but cannabinoid yield was influenced by flower production, which was significantly lower in the mowed rye mulch and control treatments. Blending raised bed production with efficient cultivation warrants research attention.

Pore unit cell network modeling of the thermal conductivity dynamics in unsaturated sandy soils: Unveiling the role of spanning‐wetting phase cluster

AbstractAs the world struggles with climate change and energy crises, understanding the role of soil in the food–water–energy nexus becomes increasingly critical. Accurately estimating the soil thermal conductivity drying curve is essential for assessing the impacts of temperature on soil biota and crop growth, environmental changes due to forest fires and global warming, and for designing geo‐energy extraction techniques such as geothermal energy piles. Existing empirical models often fail to accurately estimate the soil thermal conductivity (TC), particularly in pendular soil moisture regimes where they do not capture sharp changes in TC. This study introduces a novel approach using a pore unit cell network model to more accurately describe the dynamics of TC in variably saturated soils. A quadratic parallel scheme within each soil pore unit cell links the TCs of solid, water, and air to the overall effective conductivity. By modeling air invasion in the pore network model and employing the proposed equation, we determined the unsaturated soil TC based on varying local conductivities. The model effectively captures the significant decrease in conductivity in the pendular saturation regime, associated with the shrinkage of the spanning‐wetting cluster. Quantitative analyses showed a substantial improvement in prediction accuracy compared to existing models, especially under varying moisture conditions. Our findings have significant implications for better characterizing soil thermal and hydraulic properties, which are crucial for resource management in a changing climate and advancing geo‐energy technologies.

Impacts of soil type and drought stress on growth and cesium accumulation in Napier grass.

In our previous study, the decontamination efficiency of cesium-137 (137Cs) by Napier grass (Pennisetum purpureum Schum.) in the field was shown to be variable and often influenced by natural environmental factors. To elucidate the factors influencing this variable 137Cs-decontamination efficiency, we investigated the influences of soil type and drought stress on Cs accumulation using cesium-133 (133Cs) in Napier grass grown in plastic containers. The experiment was performed using two soil types (Soil A and B) and three different soil moisture conditions: well-watered control (CL), slight drought stress (SD), and moderate drought stress (MD). Overall, our results indicate that soil type and drought have a significant impact on plant growth and 133Cs accumulation in Napier grass. Plant height (PH), tiller number (TN), leaf width (Wleaf), and dry matter weight of aboveground parts (DWabove) and root parts (DWroot) in Soil B were greater than those in Soil A. Drought stress negatively affected chlorophyll fluorescence parameters (maximal quantum efficiency of photosystem (PS) II photochemistry and potential activity of PS II), PH, TN, Wleaf, DWabove, DWroot, and total 133Cs content (TCs), but it had a positive effect on 133Cs concentration. The 133Cs concentration in the aboveground parts (Csabove) was increased by MD approximately 1.62-fold in Soil A and 1.11-fold in Soil B compared to each CL counterpart. The TCs in the aboveground parts (TCsabove) decreased due to drought by approximately 19.9%-39.0% in Soil A and 49.9%-62.7% in Soil B; however, there was no significant effect on TCsabove due to soil type. The results of this study indicate that soil moisture is a key factor in maintaining Napier grass 137Cs-decontamination efficiency.

Atomistic Characterization of Healthy and Damaged Hair Surfaces: A Molecular Dynamics Simulation Study of Fatty Acids on Protein Layer.

Amid the bourgeoning demand for in-silico designed, environmentally sustainable, and highly effective hair care formulations, a growing interest is evident in the exploration of realistic computational model for the hair surface. In this work, we present an atomistic model for the outermost layer of the hair surface derived through molecular dynamics simulations, which comprises 18-Methyleicosanoic acid (18-MEA) fatty acid chains covalently bound onto the keratin-associated protein 10-4 (KAP10-4) at a spacing distance of ~1 nm. Remarkably, this hair surface model facilitates the inclusion of free fatty acids (free 18-MEA) into the gaps between chemically bound 18-MEA chains, up to a maximum number that results in a packing density of 0.22 nm2 per fatty acid molecule, consistent with the optimal spacing identified through free energy analysis. Atomistic insights are provided for the organization of fatty acid chains, structural features, and interaction energies on protein-inclusive hair surface models with varying amounts of free 18-MEA (FMEA) depletion, as well as varying degrees of anionic cysteic acid from damaged bound 18-MEA (BMEA), under both dry and wet conditions. In the presence of FMEA and water, the fatty acid chains in a pristine hair surface prefers to adopt a thermodynamically favored extended chain conformation, forming a thicker protective layer (~3 nm) on the protein surface. Our simulation results reveal that, while the depletion of FMEA can induce a pronounced impact on the thickness, tilt angle, and order parameters of fatty acid chains, the removal of BMEA has a marked effect on water penetration. There is a "sweet spot" spacing between the 18-MEA whereby damaged hair surface properties can be reinstated by replenishing FMEA. Through the incorporation of the protein layer and free fatty acids, the hair surface models presented in this study enables a realistic representation of the intricate details within the hair epicuticle, facilitating a molecular scale assessment of surface properties during the formulation design process.

Impact of Cu and Ce on the electrochemical, antibacterial, and wear properties of 316 L stainless steel: Insights for biomedical applications

This study provides a comprehensive investigation of the tribological, electrochemical, and antibacterial characteristics of austenitic stainless steel, type 316 L, doped with Ce and Cu. The samples were doped with varying concentrations of Ce (0.5, 1.5, and 3 wt%) and Cu (1.5, 2.5, and 3.5 wt%). The initial measurements focused on determining the final density values of each sample. Subsequently, friction wear tests were conducted under both dry and wet conditions, shedding light on the wear resistance of the materials. In addition, electrochemical polarization tests were employed to assess the influence of Ce and Cu on the corrosion resistance of AISI 316 L. Furthermore, antibacterial assessments were conducted against bacterial cultures of Staphylococcus aureus (ATCC 29213) and Escherichia coli (ATCC 25922). The findings of this study illuminate several noteworthy outcomes. Namely, the results showed that all Ce and Cu-doped samples exhibited an increase in final density values when compared with the as-received AISI 316 L. The wear test results revealed that samples doped with 0.5 wt% Ce and 2.5 wt% Cu exhibited the highest wear resistance, in both dry and wet environments. Polarization curve analysis indicated that Ce was more effective in enhancing the corrosion resistance of AISI 316 L than Cu. Notably, Ce and Cu modifications endowed the material with antibacterial properties, effectively inhibiting bacterial growth in both S. aureus and E. coli cultures. In summary, this study demonstrates that the addition of even trace amounts of Ce and Cu to AISI 316 L leads to noticeable improvements in the material's tribological, electrochemical, and antibacterial performance, underscoring its potential for diverse biomedical applications. The enhanced mechanical strength, corrosion resistance, and antibacterial activity make the doped material promising for use in various medical devices, implants, and other biomedical applications.

Recent progress in polyvinyl alcohol (PVA)/nanocellulose composite films for packaging applications: A comprehensive review of the impact on physico‐mechanical properties

AbstractAs society advances, the demand for innovative and sustainable food processing techniques and materials has grown significantly. The food industry, especially the food packaging sector, faces the challenge of developing cost‐effective and sustainable packaging materials to meet consumers' increasing demands. One promising solution for this is the use of biodegradable polymers such as polyvinyl alcohol (PVA), but standalone PVA cannot meet the required properties of packaging materials. The use of nanocellulose (NC) as fillers has been intensively studied recently. This review article provides a comprehensive overview of existing studies focusing on the preparation of PVA/NC composite films for packaging applications. The effects of NC loading on the physico‐mechanical properties of these films, including tensile strength, elongation, water absorption/swelling behavior, barrier properties, and optical properties, have been thoroughly examined. Overall, the general findings suggest that the reinforcement of NC in the PVA polymer matrix leads to improvements in the films' properties. Specifically, the addition of NC enhances tensile strength, reduces O2, CO2, and water vapor transmission rates, and decreases the films' propensity to absorb moisture or swell under wet conditions. However, it is important to note that the presence of NC compromises the optical properties of the films by reducing transparency, and the NC content beyond threshold level reduces the feasibility of the composite film. By synthesizing these findings, this review underscores the potential of PVA/NC composite films as promising materials for packaging applications. Moving forward, further research efforts are warranted to optimize the formulation and processing of these composite films to strike a balance between mechanical strength and optical clarity, thus advancing their practical utility in the packaging industry.

Leakage Retardation of Static Seals via Surface Roughness and Wettability Modification.

In this paper, the effects of surface roughness and wettability on the leakage performance of static seals were highlighted. The results show that the leakage rate is negatively correlated with the contact pressure and positively correlated with surface roughness. Surface wettability affects leakage performance. Leakage retardation is achieved by modifying the roughness and wettability at the interface. The seal interface consists of two oleophobicity surfaces and exhibits an excellent seal performance, of which the leakage reduction is approximately 64%. A theoretical model based on wettability is established to predict the leakage rates under varying wettability conditions, and its validity is confirmed. This research result is expected to be applied in the field of seals and predict the leakage performance of interfaces with different wettabilities to minimize and reduce the leakage of oil in static sealing systems.

Differential modulation of crown allometry and stem growth at gap edges in five European tree species by drought conditions

BackgroundIn Central Europe, forests are increasingly affected by various disturbances, resulting in an increasing gap formation in the canopy. In order to support goal-oriented management, more knowledge is required about the acclimation of the crown and its effects on the basal area growth of trees at the edge of a gap. MethodsThis work compared trees' growth and crown structure at the edge of a transient gap, with a gap size of more than 80 ​m2, with trees in the stand that were at least 30 ​m away from the gap. A total of 249 European beeches (Fagus sylvatica L.), Norway spruces (Picea abies L. Karst), Scots pines (Pinus sylvestris L.), oaks (Quercus spp.; Quercus petraea (Matt.) Liebl., Quercus robur L.), and silver firs (Abies alba Mill.) were examined on long-term experimental plots in southern Germany. Various crown measures were developed and calculated using high-resolution terrestrial laser scanning (TLiDAR) to capture the three-dimensional crown structures. Growth responses to edge conditions were measured based on tree rings. Using linear mixed models, we predict the basal area increment of edge trees relative to trees in the stand under wet and dry soil moisture conditions after the gap formation. ResultsWe identified i) species-specific acclimation of the crown of edge trees after the gap formation, ii) under wet soil moisture conditions a growth increase of 25%–45% for beech, pine, and oak edge trees and growth losses of 5%–60% for spruce and fir and iii) coniferous tree species benefited from the edge position regarding their basal area increment under dry soil moisture conditions and deciduous tree species grew regardless of the soil moisture conditions at the edge of a gap. ConclusionGaps have a species-specific effect on the habitus and growth of edge trees and can have both positive and negative impacts on silviculture.

Regional and farm level droughts characteristics for southwestern Uganda during 1981–2017

An increase in drought events associated with rising temperatures indicates that Uganda is facing a growing challenge from climate variability. Despite these challenges, there is a lack of comprehensive information on how climate variability affects soils, particularly drought characteristics. In an effort to address this limitation, this study utilised high-quality, in-situ climate data and soil Available Water Capacity (AWC) specific to south-western Uganda. The study employed the Palmer Drought Severity Index (PDSI) and the Standardised Precipitation-Evapotranspiration Index (SPEI) to assess drought occurrences over the period 1981–2017. Notably, the results from the 3-month SPEI indicated higher frequencies across all drought categories. Meanwhile, the 12-month SPEI exhibited more stabilised negative and positive truncations for drought and wet events, respectively. Analysing the temporal evolution of monthly PDSI values for five major soil mapping units revealed distinct patterns. Moderate droughts were observed over Lixic Ferralsols between 1981 and 1992 and between 1998 and 2008. Extreme drought events occurred during the first 5–7 months of 2017. Luvisols exhibited prolonged negative truncation levels, indicating a water deficit during several periods: 1982–1984, 1990–1994, 1998–2000, 2010, and 2012–2014. Histosols experienced drought conditions from 1982 to 1986, interspersed with wet events in 1988, 1997, 1999–2002, and 2005. The study emphasises the differential response of soil units to drought and wet conditions. As a result, the research recommends implementing water management practices such as irrigation, mulching, conservation tillage, zero tillage, and drainage for all soils to enhance resilience and sustainable agricultural practices in the region.

Investigation of the cohesive behavior of water-intervened rejuvenated SBS-modified bitumen

When water interacts with bitumen, the diffusion and cohesion characteristics between the components of bitumen are negatively impacted. Molecular dynamics simulations were employed to construct various bitumen models, including bitumen–bitumen (without water), water-containing single bitumen, water-containing bitumen–bitumen, and bitumen–water–bitumen models. The primary research objectives were as follows: comparing the changes in the densities of bitumen models with and without water, analyzing the interlayer cohesive energies of bitumen models interacting with water, evaluating the hydrogen bonds in water-containing bitumen models, and characterizing the diffusion behaviors of bitumen components. The results indicated that when water interacted with the bitumen, it filled internal voids, leading to an overall increase in volume and reduction in density. The interaction energies between the rejuvenated bitumen models and water molecules decreased as the numbers of polar sites exposed to SBS molecules decreased. The numbers of hydrogen bonds between water molecules and rejuvenated bitumen models were similar to those in aged bitumen models. As the number of fractured SBS molecular chains gradually increased, the interlayer cohesive energy in the Methylene-bis(4-cyclohexylisocyanate) (HMDI)-rejuvenated bitumen model gradually increased. Water molecules significantly influenced the interactions at the rejuvenated bitumen–rejuvenated bitumen interface, weakening the cohesion characteristics between bitumen molecules. Water interactions significantly reduced the interlayer cohesive energy of the bitumen–water–bitumen model. Conversely, the recovery process improved the interlayer cohesion characteristics of the bitumen. The diffusion characteristics of the components of bitumen SARA were significantly greater under wet conditions than under dry conditions.

Quantifying bimolecular reaction kinetics of isoprene hydroxy peroxy radical: From dry to highly humid atmospheric environment

Isoprene hydroxy peroxy radicals (ISOPOO), derived from isoprene oxidation by hydroxy radicals (OH), are key intermediates for ozone and secondary organic aerosol (SOA) formation in the atmosphere. Although ISOPOO-water complexes are ubiquitous, their impacts on ISOPOO chemistry remain obscure. Here the previously overlooked water effect on the bimolecular reaction kinetics of ISOPOO was investigated in an oxidative flow reactor. The major first-generation products of ISOPOO, isoprene hydroxy hydroperoxides (ISOPOOH), methacrolein (MACR), and methyl vinyl ketone (MVK), were measured simultaneously at various relative humidity (RH) with the help of a cold trap to avoid potential losses in direct gas sampling. We found that ISOPOO reactions were accelerated significantly under wet conditions, with a greater enhancement on 1,2-ISOPOO than 4,3-ISOPOO. 1,2-ISOPOOH yield appeared faster growth with RH than 4,3-ISOPOOH. MVK yield showed an upward-downward trend with RH, while MACR yield plateaued from 30% RH. To explain the enhancement in the ISOPOOH yield from 3% to 80% RH, the overall rate constants of 1,2-ISOPOO + HO2 and 4,3-ISOPOO + HO2 reactions at 80% RH should be 13 times and twice those at 3% RH, respectively. The empirical formulas were proposed for the first time to parameterize the water effect on ISOPOO + HO2 reactions. The updated kinetics of ISOPOO reactions were incorporated in a box model to simulate the RH-dependent ISOPOOH and C4 carbonyl yields under typical atmospheric conditions. High RH can enhance the ISOPOOH yield in urban, rural, and forest areas, and promote SOA formation correspondingly. Our findings shed light on the critical role of humidity in the reactions of ISOPOO and benefit evaluating the fate of isoprene and its impacts on air quality more accurately in the ambient atmosphere.