Throughout most of the 20th century, the Mount Lyell Mining and Railway company discharged tailings from the Mount Lyell mine into the Queen River. Tailings migrated downstream of the King River and deposited on riverbanks, the riverbeds and in the King River delta in Macquarie Harbour. This research combines mineralogical, geochemical, and geophysical techniques to characterise the King River delta and to constrain the volume of mine tailings on the King River delta. For this purpose, 25 trenches were excavated across the delta with 145 sediments samples and 20 water samples collected.Tailings in the delta are abundant in quartz (average 50 wt %), muscovite (average 16 wt %), chlorite (mean 11 wt %), pyrite (average 4 wt %), Fe-oxyhydroxides such as goethite (average 0.8 wt %), hematite (average 0.4 wt % and ferrihydrite (average 0.2 wt %), jarosite (average 0.8 wt %) and chalcopyrite (average 0.1 wt %). Sediments are dominated by Fe (average 77,468 ppm) and include high concentrations of Cu (average 1425 ppm) and trace elements such as Co (average 350 ppm). Chalcopyrite is the primary Cu mineral whereas pyrite is the main mineral host for Co. Geoenvironmental tests show tailings in the delta have acid-forming potential, as validated by pore water analyses with pH between 3.1 and 6.3. These conditions enable metal dissolution, with high contents of dissolved heavy metals, especially Fe, Cu, Co and Zn, detected in the pore waters.Apparent resistivity and shear wave profiles suggest the base of tailings is located at depths of 3–5 m. Low resistivity (i.e., <2 Ωm) indicate a saltwater intrusion into likely natural sediments below the tailings, whereas resistivity values between approximately 5 to 12 Ωm, below 15 m depth, suggests a transition to bedrock. The volume of tailings is estimated at ∼14.0 Mt and concentrations of Cu and Co imply that reprocessing of this material could be a feasible option with significant economic and environmental benefits.
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