West Antarctic Ice Sheet Divide Research Articles

Core handling and processing for the WAIS Divide ice-core project

AbstractOn 1 December 2011 the West Antarctic Ice Sheet (WAIS) Divide ice-core project reached its final depth of 3405 m. The WAIS Divide ice core is not only the longest US ice core to date, but is also the highest-quality deep ice core, including ice from the brittle ice zone, that the US has ever recovered. The methods used at WAIS Divide to handle and log the drilled ice, the procedures used to safely retrograde the ice back to the US National Ice Core Laboratory (NICL) and the methods used to process and sample the ice at the NICL are described and discussed.

Impact of known local and tropical volcanic eruptions of the past millennium on the WAIS Divide microparticle record

AbstractWe present a new method for inferring the relative location (low‐ versus high‐southern latitude), and therefore the potential climatic impact, of past eruptions based on the particle size distribution (PSD) of micrometer‐sized ash measured continuously in the West Antarctic Ice Sheet (WAIS) Divide ice core. We find that particles from a high‐southern latitude eruption (Buckle Island, Antarctica (1839 Common Era, C.E.)) have a PSD with mode diameter ≥5 µm coarser than the background dust (mode 5.1 µm), while ash particles originating from stratospheric tropical eruptions, including Tambora (1815 C.E.), Kuwae (1458 C.E.), and Unknown (1258 C.E.), have PSDs with mode diameters ~0.6–1.5 µm finer than the background. In addition, volcanic ash particles from global‐scale eruptions are deposited ~3–6 months earlier and over a shorter time interval than sulfate aerosols. We hypothesize that this phasing is driven by differences in atmospheric processing and aerosol/particle transport and deposition.

Annually resolved records of volcanism from the WAIS Divide ice core (Antarctica) for the early and late Holocene

Annually resolved records of volcanism from the WAIS Divide ice core (Antarctica) for the early and late Holocene

Seasonal to centennial-scale variability of microparticle concentration and size distribution in the WAIS Divide ice core over the past 2.4 ka

Seasonal to centennial-scale variability of microparticle concentration and size distribution in the WAIS Divide ice core over the past 2.4 ka

Interlaboratory comparison of 10Be concentrations in two ice cores from Central West Antarctica

To improve sample processing efficiency for cosmogenic radionuclide measurements in samples from the West Antarctic Ice Sheet Divide core, two chemical lines, one at Purdue University and one at the University of California, Berkeley, are being used. Sections from two shallow ice cores from West Antarctica were processed at each lab, while all 10Be accelerator mass spectrometry measurements were performed at PRIME Lab, Purdue University. Duplicate samples gave 10Be results that are identical to within the AMS measurement uncertainties of 2–3%.

Rapid development of anisotropic ice‐crystal‐alignment fabrics inferred from englacial radar polarimetry, central West Antarctica

Anisotropy in englacial radar power was measured using 60‐MHz and 179‐MHz copolarized pulse‐modulated radar at 19 sites in central West Antarctica. The study region is a 100 × 300 km2area near the West Antarctic Ice Sheet Divide that separates ice flow toward the Ross and Amundsen Embayments. The frequency dependence of the returned power indicates that most of the radar data are affected by vertical variations in the crystal‐orientation fabric (COF), though the 60‐MHz data are more affected by acidity contrasts in the top 1000 m. Significant polarimetric variations occur at most sites, likely due to effects of the anisotropic COF patterns. More anisotropic variations occur at sites with significant horizontal strain, whereas more isotropic variations occur at sites where vertical compression dominates. Azimuthal shifts with depth of the principal axes of COF were found in shallow ice near the current flow divide and at greater depths over locations of rough bed. The former indicates that the divide has differentially migrated, resulting in a rotation of the principal COF axes. Nevertheless, the regionally consistent radar signatures suggest that the first‐order ice properties in this area have remained constant and that no major changes in the strain configuration or ice topography have occurred for the past five to eight thousand years. We conclude that shallow polarimetric features can be related to the current strain configurations, and that englacial polarimetric features can help constrain current ice rheology and evolution of the ice topography.

Seasonal climate information preserved in West Antarctic ice core water isotopes: relationships to temperature, large-scale circulation, and sea ice

As part of the United States' contribution to the International Trans-Antarctic Scientific Expedition (ITASE), a network of precisely dated and highly resolved ice cores was retrieved from West Antarctica. The ITASE dataset provides a unique record of spatial and temporal variations of stable water isotopes (d 18 O and dD) across West Antarctica. We demonstrate that, after accounting for water vapor diffusion, seasonal information can be suc- cessfully extracted from the ITASE cores. We use meteo- rological reanalysis, weather station, and sea ice data to assess the role of temperature, sea ice, and the state of the large-scale atmospheric circulation in controlling seasonal average water isotope variations in West Antarctica. The strongest relationships for all variables are found in the cores on and west of the West Antarctic Ice Sheet Divide and during austral fall. During this season positive isotope anomalies in the westernmost ITASE cores are strongly related to a positive pressure anomaly over West Antarctica, low sea ice concentrations in the Ross and Amundsen Seas, and above normal temperatures. Analyses suggest that this seasonally distinct climate signal is due to the pronounced meridional oriented circulation and its linkage to enhanced sea ice variations in the adjacent Southern Ocean during fall, both of which also influence local to regional temperatures.

Atmospheric CO2 over the last 1000 years: A high‐resolution record from the West Antarctic Ice Sheet (WAIS) Divide ice core

We report a decadally resolved record of atmospheric CO2 concentration for the last 1000 years, obtained from the West Antarctic Ice Sheet (WAIS) Divide shallow ice core. The most prominent feature of the pre‐industrial period is a rapid ∼7 ppm decrease of CO2 in a span of ∼20–50 years at ∼1600 A.D. This observation confirms the timing of an abrupt atmospheric CO2 decrease of ∼10 ppm observed for that time period in the Law Dome ice core CO2 records, but the true magnitude of the decrease remains unclear. Atmospheric CO2 variations over the time period 1000–1800 A.D. are statistically correlated with northern hemispheric climate and tropical Indo‐Pacific sea surface temperature. However, the exact relationship between CO2 and climate remains elusive due to regional climate variations and/or uneven geographical data density of paleoclimate records. We observe small differences of 0 ∼ 2% (0 ∼ 6 ppm) among the high‐precision CO2 records from the Law Dome, EPICA Dronning Maud Land and WAIS Divide Antarctic ice cores. However, those records share common trends of CO2 change on centennial to multicentennial time scales, and clearly show that atmospheric CO2 has been increasing above preindustrial levels since ∼1850 A.D.

Little Ice Age cold interval in West Antarctica: Evidence from borehole temperature at the West Antarctic Ice Sheet (WAIS) Divide

The largest climate anomaly of the last 1000 years in the Northern Hemisphere was the Little Ice Age (LIA) from 1400–1850 C.E., but little is known about the signature of this event in the Southern Hemisphere, especially in Antarctica. We present temperature data from a 300 m borehole at the West Antarctic Ice Sheet (WAIS) Divide. Results show that WAIS Divide was colder than the last 1000‐year average from 1300 to 1800 C.E. The temperature in the time period 1400–1800 C.E. was on average 0.52 ± 0.28°C colder than the last 100‐year average. This amplitude is about half of that seen at Greenland Summit (GRIP). This result is consistent with the idea that the LIA was a global event, probably caused by a change in solar and volcanic forcing, and was not simply a seesaw‐type redistribution of heat between the hemispheres as would be predicted by some ocean‐circulation hypotheses. The difference in the magnitude of the LIA between Greenland and West Antarctica suggests that the feedbacks amplifying the radiative forcing may not operate in the same way in both regions.

Controls on the movement and composition of firn air at the West Antarctic Ice Sheet Divide

Abstract. We sampled interstitial air from the perennial snowpack (firn) at a site near the West Antarctic Ice Sheet Divide (WAIS-D) and analyzed the air samples for a wide variety of gas species and their isotopes. We find limited convective influence (1.4–5.2 m, depending on detection method) in the shallow firn, gravitational enrichment of heavy species throughout the diffusive column in general agreement with theoretical expectations, a ~10 m thick lock-in zone beginning at ~67 m, and a total firn thickness consistent with predictions of Kaspers et al. (2004). Our modeling work shows that the air has an age spread (spectral width) of 4.8 yr for CO2 at the firn-ice transition. We also find that advection of firn air due to the 22 cm yr−1 ice-equivalent accumulation rate has a minor impact on firn air composition, causing changes that are comparable to other modeling uncertainties and intrinsic sample variability. Furthermore, estimates of Δage (the gas age/ice age difference) at WAIS-D appear to be largely unaffected by bubble closure above the lock-in zone. Within the lock-in zone, small gas species and their isotopes show evidence of size-dependent fractionation due to permeation through the ice lattice with a size threshold of 0.36 nm, as at other sites. We also see an unequivocal and unprecedented signal of oxygen isotope fractionation within the lock-in zone, which we interpret as the mass-dependent expression of a size-dependent fractionation process.

New ice core record of atmospheric methane

Atmospheric concentrations of methane, an important greenhouse gas, have varied in the past on time scales ranging from seasons to hundreds of thousands of years. Understanding past variations is important to interpreting current natural and anthropogenic changes. Mitchell et al. present a new high‐precision, high‐resolution atmospheric methane record covering 1000–1800 C.E. from an ice core from the West Antarctic Ice Sheet Divide project that has confirmed the existence of multidecadal‐scale variability during this time period. The new record, which complements other existing ice core methane records, shows that multidecadal‐scale methane variability is only weakly correlated or uncorrelated with reconstructed temperature and precipitation variations. The authors also found that time periods when war or plague resulted in population declines are coincident with global atmospheric methane decreases. (Journal of Geophysical Research‐Biogeosciences, doi:10.1029/2010JG001441, 2011)

Multidecadal variability of atmospheric methane, 1000–1800 C.E.

[1] We present a new high-precision, high-resolution record of atmospheric methane from the West Antarctic Ice Sheet (WAIS) Divide ice core covering 1000–1800 C.E., a time period known as the late preindustrial Holocene (LPIH). The results are consistent with previous measurements from the Law Dome ice core, the only other high-resolution record of methane for this time period, and confirm most of the observed variability. Multidecadal variability in methane concentrations throughout the LPIH is weakly correlated or uncorrelated with reconstructions of temperature and precipitation from a variety of geographic regions. Correlations with temperature are dominated by changes in Northern Hemisphere high latitude temperatures between 1400 and 1600 C.E. during the onset of the Little Ice Age. Times of war and plague when large population losses could have reduced anthropogenic emissions are coincident with short periods of decreasing global methane concentrations.

Identifying annual peaks in dielectric profiles with a selection curve

AbstractA novel ‘selection curve’ method is developed to interpret annual layers in the West Antarctic ice sheet (WAIS) Divide ice core based on dielectric properties (DEP). Because dielectric measurements are non-contact and represent the integrated response of the ice volume, they are particularly useful for the brittle zone of the core. Seasonal differences in ice chemistry create an annual signal in DEP, though multiple peaks of varying strength within a year may complicate the interpretation of annual layers. The selection curve algorithm uses a spline curve whose shape selects successive annual peaks in plots of DEP. This spline curve was scaled to the average annual-layer thickness at a given depth, where the layer thickness was best estimated using the fast Fourier transform (FFT) power spectrum within a sliding 10 m window. To explore the accuracy and stability of the method, several spline curves were generated from varying lengths of calibration data taken from multiple depths in the WAIS core. Using 50 m of manually interpreted calibration data, the selection curve method matched a manual interpretation throughout the entire 1200 m dataset to within 2% root-mean-square error (RMSE). This method is equally applicable to glaciochemical and other time/depth series measurements.

Late-Holocene climate evolution at the WAIS Divide site, West Antarctica: bubble number-density estimates

AbstractA surface cooling of ∼1.7°C occurred over the ∼two millennia prior to ∼1700 CE at the West Antarctic ice sheet (WAIS) Divide site, based on trends in observed bubble number-density of samples from the WDC06A ice core, and on an independently constructed accumulation-rate history using annual-layer dating corrected for density variations and thinning from ice flow. Density increase and grain growth in polar firn are both controlled by temperature and accumulation rate, and the integrated effects are recorded in the number-density of bubbles as the firn changes to ice. Number-density is conserved in bubbly ice following pore close-off, allowing reconstruction of either paleotemperature or paleo-accumulation rate if the other is known. A quantitative late-Holocene paleoclimate reconstruction is presented for West Antarctica using data obtained from the WAIS Divide WDC06A ice core and a steady-state bubble number-density model. The resultant temperature history agrees closely with independent reconstructions based on stable-isotopic ratios of ice. The ∼1.7°C cooling trend observed is consistent with a decrease in Antarctic summer duration from changing orbital obliquity, although it remains possible that elevation change at the site contributed part of the signal. Accumulation rate and temperature dropped together, broadly consistent with control by saturation vapor pressure.

Englacial seismic reflectivity: imaging crystal-orientation fabric in West Antarctica

AbstractAbrupt changes in crystal-orientation fabric (COF), and therefore viscosity, are observed near the base of the ice sheet throughout West Antarctica. We report on active-source seismic observations from WAIS Divide, mid-stream and downstream on Thwaites Glacier, and the onset region of Bindschadler Ice Stream. These data reveal a prevalence of englacial seismic reflectivity in the bottom quarter of the ice sheet. The observed seismic reflectivity is complex but largely bed-conformable, with long-spatial-wavelength features observed in the flow direction and short-wavelength features observed across flow. A correspondence of englacial structures with bed features is also observed. We determine the origin of the reflectivity to be abrupt changes in the COF of ice, based on the following: (1) observations of englacial reflectivity are consistent with current knowledge of COF within ice sheets, (2) englacial reflectivity caused by COF contrasts requires the simplest genesis, especially at ice divides, and (3) amplitude analysis shows that the observed englacial reflectivity can be explained by contrasts in seismic velocity due to COF changes. We note that the downstream increase in the quantity and complexity of observations indicates that direct observations of COF at ice divides likely underestimate the role that fabric plays in ice-sheet dynamics.

Sulfate sources and oxidation chemistry over the past 230 years from sulfur and oxygen isotopes of sulfate in a West Antarctic ice core

The sulfur and oxygen isotopic composition of sulfate in polar ice cores provides information about atmospheric sulfate sources and formation pathways, which have been impacted regionally by human activity over the past several centuries. We present decadal scale mean ice core measurements of Δ17O, δ34S, Δ33S, and Δ36S of sulfate over the past 230 years from the West Antarctic Ice Sheet (WAIS) Divide deep ice core drill site (WDC05‐A). The low mean δ34S of non–sea‐salt sulfate at WAIS Divide (6.0 ± 0.2‰) relative to East Antarctic coastal and plateau sites may reflect a combination of stronger influence of volcanogenic and/or stratospheric sulfate with low δ34S and the influence of frost flowers on the sea‐salt sulfate‐to‐sodium ratio. Δ33S and Δ36S measurements are all within analytical uncertainty of zero but do not contradict a contribution of stratospheric sources to background sulfate deposition at WAIS Divide. Δ17O of non–sea‐salt sulfate shows a small but significant increase between the late 1700s (1.8‰ ± 0.2‰) and late 1800s (2.6‰ ± 0.2‰), but the influence of stratospheric scale volcanic events on Δ17O in the early 1800s remains uncertain. An isotope mass balance model shows that the lack of change in Δ17O of non–sea‐salt sulfate from the mid‐1800s to early 2000s (2.4‰–2.6‰ ± 0.2‰) is consistent with previous atmospheric chemistry model estimates indicating preindustrial to industrial increases in O3 as high as 50% and decreases in OH of 20% in the southern polar troposphere, as long as H2O2 concentrations also increase by over 50%.

Deep Ice Stratigraphy and Basal Conditions in Central West Antarctica Revealed by Coherent Radar

We discuss results from a high-sensitivity, multichannel, very high frequency, and surface-based radar depth sounder/imager. The instrument was used to map deep internal layers and characterize basal conditions over a 240- km <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> grid in the vicinity of the West Antarctic Ice Sheet Divide ice core site. The ice thickness at the core site was found to be about 3470 m, and we detected internal layers to within 350 m of the ice/bed interface. Radar-detected layer stratigraphy does not show evidence of flow-induced disturbances that might complicate the depth-age relationship and the interpretation of climate history preserved in the ice. We also found that bed reflectivity over the region varies by more than 30 dB. Approximately 15 dB of this variability appears to be the result of transitions from a frozen to a thawed bed in a number of places. The remainder probably results from changes in bed roughness. Our data are important for planning drilling to the bed, as well as providing constraints and boundary conditions for regional ice-flow models.

Carbon and hydrogen isotopic composition of methane over the last 1000 years

New measurements of the carbon and hydrogen isotopic ratios of methane (δ13C of CH4 and δD of CH4) over the last millennium are presented from the WAIS Divide, Antarctica, ice core (WDC05A), showing significant changes that likely were the result of human influences prior to the industrial revolution (at least as early as the 16th century of the common era (CE)). The δ13C of CH4 data corroborate the record from Law Dome, Antarctica, with high fidelity. The new δD of CH4 data set covaries with the δ13C of CH4 record. Both δ13C of CH4 and δD of CH4 were relatively stable and close to the present‐day values from ∼1000 to ∼1500 CE. Both isotopic ratios decreased to minima around 1700 CE, remained low until the late 18th century, and then rose exponentially to present‐day values. Our new δD of CH4 data provide an additional independent constraint for evaluating possible CH4 source histories. We searched a broad range of source scenarios using a simple box model to identify histories consistent with the constraints of the CH4 concentration and isotope data from 990–1730 CE. Results typically show a decrease over time in the biomass‐burning source (found in 85% of acceptable scenarios) and an increase in the agricultural source (found in 77% of acceptable scenarios), indicating preindustrial human influence on atmospheric methane as proposed in previous studies.

Fluxes of microbes, organic aerosols, dust, sea-salt Na ions, non-sea-salt Ca ions, and methanesulfonate onto Greenland and Antarctic ice

Abstract. Using a spectrofluorimeter with 224-nm laser excitation and six emission bands from 300 to 420 nm to measure fluorescence intensities at 0.3-mm depth intervals in ice cores, we report results of the first comparative study of concentrations of microbial cells (using the spectrum of protein-bound tryptophan (Trp) as a proxy) and of aerosols with autofluorescence spectra different from Trp (denoted "non-Trp") as a function of depth in ice cores from West Antarctica (WAIS Divide and Siple Dome) and Greenland (GISP2). The ratio of fluxes of microbial cells onto West Antarctic (WAIS Divide) versus Greenland sites is 0.13±0.06; the ratio of non-Trp aerosols onto WAIS Divide versus Greenland sites is 0.16±0.08; and the ratio of non-sea-salt Ca2+ ions (a proxy for dust grains) onto WAIS Divide versus Greenland sites is 0.06±0.03. All of these are roughly comparable to the ratio of fluxes of dust onto Antarctic versus Greenland sites (0.08±0.05). By contrast to those values, which are considerably lower than unity, the ratio of fluxes of methanesulfonate (MSA) onto Antarctic versus Greenland sites is 1.9±0.4 and the ratio of sea-salt Na2+ ions onto WAIS Divide versus Greenland sites is 3.0±2. These ratios are more than an order of magnitude higher than those in the first grouping. We infer that the correlation of microbes and non-Trp aerosols with non-sea-salt Ca and dust suggests a largely terrestrial rather than marine origin. The lower fluxes of microbes, non-Trp aerosols, non-sea-salt Ca and dust onto WAIS Divide ice than onto Greenland ice may be due to the smaller areas of their source regions and less favorable wind patterns for transport onto Antarctic ice than onto Greenland ice. The correlated higher relative fluxes of MSA and marine Na onto Antarctic versus Greenland ice is consistent with the view that both originate largely on or around sea ice, with the Antarctic sea ice being far more extensive than that around Greenland.

Spatial and temporal variability in snow accumulation at the West Antarctic Ice Sheet Divide over recent centuries

Ice cores collected in 2000 (ITASE 00‐1) and 2005 (WDC05A, WDC05Q) from the West Antarctic Ice Sheet Divide (WAIS Divide) project site were used to investigate the spatial and temporal variability in accumulation. The ice cores were dated based on annual layer counting of multiple glaciochemical measurements resulting in bottom depth ages for WDC05A, WDC05Q, and ITASE 00‐1 of 1775, 1521, and 1653 A.D., with mean annual accumulation rates of 0.200, 0.204, and 0.221 mweq a−1, respectively. Small‐scale spatial variability (SSV) was determined using an analysis of variance of accumulation in the ice core array, thereby quantifying the uncertainty in individual accumulation records. Results indicate that the spatial variability was 0.030 mweq a−1, or approximately 15% of the average annual accumulation. An accumulation record representative of the WAIS Divide local area over recent centuries was developed using a principal component analysis to identify the coherent accumulation signal. The WAIS Divide local record exhibited 14% interannual variability (1 standard deviation of the mean) with the SSV reduced to 0.017 mweq a−1. Correlations of the WAIS Divide local accumulation record with atmospheric indices (e.g., Antarctic Oscillation) exhibited periods when the records oscillate in and out of phase. Thus, reconstructing local and global atmospheric indices from WAIS Divide accumulation records over recent centuries may prove problematic.