Western Basin Research Articles

Geochemical characteristics and hydrocarbon generation potential of main source rocks in the Upper Triassic Xujiahe Formation, Sichuan Basin, China

In order to have a comprehensive understanding of the characterization and hydrocarbon generation potential of the source rock in the Upper Triassic Xujiahe Formation, Sichuan Basin, the geochemical data of more than 1,500 cuttings and 106 core samples were collected and analyzed. The T3x5 member of Xujiahe formation show the highest average TOC content (3.63%) followed by the T3x1+2 and T3x3 members. The TOC contents of different members show a general decreasing trend from the bottom to the top in Xujiahe formation. From the rock pyrolysis and kerogen δ13C values, the source rock trend to be kerogen type III with minor amounts of type Ⅱ2. According to the Ro values, the Xujiahe source rock shows high maturity in the northwest and low maturity in the southeast. Most of the source rock in T3x1+2 members are in high to overmature stage, while most of the source rock in the T3x3 and T3x5 member are in the mature to high mature stage. By comparing the burial history and hydrocarbon generation evolution history of source rocks in central and western Sichuan basin, it can be found that the sedimentation rate differences during the Cretaceous period is the main cause of the thermal evolution difference of the source rock. The gas generation intensity and quantity of different members are also compared. The T3x5 member show the highest gas generation potential followed by the T3x31 and the T3x1+2 members. In general, horizontally, the source rock of Xujiahe formation in Sichuan Basin is characterized by great thickness, high maturity, and high gas generation intensity in the northwest, which are gradually decrease to the southeast. Vertically, the T3x5 member show the highest gas generation content, which account for 39.6% of the total amount.

Larval connectivity of the invasive blue crabs Callinectes sapidus and Portunus segnis in the Mediterranean Sea: A step toward improved cross border management

The two invasive blue crabs, Callinectes sapidus and Portunus segnis have spread rapidly in the Mediterranean and no data exists on the connectivity of populations. Determining the source and recruitment areas is crucial to prioritize where population control measures should be put into immediate action. We simulated the dispersal of blue crab larvae using a Lagrangian model coupled at high resolution to estimate the potential connectivity of blue crab populations over a 3-year period. Our results reveal that the main areas at risk are the Spanish, French, Italian Tyrrhenian and Sardinian coasts for Callinectes sapidus with high populations connectivity. Tunisia and Egypt represent high auto recruitment zones for Portunus segnis restricted to the central and western basins. This study provides an overview of the connectivity between populations and will help define priority areas that require the urgent implementation of management measures.

Highly informative SNP markers for routine individual identification and certification of forest reproductive material in Quercus ilex and Q. suber and their hybrids

Holm oak (Quercus ilex L.) and cork oak (Q. suber L.) are two species of great ecological and socio-economical relevance in the Mediterranean western basin, mainly in the Iberian Peninsula. However, although breeding programs are in progress, basic materials providing qualified and tested Forest Reproductive Materials (FRM) are still lacking. In order to enable an accurate identification at the individual level, allowing the certification of selected material, efficient and affordable molecular markers are required.We report the identification of different sets of 96 and 500 single nucleotide polymorphism markers, selected in order to: I) allow the unambiguous identification at the individual level, both for holm oak and for cork oak and II) provide an accurate estimation of introgression level in hybrid individuals, at a low genotyping cost. These molecular tools fulfill the requirements for FRM certification, as well as for research and breeding purposes.

Disentangling the impact of Atlantic Niño on sea-air CO2 flux

Atlantic Niño is a major tropical interannual climate variability mode of the sea surface temperature (SST) that occurs during boreal summer and shares many similarities with the tropical Pacific El Niño. Although the tropical Atlantic is an important source of CO2 to the atmosphere, the impact of Atlantic Niño on the sea-air CO2 exchange is not well understood. Here we show that the Atlantic Niño enhances (weakens) CO2 outgassing in the central (western) tropical Atlantic. In the western basin, freshwater-induced changes in surface salinity, which considerably modulate the surface ocean CO2 partial pressure (pCO2), are the primary driver for the observed CO2 flux variations. In contrast, pCO2 anomalies in the central basin are dominated by the SST-driven solubility change. This multi-variable mechanism for pCO2 anomaly differs remarkably from the Pacific where the response is predominantly controlled by upwelling-induced dissolved inorganic carbon anomalies. The contrasting behavior is characterized by the high CO2 buffering capacity in the Atlantic, where the subsurface water mass contains higher alkalinity than in the Pacific.

Triassic-Early Jurassic evaporites of the Saharan Platform, Algeria: Astronomical and geodynamic constraints on stratigraphy and sedimentation

The sequence stratigraphy of the Late Triassic - Early Jurassic evaporites of the Berkine Basin is described. Disconformities occur between all the major evaporitic units but lack of biostratigraphy (or other) chronostratigraphic control precludes their precise dating. The S4 and S3 Halites are predominantly non-marine halites deposited in low-lying salinas with a barrier to the north. The top of the S4 depositional sequence is marked by the D2, usually regarded as the Tr-J boundary in the Berkine Basin. Both the S3 and S4 salt deposits thin rapidly to the south-east and are thicker in the basin centre coincident with a subcrop of Carnian? aged volcanics. A combination of thermal cooling, rifting and reactivation of N–S lineaments parallel to the Hassi Messaoud-El Biod Arch controlled the (∼1500 m thick) depocenter.Time series analysis shows that astronomical forcing played a key role in the deposition of the S3 and S4 bedded halites. The prevailing climate was monsoonal with major replenishment of the basin indicated by long eccentricity cycles (405 kyr). Sedimentation rates were estimated using eCOCO analysis with average rates of 15 cm/kyr. Well to well comparisons shows that in marginal areas thinner sedimentary sequences relate to slower accumulation rates and periods of non-deposition or deflation. The pattern is similar in the S4 and S3 halite, but the reduced mud content and amalgamation of halite beds suggests a more arid climate in S3 times.The S1+S2 unit marks the first widespread deposition of sulphate in the basin. The lowermost anhydrite beds of the S1 + S2 rest unconformably on the underlying S3 and overstep the basin margins in the south-east; the sequence is capped by the B Horizon a basin-wide carbonate shelf deposit about 25 m thick indicating increased marine influence. Above there is a rapid return to thinly bedded mudstone-halite dominated sedimentation (Lias Salifère) which is overlain by the Lias Anhydritique an alternating sequence of halite and anhydrite deposits. Astronomical parameters of the whole sequence indicate an average sedimentation rate of ∼10 cm/kyr in this marine-influenced section, slower than the halite units. Although the time series analysis cannot provide precision dating of the evaporitic sequences the results indicate that there are important breaks in the depositional record. The combined S4 and S3 halites account for 4.75 Ma and the rest of the Liassic 9.4 Ma. It seems clear that much of the depositional record is missing.These Saharan Platform basins bear much in common with other western Mediterranean evaporite basins. Many show the same overall pattern of sedimentation with increased sulphate deposition above the Tr-J boundary. In late Triassic time they formed a contiguous low-lying zone flanked by cratonic highlands. This zone spanned the Gondwana-Laurussia boundary immediately prior to its break-up and Greater Adria formed a barrier between these basins and the developing Neotethys to the east. The major changes seen in the Saharan Platform are mirrored by the break-up of Adria and the separation of Gondwana and Laurasia and the ultimate connection of the western Mediterranean and the central Atlantic.Although the cyclostratigraphy can tell us much about the absolute duration of sedimentation, the lack of significant anchor points forbids the construction of a detailed chronostratigraphic framework. In particular, the precise location of the Tr-J boundary remains unclear. Although it is usually placed at the base of the D2 Horizon, biostratigraphical evidence from Southern Tunisia places the S3 in the Norian. The sharp contrast between the S4 and S3 halites with the later evaporite sequence suggests that positioning the boundary between the S3 halite and the S1 + S2 unconformity should be given consideration.

Tectono-structural characterization and favorable sectors for hydrocarbons in the western basins of southern Cuba from non-seismic exploration methods

Las cuencas sedimentarias constituyen un objetivo tradicional de la exploración de petróleo y gas en todos los territorios. La cartografía de sus espesores sedimentarios es un elemento esencial por considerar, pero no siempre se dispone de esta información por la limitación en el volumen y calidad de los trabajos sísmicos y de perforación realizados. Las cuencas sedimentarias al sur del archipiélago cubano tienen un basamento magnético integrado por secuencias de rocas volcánicas con ofiolitas. La cartografía de los espesores sedimentarios y la composición del basamento pueden establecerse a partir del procesamiento e interpretación de los datos de campos potenciales. Se utilizó un enfoque integrado que consideró la determinación de la profundidad al basamento magnético y el modelado físico-geológico 2D de campos potenciales. Se utilizaron complementariamente, métodos morfométricos a partir del Modelo de Elevación Digital 90 × 90 m. El objetivo principal de la investigación fue caracterizar desde el punto de vista tectono-estructural las cuencas occidentales del sur de Cuba y el objetivo específico fue establecer los sectores favorables para hidrocarburos, básicamente, a partir de la espectrometría aérea con rayos gammas en sectores terrestres. El campo de las profundidades al basamento magnético (datos magnéticos y de pozos) se aproximó a los límites conocidos de las cuencas. El modelado físico-geológico 2D de campos potenciales por el perfil de estudio confirmó el modelo geológico de partida. Las localidades más promisorias para hidrocarburos correspondieron al pozo Taco Taco n.o1 (Cuenca Los Palacios) y los pozos someros La Paila y El Sulfuroso y los pozos Madruga (Cuenca Vegas).

Study on Oil and Gas Inclusions and Oil and Gas Accumulation Stages in Majiatan Area, Western Margin of Ordos Basin

The western edge of the Ordos Basin has abundant oil and gas resources. To explore the stages and direction of hydrocarbon fluids migration in petroliferous basins, the hydrocarbon-bearing strata in the Majiatan area on the west margin of the Ordos Basin was analyzed based on petrographic observations, homogenization temperature, salinity and composition of inclusions. The inclusions can be identified as five types. Type I, II and III inclusions exhibit abundant hydrocarbon content, whereas Type IV and V show poor hydrocarbon content. Based on homogenization temperature and salinity analysis, the five types of inclusions can be divided into two-stage formation, Type I, II and III included in the early stage and Type IV and V formed in the late stage. The direction of the hydrocarbon fluid migration of the early and late stages was from the southeast to the northwest, and the difference between the two stages of hydrocarbon fluid migration and inclusions formation depends on the fault activity from the Triassic to the Jurassic. This study is of great significance for future exploration of oil and gas in the Ordos Basin's western margin.

Detroit River load estimation; the need for a new monitoring approach

The Great Lakes Water Quality Agreement (GLWQA) established new Lake Erie phosphorus loading targets, including a 40% total phosphorus load reduction to its western and central basins. The Detroit and Maumee rivers’ loads are roughly equal and contribute about 90% of the load to the western basin and 54% to the whole lake. They are key drivers of central basin hypoxia and western basin algal production. So, accurate estimates of the Detroit River load are important. Direct measurement of that load near its mouth is difficult due to requiring real-time knowledge of flows around islands and the influence of Lake Erie’s seiches. Consequently, most estimates sum the loads to the St. Clair/Detroit River system. But this approach is complicated by uncertainties in the Lake Huron load and load retention in Lake St. Clair. Routine GLWQA reassessments will confirm or adjust over time the goals, loading targets, and approaches based on evolving information. So, there is a need to improve monitoring approaches that ensure accurate Detroit River loads. New approaches should take into account both the characteristics of this dynamic connecting channel and the uses of monitoring results: 1) determining the Detroit River loads to drive models, develop mass balances, set load reduction targets, and track progress; and 2) assessing the sources and processing of the loads to help guide reduction strategies. Herein, we review temporal and spatial variability in the St. Clair/Detroit River system, and suggest adjustments to monitoring that address those variabilities and both uses.

Microcystin congeners in Lake Erie follow the seasonal pattern of nitrogen availability

Cyanobacteria harmful algal blooms produce many toxic secondary metabolites called cyanotoxins. The most studied group of cyanotoxins are microcystins (MC), with over 300 congeners reported. MC-LR is the most studied congener because of its abundance and toxicity. Recent toxicology studies suggest that more hydrophobic MC congeners such as MC-LA, MC-LF, and MC-LW may be less abundant but up to seven times more toxic than MC-LR, whereas, MC-RR's toxicity is only one-fifth that of MC-LR. Hence, understanding the environmental stressors that change the MC congener profile is critical to assessing the negative impact on environmental and human health. A two-year field and experimental study investigated seasonal and spatial changes of MC congener profiles in the western basin of Lake Erie. Both studies showed that nitrogen enrichment favored the production of nitrogen-rich MC-RR (C49H75N13O12). The field study showed that nitrogen depletion favored the low-nitrogen MC-LA (C46H67N7O12). MC-LR (a medium N level, C49H75N10O12) accounted for ∼30% to 50% of the total MC concentration and was stable across nitrogen concentrations. Using the relative toxicity and concentrations of each MC congener, both LC-MS/MS and ELISA overestimated the toxicity early bloom (July) and underestimated it late bloom (September). On 24 July 2019, highly toxic MC-LW and MC-LF were detected at nearshore stations with relative toxicity exceeding drinking water standards. This study demonstrated that the less toxic, high nitrogen MC-RR dominated under nitrogen-replete conditions in the early season, whereas the more toxic, less nitrogen MC-LA dominated under nitrogen-limited conditions later in the season.

Site-contingent responses to drought of core and relict Tetraclinis articulata populations from Morocco and Spain

The growth responses to climate variability are still unknown in locally threatened conifers from dry regions, but this information is necessary for improving the conservation of relict populations under increasing aridification. We characterized the radial growth patterns and responses to climate of Tetraclinis articulata, a Cupressaceae tree endemic to the western Mediterranean Basin, in a relict population located in southwestern Spain (Doñana) and two populations from the northern Morocco where the species core habitat is found (Tétouan, Ifarten). We assessed climate-growth relationships by using tree-ring width, climate data, drought and North Atlantic Oscillation (NAO) indices. Climate-growth analyses were refined using the climwin R package to select the most informative statistical models. The main climatic constraints of growth were inferred by using the process-based Vaganov-Shashkin (VS) model explicitly considering non-linear climate-growth relationships. Tetraclinis articulata growth was favored by wet conditions from the prior autumn to the spring of the growth year. In Doñana, warmer May conditions led to growth decline but this negative effect could be reversed by wet-warm conditions in the prior late autumn. Growth in the two Moroccan sites was constrained by 6- to 18-month long droughts peaking in summer, which account for cumulative water deficit since the previous autumn. Winter and early spring precipitation were the main climate drivers of growth in the Moroccan T. articulata populations, and their year-to-year variability was linked to the NAO. The VS model simulations showed that T. articulata growth is enhanced by wet soil conditions in late winter and early spring, probably recharging shallow soil water pools. The VS model also confirmed that warmer spring-summer conditions could amplify drought stress and threaten the long-term persistence of the relict Doñana population.

Long-term phosphorus mass-balance of Lake Erie (Canada-USA) reveals a major contribution of in-lake phosphorus loading

While early efforts to reduce external phosphorus (P) loads to Lake Erie eliminated the worst eutrophication symptoms in the 1970s and 1980s, the observed intensification of these symptoms in recent decades is difficult to explain by changes in the external P loading alone. We hypothesized that, in addition to external inputs, in-lake processes that release P to the water column may be contributing to the re-eutrophication of Lake Erie. Directly measuring these internal inputs is challenging and their scaling up to the entire lake system remains fraught with uncertainty. To constrain the magnitude of the net P input associated with in-lake processes, we generated a long-term annual total P (TP) budget for the Lake St. Clair–Lake Erie system, averaged over a 14-year period, from 2003 to 2016. The budget shows that the TP output from the system substantially exceeds the sum of the external TP inputs. To balance the budget, we estimate that in-lake processes add a net internal TP load of 3783 metric tons per year (MTA) to the water column. In comparison, the mean yearly external TP load to the Lake St. Clair–Lake Erie system is 11,703 MTA. Thus, overall, in-lake processes account for about a quarter of the total (external plus internal) TP input. The internal input is not evenly distributed among the system's basins, however, with Lake St. Clair and Lake Erie's western, central, and eastern basins receiving 6, 13, 21 and 60% of the total internal P input, respectively. Our results highlight the importance of accounting for the internal P loading in nutrient cycling modeling and load reduction strategies for large lake systems.

Sedimentological and palynostratigraphical modeling of sediments penetrated by KW field wells, onshore western Niger Delta Basin, Nigeria

Sedimentological and palynostratigraphical studies were performed on 189 ditch-cutting samples composited at 50 ft intervals from four well sections located in KW field, onshore western Niger Delta Basin, Nigeria, using sieving and visual microscopic observations, hydrochloric and hydrofluoric acids digestion methods to determine their lithological character and palynologic content of the sedimentary successions. The basis of these data is to interpret the lithofacies and biostratigraphy, establish the age of the strata, establish the palynological zones and infer the environments of deposition. Five lithofacies delineated based on the sedimentological study were very coarse sand, coarse to fine sand, shaly sand, muddy sand, and sandy to silty shale. The age of the sedimentary successions ranges from Early Miocene to Pliocene based on the bio-assemblages of these key species. The Early Miocene age is characterized by the occurrence of Magnastriatites howardi, Psilatricolporites triangularis, Praedapollis africanus, Pachydermites diederixi, Spirosyncoilpites spiralis, Praedapollis flexibility, Racemonocolpites hians, Verrutricolporites rotundiporus, Verrutricolporites microporus, and Psilatricolporites divisus. The Middle Miocene age is characterized by the FAD of Crassoretitriletes vanraadshooveni, the occurrence of Belskipollis elegans, in association with Striatricolporites catatumbus, Verrutricolporites rotundiporus, Verrutricolporites microporus, Crassoretitriletes vanraadshooveni, Racemonocolpites hians, Retibrevitricolpites obodoensis, and Retibrevitricolpites protrudens. The Late Miocene age is characterized by the occurrence of Multiareolites formosus, Cyperaceaepollis sp., Stereiosporites sp., Peregrinipollis nigericus, Gemmamonoporites sp. (Cleistopholis patens), Laevigatosporites sp., Verrutricolporites sp., Nymphaeapollis clarus, and Verrutricolporites usmensis. The Pliocene age is characterized by the basal occurrence of Retistephenocolpites gracilis in association with Nymphaeapollis clarus, Cyperaceaepollis sp., Laevigatosporites sp., Verrutricolporites sp., and Crassoretitriletes vanraadshooveni. The boundary between the Early Miocene and Middle Miocene from the studied oil well sections is marked by the first appearance datum (FAD) and numerical maximum occurrence of Striatricolporites catatumbus and Belskipollis elegans and FAD of Crassoretitrilettes vanraadshooveni. The boundary between the Middle and late Miocene is defined by the LAD of Verrutricolporites rotundiporus, the quantitative top and numerical maximum occurrence of Racemonocolpites hians, and the numerical maximum occurrence of Zonocostites ramonae. The boundary between the late Miocene and the Early Pliocene is marked by the first appearance datum (FAD) and the numerical maximum occurrence of Retistephenocolpites gracilis, the numerical maximum occurrence of Echiperiporites icacinoides, and the highest abundance of Monoporites annulatus. Four palynozones PAZ-1, PAZ-2, PAZ-3, and PAZ-4, and ten sub-zones were erected. Finally, Fluvial-coastal to shallow marine environments of deposition were inferred for the sedimentary successions using sedimentological study, nature of organic matter, and association of key environmentally-sensitive biomarker species.

Cenozoic slip along the southern Sierra Nevada normal fault, California (USA): A long-lived stable western boundary of the Basin and Range

AbstractThe uplift history of the Sierra Nevada, California, is a topic of long-standing disagreement with much of it centered on the timing and nature of slip along the range-bounding normal fault along the east flank of the southern Sierra Nevada. The history of normal fault slip is important for characterizing the uplift history of the Sierra Nevada, as well as for characterizing the geologic and geodynamic factors that drove, and continue to drive, normal faulting. To address these issues, we completed new structural studies and extensive apatite (U-Th)/He (AHe) thermochronometry on samples collected from three vertical transects in the footwall to the east-dipping southern Sierra Nevada normal fault (SNNF). Our structural studies on bedrock fault planes show that the SNNF is a steeply (~70°) east-dipping normal fault. The new AHe data reveal two elevation-invariant AHe age arrays, indicative of two distinct periods of cooling and exhumation, which we interpret as initiation of normal faulting along the SNNF at ca. 28–27 Ma with a second phase of normal faulting at ca. 17–13 Ma. We argue that beginning in the late Oligocene, the SNNF marked the now long-standing stable western limit, or breakaway zone, of the Basin and Range. Slip along SNNF, and the associated unloading of the footwall, likely resulted in two periods of uplift of Sierra Nevada during the late Cenozoic. Trench retreat, driven by westward motion of the North American plate, along the Farallon–North American subduction zone boundary, as well as the gravitationally unstable northern and southern Basin and Range pushing on the cold Sierra Nevada, likely drove the late Oligoceneaged normal slip along the SNNF and the similar-aged but generally local and minor extension within the Basin and Range. We posit that the thick proto–Basin and Range lithosphere was primed for late Oligocene extension by replacement of the steepening Farallon slab with hot and buoyant asthenosphere. While steepening of the Farallon slab had not yet reached the southern Sierra Nevada by late Oligocene time, we speculate that late Oligocene slip along the SNNF reactivated a late Cretaceous dextral shear zone as the Sierra Nevada block was pulled and pushed westward in response to trench retreat and gravitational potential energy. The dominant middle Miocene normal faultslip history along the SNNF is contemporaneous with high-magnitude slip recorded along range-bounding normal faults across the Basin and Range, including the east-adjacent Inyo and White mountains, indicating that this period of extension was a major regional tectonic event. We infer that a combination of slabdriven trench retreat along the Juan de Fuca–North America subduction zone boundary and clockwise rotation of the southern ancestral Cascade Range superimposed on continental lithosphere preconditioned for extension drove this episode of middle Miocene normal slip along the SNNF and extension to the east across the Basin and Range. Transtensional plate motion along the Pacific–North America plate boundary, and likely a growing slab window, continued to drive extension along the SNNF and the western Basin and Range, but not until ca. 11 Ma when the Mendocino triple junction reached the latitude of our northernmost (U-Th)/He transect.

Features of Gravity Anomalies and Oil-Gas Distribution Rules in Central and Western Sichuan Basin, China

In order to explore the rules between gravity anomalies and oil-gas distribution characteristics in central and western Sichuan Basin, we divided the tectonic unit in central and western Sichuan basin on the base of the analysis of gravity anomaly characteristics, and studied the correlation between the oil–gas distribution and the local gravity anomaly in the study area. The results show that the variation in the range of the Bouguer gravity field in the interior of the basin is relatively small, and the southern part shows a clear gravity high zone, with gradual gravity gradient zones all around the basin periphery. The abnormal value of the residual gravity field in the basin is an obvious high–value gravity belt in the north and west, and the interior is arranged alternately with local high gravity and low gravity in the north–east direction. The tectonic units of the central and western Sichuan Basin can be divided into five regions, based on the characteristics of the Bouguer gravity field, namely, the Central Sichuan uplift zone, the West Sichuan depressional zone, the East Sichuan high steep zone, the South Sichuan low steep zone, and the North Sichuan low slow zone. Combined with geological data and Bouguer gravity anomaly processing results, the distribution of oil and gas fields in the central and western Sichuan Basin is certain correlated with the local gravity high zone and the transition zone between the local gravity high zone and the local gravity low zone. They are the major areas of oil and gas.

Spatiotemporal variation characteristics of sediment nutrient load from the soil erosion of the Yangtze River Basin of China from 1901 to 2010

Over the past 70 years, the Yangtze River Basin-the third longest river basin in the world-has been under the influence of augmented human activities. Regarding environmental protection and policy design, the total nitrogen and phosphorus (TN and TP, respectively) loads from soil erosion are objectively and quantitatively critical parameters while assessing the spatio-temporal soil erosion changes over the 1901–2010 period. First, soil erosion in our study area was calculated using the Revised Universal Soil Loss Equation (RUSLE) model. Second, the TN and TP loads from soil erosion were assessed using the constructed Nutrient Loss Empirical Model (NLEM). Third, we conducted spatial autocorrelation analysis, Mann-Kendall (M–K) trend tests, and wavelet analysis of the soil erosion, and related TN and TP loads. At Datong Station over the 1901–2010 period, the average annual TN and TP loads from soil erosion were 1.77 and 0.56 million tonnes, respectively. Moran’s I values of the average annual soil erosion, and related TN and TP loads from soil erosion indicates the existence of positive correlations, while clustering was the prevailing spatial distribution pattern. High-high (H-H) cluster areas were mainly evident in high-altitude region of the western and southern Yangtze River Basin, conversely, low-low (L-L) cluster areas were scattered primarily in regions with high population density and intense human activities. Soil erosion increased rapidly around 2001; hence, 2001 was a changing point. According to the M–K test, the time intersection of soil erosion, and related TN and TP loads at Datong Station was around 1990; hence, 1990 may have been a changing point, likely due to the operation of Gezhouba Dam during 1981-1986. This Dam trapped large amounts of sediments. If the sediment load data of control hydrological station of 12 sub-basins is available, SDR, sediment load, AN and AP calculation could be more accurate and interpretable.

Geochemical and geochronological constraints on the tectonic and magmatic evolution of the southwestern Mariana subduction zone

Interaction of a subduction zone with an oceanic plateau has implications for plate tectonics. However, the geodynamic processes and petrological responses to oceanic plateau–arc interactions remain enigmatic. The southwestern Mariana and Yap arcs have experienced interactions with the Caroline Plateau, which have affected the regional tectonism. In this study, tholeiitic basalts and metamorphosed volcanic rocks (i.e., greenstones) were recovered from the southwestern Mariana forearc. The protoliths of the metamorphosed volcanic rocks have geochemical affinities to low-silica boninites. These boninitic rocks have similar K–Ar and apatite U–Pb ages of ca. 24 Ma, which record the timing of collision between the southwestern Mariana arc and the Caroline Plateau. 40Ar/39Ar dating of plagioclase in the tholeiitic basalts dates post-collisional magmatism to ca. 18 Ma. The tholeiites have geochemical signatures of fore-arc basalts (e.g., low Ti/V ratios and light rare earth element-depleted patterns) and high Th/Yb ratios, which reflect a depleted mantle source with a subduction component inherited from a pre-collisional subduction event. We suggest that the southwestern Mariana arc is an intra-oceanic arc that underwent plateau–arc collisions. These plateau–arc interactions affected the tectonic and magmatic evolution of the southwestern Mariana arc and nearby western Pacific basins.

Baseline genetic distinctiveness supports structured populations of thornback ray in the Mediterranean Sea

Abstract The thornback ray (Raja clavata) is the most important chondrichthyan in terms of landings in the Mediterranean Sea. Intense harvesting may induce negative genetic effects reducing the resilience of overfished species. For this reason, genetic diversity information should be considered in fisheries management and conservation policies. Microsatellite markers were used to unravel the genetic features (variability, connectivity, sex‐biased dispersal) of R. clavata populations, both at the small (around the coast of Sardinia, western Mediterranean Sea) and larger spatial scales (at the pan‐Mediterranean level, and between the Atlantic Ocean and the Mediterranean Sea). Individual clustering, multivariate and variance analyses rejected the hypothesis of genetic homogeneity, with significant genetic differences between Mediterranean and Atlantic rays, as well as within the Mediterranean Sea between its western and eastern basins. The data indicated that both the Strait of Gibraltar and the Sicilian Channel seem to be effective in limiting the dispersal of thornback ray individuals, but a further structuring was identified, with the significant genetic differentiation of the populations located in the Algero‐Provençal and Tyrrhenian basins. Such a fine‐scale arrangement suggests the occurrence of additional barriers to species dispersal. A lack of significant genetic differentiation, stable over the years, was measured at a local scale among R. clavata Sardinian samples. Several possible mechanisms, both biological and abiotic (e.g. migratory behaviour, waterfronts and oceanographic discontinuities), are discussed. Overall, the genetic data presented, both at the local and regional level, could represent the baseline information for the temporal monitoring of populations and assessing the effects of present or future fisheries‐related management actions. The data obtained are information of paramount importance for minimizing the gaps in our current knowledge of the genetic diversity of thornback rays and maximizing the information needed for the correct protection of R. clavata populations.

Models of helium enrichment in helium-rich gas reservoirs of petroliferous basins in China

Owing to the characteristics of chemical inertness, low molecular weight, low boiling point, strong permeability and high heat conductivity, helium is extensively used in the fields of aerospace, low-temperature superconductivity, medicine and high tech, and it is a kind of irreplaceable strategic rare resource. So far, however, less research has been conducted on the enrichment of helium in natural gas reservoirs. To solve this problem, this paper discusses the classification standard of helium-rich gas reservoirs. Based on this, the origin, source and enrichment process of helium in typical helium-rich gas reservoirs are studied, highlighting the contribution of main helium sources to helium-rich gas reservoirs. In addition, helium enrichment models of helium-rich gas reservoir in petroliferous basins are established. And the following research results are obtained. First, 6 helium enrichment models of two categories (crust-source helium enrichment and crust-mantle mixing helium enrichment) are established for different petroliferous basins in China. Second, helium-rich gas reservoirs are characterized by using the multiple helium supply and diverse helium enrichment model. And no matter what enrichment model it is, the contribution of the main helium source to gas reservoirs is indispensable. Third, the helium in the gas reservoirs of central and western basins is mainly crust-source helium, and its enrichment models include ancient formation water moving upward along the fault to dilute helium, helium enrichment in the process of natural gas migration along ancient reservoirs, and helium enrichment of shale gas. Fourth, the helium in the helium-rich gas reservoirs of eastern basins is of crust-mantle mixing origin and its enrichment models are mainly hydrocarbon gas based, carbon dioxide based and nitrogen based. In conclusion, the establishment of the helium enrichment models of helium-rich gas reservoirs in petroliferous basins provides reference and guidance for studying helium enrichment laws and main controlling factors and is of great significance to the evaluation of favorable helium exploration areas.

The Fate and Bioavailability of Resuspended Phosphorus in Lake Erie's Western Basin

The Fate and Bioavailability of Resuspended Phosphorus in Lake Erie's Western Basin

Nutrient management in Lake Erie: Evaluating stakeholder values, attitudes, and policy preferences

Harmful algal blooms (HABs) have impaired Lake Erie’s western basin water quality since the 1960s. Though scientists agree that eutrophication is a key driver of HABs in Lake Erie, the role of nitrogen is still the subject of debate. The problem is twofold: (1) uncertainty in the specific causes of HABs can lead to inappropriate management solutions, and (2) managing a cross-boundary watershed requires collaboration and agreement on apt solutions from multiple stakeholders as well as many U.S. states and Canadian provinces. In our study, we interviewed 29 stakeholders actively involved in western Lake Erie’s watershed. We analyzed the stakeholders’ values, attitudes, and policy preferences to understand their differences, similarities, and their effects on management decisions. We found that stakeholders agree on the urgency of the problem and the necessity for increased nutrient management in Lake Erie’s western basin. Furthermore, we found that stakeholders can be represented as distinct clusters based on their values, and these value-based clusters are associated with different policy preferences. The different opinions and preferences of these value clusters span across stakeholder sectors and may affect efforts toward policy change. Stakeholders often question the feasibility and effectiveness of existing policies and policy plans. The findings shed new light on the relationship between stakeholder type and environmental values, attitudes, and policy preferences. Collaboration on HABs in Lake Erie will require open lines of communication both to improve policy and to cultivate trust among the multiple parties in this diverse watershed.