Westerschelde Research Articles

Estuarine Channel Evolution in Response to Closure of Secondary Basins: An Observational and Morphodynamic Modeling Study of the Western Scheldt Estuary

The fringes of estuaries are often characterized by the presence of side embayments (secondary basins), with dimensions in the order of hundreds of meters to tens of kilometers. The presence of secondary basins significantly alters the hydrodynamic and sediment characteristics in the main estuary, implying that loss of secondary basin area due to human interventions might affect the estuarine morphodynamics. Analysis of historical bathymetric data of the Western Scheldt Estuary (Netherlands) suggests that closure of its secondary basins has triggered the observed lateral displacement of the nearby channels. This analysis motivated investigation of the impact of secondary basins on decadal evolution of estuarine channels, using the numerical model Delft3D. Model results show that channels that form near a secondary basin are located farther away from the bank of the estuary with respect to their positions in the case without a basin. Overall, results in cases with two or three basins are similar to those in case with one single basin. The wider the basin, the farther away the nearby channel forms. Removing a secondary basin causes a lateral displacement of the nearby channel toward the bank, indicating that the observed lateral displacement of channels in the Western Scheldt is triggered by closure of its secondary basins. The physical explanation is that tidal currents in the main estuary are weaker and more rotary near secondary basins, favoring sediment deposition and shoal development at these locations. Model results are particularly relevant for estuaries with moderate to high friction and converging width.

Hexabromocyclododecane diastereomers in fish and suspended particulate matter from selected European waters\u2014trend monitoring and environmental quality standard compliance

The brominated flame retardant hexabromocyclododecane (HBCD) was monitored in fish and sediment (from one lake) or suspended particulate matter (SPM; from five rivers) at European freshwater sites to study the effects of reduction measures implemented by HBCD producers and users in recent years. Bream (Abramis brama) were sampled annually between 2007 and 2013 in the rivers Götaälv/SE, Rhône/FR, Western Scheldt/NL, Mersey/UK, and Tees/UK and in Lake Belau/DE. Sediment/SPM was taken every second year between 2008 and 2014. HBCD was analyzed by LC/MS/MS allowing the determination of the alpha-, beta-, and gamma-diastereomers. For most sites, a decrease in ∑HBCD was observed in fish (e.g., in the Rhône and Western Scheldt by about 80 and 60%, respectively, with significantly decreasing trends, p < 0.01). In the Rhône, HBCD also decreased in SPM. At the sampling site in the Tees which was impacted by a former HBCD point source, fish HBCD levels decreased only after a major flood event in 2013. While fish data indicate a decline in environmental HBCD concentrations at most sites with diffuse emissions, SPM data were less conclusive. The European environmental quality standard for HBCD in fish of 167 μg kg−1 wet weight was met by all fish samples in 2013.

The differences in morphological development between the intertidal flats of the Eastern and Western Scheldt

Human interventions have a large impact on estuarine morphology. The intertidal flats in the Eastern Scheldt and Western Scheldt estuaries (The Netherlands) have faced substantial morphological changes over the past decades. These changes are thought to be caused by human interventions, such as the construction of the storm surge barrier in the mouth of the Eastern Scheldt, and the deepening of the navigation channels of the Western Scheldt. This paper analyses several datasets and numerical simulations of hydrodynamics, providing an overview of the various morphological characteristics of the intertidal flats in the two estuaries over time and space. Apart from the volume, area and average height of these areas, also the integral steepness of each flat is quantified based on its full geometry. The analyses focus on the intertidal flats surrounded by water, which allows for a robust comparison between the different flats. The intertidal flats in the Western Scheldt appear to be substantially steeper compared to those in the Eastern Scheldt. The data indicates that a larger average height of a flat is related to a larger steepness. Despite variations in the evolution of the different flats, distinct characteristics of both estuaries are observed. An opposed trend is identified over time: the flats in the Western Scheldt have mainly increased in height, whereas the flats in the Eastern Scheldt have lowered after the completion of the storm surge barrier. This opposing development is associated with differences in tidal flow velocities in the estuaries, which are the result of human interventions.

Decadal Trends in Polycyclic Aromatic Hydrocarbon (PAH) Contamination Assessed by 1-Hydroxypyrene in Fish Bile Fluid in the Netherlands: Declining in Marine Waters but Still a Concern in Estuaries

Long-term monitoring data on the concentrations of biliary 1-hydroxypyrene (1-OHPyr) in flatfish, as a biomarker for polycyclic aromatic hydrocarbon (PAH) exposure, were analysed and evaluated to elucidate spatial differences and temporal trends in marine and estuarine PAH contamination in the Netherlands. Dab (Limanda limanda) and flounder (Platichthys flesus) with partly overlapping distributions were used as target species. In total 1831 bile samples were analysed individually: 417 dab in 1998-2005 and 1438 flounder in 1996-2012. The sampling procedure for flatfish and the PAH metabolites determination by means of high performance liquid chromatography (HPLC) with fluorescence (FL) detection were based on international guidelines. Measuring the absorbance at 380 nm was tested to correct for possible differences in feeding status, but this turned out not to be a suitable parameter for the standardisation of PAH metabolite concentrations. Both fish species showed statistically significant differences in biliary 1-OHPyr concentrations between various locations. The highest level of PAH contamination was found in flounder from the estuarine Western Scheldt, which might be partly due to local dredging activities. Dab from the central North Sea (Dogger Bank) showed the lowest level of PAH contamination. Analysis of all the data indicated mainly downward trends in PAH contamination, most clearly pronounced in the Dutch Wadden Sea. PAH exposure levels in the Dutch coastal waters including the Eastern Scheldt and the Wadden Sea, and also at the offshore North Sea monitoring sites represent levels of response that are not indicative of significant harm. In contrast, PAH contamination in the more industrialised Dutch estuaries (Western Scheldt and Ems Dollard) is still a cause for concern. Future monitoring should register the total bile volume, the sex of the fish and the method of fishing to improve the interpretation of the data. In addition, the biliary absorbance at 380 nm should be registered as it may help the interpretation of outliers in the data.

The ‘Voordelta’, the contiguous ebb-tidal deltas in the SW Netherlands: large-scale morphological changes and sediment budget 1965–2013; impacts of large-scale engineering

AbstractThe estuaries in the SW Netherlands, a series of distributaries of the rivers Rhine, Meuse and Scheldt known as the Dutch Delta, have been engineered to a large extent as part of the Delta Project. The Voordelta, a coalescing system of the ebb-tidal deltas of these estuaries, extendsc.10 km offshore and coversc.90 km of the coast. The complete or partial damming of the estuaries had an enormous impact on the ebb-tidal deltas. The strong reduction of the cross-shore directed tidal flow triggered a series of morphological changes that continue until today. This paper aims to give a concise overview of half a century of morphological changes and a sediment budget, both for the individual ebb-tidal deltas and the Voordelta as a whole, based on the analysis of a unique series of frequent bathymetric surveys. The well-monitored changes in the Voordelta, showing the differences in responses of the ebb-tidal deltas, provide clear insight into the underlying processes. Despite anthropogenic dominance, knowledge based on natural inlets can still explain the observed developments. Complete damming of the three northern estuaries Brielse Maas, Haringvliet and Grevelingen resulted in a regime shift, from mixed-energy to wave-dominated, and sediments are transported in landward and downdrift direction. This results in large morphodynamic changes – sediments are redistributed from the delta front landward – but small net volume changes – a 0.1–0.2 × 106m3a−1increase in volume over the period 1965–2010 – since the dams block sediment transport into the estuaries. Sediment volume losses of 106m3a−1are observed on the ebb-tidal delta of the partially closed Eastern Scheldt and still open Western Scheldt estuary. As a result of a reduction of the estuarine tide in the mouth of the Eastern Scheldt, the north–south-running North Sea tidal wave has gained impact on its ebb-tidal delta, which causes morphological adjustments and erosion of the Banjaard shoal area. Moreover, the Eastern Scheldt ebb-tidal delta delivers sediment to its neighbours. The stable ebb-tidal delta configuration in the Western Scheldt, despite major dredging activities, illustrates that these large inlet systems are robust and resilient to significant anthropogenic change, as long as the balance between the dominant hydrodynamic processes (tides and waves) does not alter significantly.

Predicting the impact of seasonal fluctuations on the potential ecotoxicological risk of multiple contaminants in the River Scheldt discharge into the Western Scheldt estuary

The study site, Land van Saeftinghe, is an area within the Western Scheldt estuary with Special Protection Area (SPA) status for the EU Birds directive. We used a combination of hydrodynamic and water quality monitoring, hydrodynamic and water quality and modeling, ecotoxicity modeling and observations on the ecological status to correlate the water quality to the observed ecological status of the study site.The monitoring and modeling results show that the copper concentrations are elevated above the Maximum Tolerable Concentration (MTR) during the whole year, while zinc and cadmium show a spring peak (>MTR). Other metals, and all the measured organic contaminants where below the MTR.The peak in the three metals during springtime translates into an increase in the ecotoxicity, as expressed by the calculated multi-substance Potentially Affected Fraction (ms-PAF). The ms-PAF peaked at 25% for all organisms, and 30% for benthic invertebrates. The observed ecological status for the study site at the time of monitoring (2000) was Maximum Ecological Potential (MEP). This result seems to be in contradiction with the exceedance of the MTR for three metals during spring time. However the calculated ms-PAF during the spring peak of 25% is deemed acceptable based on current policy, therefore potential ecotoxic stress is within acceptable boundaries. The ms-PAF results therefore do not contradict the MEP status.The evaluation of the ecological status versus the water quality within the EU Water Framework Directive (WFD) can be improved by using the calculated ecotoxicity (ms-PAF) instead of the water quality. We propose an additional step for water bodies which are currently ‘at risk’, based on their chemical status. In this additional step, the ms-PAF is calculated for all contaminants in the water phase, not discriminating between priority and non-priority substances. The outcome of this calculation defines if the water body is at risk.

Modeling centuries of estuarine morphodynamics in the Western Scheldt estuary

AbstractWe hindcast a 110 year period (1860–1970) of morphodynamic behavior of the Western Scheldt estuary by means of a 2‐D, high‐resolution, process‐based model and compare results to a historically unique bathymetric data set. Initially, the model skill decreases for a few decades. Against common perception, the model skill increases after that to become excellent after 110 years. We attribute this to the self‐organization of the morphological system which is reproduced correctly by the numerical model. On time scales exceeding decades, the interaction between the major tidal forcing and the confinement of the estuary overrules other uncertainties. Both measured and modeled bathymetries reflect a trend of decreasing energy dissipation, less morphodynamic activity, and thus a more stable morphology over time, albeit that the estuarine adaptation time is long (approximately centuries). Process‐based models applied in confined environments and under constant forcing conditions may perform well especially on long (greater than decades) time scales.

Risk assessment, risk management and risk-based monitoring following a reported accidental release of poliovirus in Belgium, September to November 2014.

On 6 September 2014, the accidental release of 10(13) infectious wild poliovirus type 3 (WPV3) particles by a vaccine production plant in Belgium was reported. WPV3 was released into the sewage system and discharged directly to a wastewater treatment plant (WWTP) and subsequently into rivers that flowed to the Western Scheldt and the North Sea. No poliovirus was detected in samples from the WWTP, surface waters, mussels or sewage from the Netherlands. Quantitative microbial risk assessment (QMRA) showed that the infection risks resulting from swimming in Belgium waters were above 50% for several days and that the infection risk by consuming shellfish harvested in the eastern part of the Western Scheldt warranted a shellfish cooking advice. We conclude that the reported release of WPV3 has neither resulted in detectable levels of poliovirus in any of the samples nor in poliovirus circulation in the Netherlands. This QMRA showed that relevant data on water flows were not readily available and that prior assumptions on dilution factors were overestimated. A QMRA should have been performed by all vaccine production facilities before starting up large-scale culture of WPV to be able to implement effective interventions when an accident happens.

The mineralogy of suspended matter, fresh and Cenozoic sediments in the fluvio-deltaic Rhine–Meuse–Scheldt–Ems area, the Netherlands: An overview and review

AbstractMinerals are the building blocks of clastic sediments and play an important role with respect to the physico-chemical properties of the sediment and the lithostratigraphy of sediments. This paper aims to provide an overview of the mineralogy (including solid organic matter) of sediments as well as suspended matter as found in the Netherlands (and some parts of Belgium). The work is based on a review of the scientific literature published over more than 100 years. Cenozoic sediments are addressed together with suspended matter and recent sediments of the surface water systems because they form a geoscientific continuum from material subject to transport via recently settled to aged material. Most attention is paid to heavy minerals, clay minerals, feldspars, Ca carbonates, reactive Fe minerals (oxides, siderite, sulphides, glauconite) and solid organic matter because they represent the dominant minerals and their properties form a main issue in subsurface and water management. When possible and relevant, the amounts, provenance, relationship with grain size distribution, early diagenesis and palaeohydrological evolution are described. Tables with statistical data about the mineral contents and isotopic composition of carbonates and organic matter are presented as overviews. The review on the mineralogy of Dutch fluvial and marine environments is more extensive than that for the other sedimentary environments because the first two have been studied much more intensively than the others and they also form the larger part of the Dutch deposits. The focus is on the natural background mineralogy of Dutch sediments, but this is hard for recent sediments, largely because the massive hydraulic infrastructure present in the Netherlands has probably also affected the mineralogy and geochemistry of sediments deposited in recent centuries. Many findings are summarised, several of which lead to more general insights for the Dutch situation. Ca carbonates in sediments often have several provenances and thus must be considered as mixtures. Dolomite is commonly present in addition to calcite. The importance of biotite as weatherable mica is unclear. Weathering of heavy minerals plays some role but it is unclear in which way it affects the heavy mineral associations. Clays are usually dominated by illite, smectite and their interstratified variant, while kaolinite is usually below 20% and chlorite below 5%. Vermiculite is a minor constituent in fluvial clays and its illitisation presumably happens during early diagenesis in the marine environment. Opaque Fe hydroxides can be present in addition to Fe oxyhydroxide coatings and both will play a role in redox chemistry as reactive Fe minerals. Feldspars in marine sediments must be present but they have not been properly studied. The genesis of rattle stones and carbonate concretions has not been completely elucidated. The fraction of terrigeneous organic matter in estuarine and coastal marine sediments is substantial. The available data and information are spread irregularly over the country and the reviewed information discussed in this paper is derived from relatively small-scale studies dealing with a limited amount of analysed samples. Much information is available from the Scheldt estuaries in the southwestern part of the Netherlands partly due to the severe contamination of the Western Scheldt in recent decades.

A New Fluorinated Surfactant Contaminant in Biota: Perfluorobutane Sulfonamide in Several Fish Species.

Environmental contamination and regulation of longer-chain perfluoroalkyl substances (PFASs) such as perfluorooctanesulfonate (PFOS) has given rise to the increased use of shorter-chain PFASs as alternatives in new products, although confirmation of their presence in the environment remains limited. In this study, the PFAS alternative, perfluoro-1-butane-sulfonamide (FBSA), was identified for the first time in biota in homogenate samples of fish by liquid chromatography-quadrupole time-of-flight mass spectrometry (LC-Q-ToF-MS) and quantified by ultra high performance liquid chromatography-triple quadrupole mass spectrometry (UHPLC-QQQ-MS/MS). In one flounder (Platichthys flesus) muscle sample from the Western Scheldt, The Netherlands, FBSA concentration was at 80.12 ng/g wet weight (w.w.) and was exceeded only by PFOS. FBSA was also detected in 32 out of 33 samples of freshwater fish collected (2009-2010) from water bodies across Canada. In lake trout (Salvelinus namaycush) from northern Canada (e.g., Lake Kusawa (Yukon Territory), Great Bear Lake (Northwest Territories and in the Arctic), and Lake Athabasca (northern Alberta)), the concentrations of FBSA ranged from below method detection limit (<0.01 ng/g w.w) to 0.44 ng/g w.w. and were much lower than those reported for lake trout from the more urbanized and industrialized Laurentian Great Lakes sites (3.17 ± 1.53 ng/g w.w.). In three species of fish purchased from a supermarket in Ottawa (ON, Canada), FBSA concentrations were the lowest of all fish and ranged from < MLOD to 0.29 ng/g w.w. and 0.03 to 0.76 ng/g w.w. in muscle and liver, respectively. FBSA is a bioaccumulative contaminant in fish in Canada and possibly in The Netherlands. It is likely sourced from new alternative perfluorobutane-based products, as well as other shorter chain perfluoroalkyl-based products.

Toxic elements and speciation in seafood samples from different contaminated sites in Europe

The presence of cadmium (Cd), lead (Pb), mercury (THg), methylmercury (MeHg), arsenic (TAs), inorganic arsenic (iAs), cobalt (Co), copper (Cu), zinc (Zn), nickel (Ni), chromium (Cr) and iron (Fe) was investigated in seafood collected from European marine ecosystems subjected to strong anthropogenic pressure, i.e. hotspot areas. Different species (Mytilus galloprovincialis, n=50; Chamelea gallina, n=50; Liza aurata, n=25; Platichthys flesus, n=25; Laminaria digitata, n=15; and Saccharina latissima, n=15) sampled in Tagus estuary, Po delta, Ebro delta, western Scheldt, and in the vicinities of a fish farm area (Solund, Norway), between September and December 2013, were selected to assess metal contamination and potential risks to seafood consumers, as well as to determine the suitability of ecologically distinct organisms as bioindicators in environmental monitoring studies. Species exhibited different elemental profiles, likely as a result of their ecological strategies, metabolism and levels in the environment (i.e. seawater and sediments). Higher levels of Cd (0.15–0.94mgkg−1), Pb (0.37−0.89mgkg−1), Co (0.48–1.1mgkg−1), Cu (4.8–8.4mgkg−1), Zn (75–153mgkg−1), Cr (1.0–4.5mgkg−1) and Fe (283–930mgkg−1) were detected in bivalve species, particularly in M. galloprovincialis from Ebro and Po deltas, whereas the highest content of Hg was found in P. flesus (0.86mgkg−1). In fish species, most Hg was organic (MeHg; from 69 to 79%), whereas lower proportions of MeHg were encountered in bivalve species (between 20 and 43%). The highest levels of As were found in macroalgae species L. digitata and S. latissima (41mgkg−1 and 43mgkg−1, respectively), with iAs accounting almost 50% of the total As content in L. digitata but not with S. latissima nor in the remaining seafood samples. This work highlights that the selection of the most appropriate bioindicator species is a fundamental step in environmental monitoring of each contaminant, especially in coastal areas. Furthermore, data clearly shows that the current risk assessment and legislation solely based on total As or Hg data is limiting, as elemental speciation greatly varies according to seafood species, thus playing a key role in human exposure assessment via food.

Model validation and calibration via back analysis for mechanized tunnel simulations – The Western Scheldt tunnel case

In this research, Finite Element (FE) method is applied to simulate the shield supported mechanized excavation of Western Scheldt tunnel in the Netherlands. Both 2D and 3D numerical models are created to predict the system behavior. Sensitivity analysis and parameter identification techniques are utilized to calibrate and validate the model based on field measurement. The mechanical behavior of the soil is modeled by an advanced elasto-plastic model, namely Hardening Soil model correlating small strain stiffness (HSS). Global sensitivity analysis is carried out in this paper to evaluate the relative sensitivity of model response to each input parameter. Thereafter, a parameter identification technique (back analysis) is employed to find the optimized values of the selected parameters. To accomplish this, the computationally expensive FE-model is replaced by a meta-model in order to reduce the calculation time and effort. Moreover, a soft soil constitutive model based on the modified Cam-clay model deals with primary compression of fine grained soils, is assigned to the clay layer to further improve the numerical prediction of system behavior. Due to the importance of model subsystems, such as face pressure and volume loss, the sensitivity of model response to subsystems has been evaluated. The results show that optimized parameters obtained via back analysis make the numerical simulation capable to well predict the ground settlement.

Modeling bioaccumulation and biomagnification of nonylphenol and its ethoxylates in estuarine–marine food chains

There are several studies on bioaccumulation and biomagnification of nonylphenol (NP) and its ethoxylates (NPEOs), but their toxico-kinetic mechanisms remain unclear. In the present investigation, we explored the accumulation of NP and NPEOs in estuarine–marine food chains with a bioaccumulation model comprising five trophic levels. Using this model, we estimated uptake and elimination rate constants for NPEOs based on the organisms’ weight and lipid content and the chemicals’ Kow. Further, we calculated accumulation factors for NP and NPEOs, including biota-sediment accumulation factors (BSAF) and biomagnification factors (BMF), and compared these to independent field measurements collected in the Western Scheldt estuary in The Netherlands and field data reported in the literature. The estimated BSAF values for NP and total NPEOs were below 1 for all trophic levels. The estimated BMF values were around 1 for all trophic levels except for the highest level (carnivorous mammals and birds). For this trophic level, the estimated BMF value varied between 0.1 and 2.4, depending on the biotransformation capacity. For all trophic levels, except primary producers, the accumulation estimates that accounted for biotransformation of NPEOs into NP were closer to the field data than model estimates that did not include biotransformation, indicating that NP formation by biotransformation of NPEOs might occur in organisms.

Retrospective monitoring of mercury in fish from selected European freshwater and estuary sites

Levels and trends of total mercury (THg) and methylmercury (MeHg) compounds in bream (Abramis brama) from different European sites were compared. Bream were collected between 2007 and 2013 in the estuaries of the rivers Scheldt (Netherlands), Rhône (France), Göta älv (Sweden), Tees (United Kingdom), and Mersey (UK), and in Lake Belau (Germany). A direct mercury analyzer was used to determine THg concentrations while MeHg was measured by gas chromatography/inductively coupled plasma-mass spectrometry applying stable isotope dilution. THg and MeHg in annual pool samples of bream ranged between 15.9 and 251μgkg−1 wet weight (ww) with lowest concentrations found at the reference site Lake Belau and highest in samples from the river Rhône. The EU environmental quality standard (EQS) of 20μgkg−1 ww was exceeded at all sites and in all years except at Lake Belau in 2012. Significantly decreasing trends over time were observed only in bream from the Rhône, while THg increased in bream from the Western Scheldt. The MeHg fractions of THg were always >80% and a significant difference between sites was detected only in one case (Rhône vs. Lake Belau).

Toxic pressure of herbicides on microalgae in Dutch estuarine and coastal waters

For several decades now, there has been an increase in the sources and types of chemicals in estuarine and coastal waters as a consequence of anthropogenic activities. This has led to considerable concern about the effects of these chemicals on the marine food chain. The fact is that estuarine and coastal waters are the most productive ecosystems with high primary production by microalgae. The toxic pressure of specific phytotoxic chemicals now poses a major threat to these ecosystems.In a previous study, six herbicides (atrazine, diuron, irgarol, isoproturon, terbutryn and terbutylazine) were identified as the main contaminants affecting photosynthesis in marine microalgae. The purpose of this study is to investigate the toxic pressure of these herbicides in the Dutch estuarine and coastal waters in relation to the effective photosystem II efficiency (ΦPSII) in microalgae. Temporal and spatial variations in the concentrations of these herbicides were analyzed based on monitoring data. Additionally, a field study was carried out in which chemical analysis of water was performed and also a toxicity assessment using the Pulse Amplitude Modulation (PAM) fluorometry assay that measures ΦPSII. The toxic pressure on ΦPSII in microalgae has decreased with 55–82% from 2003 to 2012, with the Western Scheldt estuary showing the highest toxic pressure. By combining toxicity data from the PAM assay with chemical analysis of herbicide concentrations, we have identified diuron and terbutylazine as the main contributors to the toxic pressure on microalgae. Although direct effects are not expected, the toxic pressure is close to the 10% effect level in the PAM assay. A compliance check with the current environmental legislation of the European Union revealed that the quality standards are not sufficient to protect marine microalgae.

Mixed-sediment transport modelling in Scheldt estuary with a physics-based bottom friction law

In this study, the main object is to investigate the performance of a few new physics-based process models by implementation into a numerical model for the simulation of the flow and morphodynamics in the Western Scheldt estuary. In order to deal with the complexity within the research domain, and improve the prediction accuracy, a 2D depth-averaged model has been set up as realistic as possible, i.e. including two-way hydrodynamic-sediment transport coupling, mixed sand–mud sediment transport (bedload transport as well as suspended load in the water column) and a dynamic non-uniform bed composition. A newly developed bottom friction law, based on a generalised mixing-length (GML) theory, is implemented, with which the new bed shear stress closure is constructed as the superposition of the turbulent and the laminar contribution. It allows the simulation of all turbulence conditions (fully developed turbulence, from hydraulic rough to hydraulic smooth, transient and laminar), and the drying and wetting of intertidal flats can now be modelled without specifying an inundation threshold. The benefit is that intertidal morphodynamics can now be modelled with great detail for the first time. Erosion and deposition in these areas can now be estimated with much higher accuracy, as well as their contribution to the overall net fluxes. Furthermore, Krone’s deposition law has been adapted to sand–mud mixtures, and the critical stresses for deposition are computed from suspension capacity theory, instead of being tuned. The model has been calibrated and results show considerable differences in sediment fluxes, compared to a traditional approach and the analysis also reveals that the concentration effects play a very important role. The new bottom friction law with concentration effects can considerably alter the total sediment flux in the estuary not only in terms of magnitude but also in terms of erosion and deposition patterns.

Intertidal landscape response time to dike breaching and stepwise re-embankment: A combined historical and geomorphological study

Intertidal flats and marshes provide important ecosystem services to coastal and estuarine societies, and have therefore been subject to extensive research. Most of these studies, however, have one thing in common: intertidal landscape response has been studied from a rather short-term perspective, mostly less than 100years. Furthermore, the impact of embankment practices on the development of the remaining intertidal area and its stability has hardly been studied at all. In this paper, a longer term perspective (sixteenth to twenty-first centuries) is used in order to (1) reconstruct intertidal landscape evolution, using both historical and soil maps and (2) assess the effect of stepwise embankment on the intertidal area, both in terms of the surface proportions of the different components of an intertidal area and the vertical and lateral sediment elevation and sedimentation rates. The reconstruction and embankment effect assessment will be applied to the Land of Saeftinghe, an intertidal area in the Western Scheldt estuary that was partially re-embanked in a stepwise manner into an embankment landscape called the Waasland polder area (Belgium/The Netherlands). Important outcomes of this study are: (1) a combination of historical–geographical methods proves to be a valuable tool for past intertidal landscape reconstruction; (2) dike breaching and partial (stepwise) re-embankment are important driving mechanisms for the evolution of the remaining intertidal landscape towards new equilibrium conditions, though the new landscape equilibria can only be reached with a certain time lag; (3) subsequent embankments with a short time interval (15 to 21years) prevent tidal marsh surface areas from reaching an equilibrium state; and (4) between 60 and 96years are needed for tidal marsh elevation to reach an equilibrium.

ON THE MODELLING OF SWELL WAVE PENETRATION INTO TIDAL INLET SYSTEMS

For the calculations of the Hydraulic Boundary Conditions in the framework of the Dutch Legal Flood Safety Assessment (WTI), wave statistics obtained at deeper water buoys need to be transformed to the toe of the dike using the wave action model SWAN. This transformation is particularly challenging in complex tidal inlet systems such as the Wadden Sea and the Western Scheldt in the Netherlands. Although various model improvements have been made in SWAN, particularly in the propagation and bottom friction dissipation, one of the unresolved issues is that the penetration of North Sea swell waves into the tidal inlets is still underestimated by SWAN. The goal of this study is to verify the hypothesis that nonlinear interactions, in particular the sub-harmonic triad interactions, play a major role in the transmission of energy from flats into the channel, and that this process can explain SWAN’s under-prediction of wave energy penetration. Since SWAN or any other wave-action equation type models lacks the relevant physics to study this problem, the Boussinesq-type TRITON model is used as well to verify the hypothesis. The conceptual idea, raised by Toledo (2013), is that sub-harmonic wave interactions between second harmonic and basic components generate a wave component of the same frequency as the primary component but at a wider angle of approach. As a consequence, the energy density spectra become directionally broader. From a series of idealized cases with monochromatic and bi-chromatic waves propagating up and down a slope we conclude that the TRITON model results confirm the conceptual idea of 2D nonlinear interactions. Both sub-harmonic wave interactions (to lower frequencies) and super-harmonic wave interactions (to higher frequencies) prove to be important. These insights can be applied to the situation with waves propagating on a tidal flat towards a channel. In case the basic components approach the channel under a sharp angle, such that they will not be able to enter the channel due to refraction, the sub-harmonic components could approach the channel under a less sharp angle and enter the channel. In our study a clear difference between the TRITON and SWAN energy density spectra in and across the channel is observed, as the 2D nonlinear interactions cannot be modeled with the co-linear 1D approach in SWAN. The hypothesis that nonlinear interactions play a major role in the transmission of energy from flats into the channel is confirmed, at least for the cases considered in this study. Additional investigations are still required in order to quantify and generalize the effect of nonlinear interactions on this transmission of energy. In addition, it is recommended to extend the presently implemented three-wave interaction formulation in SWAN to account for directional super- and sub-harmonic interactions.

Tracing organophosphorus and brominated flame retardants and plasticizers in an estuarine food web

Nine organophosphorus flame retardants (PFRs) were detected in a pelagic and benthic food web of the Western Scheldt estuary, The Netherlands. Concentrations of several PFRs were an order of magnitude higher than those of the brominated flame retardants (BFRs). However, the detection frequency of the PFRs (6–56%) was lower than that of the BFRs (50–97%). Tris(2-butoxyethyl) phosphate (TBOEP), tris(isobutyl) phosphate (TIBP) and tris(2-chloroisopropyl) phosphate (TCIPP) were the dominant PFRs in sediment with median concentrations of 7.0, 8.1 and 1.8ng/g dry weight (dw), respectively. PFR levels in the suspended particular matter (SPM) were 2–12 times higher than that in sediment.TBOEP, TCIPP, TIBP, tris(2-chloroethyl) phosphate (TCEP) and tris(phenyl) phosphate (TPHP) were found in organisms higher in the estuarine food web. The highest PFR concentrations in the benthic food web were found in sculpin, goby and lugworm with median concentrations of 17, 7.4, 4.6 and 2.0ng/g wet weight (ww) for TBOEP, TIBP, TCIPP and TPHP, respectively. Comparable levels were observed in the pelagic food web, BDE209 was the predominant PBDE in sediment and SPM with median concentrations up to 9.7 and 385ng/g dw, respectively. BDE47 was predominant in the biotic compartment of the food web with highest median levels observed in sculpin and common tern eggs of 79ng/g lipid weight (lw) (2.5ng/g ww) and 80ng/g lw (11ng/g ww), respectively.Trophic magnification was observed for all PBDEs with the exception of BDE209. Indications of trophic magnification of PFRs were observed in the benthic food web for TBOEP, TCIPP and TCEP with tentative trophic magnification factors of 3.5, 2.2 and 2.6, respectively (p<0.05). Most of the other PFRs showed trophic dilution in both food webs. The relative high PFR levels in several fish species suggest high emissions and substantial exposure of organisms to PFRs in the Western Scheldt.

Additive modelling reveals spatiotemporal PCBs trends in marine sediments

We developed generalised additive mixed models (GAMMs) to infer spatiotemporal trends of environmental PCB concentrations from an extensive dataset (n=1219) of PCB concentrations measured between 1991 and 2010 in sediments of the Belgian Coastal Zone (BCZ) and the Western Scheldt estuary. A GAMM with time, geographical zone, periodicity and the organic carbon – water partition coefficient as covariates explained 49% of the variability in the log transformed PCB sediment concentrations. The time trends unraveled two to threefold PCB concentration decreases in the BCZ during the last 20years. However, in the Western Scheldt estuary, time trends were spatially heterogeneous and not significantly decreasing. These results demonstrate that international efforts to cut down emissions of PCBs have been effective to reduce concentrations in open water ecosystems like the BCZ but had little effect in the urbanised and industrialised area of the Scheldt estuary.